• Title/Summary/Keyword: iron oxide-iron system

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The treatment of coolant wastewater of rolling plate process by High Gradient Magnetic Separation

  • Kim, Tae-Hyung;Ha, Dong-Woo;Kwon, Jun-Mo;Sohn, Myung-Hwan;Baik, Seung-Kyu;Oh, Sang-Soo;Ko, Rock-Kil;Kim, Ho-Sup;Kim, Young-Hun;Park, Seong-Kuk
    • Progress in Superconductivity and Cryogenics
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    • v.11 no.4
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    • pp.8-11
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    • 2009
  • This study introduced wastewater treatment method by High Gradient Magnetic Separation (HGMS). HGMS treatment was high efficient method for various industrial wastewaters. The system is currently research state, but we have surveyed commercialize the technology for industry. In rolling plate process, coolant wastewater was recycled by sedimentation and sand filter system. It needs several large reservoirs and long time to remove suspended solid (SS) like metal fines and iron oxide in hot rolling plate making process. If removing rate of suspended solid in rolling coolant wastewater is improved by using HGMS system, the productivity of working process can be increased and the area of reservoir can be reduced. We manufactured high temperature superconducting HGMS system that had a purpose to treatment of coolant wastewater in rolling plate process. We fabricated the prototypes of magnetic matrix filter consisting of stainless steel 430 mesh, which is a core component in the magnetic separation system, In our basic preliminary experiment using HGMS system, it has been clear that the fine paramagnetic particles in the coolant wastewater obtained from rolling plate process of POSCO can be separated with high efficiency.

Experimental Study on Particle Temperature and CO/CO2 Emission Characteristics of Pulverized Coal Combustion Condition According to Coal Types in Blast Furnace (고로 내 미분탄 연소조건에서 탄종에 따른 입자온도와 CO/CO2 배출 특성에 관한 연구)

  • Cho, Young Jae;Kim, Jin Ho;Kim, Ryang Gyun;Kim, Gyu Bo;Jeon, Chung Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.10
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    • pp.807-815
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    • 2014
  • This study was performed using a laminar flow reactor that could replicate the combustion environment of pulverized coal in a blast furnace. Since a pulverized coal injection system was developed for iron making, the combustion characteristics of pulverized coal have been important in the iron and steel industry. The flame structure, particle temperature, and exhaust gas were investigated for different types of coal. The results of this study demonstrated that the combustion characteristics of coal are influenced by several properties of individual coals. In particular, the CO emission and volatile matter content of individual coals were found to have a strong influence on their combustion characteristics. Thus, this study found the properties of the coals to be significant and focused on the particle temperature and CO and $CO_2$ emissions.

Study on Magnetic Separation of Hot Roller coolant by Using Superconducting HGMS (초전도 HGMS를 이용한 열연 냉각수의 자기분리 연구)

  • Ha, Dong-Woo;Kim, Tae-Hyung;Oh, Sang-Soo;Park, Sung-Kook;Lee, Sang-Gil;Roh, Yu-Mi
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.37-38
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    • 2007
  • It needs several large reservoirs and long time to remove suspended solid like steel fines and iron oxide in hot rolling coolant. If removing rate of suspended solid in rolling coolant is improved by using high gradient magnetic separation (HGMS) system, the productivity of working process can be increased and the area of reservoir can be reduced. Pre-treatment process that react magnetic floc with inorganic and organic flocculant in coolant was studied. Horizontal type superconducting HGMS system was manufactured successfully, which was constituted with automatic filter transportation apparatus, 6 T He-free superconducting magnet system and water circulation system. The solid suspension removal ratio in hot rolling coolant was increased by flocculation with inorganic and organic flocculant.

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The Influences of Aquifer Thermal Energy Storage (ATES) System on Geochemical Properties of Groundwater (대수층 계간 축열시스템 적용을 위한 지하수의 화학적 특성 변화)

  • Choi, Hanna;Lee, Hong-Jin;Shim, Byoung Ohan
    • Journal of Soil and Groundwater Environment
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    • v.26 no.3
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    • pp.14-24
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    • 2021
  • Aquifer thermal energy storage (ATES) system uses groundwater thermal energy for cooling and heating of buildings, and it is also often utilized to provide warm water to crops and plants for the purpose of enhancing agricultural yields. This study investigated the potential influences of a ATES system on the geochemical properties of groundwater by simulating the variation of hydrochemistry and saturation index of groundwater during ATES operation. The test bed was installed at an agricultural field, which is mainly composed of an groundwater-rich alluvial plain. The simulation results showed no significant precipitation of mineral phases such as manganese-iron oxide, carbonate and sulfate around the ATES test bed, as well as no debasement of other important water quality parameters. The implementation of ATES system in the study area was appropriate and effective for utilizing the thermal energy of groundwater for agricultural use.

Drug Delivery Study on Chitosan Nanoparticles Using Iron Oxide (II, III) and Valine (Iron Oxide(II, III)와 Valine을 이용한 키토산 나노입자의 약물전달 연구)

  • Jang, So-Hyeon;Kang, Ik-Joong
    • Korean Chemical Engineering Research
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    • v.59 no.4
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    • pp.514-520
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    • 2021
  • A drug delivery system (DDS) based on nanoparticles has been used as a mediator to improve the efficacy of a drug by controlling the amount of drug released and delivering it to a target place. Chitosan, which is non-toxic and biodegradable, has good biocompatibility and excellent adsorption, so it can be used as a drug delivery vehicle. Valine, the essential amino acids, helps muscle growth and tissue recovery, and along with other amino acids. It lowers blood sugar levels and increases growth hormone production. In this study, Valine was adsorbed on magnetic chitosan which is capable of drug absorption, and Fe3O4-Valine CNPs was prepared through cross-linking with TPP (Tripolyphosphate). And then absorption and release trends of valine were investigated with the Fe3O4-Valine CNPs. Fe3O4, which has relatively high stability, is used to make the drug carrier magnetic so that the drug can be delivered to a target place. At optimal conditions, the absorption and release tendency of Fe3O4-Valine CNP was confirmed by analyzing by UV-Vis through the Ninhydrin test which is the color reaction of amino acids and by measuring the size of the particles, it was confirmed that it is suitable as a drug carrier.

Development of a Blended Corrosion, Scale and Micro-Organism Inhibitor for Open Recirculating Cooling System

  • Choi, Dong-Jin;You, Seung-Jae;Kim, Jung-Gu;Hwang, Woo-Suk
    • Corrosion Science and Technology
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    • v.4 no.3
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    • pp.89-94
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    • 2005
  • This paper presents the results of a study that was undertaken to optimize the ratio of the components of a new multi-component inhibitor blend composed of orthophosphate/ phosphonates/ acrylate copolymer/ isothiazolone. The effects of newly developed inhibitor on carbon steel dissolution in synthetic cooling water were studied through weight loss tests, electrochemical tests, scale tests, and micro-organism tests. The obtained results were compared to blank (uninhibited specimen) and showed that developed inhibitor revealed very good corrosion, scale, and micro-organism inhibition simultaneously. All measurements indicated that the efficiency of the blended mixture exceeded 90 %. The inhibitive effects arose from formation of protective films which might contain calcium phosphate, calcium phosphonate, and iron oxide. The nature of protective films formed on the carbon steel was studied by scanning electron microscopy (SEM) and auger electron spe ctroscopy (AES). Inhibitor used in this study appeared to have better performance for scale inhibition due to their superior crystal modification effect and excellent calcium carbonate scale inhibition properties. The effect of inhibitor on microorganisms was evaluated through minimum inhibitory concentration (MIC) test. All kinds of micro-organisms used in this study were inhibited under 78ppm concentration of inhibitor.

Study on Particulate Pollutant Reduction Characteristics of Vegetation Biofilters in Underground Subway Stations (지하역사내 식생바이오필터의 입자상 오염물질 저감특성 연구)

  • Kim, Tae Han;Oh, Ji Eun;Kim, Mi Ju
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.4
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    • pp.99-105
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    • 2022
  • Public attention to the indoor environment of underground subway stations, which is a representative multi-use facility, has been increasing along with the increase in indoor activities. In underground stations, fine iron oxide, which affects the health of users, is generated because of the friction between wheels and rails. Among particulate pollutant reduction technologies, plants have been considered as a non-chemical air purification method, and their effects in reducing certain chemical species have been identified in previous studies. The present study aimed to derive the total quantitative and qualitative reduction effects of a bio-filter system comprising air purifying plants, installed in an underground subway station. The experiment proceeded in two ways. First, PM(particulate matter) reduction effect by vegetation biofilter was monitored with the IAQ(indoor air quality) station. In addition, chemical speciation analysis conducted on the samples collected from the experimental and control areas where plants and irrigation using SEM-EDS(scanning electron microscopy-energy dispersive X-ray spectroscopy). This study confirmed the effect of the vegetation bio-filter system in reducing the accumulation of particulate pollutants and transition and other metals that are harmful to the human body.

Effect of Fe2+/Fe3+ Ratio on the Crystallization of the Scoria Glass (CaO-MgO-Al2O3-SiO2 System) (Scoria 유리(CaO-MgO-Al2O3-SiO2계)의 결정화에 미치는 Fe2+/Fe3+비 효과)

  • 최병현;지응업
    • Journal of the Korean Ceramic Society
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    • v.26 no.5
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    • pp.705-711
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    • 1989
  • The glass-ceramics was prepared with the scoria(CaO-MgO-Al2O3-SiO2 system) of the locally occurring volcanic ejecta containing 10-13w/o of (FeO+Fe2O3) by melting at 140$0^{\circ}C$ for 4 hours and thermally treated for nucleation and crystallization. The sucrose was added to the scoria to adjust the Fe2+/Fe3+ ratio during the melting process. The addition of 1-2w/o of sucrose showed the glass-ceramics body with the finest particle developed and dispersed over the entire range. It is concluded that the impurity content of iron oxide and titanium oxide play the most-influencial effect on the crystallization. When 1-2w/o of sucrose was added to the scoria, the value of Fe2+/Fe3+ ratio was 0.93-1.32 and showed the best result of crystallization. The nucleation temperature and time were calculated by the measurements of exothermic peak temperatures of DTA for quenched and thermally treated glasses. The nucleation temperature of scoria glass without the addition of sucrose was estimated as 75$0^{\circ}C$, but the addition of sucrose by 2w/o showed the nucleation temperature 6$25^{\circ}C$. The nucleation time was calculated with the same DTA curves. The nucleation times estimated were about 150min. for both of glasses without and with sucrose added. Finally, the activation energies for crystallization were calculated with the DTA data. The calculated activation energies were 143 Kcal/mole for the glass without addition of sucrose and 90Kcal/mole, 87Kcal/mole, 85Kcal/mole and 71Kcal/mole for the glasses of 1w/o, 2w/o, 3w/o and 4w/o addition respectively.

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EVALUATION OF PH CONTROL AGENTS INFLUENCING ON CORROSION OF CARBON STEEL IN SECONDARY WATER CHEMISTRY CONDITION OF PRESSURIZED WATER REACTOR

  • Rhee, In Hyoung;Jung, Hyunjun;Cho, Daechul
    • Nuclear Engineering and Technology
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    • v.46 no.3
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    • pp.431-438
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    • 2014
  • The effect of various pH agents on the corrosion behavior of carbon steel was investigated under a simulated secondary water chemistry condition of a pressurized water reactor (PWR) in a laboratory, and the steel's corrosion performance was compared with the field data obtained from Uljin NPP unit 2 reactor. All tests were carried out at temperatures of $50^{\circ}C-250^{\circ}C$and pH of 8.5 - 10. The pH at a given temperature was controlled by adding different agents. Laboratory data indicate that the corrosion rate of carbon steel decreased as the pH increased under the test conditions and the highest corrosion rate was measured at $150^{\circ}C$. This high corrosion rate may be related to high dissolution and instability of Fe oxide ($Fe_3O_4$) at $150^{\circ}C$. It was also found that an addition of ethanolamine (ETA) to ammonia was more effectivefor anticorrosion than ammonia alone, and that mixed treatment reduced 50% of iron or more at pHs of 9.5 or higher, especially in the steam generator (SG) and the moisture separator & re-heater (MSR).

A Stydy on the Wetting of Ceramic Oxides by Molten Metal (용융금속에 의한 Ceramic Oxides에서의 Wetting에 관한 연구)

  • Lee, Seok-Keun;Lim, Eung-Keuk;Kim, Whan
    • Journal of the Korean Ceramic Society
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    • v.20 no.4
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    • pp.289-296
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    • 1983
  • The Wetting of fusion cast $Al_2O_3$ brick and $Al_2O_3 -ZrO_2$ brick by liquid Ag was studied by the sessile drop technique in Ar atmosphere. In this experiment the specimens were photographed per 2$0^{\circ}C$with increasing temperature from 96$0^{\circ}C$ melting point of Ag. And the method of photographing was carried out by shadow technique. The cosine of the contact angle increased linearly with increasing temperature in both systems. And the relation between the cosine of the contact angle and the temperature was Cos$\theta$=1.132+$0.75{\times}10^{-3}T$ for $Al_2O_3$ brick and Cos$\theta$=-1.706+$1.125{\times}10^{-3}T$ for $Al_2O_3 -ZrO_2$ brick In both systems the contact angle decreased as the surface of substrate became smoother. The work of adhesion which was 503.5ergs/$cm^2$ for $Al_2O_3$brick and 393.6 ergs/cm2 for $Al_2O_3 -ZrO_2$ brick at 96$0^{\circ}C$ increased parabolically with increasing temperature in both system.

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