• 한국가스학회지
• /
• 제12권4호
• /
• pp.52-57
• /
• 2008

본 연구는 pH환경 중에서 고주파 열처리한 강인주철의 마멸 부식거동을 pH환경 중에서의 접촉압력에 따른 마멸부식거동, 침지 부식 후 부식마멸거동 및 전기화학적 부식거동에 대해 고찰하였다. 응축수의 pH가 낮아질수록 마멸부식율은 급격히 증가하고, 전기화학적 양극분극에 의한 강인주철의 부식양상은 중성에서 가늘고 긴 흑연의 편상조직이 나타나지만, 강산성 중에서는 흑연이탈 현상으로 표면이 거칠게 나타난다.

• Bulletin of the Korean Chemical Society
• /
• 제28권12호
• /
• pp.2279-2282
• /
• 2007

Highly crystalline, uniform Fe nanoparticles were successfully synthesized and encapsulated in zirconia shell using sol-gel process. Two different approaches have been employed for the coating of Fe nanoparticle with zirconia. The thickness of zirconia shell can be readily controlled by altering molar ratio of Fe nanoparticle core to zirconia precursor in the first case where as reaction time was found to be most effective parameter to controlled the shell thickness in the second method. The structure and magnetic properties of the ZrO2-coated Fe nanoparticles were studied. TEM and HRTEM images show a typical core/shell structure in which spherical α-iron crystal sized of ~25 nm is surrounded by amorphous ZrO2 coating layer. TGA study showed an evidence of weight loss of less than 2% over the temperature range of 50-500 °C. The nanoparticles are basically in ferromagnetic state and their magnetic properties depend strongly on annealing temperature. The thermal treatment carried out in as-prepared sample resulted in reduction of coercivity and an increase in saturation magnetization. X-ray diffraction experiments on the samples after annealing at 400-600 °C indicate that the size of the Fe@ZrO2 particles is increased slightly with increasing annealing temperature, indicating the ZrO2 coating layer is effective to interrupt growing of iron particle according to heat treatment.

• 한국주조공학회지
• /
• 제16권6호
• /
• pp.503-512
• /
• 1996

Austempered ductile irons(ADI) are characterized by their relatively high retained austenite content which has a significant effect on mechanical properties and performance, such as ductility, toughness, wear resistance and machinability. Austenitising treatment at $900^{\circ}C$ for $1{\sim}2hours$, and austempering treatment within the temperature range $240{\sim}400^{\circ}C$ on ductile cast iron alloyed with Cu and Mo were carried out, and the effects of retained austenite content on the mechanical properties and wear resistance were investigated. In consequence, the amount of retained austenite was found to be 13.5% at the austempering temperature of $240^{\circ}C$, and was increased 28% at $400^{\circ}C$. Tensile strength and hardness of austempered ductile iron were decreased as the retained austenite content increased, but elongation was increased. The retained austenite content at the austenitising time of 2hours was more than at 1hour. The amounts of rolling wear loss were increased as the retained austenite content increased, and the wear surface was become to be rough.

• 열처리공학회지
• /
• 제12권2호
• /
• pp.108-116
• /
• 1999

Gray cast iron with a high damping capacity has been used for controlling the vibration and noise in various mechanical structures. Nevertheless, its usage has been often restricted due to its poor tensile strength. Therefore, it is necessary to improve tensile strength at the expense of a loss in damping capacity. This study is aimed at finding the best combination of tensile strength and damping capacity by varying austempering time and temperature range from $320^{\circ}C$ to $380^{\circ}C$ after austenization at $900^{\circ}C$ for 1hr. The effect of austempering condition on hardness and the volume fraction of retained austenite is investigated as well. The results obtained are summarized as follows : (1) With an increase in austempering temperature, both tensile strength and hardness decrease while damping capacity improves. (2) Austempering at $350^{\circ}C$, resulting in a mixture of upper and lower bainite with partially retained austenite, exhibits the optimum combination of tensile strength and damping capacity.

• 한국주조공학회지
• /
• 제19권1호
• /
• pp.24-32
• /
• 1999

A series of investigations for Austempered Ductile Iron (ADI) castings were carried out by using the specimens with various chemical compositions and heat treatment conditions. The rolling wear characteristics of alloyed austempered ductile irons under an unlubricated dry rolling condition was evaluated by the Amsler type test with 9.09% sliding ratio. Generally, the wear amount was increased with the austempering temperature and decreased when the hardness of the matrix was higher. The alloying elements also influenced the austempering reaction, the microstructure and the mechanical properties. In this study, the mechanical properties (i.e.) ultimate tensile strength (UTS), hardness, elongation) and the wear resistance are analysed to show the relationship between the alloying elements and the austempering temperatures. Mo, Cu and Ni are alloyed individually or in combination. It has been found that when Cu and Ni alloyed individually to a casting, the wear amount is increased than others with elements alloyed in combination. The amount of rolling wear loss was decreased when Mo was alloyed in cast iron, individually or in combination.

• Corrosion Science and Technology
• /
• 제3권6호
• /
• pp.227-232
• /
• 2004

The carboxylates as a corrosion inhibitor has been studied by many researchers because of its environmental safety and low depletion rate. However, conventional test methods of inhibitor such as weight loss measurements, linear polarization resistance and corrosion potential monitoring etc., evaluate uniform corrosion of metals. These methods are unable to evaluate crevice-related corrosions, which are encountered in most of heat exchanging facilities. In order to choose the optimum corrosion inhibitor, the appropriate test methods are required to evaluate their performances in service environment. From this point of view, polarization technique was used to evaluate the characteristics of sodium heptanoate on corrosion behavior for carbon steel. Especially a thin film crevice sensor technique were applied to simulate the crevice corrosion in this study. From these experiments, we found that oxygen as an oxidizing agent was required to obtain stable passive film on the metal. Presence of oxygen, however, accelerated crevice corrosion. Potential shift by oxygen depletion and weakened inhibitive film inside the crevice were responsible for such accelerated feature. It is shown that film for corrosion inhibition is a mixture of sodium heptanoate and iron (II) heptanoate as reaction product of iron surface and sodium heptanoate. The iron (II) heptanoate which has been synthesized by reaction of heptanoic acid and ferrous chloride in methanol solution forms bidentate complex.

• Journal of Electrical Engineering and Technology
• /
• 제13권3호
• /
• pp.1275-1284
• /
• 2018

The coaxial magnetic gear with the flux concentrating structure is known that it has the torque performance advantage over the coaxial magnetic gear having surface mounted permanent magnet, thanks to the flux focusing effect. But, if the solid cores are used in the modulating pieces and rotor cores to consider the mechanical reliability and cost reduction, the operating torque of the flux concentrating coaxial magnetic gear can be significantly diminished because the iron losses at the solid cores affect the actual transmitted torque. Furthermore, the modulating pieces and rotor cores have different characteristics of the iron losses from one another, because the space harmonic components of the magnetic flux density, which cause the iron losses, are different. Thus, in this paper, we focused on the analysis of the characteristics of the space harmonic components of the magnetic flux density and resultant eddy current losses in the surface mounted PM and flux concentrating coaxial magnetic gears, when these coaxial magnetic gears have the solid cores at the modulating pieces and rotor cores. The characteristics of pull-out torque (static torque), operating torque (dynamic torque), and efficiency are also researched, and compared by the 3D finite element analysis (FEA) and experiment.

• 한국초전도ㆍ저온공학회논문지
• /
• 제23권3호
• /
• pp.14-19
• /
• 2021

The reduction of carbon dioxide emissions becomes a global issue, the main source of carbon dioxide emissions in the Asian region is the energy conversion sector, especially coal-fired power plants. We are working to develop technologies that will at least limit the increase in carbon dioxide emissions from the thermal power plants as one way to reduce carbon dioxide emissions. Our research aims to reduce carbon dioxide emissions by removing iron oxide scale from the feedwater system of thermal power plants using a superconducting high-gradient magnetic separation (HGMS) system, thereby reducing the loss of power generation efficiency. In this paper, the background of thermal power plants in Asia is outlined, followed by a case study of the introduction of a chemical cleaning line at an actual thermal power plant in Japan, and the possibility of introducing it into the thermal power plants in China based on the results.

• Journal of Nutrition and Health
• /
• 제33권2호
• /
• pp.147-157
• /
• 2000

This study examined the effects of excess intake of calcium (Ca) and iron (Fe) supplement on bone loss, nephrocalcinosis and renal function in osteoporotic model rats. Seven-week-old female rats were first fed a Ca-deficient diet for four weeks after ovariectomy operation, and then one of nine experimental diets for additional eight weeks, containing three levels of Ca, normal (0.5%) or high (1.5%) or excess (2.5%) and three levels of Fe, normal (35ppm) or high (210ppm) or excess (350ppm). The osteoporotic model rats showed a remarkable increase in body weight, serum alkaline phosphatase (ALP) and decrease in breaking force, Ca, P, Mg contents of femur. Serum Ca concentration was not significantly affected by dietary Ca and Fe levles. Liver Ca content increased in rats fed a high-and excess-Ca diet. Kidney Ca content and microscopic Ca deposition remarkably increased in osteoporotic model rats compared to control group, and showed a tendency to decrease in rats fed a excess-Ca diet. Breaking force of femur increased with increasing dietary Ca levels, but Ca, P contents of femur and serum ALP were not significantly affected by dietary Ca and Fe levels. Serum total protein decreased in rats fed a excess-Ca diet, BUN increased in rats fed a excess-Ca diet, while serum uric acid and creatinine were not significantly affected by dietary Ca levels. Urinary creatinine, GFR increased in rats fed a high-and excess-Ca, diet, and GFR was highest in rats fed a excess-Ca/excess-Fe diet. These results suggest that excess intake of Ca may increase breaking force of femur, but not increase mineral contents of femur, and decrease kidney function. Furthermore, excess intake of Fe and Ca concurrently may aggravate kidney function leading to potential health problems in ovariectomized osteoporotic model rats.

• 대한기계학회논문집A
• /
• 제27권3호
• /
• pp.363-371
• /
• 2003

This study is mainly concerned with phenomenon of cavitation-erosion on the several materials and corrosive liquids which were applied with vibrator(suggested by ASTM G 32, 20KHz, 50$mu extrm{m}$). The maximum erosion rate by cavitation erosion in both of distilled water and sea water appeared to be proportioned to their hardness and tensile strength. Cavitation weight loss and rate of cast iron in sea water condition were greater(approximately 3 times) than that in distilled water condition, however in case of stainless steel and brass the cavitation weight loss of composite materials were not so different in both of their conditions. Cavitation weight loss of composite materials were shown as below on this test, Duratough DL : Weight loss in sea-water condition were greater (approximately 2.3 times) than it's distilled water condition. The main tendency of cavitation erosion for metals appeared that small damaged holes causing by cavitation erosion was observed with radial pattern. On the other hand, the tendency for composites appeared that small damaged holes were observed randomly.