• Title/Summary/Keyword: layer deposition

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Physical and Electrical Characteristics of Silicon Dielectric Thin Films by Atomic layer Deposition (ALD법으로 증착된 실리콘 절연박막의 물리적.전기적 특성)

  • 한창희;이주현;김운중;이원준;나사균
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.169-169
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    • 2003
  • 실리콘 절연막은 반도체 및 디스플레이 소자의 gate 절연막과 보호막으로, 그리고 배선공정에서는 층간절연막(ILD, Inter Layer Dielectric)으로 사용하는데, 주로 IPCVD, PECVD, APCVD법에 의하여 증착되고 있다. 그러나 이러한 방법들은 반도체 소자의 고집적화가 진행됨에 따라 증착온도와 step coverage 및 물성 이 문제점으로 대두되고 있다. 이러한 문제점들을 해결할 수 있는 원자층 증착(ALD, Atomic Layer Deposition)기술은 기판 표면에서의 self-limiting reaction을 통해 매우 얇은 박막을 형성할 수 있고, 두께 및 조성 제어를 정확히 할 수 있으며, 복잡한 형상의 기판에서도 우수한 step coverage를 얻을 수 있어 초미세패턴의 형성과 매우 얇은 두께에서 균일한 물리적, 전기적 특성이 요구되는 초미세 반도체 공정에 적합하다. 또 저온에서 증착이 가능해 유리를 기판으로 사용하는 TFT-LCD소자의 gate 절연막에 적용이 가능하다.

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이종접합 태양전지용 p a-Si:H 에미터 층 최적화 및 태양전지 특성 거동 연구

  • Kim, Kyung Min;Jeong, Dae Young;Song, Jun Yong;Park, Joo Hyung;Oh, Byung Sung;Song, Jinsoo;Lee, Jeong Chul
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.129.2-129.2
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    • 2011
  • 본 연구에서는 a-Si:H/c-si 구조의 이종접합 태양전지의 p a-Si:H 에미터 층의 박막 조건에 따라 태양전지 특성을 연구하였다. p, n-layer는 PECVD (Plasma-enhanced chemical vapor deposition) i-layer는 HWCVD(Hot wire chemical vapor deposition), ITO는 RF 마그네트론 스퍼터링법으로 제작하였다. p-layer의 도핑 농도, 기판 증착 온도, 증착 높낮이에 따라 특성을 비교 분석 하였다. QSSPC로 minority carrier life time, 자외 가시선 분광분석 장치로 투과 반사도를, Ellipsometer로 흡수 계수, 두께, FTIR로 막의 구성요소 등의 변화를 조사하여 개선된 p a-Si:H의 특성이 이종접합 태양전지에서 효율향상에 영향을 주는지 Photo IV와 EQE를 통하여 조사하였다.

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펄스플라즈마를 이용한 새로운 Atomic Layer Deposition 장치

  • Yeom, Min-Su;Kim, Yong-Tae
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2006.10a
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    • pp.26-30
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    • 2006
  • 펄스 플라즈마 원자층 증착 방법 (PPALD : Pulse Plasma Atomic Layer Deposition)을 이용하여 이원계 박막인 W-N 박막을 ILD layer인 TEOS 위에 제조하였다. 실험은 $WF_6$$NH_3$ 가스의 순차적 주입과 $N_2$ 가스를 이용한 purging으로 이루어지며 $NH_3$ 가스 주입 시에 pulse plasma가 적용되었다. 일반적인 ALD 증착 기구를 그대로 따르는 PPALD 방법에 의해 제조된 W-N 박막은 N-H 플라즈마 초기 표면 처리에 의해 형성된 박막 위에 증착 하였다. 증착된 박막의 텅스텐과 질소의 비율이 2:1로 균일하였고 $700^{\circ}C$의 열처리에도 안정한 특성을 보였다.

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Fabrication of three dimensional microstructures using laser direct writing technique (레이저묘화 기술을 이용한 3차원 미세구조물 제조)

  • 정성호;한성일
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.670-673
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    • 2003
  • Fabrication of three dimensional microstructures by laser-assisted chemical vapor deposition of material is investigated. To fabricate microstructures, a thin layer of deposit in desired patterns is first written using laser direct writing technique and on top of this layer a second layer is deposited to provide the third dimension normal to the surface. By depositing many layers. a three dimensional microstructure is fabricated. Optimum deposition conditions for direct writing of initial and subsequent layers with good surface quality and profile uniformity are determined. Using an arson ion laser and ethylene as the light source and reaction gas, respectively, fabrication of three-dimensional carbon microstructures is demonstrated.

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Selective Electrodeposition Using Laser Masking and DC Voltage (레이저 마스킹과 직류전원을 이용한 선택적 전해도금)

  • Shin, Hong Shik;Kim, Sung Yong
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.24 no.1
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    • pp.75-80
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    • 2015
  • This paper proposes a selective electrodeposition process that uses laser masking and a DC voltage. Selective electrodeposition using laser masking and a DC voltage is more efficient than that using laser masking and a pulse voltage. In other words, electrodeposition with a DC voltage allows for precise selective deposition without the limitation of the deposition region. Also, a selective electrodeposition method that uses laser masking and DC voltage can reduce the electrodeposition time. The characteristics of a copper layer deposited by laser masking and DC voltage were examined under various conditions. A selective copper layer with various micro patterns of $2{\mu}m$ thickness was successfully fabricated.

Characterization of Aluminum Oxide Thin Film Grown by Atomic Layer Deposition for Flexible Display Barrier Layer Application

  • Kopark, Sang-Hee;Lee, Jeong-Ik;Yang, Yong-Suk;Yun, Sun-Jin
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.746-749
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    • 2002
  • Aluminum oxide thin films were grown on a poly ethylene naphthalate (PEN) substrate at the temperature of 100$^{\circ}C$ using atomic layer deposition method. The film showed very flat morphology and good adhesion to the substrate. The visible spectrum showed higher transmittance in the range from 400 nm to 800 nm than that of PEN. The water vapor transmission value measured with MOCON for 230nm oxide-deposited PEN was 0.62g/$m^2$/day @ 38$^{\circ}C$, while that of PEN substrate was 1.4g/$m^2$/day @ 38$^{\circ}C$.

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Electrical and Optical Properties of Ti-ZnO Films Grown on Glass Substrate by Atomic Layer Deposition (원자층 증착법을 통하여 유리 기판에 증착한 Ti-ZnO 박막의 전기적 광학적 특성)

  • Lee, U-Jae;Kim, Tae-Hyeon;Gwon, Se-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.57-57
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    • 2018
  • Zinc-oxide (ZnO), II-VI semiconductor with a wide and direct band gap (Eg: 3.2~3.4 eV), is one of the most potential candidates to substitute for ITO due to its excellent chemical, thermal stability, specific electrical and optoelectronic property. However, the electrical resistivity of un-doped ZnO is not low enough for the practical applications. Therefore, a number of doped ZnO films have been extensively studied for improving the electrical conductivities. In this study, Ti-doped ZnO films were successfully prepared by atomic layer deposition (ALD) techniques. ALD technique was adopted to careful control of Ti doping concentration in ZnO films and to show its feasible application for 3D nanostructured TCO layers. Here, the structural, optical and electrical properties of the Ti-doped ZnO depending on the Ti doping concentration were systematically presented. Also, we presented 3D nanostructured Ti-doped ZnO layer by combining ALD and nanotemplate processes.

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Photoluminescence of CaS:Pb Phosphors Grown by Atomic Layer Deposition

  • Kang, Jung-Sook;Kim, Yong-Shin;KoPark, Sang-Hee;Yun, Sun-Jin;Sohn, Sang-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 2000.01a
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    • pp.29-30
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    • 2000
  • CaS:Pb thin film used as phosphor layer in electroluminescent devices were deposited by an atomic layer deposition (ALD). The photoluminescence emission and excitation spectra were measured at 5 and 300K for the $CaS:Pb^{2+}$ phosphors with different Pb concentration from 0.001 at.% to 0.648 at.%. The emission spectra of these samples were characterized as UV emission and blue emission with the center of peak around 360 and 425nm, respectively. The UV emission was dominant at the low $Pb^{2+}$ concentration of 0.001 at%, whereas with increase of Pb concentration, the blue emission became a major component and to longer wavelength.

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Silicon field emission arrays coated with a $CoSi_2$ layer grown by reactive chemical vapor deposition

  • Han, Byung-Wook;Rhee, Hwa-Sung;Ahn, Byung-Tae;Lee, Nam-Yang
    • 한국정보디스플레이학회:학술대회논문집
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    • 2000.01a
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    • pp.131-132
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    • 2000
  • We prepared Si emitters coated with a MOCVD $CoSi_2$ layer to improve the emission properties. The $CoSi_2$ layer was grown on Si field emitters in situ by reactive chemical-vapor deposition of cyclopentadienyl dicarbonyl cobalt at 600 ${\sim}$ $650^{\circ}C$. The $CoSi_2$ coated field emitters showed enhanced emission properties of current-voltage characteristics, which were due to the increase of emitting area from Fowler-Nordheim plot. And the emission current fluctuation decreased due to the chemically stable surface properties of $CoSi_2$.

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High-Efficiency ITO/Se Solar Cells (Se 태양전지(太陽電池)의 고효율화(高效率化)에 관한 연구(硏究))

  • Kim, Tae-Seoung
    • Solar Energy
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    • v.7 no.2
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    • pp.7-13
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    • 1987
  • Indium-Tin-Oxide (ITO)/Selenium heterojunction solar cells which fabricated by vacuum deposition technique and annealing process has been investigated. Prior to the Selenium deposition, a thin tellurium layer (about $10{\AA}$) was deposited onto the ITO layers to provide a sufficient mechanical bond between the Oxide and Selenium layers. The amorphous Selenium layer was deposited onto the Te-ITO layers, and then the crystallization of the amorphous Selenium was carried out using a hot plate at about $180^{\circ}C$ for 4 min. Efficient Selenium solar cells with conversion efficiency as high as 4.52% under AM1 condition has been fabricated in polycrystalline Selenium layer ($6{\mu}m$). The optimum data in manufacturing Se solar cell was listed in table.

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