• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.99-100
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• 2006

Cellular metals based on Iron have been intensively investigated during the last two decades. Because of the significant decreasing of the structural density of Iron based cellular structures, numerous technologies have been developed for their manufacturing. Besides the tremendous weight reduction a combination with other properties like energy and noise absorption, heat insulation and mechanical damping can be achieved. This contribution will give an overview about the latest state in Iron based cellular materials, including technologies in manufacturing, properties and potential applications.

• 한국재료학회지
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• 제10권6호
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• pp.385-391
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• 2000

염화철(Ferrous Choloride) 증기의 고온 수소환원 반응을 통한 미립질 철분말의 생성속도에 대한 이론적인 해석돠 실험을 수행하였다. 철분말의 생성기구는 염화철이 증발하여 생성된 증기와 운반가스인 알곤을 혼합하여 반응부로 유입시키고 수소에 의한 고온환원반을을 통하여 철분말과 함께 부산물인 염화수소(HCI) 가스를 얻게 된다. 생성된 반응부 후미에 설치한 유기용매 포집기를 이용하여 회수하였으며, 염화수소는 가성소다 수용액에 흡수시키고 이를 적정함으로써 초기 반응물인 염화철의 전환율을 계산하였다. 반응속도식의 반응물에 대하여 1차반응(1st-order reaction)이고 염화철 증가와 운반체인 알곤가스가 평형상태일 때의 속도상수는 $k=7,879exp(-53,840/RT)\textrm{dm}^3/mole.sec$으로 표시되며, 이때의 활성화에너지는 53.84kJ/mole이었다. 철분말의 TEM 사진에 의하면 입도범위는 $0.1~1.0{\mu\textrm{m}}$이며, 반응온도 및 가스유량에는 크게 영향을 받지 않는것으로 나타났다.

• 한국인쇄학회지
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• 제20권1호
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• pp.45-53
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• 2002

The removal of chelated copper from anthraquinone dyes by cementation on powdered iron was studied. The removal of chelated copper was found to be a function of solution pH, amount of NTA and iron, and reaction temperature. In the presence of NTA, reaction rate of cementation was found to be strongly dependent on reaction temperature, solution pH, amount of NTA and amount of iron powder. These experimental results can be explained successfully by the distribution of complexed copper iron in solutions.

• 한국분말재료학회지
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• 제26권6호
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• pp.481-486
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• 2019

Iron oxides currently attract considerable attention due to their potential applications in the fields of lithiumion batteries, bio-medical sensors, and hyperthermia therapy materials. Magnetite (Fe₃O₄) is a particularly interesting research target due to its low cost, good biocompatibility, outstanding stability in physiological conditions. Hydrothermal synthesis is one of several liquid-phase synthesis methods with water or an aqueous solution under high pressure and high temperature. This paper reports the growth of magnetic Fe₃O₄ particles from iron powder (spherical, <10 ㎛) through an alkaline hydrothermal process under the following conditions: (1) Different KOH molar concentrations and (2) different synthesis time for each KOH molar concentrations. The optimal condition for the synthesis of Fe₃O₄ using Fe powders is hydrothermal oxidation with 6.25 M KOH for 48 h, resulting in 89.2 emu/g of saturation magnetization at room temperature. The structure and morphologies of the synthesized particles are characterized by X-ray diffraction (XRD, 2θ = 20°-80°) with Cu-kα radiation and field emission scanning electron microscopy (FE-SEM), respectively. The magnetic properties of magnetite samples are investigated using a vibrating sample magnetometer (VSM). The role of KOH in the formation of magnetite octahedron is observed.

• Journal of Welding and Joining
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• 제32권5호
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• pp.65-71
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• 2014

Atmospheric plasma spraying (APS) is world-widely used process in the automotive industry as a method to provide wear resistance coatings for engine cylinder bore, using various materials. The weight of engine blocks can be considerably decreased by removing cast iron liners, which can finally result in the improvement of fuel efficiency. In this study, five kinds of powder materials, 1.2C steel powder and 1.2C steel powder mixed with 5, 10, 15, 20 wt.%. molybdenum powder, were deposited by atmospheric plasma spraying in order to investigate the effect of molybdenum on the wear resistance of coatings. Microstructural analysis showed that molybdenum splats were well distributed in 1.2C steel matrix with intimate bonding. The molybdenum added coatings showed better tribological properties than 1.2C steel coating. However, above the 15 wt.%. blending fraction, wear resistance was somewhat degraded with poor roughness of worn surface due to the brittle fracture occurred in molybdenum splats. Consequently, compared to conventional liner material, gray cast iron, 10 wt. pct. molybdenum blended 1.2C steel coating showed much better tribological properties and therefore it looks very feasible to replace gray cast iron liner.

• 한국재료학회:학술대회논문집
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• 한국재료학회 1997년도 한국재료학회 춘계학술발표회
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• pp.64-65
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• 1997

• 자원리싸이클링
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• 제7권4호
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• pp.43-49
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• 1998

다양한 hard ferrite용 국산 산화철(${\alpha}Fe_2O_3$)의 분체특성이 Sr-ferrite의 자기특성에 미치는 영향을 조사하였다. 산화철의 평균입도와 입도분호는 철강 냉연공장의 염산폐액 정제방법에 따라 서로 구분되었으며, Sr-ferrite의 자기특성과 미세조직에 큰 영향을 주었다. Ruthner 산화철의 응집현상은 Sr-ferrite의 포화자화를 감소시켰으며, Chemirite(CY) 산화철의 $0.80{\mu}\textrm{m}$이상의 조대한 입자는 Sr-ferrite의 고유보자력을 감소시켰다. 평균입도가 $0.14\mu\textrm{m}$로 가장 작은 Chemirite 포항2냉연(EP) 산화철을 사용하여, 5.8mol, $1150^{\circ}C$/1시간의 하소조건에서 제조된 Sr-ferrite는 포화자화가 68.2emu/g, 고유보자력이 4300Oe인 최적의 자기특성을 나타내었다.

• 자원리싸이클링
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• 제21권1호
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• pp.75-81
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• 2012

선탄경석을 환경개선물질로 순환자원화하기 위해 철산화물과 혼합하여 중금속 불용화제를 제조하고 이의 적정제조 조건과 중금속에 대한 불용화 성능을 평가하였다 선탄경석을 분쇄한 후 철산화물의 분말을 혼합하여 구형의 펠릿을 제조하고 이를 가열하여 중금속 불용화제를 제조하였다. 온도별로 가열한 결과, $1100^{\circ}C$부터 선탄경석에 함유된 탄질분에 의해 영가철이 생성되었다. 제조된 불용화제는 구형의 다공체로서 공극률은 34.63%, 겉보기 밀도는 1.31 g/mL, 공극의 평균크기는 9.82 ${\mu}m$로 측정되었다. 불용화제를 비소(V), 구리(II), 크롬(VI), 카드뮴(II)이 함유된 각각의 중금속 용액과 반응시킨 결과, 영가철이 생성된 $1100^{\circ}C$에서 제조된 펠릿이 중금속 불용화도가 높고 pH를 더 높이는 것으로 나타났다. 중금속농도 10 ppm의 용액을 99.9%이상 불용화하기까지 비소의 경우 1시간, 크롬의 경우 2시간, 구리의 경우 4시간이 필요하였다. 그러나 카드뮴의 경우 불용화도가 낮게 나타났고 중금속농도가 높을수록 불용화도가 더 낮아지는 것으로 나타났다.

• 한국결정성장학회:학술대회논문집
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• 한국결정성장학회 1998년도 PROCEEDINGS OF THE 15TH KACG TECHNICAL MEETING-PACIFIC RIM 3 SATELLITE SYMPOSIUM SESSION 4, HOTEL HYUNDAI, KYONGJU, SEPTEMBER 20-23, 1998
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• pp.65-70
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• 1998

Fine powders of $\alpha$-Fe2O3 were prepared by precipitation method using iron (III) nitrate in ethanol solvent and the thick film using this powder was made by the screen printing technology. Effects of the reaction temperature and concentration of the iron (III) nitrate on the particle size and specific surface area were studied. Also, the relationship between the powder size and properties of the thick film was discussed.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.851-852
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• 2006

The introduction of ceramic particulate into metallic powder will unavoidably lower the compressibility and formability of the mixed powder. In this study, warm compaction, which is a simple and low cost technique to produce high density PM parts, was introduced in preparing composite. The aim of this paper is to prepare the warm compacted NbC particulate reinforced Fe-based composite, then study its tribological behavior and application in the valve-guide cup. A 15 wt.% NbC reinforced iron-based composite was prepared. It possesses a relative density of 98%, a tensile strength of 515 MPa, a hardness of HRC 58 and a remarkable tribological behavior.