• 제목/요약/키워드: interfacial energy

검색결과 625건 처리시간 0.026초

차세대 태양전지의 계면 개질 전략 (Interfacial Engineering Strategies for Third-Generation Photovoltaics)

  • 임훈희;최민재;정연식
    • Current Photovoltaic Research
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    • 제4권3호
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    • pp.98-107
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    • 2016
  • Third-generation photovoltaics are of low cost based on solution processes and are targeting a high efficiency. To meet the commercial demand, however, significant improvements of both efficiency and stability are required. In this sense, interfacial engineering can be useful key to solve these issues because trap sites and interfacial energy barrier and/or chemical instability at organic/organic and organic/inorganic interfaces are critical factors of efficiency and stability degradation. Here, we thoroughly review the interfacial engineering strategies applicable to three representative third-generation photovoltaics - organic, perovskite, colloidal quantum dot solar cell devices.

Interfacial Boundary Estimation in Stratified Flow of Two Immiscible Liquids Using Hybrid-type Fourier Series

  • Kim, Bong Seok;Choi, Bong-Yeol;Kim, Kyung Youn
    • 전기전자학회논문지
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    • 제18권4호
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    • pp.463-470
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    • 2014
  • In stratified flows of two immiscible liquids, due to the vibration in a pipe, the shape of the interface is not always periodic and it causes the different end points of the interfacial boundary. In this case the performance is not good. To solve this, in this paper, the hybrid-type Fourier series is proposed, which consists of both the polynomial and the trigonometric terms. Under the stationary interfacial boundary during acquiring a full set of voltage data, the performance of the proposed method is evaluated through the numerical experiments. The results show that the proposed method performs better than the conventional Fourier series in estimating the interfacial boundary.

레이저 표면처리에 의한 수산화아파타이트 코팅된 타이타니움합금 경계면의 결합에너지 (Interfacial bonding Energy between Laser Surface Treated HA layer and Ti alloy)

  • 문덕수;김영곤;남상용;조현설;허은정;김석영;이준희
    • 대한의용생체공학회:학술대회논문집
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    • 대한의용생체공학회 1997년도 춘계학술대회
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    • pp.35-38
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    • 1997
  • The interfacial bonding energy between laser surface treated HA layer and Ti alloy substrate was investigated using a mechanical push-out tester. The initial slope of shear-stress and reduced displacement curves, maximum interfacial bond strength and bonding energy were calculated from results of the push-out test. The calculated initial slpoes are 38 MPa for the Ti alloy(A), 65 MPa for the sandblast finished specimen(B), 95 MPa for the HA plasma spray coated specimen and 49 MPa for the laser surface treated specimen(D). The maximum interfacial bonding strength are 3 MPa for the A, 19 MPa for the B, 20 MPa for the C, 10 MPa for the D. The interfacial bonding energies are $3.3\times10^{-9}J/mm^2$ for the A, $15.5\times10^{-9}J/mm^2$ for the B, $15.6\times10^{-9}J/mm^2$ for the C and $18.3\times10^{-9}J/mm^2$ for the D. Microscopic observation shows that the breaking of the laser treated specimen had been occured through the boundary between HA layer and polymer resin, but the untreated specimen had been occured through the inside of HA coating layer.

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A stress-function variational approach toward CFRP -concrete interfacial stresses in bonded joints

  • Samadvand, Hojjat;Dehestani, Mehdi
    • Advances in concrete construction
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    • 제9권1호
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    • pp.43-54
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    • 2020
  • This paper presents an innovative stress-function variational approach in formulating the interfacial shear and normal stresses in an externally bonded concrete joint using carbon fiber-reinforced plastic (CFRP) plies. The joint is subjected to surface traction loadings applied at both ends of the concrete substrate layer. By introducing two interfacial shear and normal stress functions on the CFRP-concrete interface, based on Euler-Bernoulli beam idea and static stress equations of equilibrium, the entire stress fields of the joint were determined. The complementary strain energy was minimized in order to solve the governing equation of the joint. This yields an ordinary differential equation from which the interfacial normal and shear stresses were proposed explicitly, satisfying all the multiple traction boundary conditions. Lamination theory for composite materials was also employed to obtain the interfacial stresses. The proposed approach was validated by the analytic models in the literature as well as through a comprehensive computational code generated by the authors. Furthermore, a numerical verification was carried out via the finite element software ABAQUS. In the end, a scaling analysis was conducted to analyze the interfacial stress field dependence of the joint upon effective issues using the devised code.

모세관 모델을 이용한 불포화토양의 물-가스 접촉면적 및 가스공극 크기분포의 계산 및 검증 (Capillary Bundle Model for the Estimation of Air-water Interfacial Area and the Gas-filled Pore Size Distribution in Unsaturated Soil)

  • 김헌기
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제26권1호
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    • pp.1-7
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    • 2021
  • Air-water interfacial area is of great importance for the analysis of contaminant mass transfer processes occurring in the soil systems. Capillary bundle model has been proposed to estimate the specific air-water interfacial areas in unsaturated soils. In this study, the measured air-water interfacial areas of a soil (loam) using the gaseous interfacial tracer technique were compared to those from capillary bundle model. The measured values converged to the specific solid surface area (7.6×104 ㎠/㎤) of the soil. However, the simulated air-water interfacial areas based on the capillary bundle model deviated significantly from those measured. The simulated values were substantially over-estimated at low end of the water content range, whereas the model under-estimated the air-water interfacial area for the most of the water content range. This under-estimation is considered to be caused by the nature of the capillary bundle model that replaces the soil pores with a bundle of glass capillaries and thus no surface roughness at the inner surface of the capillaries is taken into account for the estimation of the air-water interfacial area with the capillary bundle model. Subsequently, appropriate correction is necessary for the capillary bundle model to estimate the air-water interfacial area in soils. Since the soil-moisture release curve data is the basis of the capillary bundle model, the model can be of use due to its simplicity, while the gaseous tracer technique requires complicated experimental equipment followed by moment analysis of the breakthrough curves. The size distribution profile of the pores filled with gas estimated by the water retention curve was found to be similar to that of particle size at different size range. The shifted distribution of gas-filled pores toward smaller size side compared to the particle size distribution was also found.

후속 열처리에 따른 Cu 박막과 ALD Ru 확산방지층의 계면접착에너지 평가 (Effect of Post-annealing on the Interfacial adhesion Energy of Cu thin Film and ALD Ru Diffusion Barrier Layer)

  • 정민수;이현철;배병현;손기락;김가희;이승준;김수현;박영배
    • 마이크로전자및패키징학회지
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    • 제25권3호
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    • pp.7-12
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    • 2018
  • 차세대 초미세 Cu 배선 적용을 위한 원자층증착법(atomic layer deposition, ALD)을 이용하여 증착된 Ru확산 방지층과 Cu 박막 사이의 계면 신뢰성을 평가하기 위해, Ru 공정온도 및 $200^{\circ}C$ 후속 열처리 시간에 따라 4점굽힘시험으로 정량적인 계면접착에너지를 평가하였고, 박리계면을 분석하였다. 225, 270, $310^{\circ}C$ 세 가지 ALD Ru 공정온도에 따른 계면접착에너지는 각각 8.55, 9.37, $8.96J/m^2$로 유사한 값을 보였는데, 이는 증착온도 변화에 따라 Ru 결정립 크기 등 미세조직 및 비저항의 차이가 적어서, 계면 특성도 거의 차이가 없는 것으로 판단된다. $225^{\circ}C$의 공정온도에서 증착된 Ru 박막의 계면접착에너지는 $200^{\circ}C$ 후속 열처리시 250시간까지는 $7.59J/m^2$ 이상으로 유지되었으나, 500시간 후에는 $1.40J/m^2$로 급격히 감소하였다. 박리계면에 대한 X-선 광전자 분광기 분석 결과, 500시간 후 Cu 계면 산화로 인하여 계면접착 에너지가 감소한 것으로 확인되었다. 따라서 ALD Ru 박막은 계면신뢰성이 양호한 차세대 Cu 배선용 확산방지층 후보가 된다고 판단된다.

AN EXPERIMENTAL STUDY OF THE INTERFACIAL FRICTION FACTOR FOR COUNTERCURRENT STRATIFIED AIR-WATER FLOW IN NEARLY HORIZONTAL AND INCLINED PIPES

  • Yu, Seon-Oh;Kim, Yang-Seok;Chun, Moon-Hyun;Sung, Chang-Kyung;Park, Sang-Doug;Lee, Byung-Ryung;Sohn, Yong-Soo
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1996년도 춘계학술발표회논문집(2)
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    • pp.247-253
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    • 1996
  • The Interfacial friction factor for the countercurrent stratified air-wafer flow has been experimentally investigated in nearly horizontal and inclined pipes. The presence of the hydraulic jump may significantly affect both the flow pattern and the interfacial friction factor. The measured values of f$_{i}$ in nearly horizontal and two inclined pipes are of the same order of magnitude but the dependencies of the air and water velocities are slightly different.t.

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A penny-shaped interfacial crack between piezoelectric layer and elastic half-space

  • Ren, J.H.;Li, Y.S.;Wang, W.
    • Structural Engineering and Mechanics
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    • 제52권1호
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    • pp.1-17
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    • 2014
  • An interfacial penny-shaped crack between piezoelectric layer and elastic half-space subjected to mechanical and electric loads is investigated. Using Hankel transform technique, the mixed boundary value problem is reduced to a system of singular integral equations. The integral equations are further reduced to a system of algebraic equations with the aid of Jacobi polynomials. The stress intensity factor and energy release rate are determined. Numerical results reveal the effects of electric loadings and material parameters of composite on crack propagation and growth. The results seem useful for design of the piezoelectric composite structures and devices of high performance.