• 제목/요약/키워드: iron compound

검색결과 179건 처리시간 0.028초

Improving of Corrosion Resistance of Aluminum Alloys by Removing Intermetallic Compound

  • Seri, Osami
    • Corrosion Science and Technology
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    • 제7권3호
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    • pp.158-161
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    • 2008
  • It is well known that iron is one of the most common impurity elements found in aluminum and its alloys. Iron in the aluminum forms an intermetallic compounds such as $FeAl_3$. The $FeAl_3$ particles on the aluminum surface are one of the most detrimental phases to the corrosion process and anodizing procedure for aluminum and its alloys. Trial and error surface treatment will be carried out to find the preferential and effective removal of $FeAl_3$ particles on the surfaces without dissolution of aluminum matrix around the particles. One of the preferable surface treatments for the aim of getting $FeAl_3$ free surface was an electrochemical treatment such as cathodic current density of $-2kAm^{-2}$ in a 20-30 mass% $HNO_3$ solution for the period of 300s. The corrosion characteristics of aluminum surface with $FeAl_3$ free particles are examined in a $0.1kmol/m^3$ NaCl solution. It is found that aluminum with free $FeAl_3$ particles shows higher corrosion resistance than aluminum with $FeAl_3$ particles.

산세생략형 열연 용융아연도금강판의 특성 (A Study on Coating Adhesion of Hot Rolled Galvanized Iron Manufactured without pickling process)

  • 최진원;전선호
    • 한국표면공학회지
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    • 제32권1호
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    • pp.21-30
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    • 1999
  • Coating adherance behavior of low carbon steels, produced by POSCO, Korea, was studied in order to study the characteristics of hot rolled galvanized iron(HGI) manufactured without pickling line and the development of its process. Galvanizing experiments were carried out in zinc pot with 0.2wt% Al after hot rolled plates with scale were reduced at $550~750^{\circ}C$ in 10~30% hydrogen gas atmosphere during 60~400seconds. The reduced plates and coated products were examined by SST, XRD, SEM and EPMA on their surfaces and cross sections. Coating layer of HGI manufactured with pickling line was composed of retained scale, Fe-Zn-Al compound, Fe-Zn compound ($\delta_1\;and\;\zeta$ Phase) and pure zinc. It was superior to HGI in coating adhesion. It seems to be due to forming of Fe-Zn-Al compound in interface of matrix and retained porous scale.

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전통 제철실험을 통해 생산된 단조박편의 재료과학적 특성 연구 (A Study on the Metallurgical Characteristic of Hammer Scale Produced through Traditional Iron-making Experiments)

  • 조성모;조남철
    • 보존과학회지
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    • 제37권6호
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    • pp.738-747
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    • 2021
  • 제철원료별 직접제련법 복원실험으로 생산된 단조박편의 재료과학적 분석을 통해 금속학적 특성을 규명하였다. 제련을 위해 경주감포사철과 양양철광석을 이용하며, 각각 4개의 그룹을 설정하였다. 분석은 주성분, 광물 동정, 미세조직 관찰을 하였다. 주성분 분석 결과 정련·단접이 진행될수록 Fe의 함량은 증가하고 비금속개재물의 함량은 감소하였다. 광물을 동정한 결과 산화철 계열의 광물이 확인되었다. 미세조직 관찰 결과 Wüstite, Fayalite가 관찰되었으며, 일부에는 응집된 Wüstite가 관찰되었다. 일부 다각형, 장주상의 Magnetite도 확인되었다. 또한, 공극 및 불순물, 비금속개재물은 점차 감소하였다. 차후 다양한 제철원료를 이용한 복원실험을 통해 생산된 단조박편의 재료과학적 분석을 통해 금속학적 특성을 규명하고, 이를 유적에서 출토된 단조박편과 비교·검토하는 것이 필요하다.

양이온 성분이 수산화철 형성에 미치는 영향 조사 (Studying the Effect of Cation to the Formation of Iron Oxyhydroxide)

  • 오세진;이재영;권순주;유장용;주웅용
    • 한국재료학회지
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    • 제12권10호
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    • pp.796-802
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    • 2002
  • Effect of nine different cations to the formation of iron oxyhydroxide was studied using Mossbauer spectroscopy, XRD and BET. The Redox Potential and pH were measured for the determination of the internal reaction rate, as well. The phases of iron oxyhydroxide could not be the same with each other, due to the present of different cations in solution. Although the oxyhydroxide compound were composed of the same phases, the fraction of each phase was different from each other. The internal reaction rate was varied by the substitution of cation. It could be a cause of the different phase and particle size of oxyhydroxide compound.

혐기성 미생물부식에 의해 생성되는 철화합물 추정식 개발 (The Development of Estimation Model for Iron Compound Originated from Anaerobic Microbial Corrosion)

  • 전석준
    • 한국물환경학회지
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    • 제18권4호
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    • pp.379-386
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    • 2002
  • In this study, estimation model for iron compound originated from upflow, anaerobic fixed bed reactor, which treats sewage domestic wastewater, was developed. The estimation model was formulated by a mathematical expression which was based on the mass balance. Below the HRT of 60 minute, sulfide concentration combining with iron $FeS_2$ is the highest because the maximum sulfate consumption rate $V_{maxS}$ and half-saturation constant of sulfate $K_{mS}$ exert an important effect on the estimation model as temperature was increased. But increment of $FeS_2$ concentration is weakened above the HRT of 60 minutes and represent the lowest value at the HRT of 108 minutes. It implies that liquid phase distribution ratio of sulfide ${\alpha}r$ becomes lower as temperature was increased. While phosphorus concentration combining with iron $Fe_3(PO_4)_3$ is increased as HRT and temperature are increased, which is affected by phosphorus removal rate constant $k_p$. As the result of estimating the iron concentrations of corrosion by the model, the concentration of iron corrosion is higher than any other at the HRT of 108 minute and $20^{\circ}C$. The predicted values were compared with measured ones at different HRT(13.5, 27, 54, 108 min) and temperature(20, 25, $30^{\circ}C$). The experimental data could be fitted with the simulated curves. Therefore, the mathematical expression could be applicable to design full-scale wastewater treatment plants.

복합주조용 Al-Si-Mg 합금의 인장성질, 부식특성 및 주철과의 접합계면 화합물에 미치는 Cu 및 Zr 첨가의 영향 (Effects of Cu and Zr Addition on the Tensile Properties, Corrosion Characteristics and Interfacial Compounds with Cast Iron of Al-Si-Mg Alloy for Compound Casting)

  • 민경민;정기채;신제식;김정민
    • 한국재료학회지
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    • 제33권1호
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    • pp.8-14
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    • 2023
  • In order to broaden the range of application of light weight aluminum alloys, it is necessary to enhance the mechanical properties of the alloys and combine them with other materials, such as cast iron. In this study, the effects of adding small amounts of Cu and Zr to the Al-Si-Mg based alloy on tensile properties and corrosion characteristics were investigated, and the effect of the addition on the interfacial compounds layer with the cast iron was also analyzed. Although the tensile strength of the Al-Si-Mg alloy was not significantly affected by the additions of Cu and Zr, the corrosion resistance in 3.5 %NaCl solution was found to be somewhat lowered in this research. The influence of Cu and Zr addition on the type and thickness of the interfacial compounds layer formed during compound casting with cast iron was not significant, and the main interfacial compounds were identified to be Al5FeSi and Al8Fe2Si phases, as in the case of the Al-Si-Mg alloys.

김치의 섭취가 성인 남성의 철분영양상태 지표에 미치는 영향 (Effects of Kimchi Consumption on Iron Status in Adult Male Volunteers)

  • 오영주
    • Journal of Nutrition and Health
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    • 제30권10호
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    • pp.1188-1194
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    • 1997
  • The aim of this was to investigate whether the regular consumption of kimchi influences the iron status (RBC , Hb, Ht, MCH, MCV, MCHC, transferrin , serum iron, and ferritin) in volunteers. Healthy male adults(n=12) took part in the study subdivided into the control Ⅰ-phase(for 2weeks), kimchi-phase (for 4 weeks), and control Ⅱ-phase(for 2 weeks). In addition to their normal diet, participant consumed 300g of lactic acid fermented Chinese cabbage kimchi daily for four weeks. In the control Ⅰ and control Ⅱ phases, the participants kept up their normal diets without consuming any fermented foods. Dietary intakes were recorded for 3 consecutive days in each phase, with the aid of household measures. Every two weeks. blood specimens were analysed. Significant differences(p<0.05) between the phases were found in MCHC, and transferrin in blood were not significantly changed during kimchi consumption. However, serum iron and ferritin levels were significantly increased(p<0.05) during kimchi consumption, achieving the highest levels in the fourth week of the kimchi components(ascrobic acid, sulfer compound, organic acid, capsaicin, gingerol , allicin). Because of lacticacid fermented kimchi's potential to prevent anemia , the consumption of this food can be recommended.

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Two Neuroprotective Compounds from Mushroom Daldinia concentrica

  • Lee, In-Kyoung;Bong-Sik Yun;Young-Ho Kim;Ick-Dong Yoo
    • Journal of Microbiology and Biotechnology
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    • 제12권4호
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    • pp.691-691
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    • 2002
  • In the course of our screening for neuroprotective agents, a new compound (1) was isolated together with a known compound, caruilignan C (2), from the fruiting body of Daldinia concentrica. Their structures were determined on the basis of various spectral studies. Both compounds exhibited neuroprotective effect against iron-induced neurodegeneration in a primary culture of mouse cortical neurons.

Two Neuroprotective Compounds from Mushroom Daldinia concentrica

  • Lee, In-Kyoung;Yun, Bong-Sik;Kim, Young-Ho;Yoo, Ick-Dong
    • Journal of Microbiology and Biotechnology
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    • 제12권4호
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    • pp.692-694
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    • 2002
  • In the course of our screening for neuroprotective agents, a new compound (1) was isolated together with a known compound, caruilignan C (2), from the fruiting body of Daldinia concentrica. Their structures were determined on the basis of various spectral studies. Both compounds exhibited neuroprotective effect against iron-induced neurodegeneration in a primary culture of mouse cortical neurons.