• Journal of the Society of Cosmetic Scientists of Korea
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• v.46 no.4
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• pp.319-327
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• 2020

Particulate matters (PM) are small particulate pollution that decrease the function of skin barrier, which causes inflammatory skin diseases and extrinsic aging. In this study, we evaluated the effect of preventing the adherence of PMs from several cosmetic products applied to human skin using iron oxide black. The PM floating chamber consists of skin exposure area, PM inlet, floating power device, and an outlet so that PM can be naturally attached to the skin while floating in the chamber. The change in skin brightness according to the floating concentration of alternative fine dust was checked to confirm the optimal floating concentration conditions. The intensity difference (before-after intensity, Δ) before and after adhesion of iron oxide black was proportional to the amount of PM adhered. The anti-adherence effect of iron oxide black on five cosmetic products were evaluated through 20 each subjects by comparing the amount of iron oxide black adhered on the control and treatment. The difference in brightness before and after the iron oxide black attached to the skin was calculated and compared with the control group(p < 0.05). When over 150 mg of iron oxide black was adhered on the skin, the interference of intensity was low and clearly showed the skin adhered pattern. According to the application of the five cosmetics, the intensity difference was significantly lower than the control group. This means that depending on the product, it prevented the attachment of iron oxide black. This study is a safe and useful method to confirm the prevention of PM skin adherence. In conclusion, cosmetics can prevent the adherence of PM on the skin according to the formulation or ingredients characteristics.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.30 no.4
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• pp.156-161
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• 2020

Recently, as there has been growing demand for aesthetic quality in structural materials, the development of excellent color cement concrete having good coloration properties has become a requirement. This study is designed to analyze the basic physical properties of mortar and the properties of keeping the coloration under an ultraviolet ray accelerated weathering test environment according to changes in the mixing ratio between carbon black and iron oxide used as colorants. The test results show that the use of carbon black and iron oxide reduces the initial flow by 6.3~17.2 % and the air content by 3.5~31.5 % but increases the unit volume weight by 3.4~5.5 %, compared to ordinary Portland cement (OPC). In addition, the study shows that the addition of iron oxide increases the self drying shrinkage. So, caution needs to be taken on the workability of the concrete. The brightness value L^⁎ represented by black showed the most excellent black colour when carbon black 3 % and iron oxide 5 % are added. According to UV accelerated weatherproof test, the brightness value L^⁎ was found to increase in all experiment specimens by 4.28~11.97 %, and the color change by UV was found to be higher for the case where carbon black colorant was not used. Therefore, in terms of color revelation characteristics, the case using carbon black 3 % and iron oxide 5 % was found to show the best black color.

• Journal of the Korean institute of surface engineering
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• v.26 no.3
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• pp.109-114
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• 1993

Black magnetite film could be formed on Invar steel for shadows mask by iron electroplating in thickness of 0.46~0.63$\mu\textrm{m}$ on Invar steel and subsequent oxidation of iron by immersion in strongly alkaline soution for 30~60 minutes. blackness degreed of magnetite oxide film on Invar was C20BL90 in comparision of color chart of Dainippon Ink & Chemicals Inc. Co. and adhesion test showed excellent adhesion of oxide film on substrate. Magnetite oxide film grew up on iron in hot strongly alkaline solution according to 'Sato-Cohen' oxide film growth model.

• Journal of Conservation Science
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• v.36 no.5
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• pp.393-404
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• 2020

We observed changes in the properties of the glaze layer according to the content of iron oxide and inferred the composition, content, and environment of the materials used in the past during the production process of black ware. First, experiments were conducted using different ratios of iron oxide, feldspar, calcite, and ash at different temperatures and firing environments; the characteristics of glaze were classified into five groups in the oxidation environment. Different properties were identified in the reducing environment above 1200℃. The crystal identified in the experiment was similar to the glaze characteristics in the excavated black ware. The crystal phase appeared in four groups: band shape, circular, arborescent phase, and needle crystal, depending on the change in the content of iron oxide. However, the difference in crystals did not appear significantly at high temperatures. In addition, crystals of glaze were divided into two groups depending on the component ratio. The presence or absence of feldspar is thought to affect crystallinity and amorphous iron oxide and the changes in the glaze layer changed substantially depending on the amount of iron oxide. In particular, it was confirmed that the aspects of iron oxide in the oxidation and reduction environments were different and, therefore, crystallization due to the firing environment also affected the optical characteristics.

• Journal of Conservation Science
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• v.35 no.6
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• pp.573-587
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• 2019

In this study, reproducing specimens were made from mixing domestically produced magnetite, clay and non-plastic raw materials to reproduce the pigments used in the manufacture of traditional cheolhwa buncheong stoneware. In order to reveal the color fomation of glaze, 30 specimens with good color development were analyzed scientifically. Magnetite, which is the main raw material of the pigment, is a pigment capable of creating a dark black color in a reducing environment at 1,200℃. However, it reacts with the additionally added lime component and discolors to greenish yellow color in oxidizing environment at 1,230℃. Hematite is not significantly affected by the firing temperature and environment, but develops a dark black color when mixed with clay with iron content of more than 10%. The fluidity of the pigment is determined by R₂O₃/RO₂ value, which also affects the color development. In the microtexture observation, the color formation of the glaze layer and the iron oxide crystals identified some differences depending on the particle size of the pigment and the firing environment. Reproduced specimens made of magnetite are present in the form of aggregates of iron oxide in the interface between glaze layer and slip layer in the oxidizing environment at 1,200℃. However, in the reducing environment, aggregates of iron oxides do not exist in the reproduced specimens, and they are homogeneously distributed in the glaze layer and formed a dark black color. In contrast, hematite-based specimens form dendritic structures in the glaze layer in an oxidizing environment and develop black.

• Journal of Korean Society of Water and Wastewater
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• v.24 no.3
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• pp.341-349
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• 2010

It is well known that manganese is hard to oxidize under neutral pH condition in the atmosphere while iron can be easily oxidized to insoluble iron oxide. The purpose of this study is to identify removal mechanism of manganese in the D water treatment plant where is treating bank filtered water in aeration and rapid sand filtration. Average concentration of iron and manganese in bank filtered water were 5.9 mg/L and 3.6 mg/L in 2008, respectively. However, their concentration in rapid sand filtrate were only 0.11 mg/L and 0.03 mg/L, respectively. Most of the sand was coated with black colored manganese oxide except surface layer. According to EDX analysis of sand which was collected in different depth of sand filter, the content of i ron in the upper part sand was relatively higher than that in the lower part. while manganese content increased with a depth. The presence of iron and manganese oxidizing bacteria have been identified in sand of rapid sand filtration. It is supposed that these bacteria contributed some to remove iron and manganese in rapid sand filter. In conclusion, manganese has been simultaneously removed by physicochemical reaction and biological reaction. However, it is considered that the former reaction is dominant than the latter. That is, Mn(II) ion is rapidly adsorbed on ${\gamma}$-FeOOH which is intermediate iron oxidant and then adsorbed Mn(II) ion is oxidized to insoluble manganese oxide. In addition, manganese oxidation is accelerated by autocatalytic reaction of manganese oxide. The iron and manganese oxides deposited on the surface of the sand and then are aged with coating sand surface.

• Journal of the Korean Chemical Society
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• v.21 no.2
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• pp.121-124
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• 1977

A study on the formation of black iron oxide was carried in differents of Fe(III), Fe(II) ion in the aqueous solution that iron(II) sulfate was calcined under various temperature and leached in water. The results obtained was follows; (1) It was found that the sample calcined in an electric muffle furnace maintained at $500^{\circ}C$ for 1 hour and leached in water was equivalent mole (Fe(III) /Fe(II) = 1) in 20% aqueous solution. (2) When the above mentioned solution was hydrolyzed at pH range of 7 to 8 for 2 hours at $100^{\circ}C$, 93% and over of iron was recovered in the form of ${\alpha}-Fe_3O_4$ with a black colour.

• Journal of the Korean Ceramic Society
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• v.53 no.3
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• pp.376-380
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• 2016

A composite electrode made of iron oxide nanoparticles/multi-wall carbon nanotube (iNPs/M) delivers high specific capacity and cycle durability. At a rate of $200mAg^{-1}$, the electrode shows a high discharge capacity of ${\sim}664mAhg^{-1}$ after 100 cycles, which is ~ 70% of the theoretical capacity of $Fe_3O_4$. Carbon black, carbon nanotube, and graphene as anode materials have been explored to improve the electrical conductivity and cycle stability in Li ion batteries. Herein, iron oxide nanoparticles on acid treated MWCNTs as a conductive platform are combined to enhance the drawbacks of $Fe_3O_4$ such as low electrical conductivity and volume expansion during the alloying/dealloying process. Enhanced performance was achieved due to a synergistic effect between electrically 3D networks of conductive MWCNTs and the high Li ion storage ability of $Fe_3O_4$ nanoparticles (iNPs).

• Clean Technology
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• v.21 no.2
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• pp.108-116
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• 2015

Hydrogen sulfide and ammonia are one of the common malodorous compounds that can be found in emissions from many sewages treatment plants and industrial plants. Therefore, removing these harmful gases from emissions is of significance in both life and industry because they can cause health problems to human and detrimental effects on the catalysts. In this work, pyrolytic carbon blacks from waste tires were used to develop adsorbent with good adsorption capacity for removal of hydrogen and ammonia. Pellet-type adsorbents were prepared by a mixture of carbon black, metal oxide and sodium hydroxide or hydrochloric acid, and their adsorption capacities were estimated by using breakthrough curve of a continuous fixed bed adsorption column at ambient condition. The adsorbent manufactured with a mixture of carbon black, iron oxide(III) and sodium hydroxide showed the maximum working capacity of hydrogen sulfide. For ammonia, maximum working capacity was obtained by the adsorbent manufactured with a mixture of carbon black, copper oxide(II) and hydrochloric acid.

• Journal of Conservation Science
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• v.35 no.4
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• pp.331-343
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• 2019

The purpose of this study was to investigate the material characteristics of black wares excavated from Yongyeon-ri, Damyang and to clarify the correlation of the factors that develop black coulor compared with black wares excavated from other regions. As a results of absorption rate, colour coordinate, compositional mineral, section analysis and contents showed high correlation between the kilns and the waste dumplings, indicating that they were made using the same materials. Second, comparing the microtextures and contents of the glaze layer with the excavated sherds from other kilns, a characteristic coagulation phenomena of iron oxides were not observed in Yongyeon-ri and Gilmyeong-ri, and it was considered that the material, mixing ratio, and firing environment were different from those of Bonggok-dong. In addition, statistical analysis using the major components revealed that the bodies of Yongyeon-ri were highly correlated with those of Bonggok-dong, which is nearest to the region, and similar to Gilmyeong-ri in the glaze layer. The characteristics of colorant were different depending on Fe₂O₃ content and K₂O content also contributed to the classification of the composition of each excavated kiln. Conclusionally, it can be seen from the scientific analysis that the colour of black wares excluded from different regions is materially different from that of iron oxide, the coloring condition, and the firing environment.