• Safety and Health at Work
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• v.13 no.1
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• pp.129-130
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• 2022

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.7 no.3
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• pp.61-66
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• 2008

For the production of urethane prepolymer, the effect of process parameters such as diisocyanate MDI and polyol TDI was tested. In this paper, design of experiments has been adopted for studying the effect of the process parameters on the improvement of NCO and viscosity of pre-polymer. As a result of comparison of different parameters, the effect of polyol was stronger than that of isocyanate in comparison of reactivity according to the amounts of isocyanate and polyol. Especially, NCO and viscosity of pre-polymer affected a product safety.

• Journal of Environmental Science International
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• v.23 no.11
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• pp.1909-1918
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• 2014

In this experiment no solvent based polyurethane(PU) adhesives were prepared with the polyol, isocyanate, dioctyl phthalate(DOP), 2-hydroxyethylacrylate(2-HEA) and other acrylate monomers. The softenening point of the PU adhesives measured by Ring & Ball method were examined in the present study. And adhesion strength and mechanical properties such as tensile strength and 100% modulus of the PU adhesives were evaluated by Universal Test Machine. The experimental results showed that increase of both DPE-41, benzoylperoxide(BPO) and toluene diisocyanate(TDI) increased softenening point, adhesion strength, tensile strength and 100% modulus. However as DOP content increased sofenening point, adhesion strength decreased and tensile strength, 100% modulus also decreased.

• Polymer(Korea)
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• v.25 no.3
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• pp.391-398
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• 2001

Two-component polyurethane (PU) flame-retardant coatings were prepared by blending tribromo modified polyesters ($TBAO_s$) and isocyanate.$TBAO_s$ were synthesized by condensation polymerization of tribromoacetic acid, a flame-retardant component, with 1,4-butanediol, adipic acid, and trimethylolpropane. The content of tribromoacetic acid was varied by 10, 20, and 30 wt% for the reaction. Various physical properties of these new flame-retardant coatings were comparable to nonflame-retardant coatings. Coatings with 20 wt% tribromoacetic acid did not burn during the vertical burning test.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.04a
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• pp.433-436
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• 1999

Long-term durability of the reinforced concrete structures exposed to marine environment deteriorates seriously by the attack of the chloride ion from see water results in corrosion of steel reinforcement in concrete. Their coating effect is aluminum oxide-isocyanate-based coating material, resistance of chloride penetration, carbonation and freezing and thawing resistance were compared to acryl-based coating material and sealer type o waterproofing material. Aluminum oxide-isocyante-based and acryl-based coating material show higher resistance to chloride penetration and carbonation than the sealer type do waterproofing material and aluminum oxide-isocyanate-based coating resist about 99% of chloride penetration. Resultants to the accelerated test for freezing and thawing, coating concrete show higher resistance than non-coating concrete, respectively.

• Journal of the Korean Chemical Society
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• v.17 no.3
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• pp.188-192
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• 1973

Reactions of trimethylsilylethylsulfide, trimethylsilylphenylsulfide, triethylstannylethylsulfide, and triethylstannylphenylsulfide with isocyanates were studied at various temperatures for 10 days. These Si-S and Sn-S bond compounds catalyzed the production of the cyclic dimer and trimer of phenylisocyanate, diphenylcarbodiimide and 1,3,5-triphenyl-4-phenyliminohexahydro-1,3,5-triazine-2,6-dione in the reaction of phenylisocyanate. In contrast, these compounds gave only the cyclic trimer, triethylisocyanurate, from ethylisocyanate.

• Bulletin of the Korean Chemical Society
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• v.31 no.6
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• pp.1621-1627
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• 2010

The investigation of the catalytic activity of supported rhodium(I) complex [Rh(P-S)$(CO)_2$] (P-S; polymer anchored salicylic acid) toward the reductive carbonylation of nitrobenzene in DMF medium has been reported. Use of basic cocatalysts in the reaction medium enhanced the percentage of more useful phenyl carbamates. Spectroscopic studies indicate that the reaction proceeds through a dimer species [Rh(HS)(CO)(C(O)$OCH_3$)(${\mu}-OCH_3)]_2$ and phenyl isocyanate is formed as an intermediate. A plausible reaction mechanism based on the identification of reactive intermediates from the soluble rhodium variety has been proposed for the carbonylation process.

• Proceedings of the Korea Concrete Institute Conference
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• 1996.10a
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• pp.253-259
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• 1996

The purpose of this study is to investigate the fundamental properties of polyurethan concrete. Polyurethane must be expanded by means of a blowing agent during polymerization. Chemical blowing is caused by the reaction water with isocyanate. Binder system for polyurethane concrete is based on polyol and isocyanate with catalyst, surfactant, and methyl chloride. Polyurethane concretes are prepared with various grading of aggregate, and tested for compressive, flexural strengths, flow test, foaming multiple proportion, working life, condition of surface, distirbution of aggregate. From the test results, the foaming of polyurethane concretes are affceted by amount and grading of aggregate. Workability increases with raising amount of methy chloride and working life reduced according to amount of catalyst. The mix proportion of B with methyl chloride of 1% and catalyst of 0.1g for polyurethane concrete is recommended in consideration of strengths, condition of surface and balance between cost and performance.

• Bulletin of the Korean Chemical Society
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• v.28 no.5
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• pp.751-757
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• 2007

To develop new COX-2 inhibitors, 1,5-diarylhydantoins and 1,5-diaryl-2-thiohydantoins were synthesized from phenylacetic acids by esterification, bromination, C-N bond formation and cyclization. Esters 1-3 were efficiently synthesized from the starting materials by reflux in absolute methanol for 3 h containing concentrated sulfuric acid as catalyst. Bromination was carried out with N-bromosuccinimide at rt in dichloromethane. Bromides 4-6 were reacted with aniline, p-anisidine, sulfanilamide in ethanol (or N,N-dimethylformamide) to provide the amines 7-15. Hydantoins and 2-thiohydantoins 16-46 were synthesized from amines 7-15 by treating them with potassium isocyanate (or potassium thiocyanate) and triethylamine. The synthetic process from alkyl α-anilinophenylacetate 7-15 to 3-alkylhydantoins was carried out in a one-pot reaction using alkyl isocyanate (alkyl isothiocyanate).

• Elastomers and Composites
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• v.55 no.1
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• pp.20-25
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• 2020

The effect of the isocyanate index (NCO index) on the particle size and particle size distribution of a waterborne polyurethane dispersion (WPUD) with polycarbonate-diol was determined. The WPUDs were prepared using a conventional acetone process with polycarbonate-polyol (M_n = 2028), 4,4'-methylenebis(cyclohexyl isocyanate) (H₁₂MDI), 2,2-bis(hydroxymethyl) propionic acid (DMPA), and dibutyltin dilaurate catalyst. At NCO index values below 1.5, the number average particle diameter of the WPUDs significantly increased with the NCO index, whereas the particle diameter slightly varied at higher NCO indexes. The dependency of the WPUD viscosity on the NCO index exhibited similar behavior to that of the particle size. The relative values of the full width at half maximum of the WPUD particle distribution curves at various NCO indexes were not influenced by the NCO index.