• Title/Summary/Keyword: leaching characteristics

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The Characteristics of Compressive Strength and Leachability on Solidification of Chromium Tannery Sludge adding to Coal Fly Ash (비산회를 첨가한 피혁공장 크롬 슬러지의 고화시 압축강도 및 용출 특성)

  • 주소영;연익준;신필식;전병진;김광렬
    • Journal of environmental and Sanitary engineering
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    • v.16 no.1
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    • pp.53-60
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    • 2001
  • In this study, the heavy metals in tannery sludge were solidified by using cement and power plant fly ash. Solidification characteristics were discussed with the compressive strength and chromium leaching characteristics of solids. The compressive strength of cement mortar was increased by the amount of fly ash up to 24.3~33.8%, which was considered the results of pozzolanic reaction. When the content of fly ash was 20%, cement mortar showed the highest value $295kg/\textrm{cm}^2$ for 28 days curing. At early curing days, solidified chromium tannery sludge solids were showed lower compressive strength because of the retard on the hydration of cement, but the compressive strength was recovered to be more than $140kg/\textrm{cm}^2$ for 28 days curing regardless with the amounts of fly ash. Also, the results of leaching tests by KSM and TCLP method were showed that the solidified chromium sludge have leached out 0.3~2.2% and 11~17%, respectively.

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Leaching Characteristics on Clay Ground induced by Artesian Pressure (피압에 의한 점토 지반의 용탈 특성)

  • Yun, Daeho;Kim, Yuntae
    • Journal of the Korean Geosynthetics Society
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    • v.15 no.4
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    • pp.97-104
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    • 2016
  • This paper performed consolidation tests on soft ground with and without artesian pressure conditions to find out characteristics of leaching effects using two types of one-dimensional column equipment(height : 1,100mm, outer diameter : 250mm). Artesian pressure of 5.5kPa was applied to the bottom of soft ground inside column equipment. Distribution of salinity and shear strength with soil depth were measured after the consolidation test. From the results, it was found that distribution of undrained shear strength and salt concentrations were similar at the top of clay ground irrespective of artesian pressure condition. However, at the bottom of clay ground, the values of undrained shear strength and salt concentration under artesian pressure were lower than those without artesian pressure. This result indicates that structure of soft soil with artesian pressure was weakened by salt leaching. Electronic resistance results showed that void ratio under artesian pressure condition was more reduced than that without artesian pressure condition.

Study on Leaching Characteristics of $^{137}Cs\;and\;^{90}Sr$ from Cement-Solidified Radwastes (방사성 폐기물 시멘트 고화체로 부터의 $^{137}Cs$$^{90}Sr$ 용출특성 연구)

  • Hwang, Sun-Tae;Lee, Kyung-Ju;Choi, Kil-Oung;Park, Hun-Whee;Kim, Hwan-Young
    • Journal of Radiation Protection and Research
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    • v.10 no.2
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    • pp.113-121
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    • 1985
  • For the safety assessment of radwaste treatment and disposal, the leaching characteristics of $Cs^+\;and\;Sr^{++}$ from the cement-solidified radwastes was investigated by means of the survey and analysis of the activity leach rate and cumulative leach fraction of $^{137}Cs\;and\;^{90}Sr$ leaching from solidified radwastes. The cylindrical cement-solidified samples were made by the sodium silicate method and neutralization method changing the mole density of simulated liquid radwaste, type of cement, adding material and concentration of boric acid. The leaching study was carried out by the method using simulated PWR concentrated liquid radwaste solidified in cement that had been processed following the recommendations of IAEA. All the experimental results are in well accordance with the research data reported previously, but the watertight cement-solidified radwastes show rather high leach rate of radioactivity. It is learned, therefore, that the watertight cement is not adequate as the material for the solidified radwastes.

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Strength and Leaching Characteristics of Water Sludge-added Lightweight Soil Considering Reinforcing Material and Layer (정수슬러지를 혼합한 경량토의 보강에 따른 강도 및 용출 특성 분석)

  • Yun, Daeho;Lee, Byunghun;Kim, Yuntae
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.8
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    • pp.75-84
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    • 2012
  • In this paper, strength and leaching characteristics of water sludge-added lightweight soils(WALS) considering reinforcing materials(waste fishing net, glue treated waste fishing net and geogrid) and layer(1 or 2 layer) were investigated using unconfined compression test and leaching test. Several specimens of water sludge-added lightweight soil consisted of water sludge, cement, and bottom ash were prepared according to flowability. Reinforcing material added into these specimens were waste fishing net and geogrid. A glue treated waste fishing net was also added in order to increase interlocking between soil mixture and waste fishing net. Strength increased in the order of WALS reinforced by waste fishing net, glue treated waste fishing net, and geogrid. Strength of specimen with double layer-reinforcing material was greater than that of specimen with single layer reinforcing material. Leaching result of WALS was also satisfied with standard of ministry of environment.

Effective Reservoir Management Methods using Nutrients Leaching Characteristic Analysis: Case Study of the Hongdong Reservoir (홍동저수지 퇴적토의 유기물 용출 특성 분석을 통한 효율적인 저수지 관리 방안 연구)

  • Lee, Young-Shin;Shin, Sang-Hee
    • The Journal of Engineering Geology
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    • v.23 no.2
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    • pp.95-104
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    • 2013
  • This study proposes an efficient management plan for improving the water quality of agricultural reservoirs. Hongdong reservoir is located in an area that includes farmland, forest, residential housing, and livestock farms. The levels of pollutants in Hongdong reservoir were investigated with the aim of improving the water quality in the reservoir. The potential concentrations of total nitrogen (T-N) and total phosphorus (T-P) in Hongdong reservoir were 1.06-3.67 and 0.52-1.12 $g/m^2-d$, respectively. An analysis of leaching characteristics was performed under anaerobic conditions for 72 hours at $20^{\circ}C$. The concentrations of T-P and $PO_4$-P were measured by general leaching for a set period. In the case of T-P, the leaching was measured by irregular leaching due to denitrification of nitrite nitrogen ($NO_2$-N) and nitrate nitrogen ($NO_3$-N). A very small amount of $NH_3$-N on nitrogen ($N_2$) was measured due to the low pH in the column, as a consequence of the anaerobic conditions.

The Injection Characteristics and Environmental Effects for Grouting Materials Based on Cement (시멘트계 주입재 종류별 주입 특성 및 환경적 영향 연구)

  • 천병식;이재영;서덕동
    • Journal of the Korean Geotechnical Society
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    • v.19 no.2
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    • pp.159-170
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    • 2003
  • In this study, the mixed design of grout with hish strength.high permeation.high durability and environmental stability as the state of the art in material field was performed. Also, the subjects of grouting, grouting effects for ground conditions, and environmental effects were analyzed. According to these results, the fundamental data will be suggested as a design of grouting in the field application. The physical, mechanical and chemical characteristics with particle shape of the grouts were analyzed. Then, the gel-time of grouts, which is essential for workability and permeation range, were controlled. Also, the laboratory model grouting tests were performed to find the characteristics of solidification, permeation and durability with grouts. The ordinary portland, slag and microcement which have been used in the construction field were evaluated fur the environmental effects. To find the leaching of $Cr^{6+}$characteristics in cement grouts, $Cr^{6+}$ leaching tests were performed for the raw materials. Also, the results of leaching test were shorn by surrounding environment. Then, the unconfined compression strength tests were performed with the homo-gel samples, and the amount of changed $Cr^{6+}$ was measured by curing solution.

Leaching Characteristics and Potential Impact Assessment of Pollutants from Field Test Cells with Coal Bottom Ash as Fill Materials for Recycling (석탄 바닥재 메움재 재활용을 위한 Field Test Cells로부터 오염물질 배출 특성 및 잠재적 영향 평가)

  • Jang, Yong-Chul;Lee, Sungwoo;Kang, Heeseok;Lee, Seunghun
    • Journal of Environmental Impact Assessment
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    • v.22 no.2
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    • pp.135-145
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    • 2013
  • The recycling of coal bottom ash generated from coal power plants in Korea has been limited due to heterogenous characteristics of the materials. The most common management option for the ash is disposal in landfills (i.e. ash pond) near ocean. The presence of large coarse and fine materials in the ash has prompted the desire to beneficially use it in an application such as fill materials. Prior to reuse application as fill materials, the potential risks to the environment must be assessed with regard to the impacts. In this study, a total of nine test cells with bottom ash samples collected from pretreated bottom ash piles and coal ash pond in a coal-fired power plant were constructed and operated under the field conditions to evaluate the leachability over a period of 210 days. Leachate samples from the test cells were analyzed for a number of chemical parameters (e.g., pH, salinity, electrical conductance, anions, and metals). The concentrations of chemicals detected in the leachate were compared to appropriate standards (drinking water standard) with dilution attenuation factor, if possible, to assess potential leaching risks to the surrounding area. Based on the leachate analysis, most of the samples showed slightly high pH values for the coal ash contained test cells, and contained several ions such as sodium, potassium, calcium, magnesium, chloride, sulfate, and nitrate in relatively large quantities. Three elements (aluminum, boron, and barium) were commonly detected above their respective detection limits in a number of leachate samples, especially in the early leaching period of time. The results of the test cell study indicate that the pollutants in the leachate from the coal ash test cells were not of a major concern in terms of leaching risk to surface water and groundwater under field conditions as fill materials. However, care must be taken in extending these results to actual applications because the results presented in this study are based on the limited field test settings and time frame. Structural characteristics and analysis for coal bottom ash may be warranted to apply the materials to actual field conditions.

Heavy Metal Leaching Characteristics of Silicate Glass Containing EAF Dust (전기로 제강분진이 첨가된 규산염계 유리의 중금속 용출 특성)

  • Kim, Hwan-Sik;Kang, Seung-Gu;Kim, Yoo-Taek;Lee, Gi-Gang;Kim, Jung-Hwan
    • Journal of the Korean Ceramic Society
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    • v.43 no.2 s.285
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    • pp.136-141
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    • 2006
  • The stabilizing behavior of heavy metals in the silicate glass containing Electric Arc Furnace dust (EAF dust) were studied by the Toxic Characterization Leaching Procedure (TCLP) test, and the change of crystalline phase and glass network structure were investigated as a function of EAF dust content added. The glass containing EAF dust of $30\;wt\%$ an oxygen/network former ratio(R) of $2\~3$ allowing a fairly stable network structure thus showed much lower heavy metal leaching concentration than that for containing EAF dust above $50\;wt\%$ at TCLP test. For the glass containing EAF dust $50\~60\;wt\%$, however, the R was over 3, which weakened the glass network structure and increased the heavy metals leachate. Adding the EAF dust to a glass decreased the degree of Si-O-Si symmetry and increased the number of non-bridging oxygen, which decreased the chemical durability of glasses. When the dust content in a glass was over $70\;wt\%$, the Zn and Fe ions reacted to form the spinel crystal rather than to bind to network structure of glass and leaching concentration of those ions from the specimen decreased, so the spinel phase could be attributed to lowering a heavy metal leaching.