• Title/Summary/Keyword: laboratory calibration

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Determination of Chemical Composition of Toasted Burley Tobacco by Near Infrared Spectroscopy (근적외선분광법을 이용한 버어리 토스트엽의 화학성분 분석)

  • 김용옥;정한주;백순옥;김기환
    • Journal of the Korean Society of Tobacco Science
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    • v.17 no.2
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    • pp.177-183
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    • 1995
  • This study was conducted to develop the most precise NIR(near infrared spectrometric) calibration for rapid determination of chemical composition in ground samples of toasted burley tobacco using stepwise, stepup, principal component regression(PCR), partial least square(PLS) and modified partial least square(MPLS) calibration method. The number of wavelength(W) selected by stepup multiple linear regression using: second derivative spectra was as follows: total sugar(TS)-4 W, nicotine-9 W, total nitrogen(TN)-2 W, ash-8 W, total volatile base(TVB)-5 W, chlorine4 W, L of color-6 W, a of color-6 W and b of color-7 W. Comparing the calibration equations followed by each chemical components, the most precise calibration equation was MPLS for 75, a and b of color, PLS for nicotine, ash, TVB, chlorine and L of color and stepup for TN. The standard error of calibration(SEC) and standard error of performance(SEP) between result of near infrared analysis and standard laboratory analysis were 0.18, 0.40% for 75, 0.06, 0.08% for nicotine, 0.18, 0.16% for TN, 0.33, 0.46% for ash, 0.04, 0.03% for TVB, 0.08, 0.06% for chlorine, 0.54, 0.58 for L of color, 0.22, 0.22 for a of color and 0.27, 0.27 for b of color, respectively. The SEC and SEP of ash and TVB were within allowable error of standard laboratory analysis, nicotine, TN and chlorine were 1.2-2.0 times and 75 were 2.1-4.0 times larger than allowable error of standard laboratory analysis. The ratio of SEC and SEP to mean were 1.5, 1.6% for L of color, 3.7, 3.8% for a of color and 1.8, 1.8% for b of color, respectively. Key words : burley tobacco chemistry, near infrared spectroscopy.

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Water Content Calibration of Time-Domain Reflectometry Probe Using Laboratory Model Test (실내모형실험을 통한 TDR 함수량계의 현장 함수비 보정)

  • Shin, Eun Chul;Ryu, Byung Hyun;Park, Jeong Jun
    • Journal of the Korean Geosynthetics Society
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    • v.12 no.2
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    • pp.1-11
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    • 2013
  • Water content of subgrade soil in water supply systems has a large effect on performance. Many researchers lately make use of time-domain reflectometry (TDR) probes to measure the soil water content of subgrade soil from monitoring. The laboratory calibration test of TDR probe should be performed with soil field, because TDR probe can cause an error by type, gradation, density, and temperature of soil. This study shows the laboratory calibration test using TDR CS616, TDR-P3, TDR-T3. The calibration equations of TDR were then proposed. It was confirmed from the study that the data of TDR probe monitored in field could be used to estimate the freezing, unfrozen water content, and matric suction of soil.

IMU calibration technique and laboratory test (관성측정장치의 오차계수 식별기법 및 실험)

  • 성상만;이달호;이장규
    • 제어로봇시스템학회:학술대회논문집
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    • 1996.10b
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    • pp.664-667
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    • 1996
  • This paper presents the error parameter estimation technique for IMU(Inertial Measurement Unit) which is core sensor of INS(Inertial Navigation System) and verifies it via laboratory test. Firstly the error characteristic of gyroscope and accelerometer which is contained in IMU is examined and the error modelling is executed. The error of IMU can be divided into deterministic and random part, and the deterministic error can be divided into static and dynamic part. This paper consider the random part as constant. Secondly the error parameter estimation technique and following procedure for laboratory test is explained. Thirdly according to the test procedure the IMU test for static error is executed using 2-axis rate table and estimation result is presented with discussion about its validity.

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Intercomparison of KAERI Reference Photon Radiation Fields

  • S.Y.Chang;J.C.MacDonald;M.K.Murphy;Kim, B.H.;Lee, K.C.
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05d
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    • pp.34-39
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    • 1996
  • A series of measurements was peformed between KAERI and PNNL, U.S.A at KAERI secondary calibration laboratory to intercompare and verify the KAERI reference photon radiation fields by using air equivalent plastic walled ionization chambers, Different ionization chambers of two laboratories were used to determine the air kerma rate, free-in-air, at reference positions in the KAERI photon radiation fields, As the results, the agreement in the cross measurements between two laboratories was found to be within less than ${\pm}$ 3 %. This degree of consistency was considered to be encouraging, because each laboratory maintains independently its calibration traceablity with its national primary standard

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PRINCIPAL COMPONENTS BASED SUPPORT VECTOR REGRESSION MODEL FOR ON-LINE INSTRUMENT CALIBRATION MONITORING IN NPPS

  • Seo, In-Yong;Ha, Bok-Nam;Lee, Sung-Woo;Shin, Chang-Hoon;Kim, Seong-Jun
    • Nuclear Engineering and Technology
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    • v.42 no.2
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    • pp.219-230
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    • 2010
  • In nuclear power plants (NPPs), periodic sensor calibrations are required to assure that sensors are operating correctly. By checking the sensor's operating status at every fuel outage, faulty sensors may remain undetected for periods of up to 24 months. Moreover, typically, only a few faulty sensors are found to be calibrated. For the safe operation of NPP and the reduction of unnecessary calibration, on-line instrument calibration monitoring is needed. In this study, principal component-based auto-associative support vector regression (PCSVR) using response surface methodology (RSM) is proposed for the sensor signal validation of NPPs. This paper describes the design of a PCSVR-based sensor validation system for a power generation system. RSM is employed to determine the optimal values of SVR hyperparameters and is compared to the genetic algorithm (GA). The proposed PCSVR model is confirmed with the actual plant data of Kori Nuclear Power Plant Unit 3 and is compared with the Auto-Associative support vector regression (AASVR) and the auto-associative neural network (AANN) model. The auto-sensitivity of AASVR is improved by around six times by using a PCA, resulting in good detection of sensor drift. Compared to AANN, accuracy and cross-sensitivity are better while the auto-sensitivity is almost the same. Meanwhile, the proposed RSM for the optimization of the PCSVR algorithm performs even better in terms of accuracy, auto-sensitivity, and averaged maximum error, except in averaged RMS error, and this method is much more time efficient compared to the conventional GA method.

Field Intercomparison and Calibration of Net Radiometers (순복사계의 야외 상호 비교 및 보정)

  • Byung-Kwan Moon;Sang-Boom Ryoo;Yong-Hoon Youn;Jonghwan Lim;Joon Kim
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.5 no.2
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    • pp.128-137
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    • 2003
  • Net radiation (Rn) is one of the most fundamental components in surface energy budget. For an accurate measurement of Rn, periodic and consistent calibrations of net radiometers are required. With a 4-month time interval, two field experiments were conducted to inter-compare and calibrate two types of net radiometers (the Q-7.1 and the CNR1), widely used in flux measurements. Differences between the Q-7.1 and the CNR1 net radiometers were within 7.7%, and the errors after calibration against the standard net radiometer were <3.2%. Radiometric responses and calibration factors appeared to have changed with sky renditions, especially temperature difference with season's progress. We concluded that the periodically calibrated Q-7.1 can replace more expensive, more accurate CNR1 net radiometer for long-term field measurements, providing that field calibrations of net radiometers are performed every 4-6 months interval.

Determination of Microdosimetric Quantities of Several Neutron Calibration Fields at KAERI

  • Kim, B.H.;Kim, J.S.;Kim, J.L.;Chang, S.Y.;Cho, G.;McDonald, J.C.
    • Journal of Radiation Protection and Research
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    • v.28 no.4
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    • pp.327-335
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    • 2003
  • The commercially available neutron survey meter, the REM500, which uses a tissue equivalent proportional counter (TEPC) and the self-constructed TEPC were used to determine the microdosimetric quantities of several neutron calibration fields at Korea Atomic Energy Research Institute (KAERI). Microdosimetric spectra, absorbed dose, dose equivalent as well as quality factor were derived and compared with several neutron fields which were produced by using the shadow objects to make neutron scattered and being used as a kind of realistic neutron calibration fields at KAERI. The response of REM500 as a function of mean energy was evaluated with these neutron fields using the counts measured and the predetermined reference value. The response of the self-made TEPC and the REM500 was compared using one of the neutron calibration filelds of a $^{252}Cf$ source. The reference quantities of scattered neutron calibration fields were determined using a Bonner Sphere (BS). The value of frequency-mean lineal energy, dose-mean lineal energy and quality factor of two $^{252}Cf$ sources (unmoderated and $D_2O$ moderated) were determined to check the differences in the reference neutron fields between KAERI and Pacific Northwest National Laboratory (PNNL, USA) and the results were in good agreement within 1%. It means that there is no big difference in dosimetric quantifies of neutron calibration fields of two laboratories.

An Empirical Study of the Clinically Reportable Range in Clinical Chemistry (임상보고 가능범위의 실증적 연구)

  • Chang, Sang-Wu;Lee, Sang-Gon;Choi, Ho-Seong;Song, Eun-Young;Park, Yong-Won;Lee, In-Ae
    • Korean Journal of Clinical Laboratory Science
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    • v.39 no.1
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    • pp.31-36
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    • 2007
  • The purpose of the clinically reportable range (CRR) in clinical chemistry is to estimate linearity in working range. The reportable range includes all results that may be reliably reported, and embraces two types of ranges: the analytical measurement range (AMR) is the range of analyte values that a method can directly measure on the specimen without any dilution, concentration, or other pretreatment not part of the usual assay process. CAP and JCAHO require linearity on analyzers every six months. The clinically reportable range is the range of analyte values that a method can measure, allowing for specimen dilution, concentration, or other pretreatment used to extend the direct analytical measurement range. The AMR cannot exceed the manufacturer's limits. Establishing AMR is easily accomplished with Calibration Verification Assessment and experimental Linearity. For example: The manufacturer states that the limits of the AST on their instrument are 0-1100. The lowest level that could be verified is 2. The upper level is 1241. The verified AMR of the instrument is 2-1241. The lower limit of the range is 2, because that is the lowest level that could be verified by the laboratory. The laboratory could not use the manufacturer's lower limit of 2 because they have not proven that the instrument values below 2 are valid. The upper limit of the range is 1241, because although the lab has shown that the instrument is linear to 1241, the manufacturer does not make that claim. The laboratory needs to demonstrate the accuracy and precision of the analyzer, as well the validation of the patient AMR. Linearity requirements have been eliminated from the CLIA regulations and from the CAP inspection criteria, however, many inspectors continue to feel that linearity studies are a part of good lab practice and should be encouraged. If a lab chooses to continue linearity studies, these studies must fully comply with the calibration/calibration verification requirements of CLIA and/or CAP. The results of lower limit and upper limit of clinically reportable range were total protein (2.1 - 79.9), albumin (1.3 - 39), total bilirubin (0.2 - 106.2), alkaline phosphatase (13 - 6928.2), aspartate aminotransferase (24 - 7446), alanine aminotransferase (13 - 6724.2), gamma glutamyl transpeptidase (16.64 - 9904.2), creatine kinase (15.26 - 4723.8), lactate dehydrogenase (127.66 - 13231.8), creatinine (0.4 - 129.6), blood urea nitrogen (8.67 - 925.8), uric acid (1.6 - 151.2), total cholesterol (48.52 - 3162), triglycerides (36.91 - 3367.8), glucose (31 - 4218), amylase (21 - 6694.2), calcium (3.1 - 118.2), inorganic phosphorus (1.11 - 108), HDL (11.74 - 666), NA (58.3 - 1800), K (1.0 - 69.6), CL (38 - 1230).

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Evaluation of the Possibility of Daily Flow Data Generation from 8-Day Interval Measured Flow Data using SWAT-CUP (SWAT-CUP을 이용한 8일간격 유량측정자료의 일유량 확장 가능성 평가)

  • Jung, Jaewoon;Cho, Sohyun;Lim, Byungjin;Oh, Taeyoun;Ham, Sangin;Kim, Kapsoon
    • Journal of Korean Society on Water Environment
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    • v.28 no.4
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    • pp.595-600
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    • 2012
  • This study is to assess the application of SWAT-CUP(Soil and Water Assessment Tool-Calibration Uncertainty Programs) and to extend daily flow data from 8-day interval flow data which has been measured by Korean Ministry of Environment(MOE). Model sensitivity analysis and calibration were performed with sequential uncertainty fitting(SUIF-2), which is one of the programs interfaced with SWAT, in the package SWAT-CUP. The most sensitive parameters were SOL_K.sol, CH_N2.rte, CN2.mgt, SOL_BD.sol, ALPHA_BF.gw, ALPHA_BNK.rte, SOL_AWC.sol, CH_K2.rte, SFTMP.bsn, GW_DELAY.gw. Following the sensitivity analysis, SWAT-CUP calibration was carried out using 8-day interval flow data from January 2008 to December 2010. The results were then assessed based on the visual agreement and simulated flow plots and the performance statistics generated $R^2$ and NSE which are 0.71 and 0.61 respectively. Results of these statistics indicated that there was a good agreement between the observed and simulated flow. To extend daily flow data from 8-day interval flow data, parameters, which were estimated by SWAT-CUP, re-entered for SWAT model. As a result, the observed flow data were found to reflect the trend of simulated flow data. From these results, it is thought that this method could be used to provide daily flow data using 8-day interval flow data.

Relationship between porcine carcass grades and estimated traits based on conventional and non-destructive inspection methods

  • Lim, Seok-Won;Hwang, Doyon;Kim, Sangwook;Kim, Jun-Mo
    • Journal of Animal Science and Technology
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    • v.64 no.1
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    • pp.155-165
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    • 2022
  • As pork consumption increases, rapid and accurate determination of porcine carcass grades at abattoirs has become important. Non-destructive, automated inspection methods have improved slaughter efficiency in abattoirs. Furthermore, the development of a calibration equation suitable for non-destructive inspection of domestic pig breeds may lead to rapid determination of pig carcass and more objective pork grading judgement. In order to increase the efficiency of pig slaughter, the correct estimation of the automated-method that can accommodate the existing pig carcass judgement should be made. In this study, the previously developed calibration equation was verified to confirm whether the estimated traits accord with the actual measured traits of pig carcass. A total of 1,069,019 pigs, to which the developed calibration equation, was applied were used in the study and the optimal estimated regression equation for actual measured two traits (backfat thickness and hot carcass weight) was proposed using the estimated traits. The accuracy of backfat thickness and hot carcass weight traits in the estimated regression models through stepwise regression analysis was 0.840 (R2) and 0.980 (R2), respectively. By comparing the actually measured traits with the estimated traits, we proposed optimal estimated regression equation for the two measured traits, which we expect will be a cornerstone for the Korean porcine carcass grading system.