• Title/Summary/Keyword: ion water

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Studies on the sterilizing effect of the silver ion. (은 이온의 항균작용에 관한 연구)

  • 김덕묵
    • Journal of the Korean Professional Engineers Association
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    • v.20 no.3
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    • pp.26-29
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    • 1987
  • The physical and chemical characteristics of bacteriostatic water filter media are compared to granular activated carbon upon which a silver impregnated. Silver ion that has been chemically impregnated the activated carbon was the bactericidal agent in water filter media. Also, silver Ion that has teen chemically impregnated onto the activated acetate resin was the bactericidal agent in ultrasonic humidifier. Silver impregnated active carbon and silver cartridge will be able to the bactericidal agents for statical water.

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Hydroxide ion Conduction Mechanism in Mg-Al CO32- Layered Double Hydroxide

  • Kubo, Daiju;Tadanaga, Kiyoharu;Hayashi, Akitoshi;Tatsumisago, Masahiro
    • Journal of Electrochemical Science and Technology
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    • v.12 no.2
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    • pp.230-236
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    • 2021
  • Ionic conduction mechanism of Mg-Al layered double hydroxides (LDHs) intercalated with CO32- (Mg-Al CO32- LDH) was studied. The electromotive force for the water vapor concentration cell using Mg-Al CO32- LDH as electrolyte showed water vapor partial pressure dependence and obeyed the Nernst equation, indicating that the hydroxide ion transport number of Mg-Al CO32- LDH is almost unity. The ionic conductivity of Mg(OH)2, MgCO3 and Al2(CO3)3 was also examined. Only Al2(CO3)3 showed high hydroxide ion conductivity of the order of 10-4 S cm-1 under 80% relative humidity, suggesting that Al2(CO3)3 is an ion conducting material and related to the generation of carrier by interaction with water. To discuss the ionic conduction mechanism, Mg-Al CO32- LDH having deuterium water as interlayer water (Mg-Al CO32- LDH(D2O)) was prepared. After the adsorbed water molecules on the surface of Mg-Al CO32- LDH(D2O) were removed by drying, DC polarization test for dried Mg-Al CO32- LDH(D2O) was examined. The absorbance attributed to O-D-stretching band for Mg-Al CO32- LDH(D2O) powder at around the positively charged electrode is larger than that before polarization, indicating that the interlayer in Mg-Al CO32- LDH is a hydroxide ion conduction channel.

Treatment Features of Ni Wastewater by using Coffee Grounds as the Adsorbent (커피 찌꺼기를 흡착제로 한 니켈 폐수 처리 특성)

  • Seo, Myung-Soon;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.21 no.1
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    • pp.14-20
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    • 2005
  • A feasibility study has been conducted regarding the application of waste coffee grounds as an adsorbent for the treatment of nickel ion containing wastewater. The major variables which considered to influence the adsorbability of nickel ion were its initial concentration, reaction temperature, pH, and coexisting ion. The specific surface area of coffee grounds used in the experiment was found to be ca. $39.67m^2/g$, which suggesting its potential applicability as an adsorbent due to its relatively high surface area. In the experimental conditions, more than 90% of the initial amount of nickel ion was shown to adsorb within 15 minutes and equilibrium in adsorption was attained after 3 hours. The adsorption behavior of nickel ion was well explained by Freundlich model and kinetics study showed that the adsorption reaction was second-order. Adsorption was reduced with temperature and its change of enthalpy in standard state was estimated to be -807.05 kJ/mol. Arrhenius equation was employed for the calculation of the activation energy of adsorption and nickel ion was observed to adsorb on coffee grounds exoentropically based on thermodynamic estimations. As pH rose, the adsorption of nickel ion was diminished presumably due to the formation of cuboidal complex with hydroxide ion and the coexistence of cadmium ion was found to decrease the amount of nickel ion adsorption, which was proportional to the concentration of cadmium ion.

Effects of pH, Alkalinity, Chloride Ion on the Copper Pipe Corrosion (동관에서 pH, 알칼리도, 염소이온이 부식에 미치는 영향)

  • Jo, Kwan-Hyung;Kim, Sun-Il;Woo, Dal-Sik
    • Journal of Environmental Health Sciences
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    • v.33 no.1 s.94
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    • pp.43-48
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    • 2007
  • This study investigated the effects of pH, alkalinity, and chlorine ion which are important water quality impact factors to the corrosion in the simulated distribution system where the copper pipe is affixed. The result shows that pitting index was increased as the alkalinity and chloride ion increase in the distilled water, but there was no relation to pH. Actually the uniform corrosion rate was decreased as the pH increase with the laboratory tap water. In conclusion, it is necessary to control the pH which stands above minimum 7.5 to prevent pitting corrosion in the copper pipe. Consequently, comprehensive research about the effect of lime soda($Ca(OH)_2$) which was used as a coagulation additive in the water treatment plant to pipe corrosion must be accomplished additionally.

Influence of counter anions on metal separation and water transport in electrodialysis treating plating wastewater

  • Oh, Eunjoo;Kim, Joohyeong;Ryu, Jun Hee;Min, Kyung Jin;Shin, Hyun-Gon;Park, Ki Young
    • Membrane and Water Treatment
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    • v.11 no.3
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    • pp.201-206
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    • 2020
  • Electrodialysis (ED) is used in wastewater treatment, during the processing and recovery of beneficial materials, to produce usable water. In this study, sulfate and chlorine ions, which are the anions majorly used for electroplating, were studied as factors affecting the recovery of copper, nickel and water from wastewater by electrodialysis. Although the removal rates of copper and nickel ions were slightly higher with the use of chlorine ions than of sulfate ions, the removal efficiencies were above 99.9% under all experimental conditions. The metal ions of the plating wastewater flowed through the ion exchange membrane of the diluate tank and the concentrate tank while all the water moved together due to electro-osmosis. The migration of water from the diluate tank to the concentrate tank was higher in the presence of a monovalent chloride ion compared to that of a divalent sulfate ion. When sulfate was the anion used, the recoveries of copper and nickel increased by about 25% and 30%, respectively, as compared to the chloride ion. Therefore, when divalent ions such as sulfate are present in the electrodialysis, it is possible to reduce the movement amount of water and highly concentrate the copper and nickel in the plating wastewater.

Selectivity of cations in electrodialysis and its desalination efficiency on brackish water (전기투석 막여과의 이온제거 특성 및 지하염수의 담수화효율)

  • Choi, Su Young;Kweon, Ji Hyang
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.4
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    • pp.445-456
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    • 2013
  • In this study, desalination by electrodialysis with ion exchange membranes was applied to synthetic waters with various ion concentrations and also for ground waters from coastal areas in Korea. Electrodialysis performance on the synthetic solutions showed the similar tendency in operation time and current curves, i.e., shorter operation time and higher maximum current with increasing applied voltages. The ED results of synthetic waters with different ion compositions, i.e., $Na_2SO_4$, $MgSO_4$, $CaSO_4$, at the similar conductivity condition, i.e., $1,250{\mu}s/cm$ revealed that effects of mono- and divalent ions on water quality and performance in electrodialysis were different. The divalent ions had less efficiency in the ED compared to monovalent sodium ions and also divalent calcium ions showed better performance than Mg ions. The electrodialysis on the ground waters produced high quality of drinking water. The groundwater from SungRoe however showed a buildup of membrane resistance. Organic matter concentrations and great portions of divalent ions in the groundwater were possible causes of the deteriorated performance.

Influence of Cu[II] on the Growth of Korean Axolotl, Hynobius leechii (동이온이 도롱뇽유생의 성장에 미치는 영향)

  • Park, Jin Ho;Won Hark Park;Sang Ock Park
    • The Korean Journal of Ecology
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    • v.6 no.2
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    • pp.106-113
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    • 1983
  • The growth of Korean axolotl., Hynobius leechii, was analyzed in natural water as control group and in six copper ion groups contaminated by 0.1, 0.2, 0.3, 0.4, 0.5, 0.6 ppm of copper ion. The copper ion checks the growth of the axolotl. The axolotl was not survived during 30 days in the copper ion of 0.3ppm, and, in the 0.4ppm the axolotl was not survived during 10 days after hatch. The growth of head width and body length show a convexing increase pattern, while that of hind leg shows a concaving increase pattern. The copper ion checks the development of hind leg. In the growth quantity of head width, body length and hid leg, that of natural water show the most rapid increase pattern, and copper ion groups of 0.1, 0.2, 0.3ppm follow in that order. The coefficient of relative growth($\alpha$) of control group is the greater value, and the copper ion groups of 0.1, 0.2, 0.3ppm follow in that order. The contaminated groups show the negative allometry in the relative growth of the containated groups to the natural water. Body length shows positive allometry, while hind leg shows negative allometry in the relative growth to head width.

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Direct Bio-regeneration of Nitrate-laden Ion-exchange Resin (질산성질소에 파과된 이온교환수지의 생물학적 직접 재생)

  • Nam, Youn-Woo;Bae, Byung-Uk
    • Journal of Korean Society on Water Environment
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    • v.29 no.6
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    • pp.777-781
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    • 2013
  • Ion-exchange technology is one of the best for removing nitrate from drinking water. However, problems related to the disposal of spent brine from regeneration of exhausted resins must be overcome so that ion exchange can be applied more widely and economically, especially in small communities. In this background, a combined bio-regeneration and ion-exchange system was operated in order to prove that nitrate-laden resins could be bio-regenerated through direct contact with denitrifying bacteria. A nitrate-selective A520E resin was successfully regenerated by denitrifying bacteria. The bio-regeneration efficiency of nitrate-laden resins increased with the amount of flow passed through the ion-exchange column. When the fully exhausted resin was bio-regenerated for 5 days at the flowrate of 30 BV/hr and MLSS concentration of $125{\pm}25mg/L$, 97.5% of ion-exchange capacity was recovered. Measurement of nitrate concentrations in the column effluents also revealed that less than 5% of nitrate was eluted from the resin during 5 days of bio-regeneration. This result indicates that the main mechanism of bio-regeneration is the direct reduction of nitrate by denitrifying bacteria on the resin.

Effective Electrolytic Water Generation Characteristics by Overlapped Multi-layer Electrode (중첩형 다단전극에 의한 효율적인 전해 이온수 발생 특성)

  • Shin, Dong-Hwa;Hwang, Deok-Hyun;Jung, Jae-Seung;Kim, Hyung-Pyo;Kim, Jin-Gyu
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.30 no.3
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    • pp.59-64
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    • 2016
  • Applications of electrolytic ion water generated by the oxidation-reduction have gradually been expanded due to their strong sterilizing power and a surface active force. We demonstrate the effect of the multi-layer type electrode for effective ion water generation. The multi-layer type electrode has ability to generate stronger acid and alkali water by increase of the electrode reactive area. Also power consumption efficiency enhances because the electrodes disposed in middle position of the reactive cell raise the usage rate by overlapped effect as an electrolysis electrode.

Phosphorus Adsorption by Layered Double Hydroxide (층상이중수산화물을 이용한 인 흡착)

  • Jung, Yong-Jun;Min, Kyung-Sok
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.4
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    • pp.404-410
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    • 2005
  • A series of batch type adsorption experiments were performed to remove aquatic phosphorus, where the layered double hydroxide (HTAL-CI) was used as an powdered adsorbent. It showed high adsorption capacity (T-P removal: 99.9%) in the range of pH 5.5 to 8.8 in spite of providing low adsorption characteristics (pH<4). The adsorption isotherm was approximated as a modified Langmuir type equation, where the maximum adsorption amount (50.5mg-P/g) was obtained at around 80mg-P/L of phosphorus concentration. A phosphate ion can occupy three adsorption sites with a chloride ion considering the result that 1 mol of phosphate ion adsorbed corresponded to the 3 moles of chloride ion released. Although the chloride ion at less than 1,000mg-CI/L did not significantly affect the adsorption capacity of phosphate, carbonate ion inhibited the adsorption property.