• 제목/요약/키워드: ion components

검색결과 589건 처리시간 0.023초

달천 폐광산 지역에서 광미적재지와 기반암 지하수의 수질특성 연구 (Characteristics of Groundwater Quality in Bedrock and Tailing Dumps at the Abandoned Dalcheon Mine Area)

  • 양성일;강동환;김태영;정상용;김민철
    • 자원환경지질
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    • 제41권1호
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    • pp.47-56
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    • 2008
  • 본 연구에서는 달천 폐광산 지역 내 25개 지점에서 현장수질(pH, Eh)을 측정되었고, 41개 지점에서 지하수를 채수하여 주이온 성분을 분석되었다. pH와 Eh성분은 모두 사문암 지역에서 가장 높았으며, pH는 약알칼리성에서 중성의 범위로 나타났다. 연구지역 내 지하수는 탄산염암과의 반응에 의한 산화 환원 환경이 지배적이었으며, 다른 암종에 의한 영향은 매우 적은 것으로 나타났다. 연구지역의 지하수 중 양이온은 $Ca^{2+},\;Mg^{2+}$, 음이온은 $SO_4^{2-}$ 성분이 높게 나타났다. 이는 탄산염암과 사문암, 유비철석과 황철석에 함유된 황 성분이 지하수에 다량 용해되었기 때문이다. 지하수내 이온성분 사이의 상관계수는 광미적재지에서 $Ca^{2+}$$SO_4^{2-}$ 성분이 0.95, $Ca^{2+}$$Mg^{2+}$ 성분이 0.86, $Mg^{2+}$$SO_4^{2-}$ 성분이 0.85로서 높게 나타났다. 또한 기반암 지하수에서는 $Mg^{2+}$$SO_4^{2-}$ 성분이 0.86, $Ca^{2+}$$SO_4^{2-}$ 성분이 0.68 정도로 나타났다. 양이온 중 $Ca^{2+}$ 성분이 광미적재지에서 $46.85\sim323.58mg/L$, 기반암에서 $3.18{\sim}207.20mg/L$로서 가장 넓은 농도 범위를 나타내었으며, 음이온 중 $SO_4^{2-}$ 성분이 광미적재지에서 $21.54{\sim}1673.17mg/L$, 기반암은 $2.04{\sim}1024.64mg/L$로 가장 넓은 농도 범위를 나타내었다. 대수층 매질 종류에 따른 파이퍼 다이아그램 분석 결과, 광미적재지는 Ca-$SO_4$형, 사문암 지역은 Mg-$SO_4$형과 Mg-$HCO_3$형, 탄산염암 지역은 Ca-$HCO_3$형, 혼펠스 지역은 Na-K형과 $CO_3+HCO_3$형이 우세한 것으로 나타났다. 본 연구를 통해 달천 폐광산 지역의 광미적재지에서 $Ca^{2+},\;Mg^{2+}$$SO_4^{2-}$ 성분이 지하수에 다량 용해되어 지하수의 주 흐름 방향에 위치한 기반암 지하수에 유입되었음을 알 수 있었다.

철제유물의 수용성 염소이온 측정방법에 대한 안정성 평가 (Stability Evaluation on Measuring Water-soluble Chloride Anions from Iron Artifacts)

  • 이재성;박형호;유재은
    • 보존과학회지
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    • 제26권4호
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    • pp.397-406
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    • 2010
  • 철제유물에서 용출된 수용성 염소이온의 농도를 측정하는 가장 이상적인 방법은 탈염처리 용액을 이온크로마토그래피(Ion Chromatography)로 분석하는 것이지만 대부분의 문화재 관련기관에서는 예산이나 전문인력 부족 등의 이유로 사용하지 못하고 염소이온농도 측정기(Cl meter)를 주로 사용하고 있다. 본 연구는 철제유물의 탈염처리 용액에 대한 염소이온농도 측정기의 $Cl^-$ 이온 농도 측정결과와 이온크로마토그래피의 측정결과를 교차 검증하여 상호 기기간의 신뢰성과 안정성을 평가하고자 한다. 분석결과 초순수는 염소이온농도 측정기의 전극에 잔류하는 수용성 염소이온의 영향으로 미량의 염소이온이 검출되었고, Sodium sesquicarbonate 시약 성분에 미량으로 존재하는 수용성 염소이온이 검출되었다. 탈염처리한 수용액은 탈염 1차에서 가장 많은 염소이온이 측정되었으며, 탈염 2차부터 탈염 4차까지는 소폭 감소하다가 초순수을 이용하는 탈알칼리 단계에서부터 다시 감소하는 경향을 보였다. 염소이온농도 측정기마다 측정횟수에 따른 편차를 보였으며, 탈염용액 내에 염소이온 농도가 높을수록 편차는 심해졌다. 하지만 염소이온 농도가 낮을 경우 편차가 적어 철제유물의 염소이온농도를 측정하기 위한 측정기기로 안정된 결과를 보였다. 전기전도도 측정법은 알칼리 용액의 전기전도도가 높게 나타남에 따라 $Cl^-$ 이온의 함량을 예측하기에는 부적합한 것으로 판단된다.

Development of Large-Area RF Ion Source for Neutral Beam Injector in Fusion Devices

  • Chang, Doo-Hee;Jeong, Seung Ho;Kim, Tae-Seong;Park, Min;Lee, Kwang Won;In, Sang Ryul
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.179.2-179.2
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    • 2013
  • A large-area RF-driven ion source is being developed at Germany for the heating and current drive of ITER device. Negative hydrogen ion sources are major components of neutral beam injection (NBI) systems in future large-scale fusion experiments such as ITER and DEMO. The RF sources for the production of positive hydrogen ions have been successfully developed at IPP (Max-Planck-Institute for Plasma Physics), Garching, for the ASDEX-U and W7-AS neutral beam heating systems. Ion sources of the first NBI system (NBI-1) for the KSTAR tokamak have been developed successfully with a bucket plasma generator based on the filament arc discharge, which have contributed to achieve a good plasma performance such as 15 sec H-mode operation with an injection of 3.5 MW NB power. There is a development plan of RF ion source at the KAERI to extract the positive ions, which can be used for the second NBI system (NBI-2) of the KSTAR and to extract the negative ions for future fusion devices such as Fusion Neutron Source and Korea-DEMO. The development progresses of RF ion source at the KAERI are described in this presentation.

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Laser Direct Writing 방법을 이용한 광도파로 제작 (Fabrication of waveguide using UV Ar-ion laser direct writing)

  • 강희신;서정;이제훈;김정오
    • 한국레이저가공학회지
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    • 제8권1호
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    • pp.9-18
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    • 2005
  • The laser direct writing method using a UV Argon-ion laser is studied for fabrication of waveguide. The laser direct writing system is constructed with a vision camera, a xy-stage, a motion controller and the delivery components of a laser beam. The UV Argon-ion laser has wavelength range of $333.6\~363.8$ nm. A photo-active UV curable polymer for a planar light-wave circuit(PLC) of single mode is used. This polymer is irradiated by Argon-ion laser and developed by a solvent after a post-baking. The optimum laser direct writing condition is obtained experimentally by changing various process parameters such as laser power, writing speed and focal length. The propagation and coupling loss of a optical waveguide was measured as 1dB/cm and 0.6dB/cm, respectively. Also, the minimum width of waveguide of $100{\mu}m$(ZPLW-207) is obtained. Finally, the waveguides of line, bend and branch type are successfully fabricated.

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Effects of ion irradiation on microstructure and properties of zirconium alloys-A review

  • Yan, Chunguang;Wang, Rongshan;Wang, Yanli;Wang, Xitao;Bai, Guanghai
    • Nuclear Engineering and Technology
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    • 제47권3호
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    • pp.323-331
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    • 2015
  • Zirconium alloys are widely used in nuclear reactors as structural materials. During the operation, they are exposed to fast neutrons. Ion irradiation is used to simulate the damage introduced by neutron irradiation. In this article, we briefly review the neutron irradiation damage of zirconium alloys, then summarize the effect of ion irradiation on microstructural evolution, mechanical and corrosion properties, and their relationships. The microstructure components consist of dislocation loops, second phase precipitates, and gas bubbles. The microstructure parameters are also included such as domain size and microstrain determined by X-ray diffraction and the S-parameter determined by positron annihilation. Understanding the relationships of microstructure and properties is necessary for developing new advanced materials with higher irradiation tolerance.

원통형 보염기 후류에 형성되는 확산화염의 연소특성에 관한 연구 (A Study on the Combustion Characteristics of Diffusion Flame Formed in the Wake of Cylindrical Bluff Body)

  • 안진근;임덕재;노태선;송규근
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 1998년도 제17회 KOSCI SYMPOSIUM 논문집
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    • pp.23-30
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    • 1998
  • The stabilization characteristics of diffusion flame formed in the wake of a cylindrical flame holder were investigated. Distribution of turbulence intensity, concentration distribution of combustion gas, and ion currents were measured. The turbulence intensity in the wake of cylindrical- game holder is increased with increase of diameter or blockage ratio of grid. If the auxiliary fuel is injected into recirculation zone, the concentration of $C_3H_8$ is high, but the concentration of $CO_2$ is low at the boundary of recirculation zone. The region with highest average value of ion currents in the middle of flame is moved to the upstream side by the turbulent components of main stream. The flame mass with partially active reaction is moved fast for uniform flow and turbulence generator G3, but the flame mass with relatively slow reaction is moved slowly for turbulence generator G1.

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A STUDY ON WEAR AND CORROSION RESISTANCE OF CrN$_{x}$ FILMS BY CATHODIC ARC ION PLATING PROCESS

  • Han, Jeon-G.;Kim, Hyung-J.;Kim, Sang-S.
    • 한국표면공학회지
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    • 제29권5호
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    • pp.545-548
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    • 1996
  • $CrN_x$ films were deposited on SKD61 and S45C by cathodic arc ion plating process. In this study, the microstructure, microhardness, a hesion, wear and corrosion properties of the CrNx films were studied for various nitrogen partial pressures and the results were compared with those from the electroplated hard Cr. The crystal structure of the films was characterized by X-ray diffraction. Wear tests were performed under no lubricant condition at atmosphere by ball-on-disc type tribotester. Corrosion resistance of the films were studied by electrochemical corrosion test, measuring current demsity-potential curves. The results indicated that the $CrN_x$ films formed using ion plation method showed higer hardness and lower current density, friction coefficient than electroplated hard Cr. Consequently, the application of the CrNx coationgs by ion plating which is free of environmental pollution, is expected to improve lifetime of components in industrial practice.

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Solid Lubrication Characteristics of DLC Coated Alumina Seals in High Temperature

  • 옥철호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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    • pp.356-356
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    • 2007
  • Plasma immersion ion beam deposition (PIIBD) technique is a cost-effective process for the deposition of diamond like carbon thin film, the possible solid lubricant on large surface and a complex shape. We used PIIB process for the preparation of DLC thin film on $Al_2O_3$ with deposition conditions of deposition temperature range $200^{\circ}C$, working gas pressure of 1.310-1Pa. DLC thin films were coated by $C_2H_2$ ion beam deposition on $Al_2O_3$ after the ion bombardment of SiH4 as the bonding layer. Energetic bombardment of $C_2H_2$ ions during the DLC deposition to ceramic materials generated mixed layers at the DLC-Si interface which enhanced the interface to be highly bonded. Wear test showed that the low coefficient of friction of around 0.05 with normal load 2.9N and proved the advantage of the low energy ion bombardment in PIIBD process which improved the tribological properties of DLC thin film coated alumina ceramic. Furthermore, PIIBD was recognized as a useful surface modification technique for the deposition of DLC thin film on the irregular shape components, such as molds, and for the improvement of wear and adhesion problems of the DLC thin film, high temperature solid lubricant.

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MICROSTRUCTURAL STUDY OF $Fe_{1-x}Ti_x$ ALLOYS FORMED BY ION BEAM MIXING

  • Jeon, Y.;Lee, Y.S.;Choi, B.S.;Woo, J.J.;Whang, C.N.
    • 한국진공학회지
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    • 제6권S1호
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    • pp.127-132
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    • 1997
  • Microstructure of the Fe-Ti system by ion beam mixing of multilayers at 300 K and 77 K has been studied in a wide composition range. The ion bombardment was carried out using $Ar^+$ ions at 80 keV. Using grazing angle x-ray diffraction we find that the lattice parameters of these bcc solid solutions are very close to that of $\alpha$-Fe. Extended x-ray absorption fine-structure spectroscopy have been performed to investgate the short-range order in the ion-beam-mixed state. The structure parameters, such as the interatomic distance and the coordination number are estmated from the Fe K-edge Fourier filtered EXAFS spectra. The interatomic distance is independent of the alloy concentration and it is almost constant. The study of x-ray absorption near-edge structure gives information on the individual $\rho$components of the partial densityof states of the conduction band of the Fe and Ti We also find that a charge transfer from Ti to Fe atoms takes place.

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