• Title/Summary/Keyword: interfacial property

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Interfacial Characteristics of Glass Fiber/Nylon 6 Composites (유리섬유/나일론 6 복합재료의 계면특성 연구)

  • Cho, D.;Yun, S.H.;Kim, J.;Lim, S.;Park, M.;Lee, S.-S.;Chung, H.K.
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.10a
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    • pp.252-256
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    • 2002
  • 본 연구에서는 유리섬유/나일론 6 복합재료의 계면특성에 미치는 실란계 사이징제의 영향을 조사하기 위하여 microbonding test, short-beam shear test 그리고 dynamic mechanical analysis 방법을 사용하였다. 전자의 미시적인 방법과 후자의 두 가지 거시적인 접근 방법으로부터 얻은 유리섬유/나일론 6 복합재료의 계면특성에 대한 결과가 서로 일치하였다. 상업적으로 사이징 처리된 경우와 비교할 때, 본 연구에 적용된 네 종류의 실란계 사이징제는 유리섬유-나일론 6 수지의 계면결합력을 크게 향상시켰다. 특히, 3-chloropropyltrimethoxysilane (Z-6076)의 사용은 유리섬유/나일론 6 복합재료의 계면전단강도와 층간전단강도를 가장 두드러지게 증가시켰다.

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Characterization of the Ni and Ni-Cr Porous Metal Reinforced AC4C Matrix Composites Fabricated by Squeeze Casting (용탕단조법에 의한 Ni, Ni-Cr 다공질 발포금속 강화 AC4C 합금기 복합재료에 관한 연구)

  • Kim, Eok-Soo
    • Journal of Korea Foundry Society
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    • v.25 no.2
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    • pp.80-87
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    • 2005
  • The microstructure and mechanical property of the Ni and Ni-Cr porous metal reinforced AC4C matrix composites fabricated by squeeze casting were investigated. In this study Ni, Ni-Cr porous metals which are estimated to be easy to fabricate by squeeze casting are used as strengtheners for composite materials. As a matrix material, Al-7wt.%Si-0.3wt.%Mg(AC4C) has been used. In case of Ni/AC4C and Ni-Cr/AC4C composite, $750^{\circ}C$ melt temperature and minimum 25MPa squeezing pressure are needed to produce sound composite materials. The observation of interfacial reaction zone at various heat treatment condition shows that atsolutionizing temperature of above $520^{\circ}C$, the interfacial reaction zone increases proportionally with heat treatment time and the reaction products formed by interfacial reactions are mainly composed by $Al_{3}Ni$ and $Al_{3}Ni_{2}$ phases.

CNTs Electric Field Enhancement of CIGS Solar Cells

  • Han, Seong-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.67-67
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    • 2011
  • Compound semiconductor/CNTs composites have shown considerably improved efficiency improvement in photovoltaic devices, which is often attributed to two different factors. One is the formation of efficient electronic energy cascade structures. The other effect of CNTs on the performance of photovoltaic devices is the decrement of interfacial resistance. The interfacial resistances at n-type/ p-type materials and/or n-type materials/TCO electrode are reduced by an outstanding electrical property of CNTs. In addition to the effects of CNTs, we report the third reason for increment of efficiency in photovoltaic devices by CNT's well-known electrical field enhancement effects. The improved ${\beta}$ values in reverse-FE currents of CIGS electrode with SWNTs layers indicate the enhancement of electrical field in photovoltaic devices, which implies the acceleration of the electron transfer rate in the cell. Due to the formation of an efficient electronic energy cascade structure and the decrease of the interfacial resistance as well as the improvement of the electrical field in the photovoltaic devices, the power conversion efficiency of electrochemically deposited superstrate-type CIGS solar cells was increased 24.3% in the presence of SWNTs and showed 10.40% conversion efficiency.

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The Wetting Property of Indium Solder (인듐 솔더의 젖음특성)

  • 김대곤;이창배;정승부
    • Journal of Welding and Joining
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    • v.20 no.5
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    • pp.106-112
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    • 2002
  • In the present study, the wettability and interfacial tension between (bare Cu, electroless Ni/cu, immersion Au/Ni/Cu) substrates and indium solder were investigated as a function of soldering temperature, types of flux. The wettability of In solder increased with soldering temperature and solid content of flux. The wettability of In solder was affected by the substrate metal finish used, i.e., nickel, gold and copper. On the bare Cu substrate, In solder wet better than any of the substrate metal finishes tested. Intermetallic compound formation between liquid solder and substrate reduced the interfacial energy and improved wettability. For the identification of intermetallic compounds, X-Ray Diffraction(LRD) were employed. Experimental results showed that the intermetallic compounds, such as Cu11In9 and In27Ni10 are observed f3r different substrates respectively. The wetting kinetics is investigated by measuring wetting time with the wetting balance technique. The activation energy of wetting calculated for the In solder/cu substrate and In solder/electroless Au/Ni/Cu substrate are 36.13 and 27.36 kJ/mol, respectively.

The Wetting Property of Sn-3.5Ag Eutectic Solder (Sn-3.5Ag 공정 솔더의 젖음특성)

  • 윤정원;이창배;서창제;정승부
    • Journal of Welding and Joining
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    • v.20 no.1
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    • pp.91-96
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    • 2002
  • Three different kinds of substrate used in this study : bare Cu, electroless Ni/Cu substrate with a Nilayer thickness of $5\mu\textrm{m}$, immersion Au/electroless Ni/Cu substrate with the Au and Ni layer of $0.15\mu\textrm{m}$ and $5\mu\textrm{m}$ thickness, respectively. The wettability and interfacial tension between various substrate and Sn-3.5Ag solder were examined as a function of soldering temperature, types of flux. The wettability of Sn-3.5Ag solder increased with soldering temperature and solid content of flux. The wettability of Sn-3.5Ag solder was affected by the substrate metal finish used, i.e., nickel, gold and copper. Intermetallic compound formation between liquid solder and substrate reduced the interfacial energy and decreased wettability.

Study About Measurement of Interfacial Bonding Strength of STS/Al Clad sheet by Blanking Process (블랭킹 공정을 이용한 STS/Al 클래드 판재의 계면 접합력 측정에 관한 연구)

  • Kim, T.H.;Lee, K.S.;Kim, J.H.;Moon, Y.H.;Lee, Y.S.;Yoon, E.Y.
    • Transactions of Materials Processing
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    • v.27 no.5
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    • pp.267-275
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    • 2018
  • The clad sheet material is produced by a roll-bonding process of one or more materials with different properties. Good formability of clad sheet material is an essential property in to deform a clad metal sheet into a part or component. Performance of the clad sheet material largely depends on interfacial bond strength between different materials. In this study, interfacial bond strength of STS/Al clad sheet was analyzed by varying experimental parameters using a blanking process. Experimental parameters are the punching speed, clearance, and stacking order of plate materials. In addition, blanking test results were compared with bond strengths measured by the T-peel test, that analyzes interface bonding strength of the standard clad sheet. The blanking process was analyzed by the finite element method under the sticking condition of interface of different materials, and experimental results and analysis results were compared.

Interfacial Evaluation of Modified Jute and Hemp Fibers/Polypropylene (PP)-Maleic Anhydride Polypropylene Copolymers (PP-MAPP) Composites Using Micromechanical Test and Nondestructive Acoustic Emission (Micromechanical 시험법과 음향방출을 이용한 Flax 와 Hemp 섬유 강화 에폭시 복합재료의 계명 물성 평가)

  • Son, Tran Quang;Hwang, Byung-Sun;Park, Joung-Man
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.157-160
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    • 2005
  • The surface energies and acid-base interaction between the untreated and treated Jute or Hemp fibers and different matrix compositions of polypropylene-maleic anhydride polypropylene copolymers (PP-MAPP) were investigated using dynamic contact angle measurement. The contribution of the acid-base property into the interfacial adhesion of the natural fibers/matrix systems were characterized by calculating the work adhesion coming from the acid-base interaction. On the other hand, microfailure mechanism of both single Jute and Hemp fiber bundles were investigated using the combination of single fiber tensile test and acoustic emission. Distinctly different micro failure modes of the different natural fiber/polypropylene systems wet ε observed using optical microscope and determined indirectly by AE and their FFT analysis.

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Effects of Fiber Surface-Treatment and Sizing on the Dynamic Mechanical and Interfacial Properties of Carbon/Nylon 6 Composites

  • Cho, Dong-Hwan;Yun, Suk-Hyang;Kim, Jun-Kyung;Lim, Soon-Ho;Park, Min;Lee, Geon-Woong;Lee, Sang-Soo
    • Carbon letters
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    • v.5 no.1
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    • pp.1-5
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    • 2004
  • The effects of fiber surface-treatment and sizing on the dynamic mechanical properties of unidirectional and 2-directional carbon fiber/nylon 6 composites by means of dynamic mechanical analysis have been investigated in the present study. The interlaminar shear strengths of 2-directional carbon/nylon 6 composites sized with various thermosetting and thermoplastic resins are also measured using a short-beam shear test method. The result suggests that different surface-treatment levels onto carbon fibers may influence the storage modulus and tan ${\delta}$ behavior of carbon/nylon 6 composites, reflecting somewhat change of the stiffness and the interfacial adhesion of the composites. Dynamic mechanical analysis and short-beam shear test results indicate that appropriate use of a sizing material upon carbon fiber composite processing may contribute to enhancing the interfacial and/or interlaminar properties of woven carbon fabric/nylon 6 composites, depending on their resin characteristics and processing temperature.

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Finite Element Analysis for Fracture Resistance of Fiber-reinforced Asphalt Concrete (유한요소해석을 통한 섬유보강 아스팔트의 파괴거동특성 분석)

  • Baek, Jongeun;Yoo, Pyeong Jun
    • International Journal of Highway Engineering
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    • v.17 no.3
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    • pp.77-83
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    • 2015
  • PURPOSES : In this study, a fracture-based finite element (FE) model is proposed to evaluate the fracture behavior of fiber-reinforced asphalt (FRA) concrete under various interface conditions. METHODS : A fracture-based FE model was developed to simulate a double-edge notched tension (DENT) test. A cohesive zone model (CZM) and linear viscoelastic model were implemented to model the fracture behavior and viscous behavior of the FRA concrete, respectively. Three models were developed to characterize the behavior of interfacial bonding between the fiber reinforcement and surrounding materials. In the first model, the fracture property of the asphalt concrete was modified to study the effect of fiber reinforcement. In the second model, spring elements were used to simulated the fiber reinforcement. In the third method, bar and spring elements, based on a nonlinear bond-slip model, were used to simulate the fiber reinforcement and interfacial bonding conditions. The performance of the FRA in resisting crack development under various interfacial conditions was evaluated. RESULTS : The elastic modulus of the fibers was not sensitive to the behavior of the FRA in the DENT test before crack initiation. After crack development, the fracture resistance of the FRA was found to have enhanced considerably as the elastic modulus of the fibers increased from 450 MPa to 900 MPa. When the adhesion between the fibers and asphalt concrete was sufficiently high, the fiber reinforcement was effective. It means that the interfacial bonding conditions affect the fracture resistance of the FRA significantly. CONCLUSIONS : The bar/spring element models were more effective in representing the local behavior of the fibers and interfacial bonding than the fracture energy approach. The reinforcement effect is more significant after crack initiation, as the fibers can be pulled out sufficiently. Both the elastic modulus of the fiber reinforcement and the interfacial bonding were significant in controlling crack development in the FRA.

The Effect of Interfacial Properties and RTM Process of Composites with Different Cross-linking Density by Molecular Weight of Hardener (경화제의 분자량에 의한 가교밀도 차이에 따른 복합재료의 계면 물성 및 RTM 성형성에 미치는 영향)

  • Park, Ha-Seung;Shin, Pyeong-Su;Kim, Jong-Hyun;Baek, Yeong-Min;Kwon, Dong-Jun;Park, Joung-Man
    • Composites Research
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    • v.30 no.3
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    • pp.169-174
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    • 2017
  • Demand of glass fiber reinforced composites (GFRC) increased with developing aircraft and defense industries using resin transfer molding (RTM) process to produce complex product. In this research, wetting, interfacial, and mechanical properties were evaluated with different Cross-linking Density by Molecular Weight of Hardener. Epoxy resin as matrices was used bisphenol-A type and amine-type hardeners with different molecular weight. Specimens were manufactured via RTM and wetting property of resin and glass fiber (GF) mat was evaluated to viscosity of epoxy and injection time of epoxy matrix. Mechanical property of GFRC was determined via flexural strength whereas interfacial properties were determined by interlaminar shear strength (ILSS) and interfacial shear strength (IFSS). The difference in mechanical property depends upon the fiber weight fraction (wt %) of GFRC by RTM as well as the different Molecular Weight of Hardener.