• Title/Summary/Keyword: internal starches

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Fundamental Study on the Substitution of Surface Sizing Using Internal Starches(Part 1) (내첨 전분을 이용한 표면사이징 대체에 관한 기초연구(제1보))

  • Kim, Chul-Hwan;Lee, Ji-Young;Back, Kyung-Kil;Lee, Young-Rok;Chung, Ho-Kyung;Lee, Hui-Jin;Gwak, Hye-Joeng
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.41 no.2
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    • pp.20-25
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    • 2009
  • Many researches are carried out for developing the technology to substitute the surface sizing, although this process improves physical properties and water resistance of paper. This is because surface sizing has fundamental limitation to increase drying energy consumption and to restrict speed of paper machine. However, practical and effective technologies were not developed yet. In this study, we investigated the possibility of the substitution of surface sizing using internal starches, such as cationic starch and oxidized starch. To identify effects of internal starches on physical and optical properties, papers were not only made by adding internal starches into pulp slurry but papers surface sized with oxidized starch were also prepared to compare physical and optical properties. Consequently, tensile strength and internal bond of paper containing internal starches were higher than those of surface sized paper by controlling the type and addition level of cationic starch.

Exploitation of Cationic Starches for Improving Papermaking Process and Quality of Newsprints (신문용지의 제조공정과 품질 개선을 위한 양성전분의 탐색)

  • Lee, Hak-Lae;Ryu, Hoon;Ham, Chung-Hyun;Cho, Seok-Cheol
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.32 no.3
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    • pp.18-24
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    • 2000
  • To evaluate the efficiency of various cationic starches in improving retention drainage and strength properties of newsprints which are being made using extensive amount of domestic recycled wastepapers in a highly closed papermaking system diverse cationic starches have been prepared and tested. In the case of cationic starches with low charge density as the degree of substitution increas-es fines retention increased. Results also showed that the retention efficiency decreased sub-stantially for cationic starches with low DS when the conductivity of white water inceased. Tensile strength increased with the addition of cationic starches and then decreased. On the other hand internal bonding strength increased linearly with the addition of cationic starch. Oxidizing treatment of cationic starch was detrimental for retention and freeness improve-ment. Also crosslinking treatment of wet processed cationic starches made cationic starches less effective in retention and drainage.

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The Effects of Blending Starches on the Development of Plybond Strength of Two-ply Linerboard (삼성분 전분혼합에 의한 이겹지의 층간결합강도 개선)

  • Lee, Hak-Lae;Ryu, Jeong-Yong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.39 no.4
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    • pp.14-20
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    • 2007
  • The effects of blending starches with different gelatinization temperatures on the development of ply-bond strength were systematically investigated using a three component mixture design technique. Oxidized corn starches with different gelatinization temperatures were blended with natural corn starch and sprayed for plybonding. Optimum blend ratio for maximizing plybond strength improvement for the starch blends was 40% of natural starch, 27% of oxidized starch with low gelatinization temperature and 33% of oxidized starch with high gelatinization temperature. Starch granules with the lowest gelatinization temperature gelatinizes at the lowest temperature, while the natural corn starch gelatinizes at later stage of drying. The improvement of plybond strength with starch blends were verified on machine trial as well. Plybond strength improvement obtained from the machine trial was lower than that achievable with handsheets, which was attributed to the lower internal bond strength of the linerboards made from recycled fibers.

Effect of Ohmic Heating on Rheological Property of Starches (옴가열이 전분의 레올로지 특성에 미치는 영향)

  • Cha, Yun-Hwan
    • The Korean Journal of Food And Nutrition
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    • v.32 no.4
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    • pp.304-311
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    • 2019
  • Ohmic heating is a heating method based on the principle when an electrical current passes through food. Since this method is internal, electrical current damage occurred during heating treatment. The results of ohmic heated starch's external structure, X-ray diffraction, DSC analysis and RVA were differed from those of conventional heating at the same temperature. Several starches changed more rigid by structure re-aggregation. This change in starch was caused by change of physical, chemical, rheological property. The rheology of ohmic heated potato and corn starch of different heated methods were compared with chemically modified starch. After gelatinization, sample starch suspension (2%, 3%) measured flow curves by rheometer. Cross-linked chemically modified starch's shear stress was decreased with degree of substitution reversibly. Ohmic heated more dramatic, at $60^{\circ}C$. Potato starch's shear stress was less than commercial high cross-linked modified starch. Flow curves of potato starches measured at $4^{\circ}C$, $10^{\circ}C$, $20^{\circ}C$. Showed that Ohmic heated potato starch's shear stress ranging between $4^{\circ}C$ and $20^{\circ}C$ was narrower than modified starch. According to this study, ohmic heated potato starch can be used by decreasing viscosity agent like cross-linked modified starch.

Effect of Ohmic Heating on Pasting Property of Starches (옴가열이 전분의 Pasting 특성에 미치는 영향)

  • Cha, Yun-Hwan
    • The Korean Journal of Food And Nutrition
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    • v.30 no.4
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    • pp.689-695
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    • 2017
  • Ohmic heating is an internal heating method based on the principle that when an electrical current passes through food, electric resistance heat is uniformly generated internally by food resistance. Previous studies indicate that the thermal properties, external structure, internal structure, and swelling power of ohmic heat treated starch of various starches, such as potato, wheat, corn, and sweet potato, differed from those of conventional heating at the same temperature. In this study, the pasting property of starch, treated with ohmic and conventional heating, were measured by RVA (Rapid Visco-Analyzer). Our results show that as the ohmic heating temperature increased, the PV (Paste Viscosity) of the starch decreased significantly, and the PT (Pasting Temperature) increased. Changes in PV and PT indicate that the swelling of starch remains unchanged by ohm heating. The HPV (Hot Paste Viscosity), CPV (Cold Paste Viscosity) and SV (Setback Viscosity) of ohmic heated starch also differed from the conventional heated starch. The pasting property is similar to the viscosity curve of common cross-linked modified starch. In this experiment, we further confirm the similarity with modified starch and its usability.

Physicochemical Properties of Hydroxypropylated Rice Starches (하이드록시프로필화 쌀 전분의 이화학적 특성)

  • Choi, Hyun-Wook;Koo, Hye-Jin;Kim, Chong-Tai;Hwang, Seong-Yun;Kim, Dong-Seob;Choi, Sung-Won;Hur, Nam-Youn;Baik, Moo-Yeol
    • Korean Journal of Food Science and Technology
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    • v.37 no.1
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    • pp.44-49
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    • 2005
  • Physicochemical properties of hydroxypropylated rice starches were investigated. Swelling power of hydroxypropylated rice starch increased at relatively lower temperature than native rice starch. Solubility of hydroxypropylated rice starch was lower (1.9-13.4%) than that of native rice starch (2.2-13.8%), and increased with increasing amount of propylene oxide. Pasting temperature ($66.2-70.8^{\circ}C$) and peak viscosity (2,843-3,395cp) of hydroxypropylated rice starch were lower than those of native starch ($71.6^{\circ}C,\;3,976\;cp$) and decreased with increasing amount of propylene oxide, regardless of reaction time. DSC thermal transitions of hydroxypropylated rice starches shifted toward lower temperature. Amylopectin-melting enthalpy of hydroxypropylated rice starch decreased (11.8-9.8J/g) with increasing amount of propylene oxide and was lower than that of native starch (11.9 J/g). These results indicate hydroxypropylation lowered swelling power and gelatinization temperatures of rice starch, because internal bonds of rice starch molecules were sterically weaken by substituted hydroxypropyl groups.

Effect of Ohmic Heating on External and Internal Structure of Starches (옴가열이 전분의 외부와 내부 구조에 미치는 영향)

  • Cha, Yun-Hwan
    • The Korean Journal of Food And Nutrition
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    • v.28 no.1
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    • pp.126-133
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    • 2015
  • Ohmic heating uses electric resistance heat which occurs equally and rapidly inside food when the electrical current is transmitted into. Prior to the study, we have researched the potato starch's thermal property changes during ohmic heating. Comparing with conventional heating, the gelatinization temperature and the range of potato starch treated by ohmic heating are increased and narrowed respectively. This result is appeared equally at wheat, corn and sweet potato starch. At this study, we treated potato, wheat, corn and sweet potato starch by ohmic/conventional method and observed change of external structure by microscope and internal structure by X-ray diffractometer. Conventional heated at $55^{\circ}C$ potato starch was not external structural changes. But ohmic heated potato starch is showed largely change. Some small size starch particle were broken or small particles are made of larger particle together or small particles caught up in the large particle. Changes in ohmic heated potato starch at $60^{\circ}C$ was greater. The inner matter came to an external particle burst inside and only the husk has been observed. The same change was observed in the rest of the starch. The change of internal structure of potato starch was measured using X-ray diffraction patterns. There was no significant difference between ohmic and conventional heating at $55^{\circ}C$. But almost every peak has disappeared ohmic at $60^{\circ}C$. Especially $5.4^{\circ}$ peak to represent the type B was completely gone. When viewed from the above results, external changes with change in the internal crystal structure of the starch particles were largely unknown to appear. In conclusion, during ohmic heating changes of starch due to the electric field with a change in temperature by the heating was found to have progressed at the same time.