• Title/Summary/Keyword: iron species

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Heavy Metal Concentrations of Some Game Species Captured in Kyeongsangnam-do, Korea (경남지역(慶南地域)에 서식(棲息)하는 수렵조수류(狩獵鳥獸類)의 중금속(重金屬) 축적(蓄積))

  • Choi, Jai Sik;Jung, Wee Hyun;Youn, Ki Sick;Lee, Doo Pyo
    • Journal of Korean Society of Forest Science
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    • v.83 no.1
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    • pp.6-11
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    • 1994
  • Three different types of tissue taken from three game birds such as Ring-necked Pheasant, Rufous Turtle Dove, Mallard and a mammal, Korean Water Deer were analyzed for five heavy metals such as iron, zinc, copper, lead and cadmium. The main purpose of this study was to make clear the background levels of the metal concentrations in the tissues of these game species. The metal levels were generally low and could be considered as the background levels. But some markedly high levels of lead were recorded in the muscles of birds shot by the shotgun. The implications of these results were discussed with respect to the health of people.

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Aqueous U(VI) removal by green rust and vivianite at phosphate-rich environment

  • Sihn, Youngho;Yoon, In-Ho
    • Membrane and Water Treatment
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    • v.11 no.3
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    • pp.207-215
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    • 2020
  • Vivianite (Fe32+(PO4)2·8H2O) and green rust ([Fe42+Fe23+(OH)-12][SO42-·2H2O]2-), ferrous containing minerals, could remove aqueous U(VI) in 5 min. and the efficiencies of green rust were roughly 2 times higher than that of vivianite. The zeta potential measurement results implies that the better performance of green rust might be attributed to the favorable surface charge toward uranyl phosphate species. The removal behaviors of the minerals were well fitted by pseudo-second order kinetic model (R2 > 0.990) indicating the dominant removal process was chemical adsorption. Effects of Ca2+ and CO32- at pH 7 were examined in terms of removal kinetic and capacity. The kinetic constants of aqueous U(VI) were 8 and 13 times lower (0.492 × 10-3 g/(mg·min); 0.305 × 10-3 g/(mg·min)) compared to the value in the absence of the ions. The thermodynamic equilibrium calculation showed that the stable uranyl species (uranyl tri-carbonate) were newly formed at the condition. Surface investigation on the reacted mineral with uranyl phosphates species were carried out by XPS. Ferrous iron and U(VI) on the green rust surface were completely oxidized and reduced into Fe(III) and U(IV) after 7 d. It suggests that the ferrous minerals can retard U(VI) migration in phosphate-rich groundwater through the adsorption and subsequent reduction processes.

Fe and Al Behaviors in Precipitates and Pollution Characteristics of Acid Mine Drainage from the Donghae Abandoned Coal Mine, Taebaek, Korea (태백시 동해폐탄광 산성광산배수의 오염현황과 하상퇴적물 내 철, 알루미늄의 거동특성)

  • Choo, Chang Oh;Park, Jung-Won;Lee, Jin Kook
    • The Journal of Engineering Geology
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    • v.29 no.4
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    • pp.579-598
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    • 2019
  • We investigated geochemical contaminants and Fe, Al behavior in precipitates of acid mine drainage (AMD) from the Donghae abandoned coal mine, Taebaek, Gangwon Province using aqueous chemical analyses, XRD, IR, and 27Al NMR, Our results showed that water chemistry changed with pH and Eh, and saturation indices of chemical species in the AMD. According to saturation calculated by visual MINTEQ, the AMD was saturated with various Fe-, Al-oxyhydroxide minerals. Reddish brown precipitates are composed of schwertmannite, ferrihydrite, and goethite, whereas whitish precipitates are composed mostly of alumimous minerals such as poorly crystallized basaluminite with trace Al13-Tridecamer. It is important to apply active treatment methods rather than simple storage pond and to control the precipitation and solubility of iron species and aluminous species for ensuring remediation and control for the AMD discharged from the Donghae abandoned coal mine.

Community Structure, Phytomass, and Primary Productivity in Thuja orientalis Stands on Limestone Area

  • Kwak, Young-Se;Lee, Choong-Il
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.3 no.3
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    • pp.189-196
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    • 1999
  • The community structure, phytomass, and primary productivity in Thuja orientalis stands on a limestone area located in Maepo-up, Chungbuk province in Korea were estimated quantitatively. Seven species including a small proportion of Quercus dentata were identified in the tree layer, 26 species including Ulmus macrocarpa in the shrub layer, and 79 species including Carex lnceolata in the herb layer of the Thuja stands. The vertical distribution of the fine root phytomass exhibited a power functional decrease relative to the soil depth. The seasonal changes in the fine root phytomass at a soil depth of 5 cm were closely related to the pecipitation in the study area. The productivity of the stand of stems, branches, leaves, and roots were 10.72, 0.82, 0.45 and 6.46 ton DM. $ha^{-1}$ .$yr^{-1}$, respectively. The Thuja stand had a high foliage(25%) and low rate of production per unit of foliage. The annual turnover rate of the fine roots int he Thuja stand was 6.71 $yr^{-1}$. The net primary production of the overstory including the understory was estimated at 19.48 ton DM.$ha^{-1}$.$yr^{-1}$ including an underground section of 6.46 ton DM.$ha^{-1}$.$yr^{-1}$(33%). The allocation ratio of net production to root was lower in the limestone Thuja communities than at the nearby non-limestone ones, whereas the production efficiency to leaf weight was higher in the limestone communities. These results would seem to indicate that the limited production capacity is due to the calcium toxicity and low availability of iron and phosphorus in a limestone soil with a high pH, calcium, and bicarbonate content with a strategy for survival in a hostile habitat.

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A study on the chemical treatment of biodeterioration about stone pagoda of Iksan Mireuksaji-Focusing on bio-treatment using K201 (익산 미륵사지석탑의 생물침해 방지를 위한 보존처리제 적용실험-K201 생물처리제를 중심으로)

  • Yang, Hee-Jae;Chung, Yong-Jae;Kim, Sa-Dug;Kim, Gwaoung-Hun
    • 보존과학연구
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    • s.24
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    • pp.81-98
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    • 2003
  • The biodeterioration on Iksan Mireuksaji pagoda has been studied with fucus on application of K201 as a chemical treatment. Total of 39species, including 10 algae, 16 lichens, 6 mosses and 7 unidentified bacteria and fungi, were collected and identified on the surface of the pagoda. Most of them caused serious discoloration on the surface. The effectiveness and stability of K201 was examined by applying it on some part of the pagoda. A mild spraying of solution diluted to half of original reagent was good enough to eliminate all the deteriorating species on the surface. Most of discoloration disappeared after the treatment except the red color caused by iron substance. The effectiveness of the regent was compared with water wash. The stone was first washed with water and the dirt on the surface was scrubbed off from the surface. The initial surface of the stone was clearer in water wash. However, many of the deteriorating species reappear in 4 weeks after water wash. Although spraying of the reagent K201 could noteliminate all the remnant of dead organisms as good as scrubbing the surface, no deteriorating algae or lichen was observed until two month after treatment. Therefore, spraying method with chemicals seems more stable and reliable way to remove the biodeterioration than physical scrubbing of the surface.

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Scanning Electron Microscopic Study of Slime Formations in a Water Injection Station of Oil India Limited in Assam, India

  • Bhagobaty, Ranjan K.;Purohit, S.;Nihalani, M.C.
    • Applied Microscopy
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    • v.45 no.4
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    • pp.249-253
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    • 2015
  • Microorganisms specifically groups of bacteria exhibiting physiological activities of production of acids are a major cause of concern because of their ability to induce corrosion in oil field pipelines and metal systems involved in water handling. Water Injection Stations as a means of secondary recovery from existing oil producing reservoirs, are often employed in most upstream oil and gas industries to ensure replenishment of voidage, maintenance of reservoir pressure and optimization of crude emulsion throughput. In the present study, scanning electron microscopy of macroscopic orange coloured slime formations sampled from leaking valves on the flow-lines of a Water Injection Stations of Oil India Limited revealed the presence of filamentous bacterial mats in association with diatoms. The species composition of the acidic slime formations from the sampled locations reveal the possible role of acid producing iron oxidizing bacteria (IOB) like Acidithiobacillus ferrooxidans in association with Gomphonema sp. in creating conditions for bio-corrosion.

A Cu, Zn superoxide dismutase (SOD1) from Cordyceps militaris: cDNA cloning, expression and characterization

  • Park, Nam-Sook;Lee, Sang-Mong;Sohn, Hung-Dae;Jin, Byung-Rae
    • Proceedings of the Korean Society of Sericultural Science Conference
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    • 2003.10a
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    • pp.66-70
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    • 2003
  • The first line of antioxidant defense against reactive oxygen species includes the enzymatic activity of the superoxide dismutase (SOD) that catalyzes the disproportionation of superoxide to hydrogen peroxide and water. The SOD mainly removes highly toxic $O_2$$^{[-10]}$ and also prevents $O_2$$^{[-10]}$ mediated reduction of iron and subsequent OH$^{[-10]}$ generation. Along with an interest in SOD as a first line of defense against damage mediated by the superoxide anion, the SOD1 enzyme has been subjected to investigation in the molecular and cellular level. (omitted)

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Inhibition of Glutamate-Induced Change in Mitochondrial Membrane Permeability in PC12 cells by 1-Methylated β-carbolines

  • Han, Eun-Sook;Lee, Chung-Soo
    • Biomolecules & Therapeutics
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    • v.11 no.2
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    • pp.112-118
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    • 2003
  • 1-Methylated $\beta$-carbolines (harmaline and harmalol) and antioxidants (N-acetylcysteine and ascorbate) reduced the loss of cell viability in differentiated PC 12 cells treated with 5 mM glutamate. $\beta$-Carbolines prevented the glutamate-induced decrease in mitochondrial membrane potential, cytochrome c release and caspase-3 activation in PC 12 cells. $\beta$-Carbolines reduced the formation of reactive oxygen species and depletion of glutathione due to glutamate in PC12 cells. $\beta$-Carbolines revealed a scavenging action on hydrogen peroxide and reduced the iron and EDTA-mediated degradation of 2-deoxy-D-ribose. The results suggest that I-methylated $\beta$-carbolines attenuate the cytotoxic effect of glutamate on PC12 cells by reducing the alteration of mitochondrial membrane permeability that seems to be mediated by oxidative stress.

A Mathematical Model Development for Microbial Arsenic Transformation and Transport

  • Lim, Mi-Sun;Yeo, In-Wook;Lee, Kang-Kun
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.318-322
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    • 2004
  • Arsenic is a toxic and carcinogenic metalloid, whose sources in nature include mineral dissolution and volcanic eruption. Abandoned mines and hazardous waste disposal sites are another major source of arsenic contamination of soil and aquatic systems. To predict concentrations of the toxic inorganic arsenic in aqueous phase. the biogeochemical redox processes and transport behavior need to be studied together and be coupled in a reactive transport model. A new reaction module describing the fate and transport of inorganic arsenic species (As(II)), dissolved oxygen, nitrate, ferrous iron, sulfate, and dissolved organic carbon are developed and incorporated into the RT3D code.

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Studies on Inorganic Components of Korean Mushrooms(I) - Inorganic Components of Laccaria laccata, Laccaria amethystina, Laccaria tortilis and Laccaria vinaceoavellanea ­- (한국산 버섯류의 무기성분(無機成分)에 관한 연구(I) - 졸각버섯, 자주졸각버섯, 밀졸각버섯, 색시졸각버섯의 무기성분 -)

  • Park, Wan-Hee
    • The Korean Journal of Mycology
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    • v.16 no.4
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    • pp.242-246
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    • 1988
  • To determine contents of inorganic elements of Laccaria, the carpophores of Laccaria laccata(Fr.) Berk. et Br., Laccaria amethystina(Fr.) Berk. et Br., Laccaria tortilis(S.P. Gray) Cooke and Laccaria vinaceoavellanea Hongo were incinerated and analyzed by atomic absorption spectrophotometer. Total contents of determined inorganic elements(except Cd) were highst in Laccaria tortilis than the other three mushrooms, and Laccaria vinaceoavellanea, Laccaria laccata and Laccaria amethystina in that order. The four species mushrooms contained potassium, iron, zinc, sodium, copper, manganese, and calsium in that order, and the content of potassium was the highst than the other inorganic components. The content of cadmium was Laccaria tortilis, Laccaria laccata, Laccaria vinaceoavellanea and Laccaria amethystina in that order.

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