• Journal of the Korean Society of Groundwater Environment
• /
• v.4 no.4
• /
• pp.199-211
• /
• 1997

As a part of study on geological disposal of radioactive waste, hydrogeochemical characteristics of deep granitic groundwater in Korea were investigated through the construction of a large geochemical dataset of natural water, the examination on the behaviour of dissolved constituents, and the consideration of phase stability based on thermodynamic approach. In granitic region, the contents of total dissolved solids increase progressively from surface waters to deep groundwaters, which indicates the presence of more concentrated waters at depth due to water-rock interaction. The chemical composition of groundwater evolves from initial $Ca^{2＋}$－(C $l^{－}$＋S $O_4$$^{2-}$) or $Ca^{2＋}$-HC $O_3$$^{－}$ type to final N $a^{＋}$-HC $O_3$$^{－}$ or N $a^{＋}$－(C $l^{－}$＋S $O_4$$^{2-}$) type, via $Ca^{2＋}$-HC $O_3$$^{－}$ type. Three main mechanisms seem to control the chemical composition of groundwater in the granitic region; 1) congruent dissolution of calcite at shallower depth, 2) calcite precipitation and incongruent dissolution of plagioclase at deeper depth, and 3) kaolinite-smectite or/and kaolinite-illite reaction at equilibrium at deeper depth. The behaviour of dissolved major cations (C $a^{2＋}$, $K^{＋}$, $Mg^{2＋}$, M $a^{＋}$) and silica is likely to be controlled by these reactions.

• Korean Journal of Fisheries and Aquatic Sciences
• /
• v.21 no.4
• /
• pp.246-258
• /
• 1988

Semi-quantitative analysis of $less-than-2{\mu}m$ clay minerals in thirty-nine superficial sediments from the Chinju Bay, southern coast of Korea, was made to reveal the distribution, provenance and dispersal pattern of fine-grained sediments. Additional nine samples were also taken from the Choryang Cheon (a river draining the kaolin-rich Hadong area) to investigate the influence of river a discharge. Grain size analysis for the Chinju Bay sediment samples was performed simultaneously as an aid to understand the sediment types and depositional environments. Except for the northeastern part, clayey mud predominates the entire bay. Average relative abundance of the four major clay minerals, I. I., illite, kaolinite, chlorite and smectite, is $55.1\%,\;23\%,\;21.5\%\;and\;0.4\%$, respectively. Although illite dominant clay mineral, the average content is about $10\~20\%$ tourer than that of the nearby continental shelf area. On the contrary, kaolinite content in the bay is about $10\%$ higher than that of the shelf area. Recent clay minerals of the Chinju Bay are mainly derived from the nearby inland area through numerous rivers and streams. Transport from shelf area, however. also seems to be important.

• Korean Journal of Fisheries and Aquatic Sciences
• /
• v.23 no.2
• /
• pp.145-154
• /
• 1990

Amounts of total suspended matter(TSM) around the Kori waters have been monitored for two years to understand the dispersal pattern of fine-grained sediment. Average concentration of the TSM is $3\~4\;mg/\iota$ in the surface and $3.5\~5\;mg/\iota$ in the near-bottom water. Semi-quantitative analysis for the four major clay minerals in TSM is also performed. The average relative abundance of each clay mineral such as illite, kaolinite, chlorite, and smectite is $65\%,\;17\%,\;17\%$, and $1\%$, respectively. It seems that the majority of recent fine-grained sediment deposited around the Kori area is derived from the Nakdong River. The texture of surface sediment is also dominated by fine-grained fraction leading up to $90\%$ of silt and clay content. The grain size decreases seaward progressively.

• Journal of the Mineralogical Society of Korea
• /
• v.7 no.1
• /
• pp.49-61
• /
• 1994

As the groundwater flows along the fractures of crystalline rocks, it will be in contact with the fracture walls mostly coated by secondary minerals which are quite different form those of host rocks. The presence of fracture-filling minerals in crystalline rocks is important on the view point of radioactive waste disposal because of their great surface reactivity. The Surichi drill hole of 200 m in depth in the Yugu area composed mainly of Precambrian gneiss was selected to study the formation process of clay minerals on the fracture wall of gneiss, and their relation with present groundwater. The water-rock interaction in fractures resulted in the formation of gibbsite and clay minerals. They are formed by two different processes : (1) Incongruent dissolution of feldspar by groundwater diffused from a fracture path into rock matrix produced smectite and illite in situ, (2) on the wall of fracture, gibbsite, kaolinite, smectite and illite are formed by precipitation of dissolved species in groundwater. They show the paragenetic sequence such as gibbsite${\leftrightarrow}$kaolinite${\leftrightarrow}$smectite or illite. The paragenetic sequence of fracture-filling minerals was controlled by increase of pH of groundwater, decrease of fracture permeability by precipitation of fillings, and immobility of alkali or alkaline earths in groundwater. The groundwater from the Surichi borehole is a $Na-HCO_{3}$ type with pH range of 8.6-9.2. The sodium and bicarbonate in groundwater would be supplied by the dissolution of albite and calcite, respectively. The saturation index of groundwater and surface water calculated by WATEQ4F indicates that gibbsite and kaolinite are under precipitation to equilibrium state, and that smectite and illite are under equilibrium to redissolution environment. The stability relation of clay minerals in the $Na_{2}O-Al_{2}O_{3}-SiO_{2}-H_{2}O$ system shows that kaolinite is stable for all waters.

• 한국석유지질학회:학술대회논문집
• /
• spring
• /
• pp.48-55
• /
• 1998

The Pohang Basin is located in Pohang City and adjacent coastal areas in the southeastern Korea. It has a sequence of 900 meters of Neogene marine sediments (Yeonil Group) while offshore basins in the East Sea, e.g., the Ulleng basin, is over 10 Km in thickness. An understanding of the marine Yeonil Group in the Pohang Basin may provide insights into the hydrocarbon potential of the offshore East Sea regions. Heulandite, smectite, dolomite, kaolinite and opal-CT are commonly found as diagenetic minerals in the Yeonil Group. Among these minerals, heulandite occurs as a main cement only in sandstones consisting of volcanic matrix, Smectite composition and diagenetic mineral facies such as heulandite and opal-CT may reflect that the Yeonil Group has undergone shallow burial, temperatures below about 60 degrees. This suggest that sandstones have experiened weak diagenetic alteration. In order to reconstruct the thermal history of the basin, apatite fission-track analysis was carried out. Aapparent apatite fission-track ages (AFTAs) exhibit a broader range of ages from 238 Ma to 27 Ma with mean track lengths in the range of $15.24\pm8.0$ micrometers, indicating that these samples had undergone significant predepositional thermal alteration. The Triassic to Cretaceous AFTAs seem In represent the timing of cooling of their sedimentary sources. Late Cretaceous mean AFTA $(79.0\pm8.0 Ma)$ on the Neogene Yeonil Group indicates that the Yeonil Group had not been buried deeper than 2km since its deposition. The organic matters of. the Pohang Basin remain in the immature stage of thermal evolution because burial depth and temperature were not sufficient enough for maturation even in the deep section of the basin.

• Korean Journal of Soil Science and Fertilizer
• /
• v.31
• /
• pp.36-44
• /
• 1998

우리 나라에서 토양의 점토광물에 관한 최초의 연구는 1958년 김제지방의 답 토양에 관한 연구로 (Dewan, 1958)시작되었다. 1960년대 시작하여 1970년대 까지는 주로 토양점토광물의 동정이 이루어 졌다. 점토광물의 동정(同定)에 사용된 잔적토(殘積土)(Residual Soil)로는 화강암(花崗岩), 화강편마암(花崗片麻岩), 현무암(玄武岩), 석회암(石灰岩), 혈암(頁岩), 제(第)3기층(紀層), 홍적층(洪積層) 유래 토양과 토양종류별(土壤種類別)로는 과부식회색토(寡腐植灰色土), 염류토(鹽類土), 충적토(沖積土), 적황색토(赤黃色土), 화산회토(火山灰土), 퇴적토(堆積土), 갈색토(褐色土), 암쇄토(岩碎土), 저위생산답(低位生産畓)이였으며, 토양점토광물(土壤粘土鑛物)과 작물수량성(作物收量性) 관계에 관한 연구가 실시되었다. 1980년대에 들어와서는 토양중의 1차광물과 점토광물의 풍화에 대한 안정도와 1차광물의 동정이 행해졌으며, 이밖에 Kaolinite 입자의 전하에 관한 연구등 점토광물의 흡착과 활성 연구, 점토광물의 토양개량재로서의 흡착과 화학적 특성 변화 연구와 점토광물의 토양개량 시용효과에 관한 연구가 행해졌다. 1990년대에 들어와서는 토양 중의 1차광물과 점토광물의 정량에 대한 자료가 축척되었고, 토양의 풍화에 대한 안정성과 생성기작, Zeolite와 새로운 광물이 합성되었다. 또한 합성광물을 이용한 농업과 산업광물로의 응용성 환경 산업에서의 적용가능성에 대한 평가가 시도되었다. 토양의 점토광물의 조성에 관한 연구는 토양 모재를 중심으로 이루어졌는데, 화강암(花崗岩)에서는 Halloysite, 화강편마암(花崗片麻岩)에서는 Kaolinite, Metahalloysite, Illite, 산성암(酸性岩)에서는 Kaolinite, Venrmiculite와 Chlorite의 중간광물, 현무암(玄武岩)에서는 Illite, Kaolinite, Vermiculite, 석회암(石灰岩)에서는 Vermiculite-Chlorite 중간광물, Kaolinite와 Illite, 혈암(頁岩)에서는 Kaolinite, Halloysite, Illite 외 Vermiculite-Chlorite, 화산회토(火山灰土)에서는 Allophane이 주광물이었다. Soil Taxonomy와 토양광물과의 관계에서, 답 토양에서는 Entisols의 주점토광물은 2:1형과 1:1형 광물이지만 Inceptisols와 Alfisols에서는 Halloysite가 대부분이다. 밭 토양의 경우는 Alfisols의 주점토광물은 Vermiculite, Illite, Kaolinite이었고, Ultisols에서는 Vermiculite-Chlorite 중간광물이었다. 산림토양에서는 Inceptisols중에서 Andept는 Allophane, Alfisols에서는 2:1 광물이지만, Ultisols에서는 Halloysite이다. 모재별 조암 광물의 풍화와 점토광물의 생성과정에서 화강암(花崗岩)과 화강편마암(花崗片麻岩)의 장석류(長石類)는 kaoline광물로, 이 밖의 운모광물(雲母鑛物), 녹니석(綠泥石), 각섬석(角閃石), 휘석(輝石)으로부터 생성된 illite, chlorite, vermiculite는 풍화중간에 혼층단계(混層段階)를 거쳐서 kaoline 광물로 풍화된다. 석회암(石灰岩) 토양의 smectite가 Mg농도가 높은 토양용액으로부터 침전되어 생성되었거나 운모 또는 chlorite에서 유래된 vermiculite의 변성작용에 의해 생성되고, 혈암(頁岩)토양의 점토에 illite가 주로 풍화에 저항성이 큰 미립자의 함수백운모(含水白雲母)로부터 유래되며, 현무암(玄武岩) 중의 장석류(長石類)는 kaoline광물로, 휘석(輝石)은 chlorite${\rightarrow}$illite의 풍화과정을 거친다. Zeolite, 함불석 Bentonite, Bentonite 등 우량점토 광물이 분포과 광물조성, 이화학적 특성이 조사되었고, 토양의 물리적, 화학적 성질의 개선을 필요로 하는 토양의 개량을 위해서 Bentonite, Zeolite, Vermiculite 등의 토양 개량재(改良材)로서의 기초연구와 이들 개량재 시용효과에 관한 연구 등이 주로 논토양에서 수행되었다. 점토광물과 수량관계를 보면 Montmorillonite를 주점토광물로 함유된 답 토양의 수도수량이 1:1 광물을 주점토광물로 함유하고 있는 토양에서의 수도수량 보다 높았다. 토양광물에 관한 기초연구(基礎硏究)로서 양이온교환능과 포화이온의 영향, 입자의 전기화학적 성질, 흡탈착 성질, 표면적과 등전점, 해성점토에 대한 압밀점토(壓密粘土)의 변형율(變形率)의 추정 등이 주로 연구되었다. 부가가치가 낮거나 폐기되는 광물을 이용하여 토양개량재 혹은 흡착제를 형성하는 연구가 알카리 처리에 의한 Zeolite 합성에 집중되었다.

• Korean Journal of Mineralogy and Petrology
• /
• v.33 no.3
• /
• pp.175-183
• /
• 2020

There have rarely been performed for the clay mineralogy of the East Sea sediments except for few studies about paleoenvironmental aspect. This study inferred the provenance of sediments based on the clay mineral characteristics and distribution pattern for the 120 sediment samples collected by the box corer from the Gangneung-Donghae area between 2017-2019. The relative proportions of the four major clay minerals are abundant in the order of illite, chlorite, kaolinite, and smectite. The continental shelf sediments below water depth 150 m have more chlorite and kaolinite content and better illite crystallinity, but less illite and smectite content, and S/I index than those of continental slope sediments. Clay mineral composition of the continental shelf sediments are influenced by the adjacent continental geology, because north site (Gangneung area) has more chlorite but south site (Donghae area) has more kaolinite. These characteristics and distribution pattern of clay minerals indicate that the provenance of sediments are different between continental shelf and continental slop. The continental shelf sediments may be introduced the study area by the adjacent small rivers whereas the continental slope sediment might be supplied by current from the south of the study area.

• Journal of the Mineralogical Society of Korea
• /
• v.18 no.2
• /
• pp.135-144
• /
• 2005

In the high-Ca limestone zone of the Pungchon Formation of the Lower Chosun Supergroup, cryptocrystalline alterations with reddish brown color occur as fissure-fillings or coatings, which was originated from the upper formation, i. e., the Hwajeol Formation. The precipitates result in degradation and contamination of the high-Ca limestone ore in grade and quality, showing characteristic occurrence and mineral composition typical of suggesting a supergene origin. Chalcedonic quartz, kaolinite, illite, goethite and hematite are constituting a characteristic authigenic mineral assemblage and, in places, smectite is less commonly included in the weathering product. In addition to these authigenic phases, some detrital minerals such as mica and orthoclase constituting relatively coarser grains are also rarely present in the supergene alterations. A rather complex clay facies consisting of kaolinite, illite and smectite in the alterations seems to correspond to the typical clay composition of the reported residual pedogenic soils by limestone weathering. The cryptocrystalline weathering product is partly altered to stilbite, a characteristic hydrothermal zeolite, in places, by the hydrothermal contact of late stage. The time of formation and infiltration of the supergene alterations seems to correspond to the stage just after the epithermal alteration of the Pungchon Limestone, i. e., an early Jurassic age. The supergene alteration, which may imply the stage of uplifting, weathering and erosion of the Chosun Supergroup, appears to have undergone at an oxygen-rich environment in descending water of meteoric origin by means of a chemical leaching and diffusion.

• Journal of the Mineralogical Society of Korea
• /
• v.32 no.3
• /
• pp.173-184
• /
• 2019

Variations in grain size distribution and clay mineral assemblage are closely related to the sedimentary facies that reflect depositional conditions during the glacial and interglacial periods. Gravity cores BS17-GC15 and BS17-GC04 were collected from the continental shelf and rise in the eastern Bellingshausen Sea during a cruise of the ANA07D Cruise Expedition by the Korea Polar Research Institute in 2017. Core sediments in BS17-GC15 consisted of subglacial diamicton, gravelly muddy sand, and bioturbated diatom-bearing mud from the bottom to the top sediments. Core sediments in BS17-GC04 comprised silty mud with turbidites, brownish structureless mud, laminated mud, and brownish silty bioturbated diatom-bearing mud from the bottom to the top sediments. The clay mineral assemblages in the two core sediments mainly consisted of smectite, chlorite, illite, and kaolinite. The clay mineral contents in core GC15 showed a variation in illite from 28.4 % to 44.5 % in down-core changes. Smectite contents varied from 31.1 % in the glacial period to 20 % in the deglacial period and 25.1 % in the interglacial period. Chlorite and kaolinite contents decreased from 40.5 % in the glacial period to 30.3 % in the interglacial period. The high contents of illite and chlorite indicated a terrigenous detritus supply from the bedrocks of the Antarctic Peninsula. Core GC04 from the continental rise showed a decrease in the average smectite content from 47.2 % in the glacial period to 20.6 % in the interglacial period, while the illite contents increased from the 21.3 % to 43.2 % from the glacial to the interglacial period. The high smectite contents in core GC04 during the glacial period may be supplied from Peter I Island, which has a known smectite-rich sediment contributed by Antarctic Circumpolar Currents. Conversely, the decrease in smectite and increase in chlorite and illite contents during the interglacial period was likely caused by a higher supply of chlorite- and illite-enriched sediment from the eastern Bellingshausen Sea shelf by the southwestward flowing contour current.

• Proceedings of the Mineralogical Society of Korea Conference
• /
• 2003.05a
• /
• pp.66-66
• /
• 2003

King George island, Antarctica, is mostly covered by ice sheet and glaciers, but the land area is focally exposed for several thousand years after deglaciation. For a mineralogical study of chemical weathering in the polar environment, glacial debris was sampled at the well-developed patterned ground which was formed by long periglaclal process. As fresh equivalents, recently exposed tills were sampled at the base of ice cliff of outlet glaciers and at the melting margin of ice cap together with fresh bedrock samples. Fresh tills are mostly composed of quartz, plagioclase, chlorite, and illite, but those derived from hydrothermal alteration zone contain smectite and illite-smectite. In bedrocks, chlorite was the major clay minerals in most samples with minor illite near hydrothermal alteration zone and interstratified chlorite-smectite in some samples. Smectite closely associated with eolian volcanic glass was assigned to alteration in their source region. Blocks with rough surface due to chemical disintegration showed weathering rinds of several millimeter thick. Comparision between inner fresh and outer altered zones did not show notable change in clay mineralogy except dissolution of calcite and some plagioclase. Most significant weathering was observed in the biotite flakes, eolian volcanic glass, sulfides, and carbonates in the debris. Biotite flakes derived from granodiorite were altered to hydrobiotite and vermiculite of yellow brown color. Minor epitactic kaolinite and gibbsite were formed in the cleaved flakes of weathered biotite. Pyrite was replaced by iron oxides. Calcite was congruently dissolved. Volcanic glass of basaltic andesite composition showed alteration rim of several micrometer thick or completely dissolved leaving mesh of plagioclase laths. In the alteration rim, Si, Na, Mg, and Ca were depleted, whereas Al, Ti, and Fe were relatively enriched. Mineralization of lichen and moss debris is of much interest. They are rich of A3 and Si roughly in the ratio of 2:1 to 3:1 typical of allophane. In some case, Fe and Ti are enriched in addition to Al and Si. Transmission electron microscopy of the samples rich of volcanic glass showed abundant amorphous aluminosilicates, which are interpreted as allophane. Chemical weathering in the King George Island is dominated by the leaching of primary phyllosilicates, carbonates, eolian volcanic glass, and minor sulfides. Authigenesls of clay minerals is less active. Absence of a positive evidence of significant authigenic smectite formation suggests that its contribution to the clay mineralogy of marine sediments are doubtful even near the maritime Antarctica undergoing a more rapid and intenser chemical weathering under more humid and milder climate.