• 제목/요약/키워드: kinetic modeling

검색결과 262건 처리시간 0.028초

계단형 보에서의 파형 난류 흐름 수치모의 (Numerical Modeling of Wave-Type Turbulent Flow on a Stepped Weir)

  • 백중철;이남주;윤영호
    • 대한토목학회논문집
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    • 제37권3호
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    • pp.575-583
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    • 2017
  • 계단형 보와 여수로 같은 수공구조물의 상부에서는 스키밍 흐름 그리고 직하류부에서는 정상파를 포함하는 도수 현상인 파형흐름과 같이 다양한 형태의 흐름이 발생한다. 연구에서는 하이브리드 RANS-LES 난류 모델링 기법과 자유수면 변동을 해석하기 위한 VOF (volume of fluid)기법을 병합한 3차원 부정류 수치모형을 이용하여 계단형 보가 설치된 사각형 개수로에서 발생하는 파형흐름과 스키밍 흐름을 포함하는 난류흐름을 수치모의 하였다. 시간평균 수치모의 결과와 기존 수리모형 실험 결과를 비교분석한 결과, 수치모의는 보 하류부에서의 평균유속분포의 변화, 정체파와 수면와류를 포함하는 파형흐름의 전반적인 수면 변화, 파형흐름의 파고와 길이, 정체파 하부에서 발생하는 재순환 흐름 영역의 길이 등을 양호하게 잘 재현하는 것으로 나타났다. 수치모의를 통해서 자유수면과 순간 유속 벡터의 변동, 전단응력과 난류에너지의 분포 그리고 3차원 난류조직구조와 총압력분포의 형태와 변동 자료를 제시하여 스키밍 흐름과 파형흐름 영역에서의 독특한 흐름 거동 특성을 규명하였다.

Kinetic analysis of 64Cu-NODAGA-gluco-E[c(RGDfK)]2 for a tumor angiogenesis PET tracer

  • Choi, Jae Yong;Park, Ji-Ae;Kim, Jung Young;Lee, Ji Woong;Lee, Minkyung;Shin, Un Chol;Kang, Joo Hyun;An, Gwang Il;Lee, Kyo Chul;Ryu, Young Hoon;Kim, Kyeong Min
    • 대한방사성의약품학회지
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    • 제2권2호
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    • pp.108-112
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    • 2016
  • Molecular imaging with the radiolabeled RGD peptides for ${\alpha}_v{\beta}_3$ integrin has been an increasing interest for tumor diagnosis and the treatment monitoring. Recently, $^{64}Cu$-NODAGA-gluco-E[c(RGDfK)]$_2$ was developed for quantification of ${\alpha}_v{\beta}_3$ integrin and its biological properties was elucidated. To better understand the molecular process in vivo, we performed the kinetic analysis for the $^{64}Cu$-NODAGA-gluco-E[c(RGDfK)]$_2$. After preparation of a radiotracer, dynamic PET images were obtained in the U87MG xenograft mice for 60 min (n = 6). Binding potential values were estimated from the 3-tissue compartment model, reference Logan and simplified reference tissue model. In the early time frame (0-20 min), the liver, kidney, intestine, urinary bladder and tumor were visualized but these uptakes were diminished as time went by. The tumors showed a good contrast at 40 min after administration. $^{64}Cu$-NODAGA-gluco-E[c(RGDfK)]$_2$ showed the 2-fold uptake in the tumor compared with that in the muscle. The parametric maps for binding values also provide the higher tumor-to-background contrast than the static images. A binding value obtained from the 3-tissue compartment model was comparable to other modeling methods. From these results, we conclude that $^{64}Cu$-NODAGA-gluco-E[c(RGDfK)]$_2$ may be a promising PET radiotracer for the evaluation of angiogenesis.

유연생산 시스템 구축을 위한 공작물 자동교환 유닛의 수평 이송 기구 설계에 관한 연구(파트 2) (A Study on the Design of Horizontal Traverse Units in an Automatic Object Changer Unit to Establish a Flexible Production System (Part 2))

  • 박후명;성재경;이용중;하만경
    • 한국기계가공학회지
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    • 제7권2호
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    • pp.52-59
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    • 2008
  • The objective of this study is to develop an automatic object changer unit to improve processing problems existed in the conventional horizontal machining center. To achieve this goal, this study designed a horizontal transfer as the second project continued to the first project that designed a upward and downward traverse unit. A horizontal traverse unit shows a symmetric structure and consists of frame, which consists of four unit tools, motor and reducer, which are fixed at a frame, operation unit with pinions, first traverse unit, and second traverse unit. Constraint conditions based on the operation mechanism with these elements were configured and obtained following results after modeling a model for a traverse motor. In the kinematic expression of sliding motion with one degree of freedom, the sliding motion is constrained. Also, the rack 3 installed at a frame is used to configure possible kinematic constraint conditions of the rack 2 according to the rolling motion of the pinion 2 in the first traverse unit. In addition, the moment of inertia that is a type of kinetic energy in a converted horizontal traverse unit in the side of the reducer can be applied to introduce the moment of inertia of a converted horizontal traverse unit in the side of the reducer by using the sum of kinetic energy in the rack and pinion, which is a part of the horizontal traverse unit. Also, the equation of motion of the converted upward and downward traverse unit in the side of the motor using the equation of motion of the motor. Furthermore, the horizontal traverse unit predetermines the mass of the first and second traverse unit and applied load including the radius and reduction ratio of the pitch circle in the pinion 1 and applied load to the rack 2. Then, a proper motor can be determined using several parameters in the upward and downward traverse unit in order to verify such predetermined specifications. In future studies later this study, a simulation that verifies the results of the previous two stages of studies using a finite element method.

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Lower the Detection Limits of Accelerator Mass Spectrometry

  • ;송종한;김준곤;김재열;오종주;김종찬
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.243-244
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    • 2013
  • Over the past 15 years, several groups have incorporated radio-frequency quadrupole (RFQ) based instruments before the accelerator in accelerator mass spectrometry (AMS) systems for ion-gas interactions at low kinetic energy (<40 eV). Most AMS systems arebased on a tandem accelerator, which requires negative ions at injection. Typically, AMS sensitivity abundance ratios for radioactive-to-stable isotope are limited to Xr/Xs >10^-15, and the range of isotopes that can be analyzed is limited because of theneed to produce rather large negative ion beams and the presence of atomic isobaric interferences after stripping. The potential of using low-kinetic energy ion-gas interactions for isobar suppression before the accelerator has been demonstrated for several negative ion isobar systems with a prototype RFQ system incorporated into the AMS system at IsoTrace Laboratory, Canada (Ontario, Toronto). Requisite for any such RFQ system applied to very rare isotope analysis is large transmission of the analyte ion. This requires proper phase-space matching between the RFQ acceptance and the ion beam phase space (e.g. 35 keV, ${\varphi}3mm$, +-35 mrad), and the ability to control the average ion energy during interactions with the gas. A segmented RFQ instrument is currently being designed at Korea Institute for Science and Technology (한국과학기술연구원, KIST). It will consist of: a) an initial static voltage electrode deceleration region, to lower the ion energy from 35 keV down to <40 eV at injection into the first RFQ segment; b) the segmented quadrupole ion-gas interaction region; c) a static voltage electrode re-acceleration region for ion injection into a tandem accelerator. Design considerations and modeling will be discussed. This system should greatly lower the detection limits of the 6 MV AMS system currently being commissioned at KIST. As an example, current detection sensitivity of 41Ca/Ca is limited to the order of 10^-15 while the 41Ca/Ca abundance in modern samples is typically 41Ca/Ca~10^-14 - 10^-15. The major atomic isobaric interference in AMS is 41K. Proof-of-principal work at IsoTrace Lab. has demonstrated that a properly designed system can achieve a relative suppression of KF3-/41CaF3- >4 orders of magnitude while maintaining very high transmission of the 41CaF3- ion. This would lower the 41Ca detection limits of the KIST AMS system to at least 41Ca/Ca~10^-19. As Ca is found in bones and shells, this would potentially allow direct dating of valuable anthropological archives and archives relevant to our understanding of the most pronounced climate change events over the past million years that cannot be directly dated with the presently accessible isotopes.

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Investigation of Autoignition of Propane and n-Butane Blends Using a Rapid Compression Machine

  • Kim, Hyunguk;Yongseob Lim;Kyoungdoug Min;Lee, Daeyup
    • Journal of Mechanical Science and Technology
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    • 제16권8호
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    • pp.1127-1134
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    • 2002
  • The effects of pressure and temperature on the autoignition of propane and n-butane blends were investigated using a rapid compression machine (RCM) , which is widely used to examine the autoignition characteristics. The RCM was designed to be capable of varying the compression ratio between 5 and 20 and minimize the vortex formation on the cylinder wall using a wedge-shaped crevice. The initial temperature and pressure of the compressed gas were varied in range of 720∼900 K and 1.6∼ 1.8 MPa, respectively, by adjusting the ratio of the specific heat of the mixture by altering the ratio of the non-reactive components (N$_2$, Ar) under a constant effective equivalence ratio (ø$\_$f/= 1.0) The gas temperature after the compression stroke could be obtained from the measured time-pressure record. The results showed a two-stage ignition delay and a Negative Temperature Coefficient (NTC) behavior which were the unique characteristic of the alkane series fuels. As the propane concentration in the blend were increased from 20% and 40% propane, the autoignition delay time increased by approximately 41 % and 55% at 750 K. Numerical reduced kinetic modeling was performed using the Shell model, which introduced some important chemical ideas, represented by the generic species. Several rate coefficients were calibrated based on the experimental results to establish an autoignition model of the propane and n-butane blends. These coefficients can be used to predict the autoignition characteristics in LPG fueled Sl engines.

열/화학적 에너지 평형을 고려한 통합 연료 개질 시스템의 수치적 연구 (Numerical Analysis of Integrated Fuel Processing System Considering Thermo-Chemical Energy Balance)

  • 노정훈;정혜미;정운호;윤왕래;엄석기
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 추계학술대회 초록집
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    • pp.111.1-111.1
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    • 2010
  • This paper focuses on a systematic configuration of steam reforming fuel processor, particularly designed for small and medium sized hydrogen production application. In a typical integration of the fuel processor, there exist significant temperature gradients over the entire system which has negative effect on both catalyst life-time and system performance. Also, the volumetric inefficiency should be avoided to obtain the possible compactness for the commercial purpose. In the present work, the computational analysis will be performed to gain the fundamental insight on the transport phenomena and chemical reactions in the reformer consisting of preheating, steam reforming (SR), and water gas shift (WGS) reaction beds in the flow direction. Also, the fuel processing system includes a top-fired burner providing necessary thermal energy for endothermic catalytic reactor. A fully two-dimensional numerical modeling for a integrated fuel processing system is introduced for in-depth analysis of the heat and mass transport phenomena based on surface kinetics and catalytic process. In the model, water gas shift reaction and decomposition reaction were assumed to be at equilibrium. A kinetic model was developed and then computational results were compared with the experimental data available in the literature. Finally, the case study was done by considering the key parameters, i.e. steam to carbon (S/C) ratio and temperature. The computer-aided models developed in this study can be greatly utilized for the design of advanced fast-paced compact fuel processors research.

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폐감귤박으로 만든 활성탄을 이용한 염료 Eosin Y 흡착에서 반응표면 모델링 (Response Surface Modeling for the Adsorption of Dye Eosin Y by Activated Carbon Prepared from Waste Citrus Peel)

  • 감상규;이민규
    • 공업화학
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    • 제29권3호
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    • pp.270-277
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    • 2018
  • 반응 표면법(RSM)과 Box-Behnken 설계(BBD) 통계 방법을 사용하여 폐감귤박으로 만든 활성탄(WCAC)에 의한 염료 Eosin Y의 흡착을 검토하였다. 실험은 Eosin Y의 농도(Conc. : 30~50 mg/L), 용액 온도(Temp. : 293~313 K) 및 흡착제 투여량(Dose : 0.05~0.150 g/L)의 3가지 입력 변수를 가진 BBD에 따라 수행하였다. 염료 Eosin Y 제거에 대해 얻어진 2차 다항식 모델의 회귀분석 결정계수($R^2$) 값이 0.9851이고 적합성 결여(Lack of fit)의 p 값은 0.342로 실험 데이터는 2차 다항식 모델에 잘 부합하였다. 염료 농도 50 mg/L, 온도 333 K 및 흡착제 투여량 0.1056 g에서 최적 염료 흡착량 59.3 mg/g이 얻어졌다. WCAC에 의한 Eosin Y의 흡착공정은 유사 2차 속도식에 의해 잘 기술되었으며, 등온 실험결과는 Langmuir 모델식을 따랐다.

GT-POWERTM를 이용한 Lean NOx Trap 촉매 성능 모델링 (A Performance Modeling of the Lean NOx Trap Catalyst with GT-POWERTM)

  • 김현준;한만배;전지용;김태민
    • 한국자동차공학회논문집
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    • 제21권6호
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    • pp.64-71
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    • 2013
  • In this study we designed a lean $NO_x$ trap (LNT) model with $GT-POWER^{TM}$ program and then the LNT model was compared to the bench flow reactor test results. This model consists of 9 kinetic reactions to represent the main steps of NO oxidation, $NO_x$ adsorption, $NO_x$ release and then its reduction. The comparison was performed on the operating conditions at the space velocity of 50,000 1/hr and 80,000 1/hr with the temperature range of $200^{\circ}C{\sim}500^{\circ}C$ with the even spaced temperature step of $50^{\circ}C$. The experimental results show that the $NO_x$ conversion efficiency was enhanced by the temperature up to $350^{\circ}C$ and then decayed at higher temperatures. The LNT model predicts the similar trend of the $NO_x$ conversion efficiency to the experimental results below $350^{\circ}C$, but overestimates above $350^{\circ}C$. This overestimation comes from the higher reduction efficiency which was obtained by the different reduction gas composition such as $C_3H_6$ in the model to replace $CH_4$, $C_2H_4$ in the bench test.

Multi-zone 모델링을 통한 온도성층화와 농도성층화가 존재하는 DME HCCI 엔진의 운전영역에 관한 수치해석연구 (Comparison of DME HCCI Operating Ranges for the Thermal Stratification and Fuel Stratification based on a Multi-zone Modeling)

  • 정동원;임옥택
    • 한국자동차공학회논문집
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    • 제19권2호
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    • pp.35-41
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    • 2011
  • This work investigates the potential of in-cylinder thermal stratification and fuel stratification for extending the operating ranges in HCCI engines, and the coupling between thermal stratification and fuel stratification. Computational results areemployed. The computations were conducted using both a custom multi-zone version and the standard single-zone version of the Senkin application of the CHEMKINII kinetics rate code, and kinetic mechanism for di-methyl ether (DME). This study shows that the potential of thermal stratification and fuels stratification for extending the high-load operating limit by a staged combustion event with reduced pressure-rise rates is very large. It was also found that those stratification offers good potential to extend low-load limit by a same mechanism in high-load. However, a combination of thermal stratification and fuel stratification is not more effective than above stratification techniques for extending the operating ranges showing similar results of fuel stratification. Sufficient condition for combustion (enough temperature for) turns misfire in low-load limit to operate engines, which also leads to knock in high-load limit abruptly due to the too high temperature with high. DME shows a potential for maximizing effect of stratification to lower pressure-rise rate due to the characteristics of low-temperature heat release.

도시 브랜드 이미지가 도시 브랜드 인지도와 도시 충성도에 미치는 영향 (The Effects of City Brand Image on City Brand Recognition and City Loyalty)

  • 김도헌
    • 산경연구논집
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    • 제9권3호
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    • pp.69-79
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    • 2018
  • Purpose - Competition among cities around the world are rapidly shifting from competition of production factors such as labor costs and quality of raw materials to competition between the consumption factors such as quality of life, settlement environment, culture, and place. The entry into the era of competition between consumption factors is not only attracting investment for strengthening city competitiveness, but also actively inducing urban image reconstruction and new image making. Therefore, various studies related to urban marketing are being carried out. The object of this study is to investigate the effect of city brand image on city brand recognition and city loyalty based on the questionnaire of external citizens about Changwon city. Research design, data, and methodology - The data were collected from 200 Seoul and Busan citizens. Reliability and exploratory factor analysis were conducted through the SPSS program, and confirmatory factor analysis and structural equation modeling were conducted by using the AMOS program. Results - As a result of the hypothesis test, six hypotheses were adopted among the nine hypotheses. In summary, pleasant image, dynamic image, and good administrative image have a significant positive impact on city brand recognition. The magnanimous image did not have a significant effect on city brand recognition. In the impact of city brand image on city loyalty, magnanimous image and good administrative image had significant positive impact on city loyalty. Pleasant images and dynamic images did not significantly affect city loyalty. In addition, city brand recognition positively influenced city loyalty. Conclusions - First, it is possible to say that there is an academic significance of this research in its contribution to regional revitalization by investigating mutual influences in urban aspect by combining place marketing with image, recognition, and loyalty. Secondly, kinetic images such as pleasant image and dynamic image have more influence on recognition, and static images such as magnanimous images have more influence on loyalty. So, further research will be necessary to establish theories. Finally, In order to increase city brand recognition and city loyalty to local city, efforts should be made to improve urban images such as pleasant image, magnanimous image, dynamic image, and good administrative image.