• Title/Summary/Keyword: layered materials

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Exfoliation of Dion-Jacobson Layered Perovskite into Macromolecular Nanoplatelet

  • Lee, Won-Jae;Yeo, Hyun Jung;Kim, Do-Yun;Paek, Seung-Min;Kim, Young-Il
    • Bulletin of the Korean Chemical Society
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    • v.34 no.7
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    • pp.2041-2043
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    • 2013
  • A layered perovskite of Dion-Jacobson phase, $RbLaTa_2O_7$, was successfully exfoliated into colloidal suspension via successive ion-exchange and intercalation reaction. The pristine perovskite $RbLaTa_2O_7$ was synthesized by conventional solid-state reaction, and then, it was ion-exchanged with hydrochloric acid to obtain a protonic form of perovskite. The resulting proton-exchanged perovskite was reacted with ethylamine to increase interlayer spaces for further intercalation reaction. Finally, the ethylamine-intercalated form was exfoliated into nanosheets via an intercalation of bulky organic cations (tetrabutylammonium). According to X-ray diffraction (XRD) analysis, the TBA-intercalated form showed remarkably increased interlayer spacing (${\Delta}d$ = 1.67 nm) in comparison with that of the pristine material. Transmission electron microscopic image of exfoliated perovskite clearly revealed that the present exfoliated perovskite were composed of very thin layers. This exfoliated perovskite nanosheets could be applicable as building blocks for fabricating functional nanocomposites.

A Study on the Acoustic Characteristics and Absorption Performance Improvement Method of Double Layered Sound Absorption System Using High Density Polyester Absorbing Materials (고밀도 폴리에스터 흡음재를 이용한 이중층 흡음시스템의 음향특성 및 흡음성능 향상 방안에 관한 연구)

  • Yoon, Je-Won;Jang, Kang-Seok;Cho, Yong-Thung
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.26 no.3
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    • pp.331-339
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    • 2016
  • To improve the acoustic performance of sound absorbing materials, the thickness of the material should be increased or the sound absorbing material having an irregular surface shape should be used. In this study, the acoustic characteristics and methods to improve the acoustic performance of a sound absorbing system equipped with double layered polyester sound absorbing materials were investigated. The numerical model was set up and the results obtained from the model were compared with the actual measurement data. And, strategies to improve the acoustic performance of sound absorbing systems with double layered sound absorbing materials made of polyester with different configuration were shown. So, this study is expected to be usefully used at sites that require high acoustic absorption performance with minimal installation thickness to reduce sounds reflection in narrow spaces such as interior of subway tunnels or in noise barriers installed adjacent to rails.

Recent Development in Fabrication and Control of Layered-Double Hydroxide Nanostructures (층상 이중 수산화물 나노물질의 성장 제어기술 연구동향)

  • Jeon, Chan-Woo;Park, Il-Kyu
    • Journal of Powder Materials
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    • v.25 no.6
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    • pp.514-522
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    • 2018
  • Layered-double hydroxide (LDH)-based nanostructures offer the two-fold advantage of being active catalysts with incredibly large specific surface areas. As such, they have been studied extensively over the last decade and applied in roles as diverse as light source, catalyst, energy storage mechanism, absorber, and anion exchanger. They exhibit a unique lamellar structure consisting of a wide variety of combinations of metal cations and various anions, which determine their physical and chemical performances, and make them a popular research topic. Many reviewed papers deal with these unique properties, synthetic methods, and applications. Most of them, however, are focused on the form-factor of nanopowder, as well as on the control of morphologies via one-step synthetic methods. LDH nanostructures need to be easy to control and fabricate on rigid substrates such as metals, semiconductors, oxides, and insulators, to facilitate more viable applications of these nanostructures to various solid-state devices. In this review, we explore ways to grow and control the various LDH nanostructures on rigid substrates.

Physical and Mechanical Properties of Sludge-Particle Board Manufactured by Composition Types and Composition Ratios from Mixed or Layered Paper Sludge and Wood Particle (구성형태(構成形態)와 구성비율별(構成比率別)로 제조(製造)한 슬러지-파티클보드의 물리적(物理的) 및 기계적(機械的) 성질(性質))

  • Lee, Phill-Woo;Yoon, Hyoung-Un
    • Journal of the Korean Wood Science and Technology
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    • v.24 no.1
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    • pp.17-26
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    • 1996
  • This research was accomplished to evaluate possibility of using paper sludge for the raw materials of wood based panel products. The experimental panels were manufactured by four mixed ratios, the proportion of paper sludge to wood particle: 20:80, 30:70, 40:60, 50:50% (oven dry weight basis) and by three composition types, sludge-particle mixed board, three layered sludge-particle board and three layered particle board. They were tested mechanical (bending strength and internal bond) and physical properties (water absorption, thickness swelling and linear expansion). From the results they were shown that bending strength of mixed and three layered sludge-particle board were decreased with increasing of composition ratios of sludge. And the mechanical and physical properties of the boards of three layered composition types have superior to those of mixed composition type. Although composition ratios of sludge increased, the internal bond strength and dimensional stability of sludge-particle board not decreased quantitatively. We concluded that the mechanical and physical properties of three layered sludge-particle board were similar w those of three layered particle-board (control) made by our laboratory design. Therefore, it was recognized that paper sludge can be used as potential raw material in particle-board manufacturing industry.

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Characteristic Changes of Layered Techniques in the Hussein Chalayan's Collections (후세인 샬라얀 컬렉션에 나타난 레이어드 기법의 변화 특성 연구)

  • Koo, Mi-Ji
    • Journal of the Korea Fashion and Costume Design Association
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    • v.9 no.3
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    • pp.221-230
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    • 2007
  • This research was focused on the changes of layered techniques in Hussein Chalayan's collections. For this purpose, the layered techniques in 134 works from Chalayan's collections, 97S/S to 06S/S, which were obtained from fashion magazines and fashion internet site, were analyzed and classified into 15 groups. Layered techniques in his works apparently expressed his philosophy about deconstruction. Multilayered feeling was given through using various techniques such as one layer clothing which was showed like multi-layered clothing. Others were multi-layer clothing which felt like one layer, breaking the stereotyped line of clothing into atypical construction and using various materials or constructive lines which made the optical feeling like one layer or multi-layer clothing, and so on. These layered techniques in Chalayan's collections were differentiated into several categories, such as techniques which were revealed in every collections, techniques which were differentiated from one another collections, techniques which were continuously showed through three collections for connection with each collection, techniques which were used only for Spring/Summer season, and techniques which were uniquely showed in early collection or recent collections.

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Thermoelectric properties of multi-layered Bi-Te/In-Se/Bi-Te thin film deposited by RF magnetron sputter

  • Kim, Hyo-Jung;Kim, Kwang-Chon;Choi, Won-Chel;Jung, Kyoo-Ho;Kim, Hyun-Jae;Park, Chan;Kim, Jin-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.231-231
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    • 2010
  • Thermoelectric properties of a multi-layered thin film, which was composed with indium selenide and bismuth telluride, were investigated. The structure of the layered thin film is Bi-Te /In-Se/Bi-Te and it was prepared on sapphire substrate by RF magnetron sputter using stoichiometric $Bi_2Te_3$ (99.9%) and $In_2Se_3$(99.99%) target at room temperature. Then, it was annealed at temperature range of 150 - $500^{\circ}C$ in Ar ambient. Structural characterizations were done using X-ray diffraction(XRD, BRUKER, D8, 60kW) and transmission electron microscopy (TEM, FEI, Tecnai, F30 S-Twin), respectively. Cross-section of multi-layer structure was observed by Scanning electron microscopy (SEM). The resistivity and Seebeck coefficient of these samples were also measured by conventional equipment at room temperature. The maximum value of power factor was $1.16\;{\mu}W/k^2m$ at annealing temperature of $400^{\circ}C$.

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Efficient Transdermal Penetration and Improved Stability of L-Ascorbic Acid Encapsulated in an Inorganic Nanocapsule

  • Yang, Jae-Hun;Lee, Sun-Young;Han, Yang-Su;Park, Kyoung-Chan;Choy, Jin-Ho
    • Bulletin of the Korean Chemical Society
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    • v.24 no.4
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    • pp.499-503
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    • 2003
  • Encapsulation of L-ascorbic acid (vitamin C) within a bio-compatible layered inorganic material was achieved by coprecipitation reaction, in which the layered inorganic lattice and its intercalate of vitamin C are simultaneously formed. The nano-meter sized powders of vitamin C intercalate thus prepared was again encapsulated with silica nano-sol to form a nanoporous shell structure. This ternary nanohybrid of vitamin Clayered inorganic core-$SiO_2$ shell exhibited an enhanced storage stability and a sustained releasing of vitamin C. Furthermore, the nano-encapsulation of vitamin C with inorganic mineral was very helpful in delivering vitamin C molecules into skin through stratum corneum, facilitating transdermal penetration of vitamin C in topical application.

Design of Loudspeaker using Composite Plate and Piezofilm Actuator (복합재료 평판과 압전필름 작동기를 이용한 저음용 평판 스피커 설계)

  • 황준석;김승조
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 1999.11a
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    • pp.124-129
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    • 1999
  • In this study, a design method for the flat sound radiator is developed to make new sound radiator system, whose shape is much thinner than that of conventional loudspeaker. Piezofilm (PVDF) is used as actuators of flat sound radiator. To avoid the distortion of sound radiated from flat sound radiator, the frequency response of radiated sound to be flat is taken as the design objective. The electrode pattern and orientation angle of piezofilm actuator is optimized to satisfy the design objective. The formulation is based on the coupled finite element and boundary element method. Genetic algorithm is used in the optimization process, which is useful in the optimization of discrete design variables. Frequency response with optimized piezofilm actuator is made flat enough to satify the design objective. For the enhancement of sound power, double-layered piezofilm actuators are also considered. The sound power with double-layered actuator becomes larger than that with single-layered actuator as expected.

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