• Bulletin of the Korean Chemical Society
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• v.35 no.9
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• pp.2673-2678
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• 2014

The detailed mechanisms of the efficient $\small{L}$-proline and pyrrolidine catalyzed transamidation of acetamide with benzylamine have been investigated using density functional theory (DFT) calculations. Our calculated results show: (1) the mechanisms of two catalytic cycle reactions are similar. However, the rate-determining steps of their reactions are different for the whole catalytic process. One is the intramolecular nucleophilic addition reaction of 1-COM, the other is hydrolysis reaction of 2-C. (2) COOH group of $\small{L}$-proline is essential for efficient transamidation. The computational results are in good agreement with the experiment finding and mechanism resported by Rao et al. for $\small{L}$-proline-catalyzed synthesis of amidesin good to excellent yields.

• Journal of the Institute of Electronics Engineers of Korea SD
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• v.38 no.5
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• pp.338-346
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• 2001

An infrared imaging method in which direct measurement of energy gap variations can be achieved by digital image processing is proposed. This method allows economic and easy evaluation of the temperature coefficients of a semiconductor energy gap. The key components of the method are a polychromator, a computer equipped with a frame grabber and a variable temperature cryostat. Tentative experimentation conducted on LEC grown semi-insulating GaAs has resulted in a fairly good agreement with the theoretical model. This proposed method could be applicable for most compound semiconductors.

• KCI Concrete Journal
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• v.13 no.2
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• pp.19-25
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• 2001

A simple expression to predict bond strength of reinforcing bars with rib deformation to the surrounding is derived for the case of splitting bond failure. Finite element analysis is used to model the confining behavior of concrete cover. The roles of the interfacial properties, specifically, the friction coefficient, cohesion, the relative rib area and the rib face angle are examined. Values of bond strength obtained using the analytical model are in good agreement with the bond test results from the previous studies. The analytical model provides insight into interfacial bond mechanisms and the effects of the key variables on the bond strength of deformed bars to concrete. Based on the comparison between the analytical results and the test results, the values of cohesion, coefficient of friction, and the effective rib face angle are proposed.

• Journal of Ocean Engineering and Technology
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• v.23 no.3
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• pp.14-19
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• 2009

The present study developed a model to estimate the light weight of an ultra-large container ship. The weight estimation model utilized container ship data obtained from shipyards and the subdivided this weight data into appropriate weight groups. Parameters potentially affecting the group weight were selected and expanded based on experience for weight estimation, and a correlation analysis was performed by the SPSS program to determine the key parameters characterizing the group weight. A weight estimation model applying the multi-regression analysis was proposed to assess the weight of an ultra-large container ship at the preliminary design stage, and the results obtained by the suggested method showed good agreement with the shipyard data.

• Culinary science and hospitality research
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• v.11 no.4 s.27
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• pp.118-133
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• 2005

In the management activities of head office in supporting franchisees in domestic food-service enterprises, the raw material supply plays a positive role to support franchisees' operation activity and it comes into conflict with them at the same time. In this paper, I have tried to find out the relationship between raw material supplying and the satisfaction of the franchisees by experimental research in order to research the route of head office's raw material supplying. To sum up the results, it was found out there is no meaningful relationship between the raw material supplying and the franchisees satisfaction (intention to renew the agreement), It indicates it would be more effective for the franchisees to buy the raw materials from the suppliers developed by the franchisees except some key materials in order to reduce the conflicts with the franchisees.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2005.04a
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• pp.134-136
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• 2005

Homogenization method is adopted to predict the permeability tenor for glass fiber plain woven fabrics. Calculating the permeability tensor numerically is an encouraging task because the permeability tensor is a key parameter in resin transfer molding (RTM). Based on multi-scale approach of the homogenization method, the permeability for the micro-unit cell within fiber tow is computed and compared with that obtained from flow analysis for the same micro-unit cell. It is found that they are in good agreement. In order to calculate the permeability tensor of macro-unit cell for the plain woven fabrics, the Stokes and Brinkman equations which describe inter-tow and intra-tow flow respectively are employed as governing equations. The effective permeabilities homogenized by considering intra-tow flow are compared with those obtained experimentally. Control volume finite element method (CVFEM) is used as a numerical method. It is shown that the asymptotic expansion homogenization method is an attractive method to predict the effective permeability for heterogeneous media.

• Proceedings of the KSME Conference
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• 2004.11a
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• pp.1418-1423
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• 2004

A parametric study on the interactions of two spheres aligned in the streamwise direction is carried out using an immersed boundary method. The numerical results for the case of single sphere for the range of Re ${\leq}$ 300 are in good agreement with other authors' experimental and numerical results currently available. Then, our main investigation is focused on identifying the change of the vortical structures in the presence of a nearby sphere aligned in the streamwise direction for the range Re ${\leq}$ 220. It turns out that significant changes in physical characteristics are noticed depending on how close the two spheres are. In this paper, not only quantitative changes in the key physical parameters such as the force coefficients, but also qualitative changes in vortex structures are reported and analyzed.

• Proceedings of the Korean Society of Broadcast Engineers Conference
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• 2007.02a
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• pp.169-172
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• 2007

최근 DMB 서비스와 같이 저 전력 무선 환경에서 유료 콘텐츠 서비스가 활발히 이루어지고 있다. 이러한 콘텐츠 서비스를 정당한 서비스 수신자에게 제공하기 위해서는 서비스 제공자와 수신자 사이에 안전한 키 교환이 필요하다. 본 논문에서는 모바일 콘텐츠 서비스를 위한 효율적 인 ID-기반의 그룹 키 교환, 즉 다수의 서비스 수신자들(클라이언트)과 서비스 제공자(서버) 사이의 인증된 동적 그룹 키 교환 프로토콜을 제안한다 제안한 프로토콜은 클라이언트의 계산량이 낮아 저 전력 모바일 환경에 적합하며, 또한 가입과 탈퇴 발생 시에도 효율적으로 키 교환을 수행할 수 있다. 제안한 그룹 키 교환 프로토콜은 랜덤 오라클 모델에서 그 안전성을 제공한다.

• Proceedings of the Korea Institutes of Information Security and Cryptology Conference
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• 2006.06a
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• pp.506-510
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• 2006

3G 이동통신기술중 하나인 UMTS(Universal Mobile Telecommunications System)에서는 무선 구간의 안전한 통신을 위해 UMTS-AKA(Authentication and Key Agreement) 프로토콜이 사용된다. 그러나 SN(Serving Network)과 HN(Home Network)의 통신량 소비 문제, SQN(SeQuence Number) 동기화 문제 등 여러 가지 문제점이 제기되었다. 본 논문에서는 기존 프로토콜의 문제점과 IMSI(International Mobile Subscriber Identity)의 노출로 인한 프라이버시 문제점을 해결하고, ECDH(Elliptic Curve Diffie Hellman) 기법으로 완전한 전방향 안전성을 제공하는 프로토콜을 제안한다.

• Proceedings of the Korea Institutes of Information Security and Cryptology Conference
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• 2006.06a
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• pp.661-664
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• 2006

무선 이동 Ad hoc 네트워크는 고정된 인프라의 도움 없이 이동 노드들의 협력에 의해 자율적으로 구성되는 독립적이고 융통성 있는 네트워크이다. 최근 상업적인 분야에서도 Ad hoc 네트워크의 응용에 대한 관심이 급증하면서 Ad hoc 네트워크의 보안 문제도 해결되어야 할 기술적 요구사항으로 대두되고 있다. 특히, 이러한 요구사항을 만족시키기 위해 Ad hoc 네트워크상에서 공개키 기반구조(PKI)를 도입하는 것은 고정된 인프라를 사용하지 않는 애드혹 네트워크 특성상 매우 제한적인 기법이다. 또한 password를 기반으로 하는 인증된 키교환을 하기위해서는 모든 사용자가 사전에 password를 공유를 해야 하는 불편함이 있다. 본 논문에서는 인증을 위한 제 3의 신뢰기관이나, 사전 비밀 공유가 필요 없는 인증된 키교환 프로토콜을 제안한다.