• Title/Summary/Keyword: laser spectroscopy

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Rapid Detection of Trace 1,4-Dichlorobenzene Using Laser Mass Spectrometry

  • Ding, Lei;Ma, Jing;Zheng, Haiyang;Fang, Li;Zhang, Weijun;Kim, Duk-Hyeon;Cha, Hyung-Ki
    • Bulletin of the Korean Chemical Society
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    • v.27 no.9
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    • pp.1393-1396
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    • 2006
  • The 1+1 two-photon Resonant Enhanced Multiphoton Ionization (REMPI) spectra of 1,4-dichlorobenzene was obtained from 240 nm through to 250 nm on a laser mass spectrometer. Special care was taken to build up a heatable sample inlet system suitable for detecting a trace semi-volatile organic compound and reducing the memory effort on the inner wall of the inlet system. The detection limits of 1,4-dichlorobenzene in ppbV/V concentration range at certain wavelengths are presented.

Semiconductor laser-based absorption spectroscopy for monitoring physical vapor deposition process (증기증착 공정 감시를 위한 반도체 레이저 흡수 분광학)

  • 정의창;송규석;차형기
    • Journal of the Korean Vacuum Society
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    • v.13 no.2
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    • pp.59-64
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    • 2004
  • A study on the semiconductor laser-based atomic absorption spectroscopy was performed for monitoring physical vapor deposition process. Gadolinium metal was vaporized with a high evaporation rate by electron beam heating. Real-time atomic absorption spectra were measured by using tunable semiconductor laser beam at 770-794 nm (center wavelength of 780 nm) and its second harmonic at 388-396 nm. Atomic densities of metal vapor can be calculated from the absorption spectra measured. We plot the atomic densities as a function of the electron beam power and compare with the evaporation rates measured by quartz crystal monitor. We demonstrate that the semiconductor laser-based spectroscopic system developed in this study can be applied to monitor the physical vapor deposition process for other metals such as titanium.

The Characteristics of Dye Jet and Dye Laser Output Depending on the Reynold's Number (레이놀드 수에 따른 색소 젯트의 특성 및 색소레이저의 출력변화)

  • Kim, Sung Ho;Ko, Do-Kyeong;Lee, Jong-Min;Lim, Gwon;Jo, Jae-Heung;Chang, Soo
    • Korean Journal of Optics and Photonics
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    • v.5 no.4
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    • pp.461-465
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    • 1994
  • The spatial flatness of dye jet depending on the Reynold's number has analyzed by using a Michelson interferometer. When the Reynold's number of dye jet was 600, the flatness of the flow was the best. Under this condition, the dye laser with Littman-type configuration has been operated in a single longitudinal mode at the pumping energy of 0.5~1.0 mJ/pulse. The conversion efficiency and beam divergence were 4.7% and 3 mrad, respectively. ively.

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I2-Saturated Absorption Spectroscopy for Frequency-Stabilization of He-Ne Laser at 543 nm (543 nm 헬륨네온 레이저의 주파수 안정화를 위한 I2 포화흡수분광)

  • Kim, Kyung-Chan;Eum, Nyeon-Sik;Hong, Joo-Hyun;Seo, Ho-Sung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.3
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    • pp.859-865
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    • 2010
  • We have designed and assembled a saturated absorption-spectroscopy system of $^{127}I_2$ for the frequency stabilization of the 543 nm He-Ne laser. The frequency of a internal-mirror 543 nm He-Ne laser was swept by utilizing the temperature and PZT change of the laser cavity length. Frequency modulation was applied to the output laser mirror with a PZT modulator for the third harmonic signal. A portion of the hyperfine spectrum originated from the R(12)26-0 and R(106)28-0 transitions of the B-X system of $^{127}I_2$ was observed as the third-derivative signal using a saturated absorption spectroscopy. The signal-to-noise ratio of a typical hyperfine spectrum signal was estimated to be 30:1.

Direct Aerosol Analysis by Time Resolved Laser Plasma Spectroscopy - Improvement by Single Shot Measurements

  • Schechter, Israel
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.779-786
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    • 1995
  • Environmental and industrial aerosols can be analyzed on-line by laser plasma spectroscopy. The main problem in direct (no preparation or presorting) aerosol analysis is the extensive spectral fluctuations. A method to partially solve this problem is proposed. It is based on single shot measurements and application of a special rejection algorithm. The major factors that influence the spectral variations are discussed, in relation to the correction possibility by a rejection program. The method works well when average intensity of the single spectra is relatively high, as compared to detector's saturation limit. If intensities are too low, the accumulation of readout noise is critical, and no improvement is expected.

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Circular Polarization Spectroscopy in ^{87}Rb D_2$ line and Laser Frequency Stabilization (^{87}Rb D_2$ 전이선에 대한 원편광 분광 연구 및 레이저 주파수 안정화)

  • 문한섭;김승일;김현아;김중복;이호성
    • Korean Journal of Optics and Photonics
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    • v.6 no.4
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    • pp.317-323
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    • 1995
  • Doppler-free circular polarization spectroscopy in 87Rb Dz line has been carried out by using a diode laser whose linewidth was narrowed by an external cavity, and experimental results were compared with an optical pumping polarization spectroscopy theory. A dispersive spectrum obtained in a weak pump beam was completely fitted to a single cycle optical pumping theory. The laser frequency was locked to a Rb atomic hyperfine transition line without any frequency modulation by using the dispersive curve as an error signal. ignal.

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A Study on the Pulsed Laser Deposition of Diamond like Carbon Thin Films (다이아몬드상 카본박막의 펄스레이저 증착법 연구)

  • Sim, Gyeong-Seok;Lee, Sang-Ryeol
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.6
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    • pp.403-409
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    • 1999
  • We fabricated diamond like carbon (DLC) thin films using pulsed laser deposition (PLD) method. Among many deposition parameters, the effects of the deposition temperature and the laser energy density were investigated. Structural properties of the films were studied by Raman spectroscopy. The surface morphologies and cross-section imagies of the films were investigated by atomic force microscopy (AFM) and scanning electron microscopy (SEM) respctively. DLC thin films fabricated at $12 J/cm^2$ of a laser energy density and $300^{\circ}C$ of a deposition temperature showed the best quality.

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Characteristics of Metal Surface Heat Treatment by Diode Laser (다이오드 레이저를 이용한 금속 표면 열처리 특성)

  • Choi, Seong-Dae;Cheong, Seon-Hwan;Kim, Gi-Man;Yang, Seung-Cheol;Kim, Jam-Gyu
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.6 no.3
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    • pp.16-23
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    • 2007
  • An experimental investigation with diode laser system was carried out to study the effect of surface heat treatment on the die materials(SM45C, SKD11, SK3). The surface heat treatment characteristics of the laser beam are evaluated using hardness tests, optical microscopy, X-ray diffraction and energy dispersive X-ray spectroscopy(EDS). Results indicated that the beam size, focal length, feed rates are changed surface hardened characteristics. SM45C is higher hardness than other materials and composed to martensite grain at hardened zone, whereas other materials(SKD11, SK3)are low hardness than expected and composed to austenite and allayed martensite at hardened zone. The intensive X-ray diffraction patterns of (110)-(200)-(211) is detected hardened surface and the hardened surface distributed plenty of carbon density than metal zone.

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Effect of Laser Surface Modification of Cemented Carbide Substrates on the Adhesion of Diamond Films (Cemented Carbide기판의 레이저 표면 개질이 다이아몬드 박막의 접합력에 미치는 영향)

  • Lee, Dong-Gu
    • Journal of the Korean Society for Heat Treatment
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    • v.13 no.3
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    • pp.170-176
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    • 2000
  • A novel method for improving the adhesion of diamond films on cemented carbide tool inserts has been investigated. This method is based on the formation of a compositionally graded interface by developing a microrough surface structure using a pulsed laser process. Residual stresses of diamond films deposited on laser modified cemented carbides were measured as a function of substrate roughness using micro-Raman spectroscopy. The surface morphology and roughness of diamond films and cemented carbides were also investigated at different laser modification conditions. It was found that the increasing interface roughness reduced the average residual stress of diamond films, resulting in improved adhesion of diamond films on cemented carbides.

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