• Title/Summary/Keyword: isotope ratio.

Search Result 254, Processing Time 0.03 seconds

Classification of nuclear activity types for neighboring countries of South Korea using machine learning techniques with xenon isotopic activity ratios

  • Sang-Kyung Lee;Ser Gi Hong
    • Nuclear Engineering and Technology
    • /
    • v.56 no.4
    • /
    • pp.1372-1384
    • /
    • 2024
  • The discrimination of the source for xenon gases' release can provide an important clue for detecting the nuclear activities in the neighboring countries. In this paper, three machine learning techniques, which are logistic regression, support vector machine (SVM), and k-nearest neighbors (KNN), were applied to develop the predictive models for discriminating the source for xenon gases' release based on the xenon isotopic activity ratio data which were generated using the depletion codes, i.e., ORIGEN in SCALE 6.2 and Serpent, for the probable sources. The considered sources for the neighboring countries of South Korea include PWRs, CANDUs, IRT-2000, Yongbyun 5 MWe reactor, and nuclear tests with plutonium and uranium. The results of the analysis showed that the overall prediction accuracies of models with SVM and KNN using six inputs, all exceeded 90%. Particularly, the models based on SVM and KNN that used six or three xenon isotope activity ratios with three classification categories, namely reactor, plutonium bomb, and uranium bomb, had accuracy levels greater than 88%. The prediction performances demonstrate the applicability of machine learning algorithms to predict nuclear threat using ratios of xenon isotopic activity.

Measurement of Oxygen Isotope Ratio in Water Vapor by using Tunable Diode Laser Absorption Spectroscopy(TDLAS) - II (다이오드레이저 흡수분광법을 이용한 수증기의 산소 동위원소 성분비 측정 - II)

  • Jung, Do-Young;Park, Sang-Eon;Kim, Jae-Woo;Ko, Kwang-Hoon;Im, Kwon;Jung, Eui-Chang;Kim, Chul-Joong
    • Proceedings of the Optical Society of Korea Conference
    • /
    • 2003.02a
    • /
    • pp.202-203
    • /
    • 2003
  • 여러 가지 원소의 동위원소 성분 분석은 생물학, 화학, 환경학, 연대학, 기후학 연구에 있어서 중요한 정보를 제공하는 유용한 수단이다. 동위원소 성분비를 측정하는 방법으로는 가스 동위원소 질량분석기를 이용한 방법이 사용되어 왔지만, 최근 다이오드 레이저의 발달과 함께 다이오드레이저 흡수분광법(TDLAS)이 개발되어 사용되고 있다. TDLAS 방법의 경우 질량분석기를 이용하는 방법에서는 측정이 불가능한 동일질량 분자의 동위원소 성분비를 측정할 수 있다. (중략)

  • PDF

Measurement of Oxygen Isotope Ratio in Water Vapor by using Tunable Diode Laser Absorption Spectroscopy(TDLAS) - I (다이오드레이저 흡수분광법을 이용한 수증기의 산소 동위원소 성분비 측펑 - I)

  • Jung, Do-Young;Park, Sange-On;Kim, Jae-Woo;Ko, Kwang-Hoon;Im, Kwon;Jung, Eui-Chang;Kim, Chul-Joong
    • Proceedings of the Optical Society of Korea Conference
    • /
    • 2003.02a
    • /
    • pp.200-201
    • /
    • 2003
  • 여러 가지 원소의 동위원소 성분 분석은 생물학, 화학, 환경학, 연대학, 기후학 연구에 있어서 중요한 정보를 제공하는 유용한 수단이다. 그 중에서도 수소, 산소, 그리고 탄소 동위원소 성분비의 정밀한 측정은 지구의 기후 변화 연구 등에 필수적인 수단이며, 가깝게는 식음료의 원산지 및 품질 확인에 이르기까지 다양하게 응용되고 있다 대표적으로 활용되고 있는 예를 보면 다음과 같다. 1. Authenticity Control and Detection of Adulteration: 쥬스류에 첨가제를 사용했는지의 여부를 확인할 수 있고, 포도주의 진품 여부를 확인할 수 있으며 원산지 확인도 가능하다. (중략)

  • PDF

Determination of methamphetamine in the hair of Korean abuser by CG/MS (GC/MS에 의한 한국인의 모발중 Methamphetamine검출)

  • 유영찬;정희선;최화경
    • YAKHAK HOEJI
    • /
    • v.37 no.4
    • /
    • pp.356-361
    • /
    • 1993
  • A sensitive method for the determination of methamphetamine(MA) and amphetamine(AM) in hair was developed by gas chromatography/mass spectrometry using stable isotope-labeled internal standards, amphetamine-d$_{5}$ and methamphetamine-d$_{5}$. Hair sample was washed with MeOH, incubated with MeOH(I% HCI) overnight at $37^{\circ}C$ while stirring and extracted using solid phase extraction column on a vacuum manifold. The extract obtained was pentafluoropropionated, and applied to GC/MS. The calibration curves of MA and AM were linear from 2.5 to 250 ng (r>0.99 for both). The limit of detection was 0.1 ng/mg in hair and cut-off level was set at 0.25 ng/mg for both. Hair samples of 27 MA abusers showed positive results in the range 0.7 to 106.8 ng/mg. AM, its metabolite, was detected in 20 out of 27 samples. The ratio of MA versus AM was 4.6~38.3 in specimens. Hair analysis for methamphetamine by GC/MS is an effective method for identifying long-term drug abusers.

  • PDF

Radioimmunotherapy (I): Development of Radioimmunoconjugates (방사면역치료(I): 방사면역접합체 개발)

  • Choi, Tae-Hyun;Lim, Sang-Moo
    • Nuclear Medicine and Molecular Imaging
    • /
    • v.40 no.2
    • /
    • pp.66-73
    • /
    • 2006
  • Monoclonal antibodies are designed to bind specifically to certain antigen, give therapeutic effect to the target and to be produced in large scale with homogeneity. The monoclonal antibodies conjugated with radionuclide can deliver therapeutic irradiation to the target, and showed successful results in certain malignancies, which is known as radioimmunotherapy. The target-to-background ratio depends on the antigen expression in the target and normal tissues, which is related to the therapeutic efficacy and toxicity in radioimmunotherapy. For the solid tumor beta-ray energy should be high, but lower beta energy is better for the hematological malignancies. I-l31 is widely used in thyroid cancer with low cost and high availability. Labeling monoclonal antibody with I-131 is relatively simple and reproducible. Some preclinical data for the I-131 labeled monoclonal antibodies including acute toxicity and efficacy are available from already published literatures in KIRAMS, physician sponsored clinical trial protocols using Rituximab, KFDA approved anti-CD20 chimeric monoclonal antibody and I-131 were approved by KFDA and currently are ongoing.

Comparative Measurement of Transverse Nuclear Magnetization of Polarized 129Xe and 131Xe by Spin-exchange Optical Pumping

  • Yu, Ye Jin;Min, Seong Ho;Moon, Han Seb
    • Current Optics and Photonics
    • /
    • v.4 no.6
    • /
    • pp.466-471
    • /
    • 2020
  • We analyze the transverse nuclear magnetizations of 129Xe and 131Xe in a vapor cell containing natural Xe, 87Rb, and buffer gases. Th e Xe atoms are polarized th rough spin-exch ange optical pumping (SEOP) with Rb atoms under low-magnetic-field conditions. From the free-induction-decay (FID) signal, we measure the nuclear magnetization of the Xe atoms in the Xe-Rb vapor cell. Furthermore, we measure the dependence of the gyromagnetic ratio on the magnetization of 129Xe and 131Xe by examining the amplitude of the FID signal of each isotope, and we evaluate the relationship between the magnetic field gradient and transverse relaxation rate for both of the 129Xe and 131Xe isotopes.

Evaluation of Airborne Pb Sources in an Industrialized City by Applying Pb Isotope Ratios and Concentrations in PM10 (PM10 내 납의 동위원소와 농도를 활용한 산업도시지역 대기 중 납 오염원 평가)

  • Jo, Wan-Kuen;Lee, Heon-Chul;Kim, Mo-Keun
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.33 no.3
    • /
    • pp.174-182
    • /
    • 2011
  • The present study evaluated the major lead sources in a steel metallurgy industrialized city by measuring lead isotopes/lead concentrations of ambient air and potential sources in an industrial area and residential areas according to relative distance. The quality control program obtained during the measurement procedure for lead isotopes and concentrations exhibited $0.5ng/m^3$ for method detection limit, more than 90% for recoveries of standard particulate matters, and lower than 0.2% for reproducibility errors of four lead isotopes ($^{204}Pb$, $^{206}Pb$, $^{207}Pb$, $^{208}Pb$). For all three lead isotope ratios ($^{206}Pb/^{204}Pb$, $^{207}Pb/^{206}Pb$, $^{208}Pb/^{206}Pb$), the ratios were obtained in the industrial area were closer to nearby residential area than those of a residential area far away from the industrial area, thereby suggesting that lead sources were more similar each other in the industrial and nearby residential area. Furthermore, for both summer and winter seasons ambient lead concentrations were more than four times higher in the industrial area than in the residential areas and in turn, they were higher in the nearby residential area compared with the far-away residential area. As a result, it was suggested that lead emitted from the industrial area would influence more the ambient lead in the nearby residential area than the far-away residential area. Both slag and traffic emissions are likely to be major lead sources in the industrial and nearby residential areas, since their three lead isotope ratios ($^{206}Pb/^{204}Pb$, $^{207}Pb/^{206}Pb$, $^{208}Pb/^{206}Pb$) were similar to the ratios obtained from ambient air of these two areas. In addition, the lead isotope ratios revealed different pattern between seasons, and the ambient lead concentrations were higher for winter than for summer.

A Study on the Behavior of Surface-Applied Urea with $^{15}N$ Isotope Dilution Technique in Paddy Soil (논토양에서 중질소(N-15)를 이용한 표면시용 요소로부터 유래하는 질소의 행동에 관한 연구)

  • Lee, Sang-Mo;Yoo, Sun-Ho
    • Applied Biological Chemistry
    • /
    • v.37 no.4
    • /
    • pp.277-286
    • /
    • 1994
  • The pot experiment using $^{15}N$ isotope dilution technique was carried out to calculate the balance of nitrogen of surface applied urea in the rice-soil system. The $^{15}N$ concentration was determined by stable isotope ratio mass spcetrometer (model: VG ISO-GAS MM622). In the pots with $^{15}N$ labeled urea application at the rates of 15 and 30 kg N/10a, the percentage of nitrogen derived from fertilizer (NDFF) in rice was higher at the rate of 30 kg N/10a (average 89%) than at the rate of 15 kg N/10a (average 64%). However, the recovery as percentage of fertilizer N by rice was higher at the rate of 15 kg N/10a (65.5%) than at the rate of 30 kg N/10a (54.2%). The percentage of the fertilizer N remained in extractable inorganic N form at the rates of 15 and 30 kg N/10a were $13.5%\;(NH_4-N\;5.53%,\;NO_3-N\;7.99%)$ and $16.5%\;(NH_4-N\;7.49%,\;NO_3-N\;8.98%)$ in unplanted soil, and $2.0%\;(NH_4-N\;0.63%,\;NO_3-N\;1.32%)$ and$2.3%\;(NH_4-N\;0.87%,\;NO_3-N\;1.40%)$ in soil planted to rice, respectively. The dominant form of inorganic-N in soil after harvest was $NO_3-N$ form rather than $NH_4-N$ form regardless of urea application rate or rice cultivation. The percentage of the fertilizer N remained in organic N form at the rates of 15 and 30 kg N/10a were 65.0 and 41.8% in unplanted soil, and 23.7 and 26.9% in soil planted to rice, respectively. In conclusion, the efficiency of surface-applied urea was greater at the rate 15 kg N/10a than at the rate of 30 kg N/10a.

  • PDF

Evaluation on the Fate of Cd in Soil and Plant by using Stable Isotope Methodology (Cd 안정동위체를 이용한 토양과 식물계에서 Cd의 거동해석)

  • Yun, Sun-Gang;Jung, Gu-Bok;Kim, Won-Il;Lee, Jong-Sik;Kim, Min-Kyeong;Kim, Jin-Ho;Shin, Joong-Du;Lee, Deog-Bae;Kim, Sam-Cwan
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.41 no.3
    • /
    • pp.223-227
    • /
    • 2008
  • This experiment was conducted to describe the distribution of stable isotope Cd in the mine tailing and uncultivated soils derived from different parent rocks (Igneous rock, Metamorphic rock, and Sedimentary rock) as well as the movement of Cd isotopes from soil to plants, soybean and pepper. The results showed that there was no significant difference in isotopic ratios in soil among the eight kinds of stable isotope of Cd. However the relationship among isotopic ratios of stable isotope of Cd in soils were classified to four types, linear type between $Cd^{106}/Cd^{111}$ and $Cd^{108}/Cd^{111}$, quadratic type between $Cd^{114}/Cd^{108}$ and $Cd^{111}/Cd^{110}$, reverse quadratic type between $Cd^{110}/Cd^{116}$ and $Cd^{108}/Cd^{116}$, and cluster type between $Cd^{110}/Cd^{113}$ and $Cd^{116}/Cd^{113}$. While the individual stable isotopes of Cd in root were remained except on the plot of pepper without mine tailing application. $Cd^{116}$, $Cd^{114}$, and $Cd^{112}$ played active roles among other stable isotopic Cds in bean and red pepper, and $Cd^{116}$ was ranked the highest abundance ratio. Contrary to crop itself, the abundance ratios of $Cd^{116}$ in bean and read pepper roots were decreased, and the ones of other Cds were relatively increased.

Comparison of Solidification Pre-treatment Methods for the Determination of δ13C of Dissolved Organic Carbon: Alkaline Persulfate Oxidation-Carbonate Precipitation vs. Freeze Drying (용존유기탄소의 δ13C : 분석시 고형화 전처리 방법 비교 알칼린 과황산칼륨산화 탄산침전과 동결건조)

  • Jeon, Byeong-Jun;Park, Hyun-Jin;Choi, Woo-Jung;Park, Yong-Se;Lee, Sang-Mo;Yoon, Kwang-Sik
    • Korean Journal of Environmental Agriculture
    • /
    • v.36 no.2
    • /
    • pp.113-118
    • /
    • 2017
  • BACKGROUND: The carbon (C) isotope ratio (${\delta}^{13}C$) of dissolved organic C (DOC) is an indicator of water pollution source. In this study, the potential use of two pre-treatments for the ${\delta}^{13}C$ analysis, alkaline persulfate oxidation coupled with carbonate precipitation (precipitation) and freeze drying (drying), were compared to suggest a more feasible pre-treatment method. METHODS AND RESULTS: Two reference materials with different ${\delta}^{13}C$ values were used for the experiments; chemical grade glucose ($-12.0{\pm}0.02$‰) and pig manure compost extract ($-23.3{\pm}0.04$‰). In the precipitation method, the measured ${\delta}^{13}C$ values were consistently lower than the theoretically calculated values as dissolved $CO_2$ could not be removed due to the alkaline property of the reagents and the dissolution of air $CO_2$ into the alkaline solution. The drying method also resulted in more negative ${\delta}^{13}C$ than the calculated ${\delta}^{13}C$; however, the difference was systematic ($3.9{\pm}0.3$‰) and there was a strong correlation (${\delta}^{13}C_{calculated}=0.87{\times}{\delta}^{13}C_{measured}-0.624$, $r^2=0.98$) between the calculated and measured ${\delta}^{13}C$. Calibration of ${\delta}^{13}C$ using the relationship between the calculated and the measured ${\delta}^{13}C$ values produced reliable and accurate ${\delta}^{13}C$ values. CONCLUSION: Our results suggest that the drying method is more accurate pre-treatment method to minimize the influence of air $CO_2$ compared to the precipitation method for the determination of ${\delta}^{13}C$ of DOC.