• 공업화학
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• 제22권2호
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• pp.190-195
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• 2011

다중층을 형성하여 광자를 가두는 효과와 산란층의 효과를 보고, $TiCl_4$ 처리를 통해 전극에서의 전자의 재결합이 줄어드는 정도와 그에 따른 효과를 알아보기 위하여 여러 가지 방법으로 $TiO_2$ 전극을 형성하고, 가장 최적의 전극 조건을 알아보았다. 각 전극의 특성을 알기 위해서 I-V 곡선, UV-VIS 분광기, EIS, IPCE를 측정하였다. 그 결과, I-V 곡선을 통해 한 층 보다는 다중층이 효율이 더 높은 것을 확인할 수 있었고, 기판 표면과 전극표면에 $TiCl_4$ 처리를 함으로써 EIS분석을 통해 반응저항이 감소하여 효율이 증가함을 확인할 수 있었다. 여러 전극 조건 중 산란층을 지닌 전극이 기본 한 층을 사용한 전극의 효율보다 약 19% 정도 높아짐을 확인하였다. 이러한 효율의 증가는 장파장을 투과하는 빛이 산란층을 통과할 때 전자 이동 경로가 길어지게 되어 단락전류의 값을 증가시키기 때문이다. 이에 따라, $J_{SC}$는 약 10% 정도 증가하였으며, IPCE는 최대 피크에서 약 12%가 향상되는 특성을 보였다.

• Geomechanics and Engineering
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• 제17권4호
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• pp.333-342
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• 2019

Geological dynamic hazards during coal mining can be caused by the failure of a composite system consisting of roof rock and coal layers, subject to different loading rates due to different advancing velocities in the working face. In this paper, the uniaxial compression test simulations on the composite rock-coal layers were performed using $PFC^{2D}$ software and especially the effects of loading rate on the stress-strain behavior, strength characteristics and crack nucleation, propagation and coalescence in a composite layer were analyzed. In addition, considering the composite layer, the mechanisms for the advanced bore decompression in coal to prevent the geological dynamic hazards at a rapid advancing velocity of working face were explored. The uniaxial compressive strength and peak strain are found to increase with the increase of loading rate. After post-peak point, the stress-strain curve shows a steep stepped drop at a low loading rate, while the stress-strain curve exhibits a slowly progressive decrease at a high loading rate. The cracking mainly occurs within coal, and no apparent cracking is observed for rock. While at a high loading rate, the rock near the bedding plane is damaged by rapid crack propagation in coal. The cracking pattern is not a single shear zone, but exhibits as two simultaneously propagating shear zones in a "X" shape. Following this, the coal breaks into many pieces and the fragment size and number increase with loading rate. Whereas a low loading rate promotes the development of tensile crack, the failure pattern shows a V-shaped hybrid shear and tensile failure. The shear failure becomes dominant with an increasing loading rate. Meanwhile, with the increase of loading rate, the width of the main shear failure zone increases. Moreover, the advanced bore decompression changes the physical property and energy accumulation conditions of the composite layer, which increases the strain energy dissipation, and the occurrence possibility of geological dynamic hazards is reduced at a rapid advancing velocity of working face.

• 한국미생물·생명공학회지
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• 제20권6호
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• pp.687-692
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• 1992

혼합배양중의 각 미생물의 생균수 측정은 순수배양보다 훨씬 복잡하다. 특히 두 균주의 크기가 비슷한 경우에는 사용할 수 있는 방법이 더 제한된다. 본 연구에서는 두 균의 크기가 비슷한 경우에도 적용될 수 있는 간단한 생균수 측정방법을 개발하였다. 미생물 배양액의 산소흡수속도(OUR)는 세포수에 비례하며 이때의 비례상수인 최대 비산소흡수속도( maximum specific OUR)를 알고 있으면 배양액의 OUR을 측정함으로써 간접적으로 생균수를 구할 수 있게된다. 혼합배양의 경우 산소흡수속도는 각 미생물의 호흡속도의 합이 되며, 각 미생물의 호흡속도가 서로 다르고 또한 온도의존성이 다르다면 호흡속도의 측정을 이용하여 각 생균수를 간접적으로 측정할 수 있다.

• 한국압력기기공학회 논문집
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• 제12권1호
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• pp.62-69
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• 2016

Current guidance considers that uniaxially loaded specimen with a deep crack is used for the determination of the ductile-to-brittle transition temperature. However, reactor pressure vessel is under biaxial loading in real and the existence of deep crack is not probable through periodic in-service-inspection. The elastic stress intensity factor and the elastic-plastic J-integral which were used for crack-tip stress field and fracture mechanics assessment parameters. The difference of the loading condition and crack geometry can significantly influence on these parameters. Thus, a constraint effect caused by differences between standard specimens and a real structure can over/underestimate the fracture toughness, and it affects the results of the structural integrity assessment, consequentially. The present paper investigates the constraint effects by evaluating the master curve $T_0$ reference temperature of PCVN (Pre-cracked Charpy V-Notch) and small scale cruciform specimens which was designed to simulate biaxial loading condition with shallow crack through the fracture toughness tests and 3-dimensional elastic-plastic finite element analyses. Based on the finite element analysis results, the fracture toughness values of a small scale cruciform specimen were estimated, and the geometry-dependent factors of the cruciform specimen considered in the present study were determined. Finally, the transferability of the test results of these specimens was discussed.

• Coupled systems mechanics
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• 제4권4호
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• pp.279-295
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• 2015

The article presents a theoretical-experimental approach developed for modeling the coefficient of sliding friction in the dynamic system tool-workpiece in slide diamond burnishing of low-alloy unhardened steels. The experimental setup, implemented on conventional lathe, includes a specially designed device, with a straight cantilever beam as body. The beam is simultaneously loaded by bending (from transverse slide friction force) and compression (from longitudinal burnishing force), which is a reason for geometrical nonlinearity. A method, based on the idea of separation of the variables (time and metric) before establishing the differential equation of motion, has been applied for dynamic modeling of the beam elastic curve. Between the longitudinal (burnishing force) and transverse (slide friction force) forces exists a correlation defined by Coulomb's law of sliding friction. On this basis, an analytical relationship between the beam deflection and the sought friction coefficient has been obtained. In order to measure the deflection of the beam, strain gauges connected in a "full bridge" type of circuit are used. A flexible adhesive is selected, which provides an opportunity for dynamic measurements through the constructed measuring system. The signal is proportional to the beam deflection and is fed to the analog input of USB DAQ board, from where the signal enters in a purposely created virtual instrument which is developed by means of Labview. The basic characteristic of the virtual instrument is the ability to record and visualize in a real time the measured deflection. The signal sampling frequency is chosen in accordance with Nyquist-Shannon sampling theorem. In order to obtain a regression model of the friction coefficient with the participation of the diamond burnishing process parameters, an experimental design with 55 experimental points is synthesized. A regression analysis and analysis of variance have been carried out. The influence of the factors on the friction coefficient is established using sections of the hyper-surface of the friction coefficient model with the hyper-planes.

• Nuclear Engineering and Technology
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• 제52권5호
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• pp.1029-1035
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• 2020

The detector suffers from pulse pileup by overlapping of the signals when it was used in high radiation fields. The pulse pileup deteriorates the energy spectrum and causes count losses due to random co-incidences, which might not resolve within the resolving time of the detection system. In this study, it is aimed to propose a new pulse pileup correction method. The proposed method is to correct the start point of the pileup pulse. The parameters are obtained from the fitted exponential curve using the peak point of the previous pulse and the start point of the pileup pulse. The amplitude at the corrected start point of the pileup pulse can be estimated by the peak time of the pileup pulse. The system is composed of a NaI (Tl) scintillation crystal, a photomultiplier tube, and an oscilloscope. A 61 μCi ¹³⁷Cs check-source was placed at a distance of 3 cm, 5 cm, and 10 cm, respectively. The gamma energy spectra for the radioisotope of ¹³⁷Cs were obtained to verify the proposed method. As a result, the correction of the pulse pileup through the proposed method shows a remarkable improvement of FWHM at 662 keV by 29, 39, and 7%, respectively.

• Asian-Australasian Journal of Animal Sciences
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• 제28권6호
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• pp.807-815
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• 2015

The present study aimed at evaluating the intensity of Tifton 85 conditioning using a mower conditioner with free-swinging flail fingers and storage times on dehydration curve, fungi presence, nutritional value and in vitro digestibility of Tifton 85 bermudagrass hay dry matter (DM). The dehydration curve was determined in the whole plant for ten times until the baling. The zero time corresponded to the plant before cutting, which occurred at 11:00 and the other collections were carried out at 8:00, 10:00, 14:00, and 16:00. The experimental design was randomised blocks with two intensities of conditioning (high and low) and ten sampling times, with five replications. The high and low intensities related to adjusting the deflector plate of the free iron fingers (8 and 18 cm). In order to determine gas exchanges during Tifton 85 bermudagrass dehydration, there were evaluations of mature leaves, which were placed in the upper middle third of each branch before the cutting, at every hour for 4 hours. A portable gas analyser was used by an infrared IRGA (6400xt). The analysed variables were photosynthesis (A), stomatal conductance (gs), internal $CO_2$ concentration (Ci), transpiration (T), water use efficiency (WUE), and intrinsic water use efficiency (WUEi). In the second part of this study, the nutritional value of Tifton 85 hay was evaluated, so randomised blocks were designed in a split plot through time, with two treatments placed in the following plots: high and low intensity of cutting and five different time points as subplots: cutting (additional treatment), baling and after 30, 60, and 90 days of storage. Subsequently, fungi that were in green plants as well as hay were determined and samples were collected from the grass at the cutting period, during baling, and after 30, 60, and 90 days of storage. It was observed that Tifton 85 bermudagrass dehydration occurred within 49 hours, so this was considered the best time for drying hay. Gas exchanges were more intense before cutting, although after cutting they decreased until ceasing within 4 hours. The lowest values of acid detergent insoluble nitrogen were obtained with low conditioning intensity after 30 days of storage, 64.8 g/kg DM. The in vitro dry matter of Tifton 85 bermudagrass did not differ among the storage times or the conditioning intensities. There was no fungi present in the samples collected during the storage period up to 90 days after dehydration, with less than 30 colony forming units found on plate counting. The use of mower conditioners in different intensities of injury did not speed up the dehydration time of Tifton 85.

• 센서학회지
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• 제9권1호
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• pp.70-75
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• 2000

단결정 실리콘웨이퍼를 사용한 태양전지 제조에 있어 가장 큰 문제점은 재료의 높은 가격이다. 본 연구에서는 이러한 문제의 해결방안으로 현재 DRAM 소자 제조과정에서 폐기되는 웨이퍼를 리사이클링하여 태양전지를 제작하고 저가의 제조공정과 전지의 특성을 연구하였다. DRAM용 실리콘 웨이퍼는 비저항이 높고 두꺼워 태양전지 재료로서 부적합하나, 본 연구에서는 후면전계 (Back Surface Field) 형성, 표면 Texturing, 반사 방지막 형성 등의 공정들을 조합하여 효율향상을 위한 최적조건을 찾아내고, 두께변화에 따른 효율변화를 조사하였다. 최적화된 위의 모든 조건들을 적용하였을 때, $4\;cm^2$의 면적, $300\;{\mu}m$ 두께를 가지는 태양전지에서 단락전류밀도 ($J_{sc}$)는 $28\;mA/cm^2$, 개방전압 ($V_{oc}$) 0.51V, 충실도(Fill Factor)면에서는 0.53으로 가장 높은 값을 얻었고, 10% 이상의 효율을 확보할 수 있었다. 이와 같은 방법으로 폐기되는 실리콘 웨이퍼들을 재활용하여 실용성이 큰 저가의 단결정 실리콘 태양전지를 제작할 수 있는 방법을 확보할 수 있었다.

• 한국환경과학회지
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• 제29권10호
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• pp.989-996
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• 2020

This study was conducted to determine the effect of low temperature and low radiation conditions on the yield and quality of hot pepper at an early growth stage in Korea. In plastic greenhouses, low temperature, low temperature with covered shading treatments were set 17 to 42 days after transplanting. The pepper growing degree days decreased by 5.5% due to the low temperature during the treatment period. Radiation decreased by 74.7% due to the covered shading. After commencing treatments, pepper plant growth decreased with low temperature and low radiation. Analysis of the yield showed that the first harvest was delayed by low radiation. The cumulative yields of 119 days after transplanting were 1,956, 2,171, and 2,018 g/㎡ for control, low temperature, and low temperature with low radiation respectively. Capsaicin and dihydrocapsaicin concentrations in pepper fruit decreased with low temperature and low radiation. To investigate the photosynthetic characteristics according to the treatment, the carbon dioxide reaction curve was analyzed using the biochemical model of photosynthesis. Results showed that the maximum photosynthetic rate, V_cmax (maximum carboxylation rate), J (electric transportation rate), and TPU (triose phosphate utilization) decreased at low temperatures; the maximum photosynthetic rate, J, and g_m (dark respiration rate) were reduced by shading. These results indicate that low temperature and low radiation can retard early growth, yield, and quality, but these can also be recovered 119 days after planting. Based on the results, the yield and quality of pepper can recover from abiotic stresses with proper cultivation.

• 대한화학회지
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• 제44권5호
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• pp.453-459
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• 2000

최근 정보 표시 소자로 전계 방출 표시 소자(FED),PDP.LCD 등이 주목받고 있다. 음극선 발광 형광체는 FED뿐만 아니라 형광 표시판(VFD) 등이 중요한 핵심 소자이다. 따라서 본 연구에서는 FED에 응용 가능한 새로운 모체 탐색을 시도하였고 $LaGaO_3$모체에 $Eu^{3+}$를 첨가한 적색 형광체를 합성하여 광 특성을 분석하였다. $Eu^{3+}$의 농도에 따른 발광 스펙트럼, 여기 스펙트럼과 잔광 시간 곡선을 통해 $LaGaO_3$: $Eu^{3+}$의PL거동을 규명하였다. 잘 알려진 $Eu^{3+}$ 캐스캐이딩(cascading)과 다중 음향 양자(multiphonon emisson)에 의한 cross-relaxation은 $LaGaO_3$: $Eu^{3+}$ 형광체에서도 확인되었다. 또한, Inokutti-Hirayama식으로 부터 결정된 $Eu^{3+}$ 사이의 다중극자 상호 작용(multipolar interaction)유형은 이중 극자 상호 작용(dipole-dipole interaction)으로 밝혀졌다. 본 연구를 통해 $^5D_0$ 전이의 직접 소광 기구(direct quenching mechanism)를 새롭게 제안하였다. 소광 유형은 농도에 의존하며, 0.2몰 이하에서는 확산 율속 단계에 의한 소광 현상이 우세하다가 0.3몰 이상 부터는 $^5D_0$에서 전하 이동 띠(Charge Transfer Band,CTB)로 전이되는 직접 소광 유형이 지배적이다. 음극선 거동은 800V의 가속 전압하에서 여기시켜 측정하였고, PL거동과 같이 0.125몰일때 가장 큰 615nm의 발광 휘도를 나타내었다.