• 펄프종이기술
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• 제38권5호
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• pp.24-30
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• 2006

This study was performed to characterize inverse emulsion type cationic polyacrylamide (PAM) and to compare with powder and salt dispersion type PAMs as a retention and drainage aid. Salt dispersion type PAM has defects of high amount of salt which increases conductivity of white water, low active polymer contents and relatively worse retention and drainage properties than others because of its low molecular weight. Powder type PAM has benefit of high active polymer contents and good retention and drainage properties, but defects of low dissolution speed and insoluble particle generation were observed. However, inverse emulsion type showed the best retention and drainage aids among them by controlling molecular weight and morphology easily and it had relatively higher active polymer contents and better solubility.

• 한국염색가공학회지
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• 제7권4호
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• pp.45-53
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• 1995

Natural rubber(NR)-polyacrylamide(PAAm) graft copolymers(GP)(toluene soluble GP : TSGP, water dispersible GP : WDGP) have been synthesized as coupling agents by pre-emulsification methods based on "inverse emulsion graft polymerization" technique. The polymerization was carried out at $65^{\circ}C$ using Azobisisobytyro nitrile(AIBN) as an initiator in the inverse emulsion system formed by inxing NR toluene solution with inverse emulsion of awueous AAm solution emulsified with $Tween^{\#}$ 80 in toluene. The mechanism of inverse emulsion graft copolymerization was studied on AAm conversion, % grafting, grafting efficiency, NR conversion, production ratio of TSGP and amount of GP(sum of TSGP and WDGP). The reaction has been confirmed through use of optical microscope to proceed via adsorption of emulsifier colloid particles onto the stretched NR molecule. From the analysis of the effects of various polymerization conditions on the grafting, it has also been found that the present rection system can easily yield high(over 90%) grafting efficiency and AAm conversion and relatively high(over 80%) NR conversion.onversion.

• 한국응용과학기술학회지
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• 제6권1호
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• pp.1-7
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• 1989

To developed new process for obtaining maximum molecular weight of anionic acrylamide and acrylic acid copolymer by inverse emulsion polymerization. Concentration of initiator, reducing agent, surfactant and mole ratio of acrylamide-acrylic acid were studied for the process. Semi-batch processes with method of redox, control of reaction temperature, feeding method of monomer and reaction time, was suitable for maximum molecular weight of P(AMAC) from this process obtained $3.09\;{\time}\;10^6({\bar{M}}n.)$ and $4.41\;{\time}\;10^6({\bar{M}}w.)$ in molecular weight measured by the intrinsic viscosity method. inverse emulsion polymerization mechanism of P(AMAC) does not followed the Smith-Ewart and Medvedev theory, but selected for concentration of initiator, reducing agent, surfactant, water solubility of monomer.

• 펄프종이기술
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• 제39권3호
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• pp.36-40
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• 2007

It has been problematic to repulp the dry broke treated with permanent wet strength agents like PAE, UF and MF. Solution type GPAM has the benefit of easy repulping but it has problems of cocross-linking and tends to gel. Therefore, the product concentration must be lower than 10% to reduce the gel generation problem. We developed emulsion type GPAM by an inverse emulsion technology to resolve both the repulping problem with permanent wet strength agents and the stability problem of GPAM solution products.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2008년도 춘계학술대회
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• pp.1-9
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• 2008

• 대한기계학회논문집B
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• 제39권8호
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• pp.677-682
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• 2015

격자 볼츠만 기법(Lattice Boltzmann method)을 사용하여 에멀전의 유변학적 특성을 파악하기 위한 시뮬레이션을 수행하였다. 간단한 전단 유동하에서 온도와 전단속도, 계면장력에 변화를 주어 에멀전(decane-in-water)의 상대점도를 계산하고 이를 분석하였다. 에멀전의 상대점도는 온도가 증가함에 따라 감소하였고, 전단속도가 증가함에 따라 감소하는 전단박하(Shear thinning) 현상을 보여주었다. 이는 크로스 모델(Cross model)을 통해 검증하였고 일치하는 경향을 보여주었다. 계면에 존재하는 계면활성제(Surfactant)를 통해 제어되는 계면장력이 증가할수록 상대점도는 감소하는 경향을 보여주었다. 이것은 큰 계면장력에서는 기름방울의 변형이 억제되고 점도가 상대적으로 높은 기름방울의 표면적이 감소하면서 나타난다고 해석할 수 있다.

• Tribology and Lubricants
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• 제2권2호
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• pp.12-19
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• 1986

냉각성, 난연성, 그리고 경제성의 면에서 우수한 윤활특성을 갖고 있는 이멀션윤활제를 사용하여 로울러와 프레이트간의 선접촉 및 광간섭계의 실험장치를 통하여 탄성유체윤활 영역에서의 윤활기구 및 분산립자의 거동기구를 명확히 하여 다음과 같은 결론을 얻었다. 1. 스퀴즈 유막내의 유동은 윤활간극이 비교적 넓은 경우와 좁은 경우로 대별하여 전자의 경우에는, 입자분포 및 속도분포의 영향이 크게 나타나며, 후자의 경우는 이멀션입자가 간극내에 정지하여 유막두께의 감소와 더불어 변형되어 간다. 2. 스퀴즈 유막내의 O/W, W/O 각 이멀션의 유동은 간극이 클 경우, 입경에 의한 속도차가 역으로 나타나고, 작은 경우에는 잔류액적의 분포가 서로 다르며 그밖에 O/W 형은 W/O 형에 비하여 분산입자가 쉽게 변형하는 것을 알 수 있다. 3. EHL영역입구부에서는 입자의 유동속도가 극히 적은 정체영역이 존재하며, 그 부근에서의 입자의 거동은 입경에 따라서 다르다. 4. 2색광에 의한 광간섭선의 관찰에 의하여 탄성유체윤활 영역내를 통과하는 이멀션유를 확인함과 동시에 EHL영역입구부에서의 분열거동이 관찰되었다.

• 폴리머
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• 제35권4호
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• pp.363-369
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• 2011

콘크리트 제조 시 사용되는 잉여수를 지연 흡수시키기 위하여 역유화중합법으로 중합된 가교 poly(sodium acrvlate) (cPSA)를 ethylene glycol dimethacrylate(EGDMA)로 표면 가교시켰다. cPSA의 제조에서 연속상은 paraffin liquid, 단량제는 8 M 농도의 NaOH 수용액으로 90% 중화된 acrylic acid(AA), 가교제는 N,N-methylene bisacrylamide(MBA), redox 개시제는 ammonium persulfate(APS)와 sodium metabisulfite(SMBS)를 사용하여 역유화중합법으로 제조하였다. 제조된 cPSA는 EGDMA플 사용하여 표면 가교 반응을 수행하였다. 시멘트 수용액에서 $Ca^{2+}$ 이온과 cPSA의 상호 작용을 관찰하기 위하여 FTIR spectroscopy 분석법을 사용하였다. 제조된 흡수제들을 탈이온수 $Ca(OH)_2$ 수용액(pH 12) 및 시멘트 포화 수용액에서의 팽윤비를 측정하였으며, cPSA는 2시간만에 팽윤이 완료되었지만, 표면이 가교된 cPSA-EGDMA는 3시간 후 팽윤이 거의 완료되는 것을 관찰하였다. 또한 합성한 cPSA-EGDMA를 첨가함으로써 시멘트의 응결시간과 모르타르의 압축강도 증가를 관찰하였다.

• 한국분말재료학회지
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• 제18권4호
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• pp.347-358
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• 2011

Two different schemes were adopted to fabricate ordered macroporous structures with face centered cubic lattice of air spheres. Monodisperse polymeric latex suspension, which was synthesized by emulsifier-free emulsion polymerization, was mixed with metal oxide ceramic nanoparticles, followed by evaporation-induced self-assembly of the mixed hetero-colloidal particles. After calcination, inverse opal was generated during burning out the organic nanospheres. Inverse opals made of silica or iron oxide were fabricated according to this procedure. Other approach, which utilizes ceramic precursors instead of nanoparticles was adopted successfully to prepare ordered macroporous structure of titania with skeleton structures as well as lithium niobate inverted structures. Similarly, two different schemes were utilized to obtain disordered macroporous structures with random arrays of macropores. Disordered macroporous structure made of indium tin oxide (ITO) was obtained by fabricating colloidal glass of polystyrene microspheres with low monodispersity and subsequent infiltration of the ITO nanoparticles followed by heat treatment at high temperature for burning out the organic microspheres. Similar random structure of titania was also fabricated by mixing polystyrene building block particles with titania nanoparticles having large particle size followed by the calcinations of the samples.

• Journal of Pharmaceutical Investigation
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• 제40권2호
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• pp.73-78
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• 2010

Hydrogels are thought to be a promising delivery carrier for protein drugs because of their favorable aqueous environment compared with nano/micro-particles of hydrophobic polymer such as PLGA. In this study, nano-sized hydrogels (nanogels) were fabricated using inverse-miniemulsion polymerization method. The mean size of nanogels in range of 90-160nm and affected by the preparation parameters such as sonication time and concentration of monomer. While longer sonication time and lower concentration of acrylamide monomer showed a tendency to produce smaller nanogels and to have lower lysozyme activity, variation of bis-methylene acrylamide concentration made no difference. Although both longer soncaton time and lower acrylamide concentration increased in vitro release rate, acrylamide concentration was more effectively affected to the control of protein release rate, which indicated that the release rate of protein from nanogels affected by not only their size but also internal structure. In conclusion, nanogels prepared by inverse-miniemulsion can be a useful carrier for application of protein drug, because of simple process, minimum contact of organic solvent and high protein activity.