• Title/Summary/Keyword: leaching material

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Leaching Characteristics of Foundry Sands When Used as Reactive Media in Permeable Reactive Barriers (반응벽체에 쓰인 주물사의 용출특성에 관한 연구)

  • ;Benson, Craig H
    • Journal of the Korean Geotechnical Society
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    • v.18 no.5
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    • pp.179-193
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    • 2002
  • Waste foundry sands were tested to determine their leaching characteristics when used as reactive media in permeable reactive barriers (PRBs). Water leach tests and column leach tests were performed on twelve foundry sands and three reference materials such as Peerless iron, a local fill material, and torpedo sand. The latter three materials were tested to compare concentrations of heavy metals and anions found in other materials commonly placed below the groundwater table with those from the foundry sands. Results of water leach tests md total elemental analyses showed that all of the laundry sands are Category 2 materials per Section NR 538 of the Wisconsin Administrator Code. However, tests on Peerless iron, torpedo sand, and a typical fill material indicate that these materials, which are commonly placed below the groundwater table, also are Category 2 materials. Thus, using foundry sand as a PR3 medium should pose no greater risk than that imposed using conventional construction materials.

The effects of current density and nickel content on copper electrowinning by energy saving system (에너지절약형 동(Cu)전해채취 및 전류밀도의 영향)

  • Lee, Hoo-In;Lee, Jae-Chun;Park, Jin-Tae;Kim, Min-Seuk;Sohn, Jeong-Soo;Koyama, Kazuya
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.386-387
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    • 2006
  • This study is about the recycling technology of scrap a PCB(printed circuit board) produced in home appliances or automobile industry. And we develop the recycling technology of cooper (Cu)which is contained to leaching solution. In stead of electrolytic collecting in existing sulphuric atmosphere, we apply process using the ammonia solution which is used in economizing energy. So m the process of electrolyzing scrap a PCB through the leaching and separation, we examine the effect of the nickel contained to the solution and the cooper degree of purity which is changed according to current density.

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Effects of TiO$_2$ Photodegradation on Leaching from Epoxy Resin Chemical in Water and Biological Toxicity (수용액에 용출된 에폭시수지 화합물의 TiO$_2$ 광분해효과와 생물독성에 미치는 영향)

  • Yeo Min Kyeong;Cho Eun Joung
    • Environmental Analysis Health and Toxicology
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    • v.19 no.3
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    • pp.271-278
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    • 2004
  • Epoxy resins are mostly used as a molding material for drinking water tank. Bisphenol A is used at a constituent material for epoxy resins and is widely suspected to act as an endocrine disrupter. In this study, we investigated embryo hatching in zebrafish reared in water undergone leaching process of expoxy resin, and found a decreased survival rate. Bisphenol A eluted from epoxy resin in drinking water tank was completely degraded by TiO$_2$ photocatalysis. We detected 7.8 ng/ml of bisphenol A in epoxy resin tank, and observed that the concentration was undetectable after 48h photocatalysis over TiO$_2$. There was no toxicity in hatching rates in zebrafish and morphogenesis after photocatalysis. The effect of TiO$_2$ photocatalytic reactions on the catalase activities in the f]y stage of zebrafish was also examined. At 1 week post hatching, cataiase activities were higher both in the group of epoxy resin with 48 h TiO$_2$ photocatalysis and in the TiO$_2$ photocatalysis for 48 hours were higher than control group. However catalase activities of the treatment group of epoxy resin by TiO$_2$ photocatalysis for 48 hours were similar to control in 5 weeks post hatching fries. In conclusion, the toxicity of TiO$_2$ photocatalysis was not observed in this zebrafish.

The electrochemical Characteristics on the Anode Material of Lithium Ion Secondary Batteries with Discharge Voltage (방전전압에 따른 리튬 이온 2차전지용 음극물질의 전기화학적 특성)

  • Park, Jong-Gwang;Han, Tae-Hui;Jeong, Dong-Cheol;Im, Seong-Hun;Han, Byeong-Seong
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.6
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    • pp.328-334
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    • 2000
  • A lithium ion secondary battery using carbon as a negative electrode has been developed. Further improvements to increase the cell capacity are expected by modifying the structure of the carbonaceous material. There are hopes for the development of large capacity lithium ion secondary batteries with long cycle, high energy density, high power density, and high energy efficiency. In the present paper, needle cokes from petroleum were examined as an anode of lithium ion secondary battery. Petroleum cokes, MCL(Molten Caustic Leaching) treated in Korea Institute Energy Research, were carbonized at various temperatures of 0, 500, 700, $19700^{\circ}C$ at heating rate of $2^{\circ}C$/min for lh. The electrolyte was used lM liPF6 EC/DEC (1:1). The voltage range of charge & discharge was 0.0V(0.05V) ~ 2.0V. The treated petroleum coke at $700^{\circ}C$ had an initial capacity over 560mAh.g which beyond the theoretical maximum capacity, 372mAh/g for LiC6. This phenomena suggests that carbon materials with disordered structure had higher cell capacity than that the graphitic carbon materials.

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Evaluation of Leaching Stability of Preservative Treated Wood in the Seawater for the use of a Fish-breeding Ground (해양어초사용을 위한 방부목재의 해수 용탈성 평가)

  • Lee, Myung Jae;Lee, Dong-Heub;Son, Dong-Won
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.3 s.131
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    • pp.53-63
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    • 2005
  • This study attempted to obtain the basic data of utilizable possibility of preservative treated wood as a material used in a marine ranch. To evaluate the leaching stability of CCA-, CCFZ-, and ACQ-treated woods in seawater, the specimens treated with 2% and 3% (w/v) of CCA, CCFZ, and ACQ were exposed to deionized water, synthetic seawater and natural seawater for 41 days and then each component released was periodically determined. There was little amount of copper and chromium released from CCA-treated wood exposed in both deionized and seawater. Although relatively large amount of arsenic was released from CCA-treated wood, the release rate in seawater was lower than that in deionized water. The release rate of chromium and zinc from CCFZ-treated wood were somewhat greater in deionized water, but lower in seawater than in deionized water. Retention level and salinity of synthetic seawater had little effect on the release rate of components. The ACQ-treated wood had greater copper release than CCA- and CCFZ-treated wood, and the amount of copper released did not affected by leaching media used.

The Environmental Safety Evaluation on Heavy Metal Leaching of Deteriorated Concrete under Severe Conditions (가혹한 조건에서 열화된 콘크리트의 중금속 용출에 대한 환경 안전성 평가)

  • Choi, Yun-Wang;Oh, Sung-Rok;Park, Man-Seok;Kim, Sang-Chel;Jung, Sang-Hwa
    • Journal of the Korea Concrete Institute
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    • v.25 no.5
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    • pp.539-546
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    • 2013
  • Cement industry in 1997 began to use industrial waste in cement factory for purpose of resource recycling. However recently, environmental hazard of the cement in accordance with recycling of industrial waste have been raised a problem by contamination around the cement factory and heavy metal leaching in cement. In particular, the presence of $Cr^{6+}$ in cement has become a critical issue, the studies for minimizing of $Cr^{6+}$ in cement have been performed. But, in domestic, most of the research on heavy metal leaching was carried out from the perspective of the cement. Environmental safety assessment in terms of concrete is needed because cement is used to the concrete material. Therefore, this paper was evaluated heavy metals leaching of deteriorated concrete by severe conditions. test result showed that $Cr^{6+}$ were not detected from all the variables.

Properties of Concrete Mixed with Waste Incinerated Bottom Ash (쓰레기 소각재를 혼입한 콘크리트의 재료특성 및 강도특성)

  • 어석홍;홍기호;최덕진;김희성
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.217-222
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    • 2002
  • The purposes of this study are to investigate the material characteristics and strength properties of concrete mixed with waste incinerated bottom ash(BA), and to evaluate the leaching of environmentally harmful heavy metals from the bottom ash itself and from hardened concrete mixed with bottom ash. For this purpose, two reference mixes with W/C ratios of 0.45 and 0.55 were used, and the replacement proportion of BA was varied with the ratios of 0%, 30%, 50%, 70%, and 100% by volume of fine aggregate in the reference mixes. The variation of compressive and splitting tensile strength, workability and unit weight of concrete were considered. Test results showed that the strengths, workability and unit weight decreased with increase in proportion of BA replaced. Leaching test results showed that there would be no environmentally harmful problem from using BA as the substitutes of fine aggregates in concrete.

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Heavy-Metal Leaching Properties of Fly-ash for Shotcrete (폐석탄회를 활용한 숏크리트의 중금속 용출특성)

  • Park, Cheol-Woo;Sim, Jong-Sung;Kang, Tae-Sung;Park, Seong-Eun;Choi, Woo-Hyun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.427-428
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    • 2009
  • In order to utilize fly ash as a shotcrete material, this research conducted a heavy-metal leaching test to inspect the influence on environmental. The measured amount of the heavy metals in the leachate was well below the suggested guidelines from Korea and U.S.A.

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Synthesis of zeolite from power plant fly ash (화력발전소 비산회를 이용한 제올라이트합성)

  • 김재환;연익준;김광렬
    • Journal of environmental and Sanitary engineering
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    • v.12 no.1
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    • pp.49-58
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    • 1997
  • A study on the synthesis of zeolite from bituminous coal ESP fly ash as a raw material, which was emitted from the power plant, was carried out to reduce environmental problems and reuse of the industrial wastes. Bituminous coal fly ash was used as the source of silica and alumina. Zeolite was synthesized by hydrothermal reaction in aqueous NaOH solution with sodium aluminate as additive. The objective of this study is to elucidate the effect of several experimental variables on the synthesis of zeolite. The effects of preroasting temperature, mixing speed, leaching alkalinity, and molar ratio of Na$_{2}$O/SiO$_{2}$ and SiO$_{2}$/Al$_{2}$O of the products were investigated. The synthesized zeolite was proved to be NaA, which is known as 4A type, by comparing with SEM images, and X-ray diffraction analysis. And also we know that the transformation of zeolite A take places into other types of zeolites, i.e. Hydroxysodalite, zeolite P, with the variation of leaching alkalinity.

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solidification/Stabilization of Hazardous Wasted Using Cementitious Material(I) (특수시멘트 고화재를 이용한 지정폐기물의 고형화/안정화(I))

  • Lim, C.Y.;Paik, S.H.;Um, T.S.;Choi, L.;Oh, B.H.;Lee, K.H.
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.04a
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    • pp.205-210
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    • 2000
  • This study concerns the cement-solidification. stabilization of the electric furnace dust. Compressive strength and leaching test of heavy metals were evaluated for varing types and ratios of cements and the effect of some additives of hauyne clinker and slag were also discussed. In this cases of using cement binders more than 30%, the compressive strength showed the values over 150kgf/cm2. so it can be used as filler for concrete precastings. Type III cement and Hauyne clinker improved the compressive strength, especially early strength. Leaching amount of heavy metals was decreased when using type III cement and adding hauyne clinker and slag. The values were especially low in the case of slag addition.

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