• Title/Summary/Keyword: interface properties

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Mass Transport Properties and Influence of Natural Convection for Voltammetry at the Agarose Hydrogel Interface

  • Kim, Byung-Kwon;Park, Kyungsoon
    • Journal of Electrochemical Science and Technology
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    • v.13 no.3
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    • pp.347-353
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    • 2022
  • Agarose hydrogel, a solid electrolyte, was investigated voltammetrically in terms of transport properties and natural convection effects using a ferrocenyl compound as a redox probe. To confirm the diffusion properties of solute on the agarose interface, the diffusion coefficients (D) of ferrocenemethanol in agarose hydrogel were determined by cyclic voltammetry (CV) according to the concentration of agarose hydrogel. While the value of D on the agarose interface is smaller than that in the bulk solution, the square root of the scan rate-dependent peak current reveals that the mass transport behavior of the solute on the agarose surface shows negligible convection or migration effects. In order to confirm the reduced natural convection on the gel interface, scan rate-dependent CV was performed in the solution phase and on the agarose surface, respectively. Slow scan voltammetry at the gel interface can determine a conventional and reproducible diffusion-controlled current down to a scan rate of 0.3 mV/s without any complicated equipment.

Evaluation of elastic-plastic behavior in MMC interface according to the reinforced fiber placement structure (강화섬유 배치구조에 따른 MMC계면에서의 탄소성거동 평가)

  • Kang, Ji-Woong;Kim, Sang-Tae;Kwon, Oh-Heon
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.410-414
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    • 2004
  • Under longitudinal loading continuous fiber reinforced metal matrix composite(MMC) have interpreted an outstanding performance. However, the applicability of continuous fiber reinforced MMCs is somewhat limited due to their relatively poor transverse properties. Therefore, the transverse properties of MMCs are significantly influenced by the properties of the fiber/matrix interface. In this study, elastic-plastic behavior of transversely loaded unidirectional fiber reinforced metal matrix composites investigated by using elastic-plastic finite element analysis. Different fiber placement(square and hexagon) and fiber volume fractions were studied numerically. The interface was treated as three thin layer (with different properties) with a finite thickness between the fiber and the matrix. The analyses were based on a two-dimensional generalized plane strain model of a cross-section of an unidirectional composite by the ANSYS finite element analysis code.

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Study on the AC Interfacial Breakdown Prosperities in the Interface between Toughened Epoxy and Rubber (Toughened Epoxy/Rubber계면의 교류 절연파괴 현상에 관한 연구)

  • 김태형;배덕권;이동규;정일형;김충혁;이홍표;이준웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.771-774
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    • 2000
  • Recently, complex insulation method is used in insulation system for underground power delivery devices. Considering the interfaces which affect stability of insulation system, By modeling interface between Epoxy and Rubber, AC interfacial breakdown properties with variation of many conditions to influence on electrical properties were investigated. In this paper, toughened Epoxy and Silicone rubber were used for materials to make interface .

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Elastic-Plastic Stress Distributions Behavior in the Interface of SiC/Ti-15-3 MMC under Transverse Loading(II) (횡하중을 받는 SiC/Ti-15-3 MMC 복합재 계면영역에서의 탄소성 응력장분포거동(II))

  • Kang Ji-Woong;Kwon Oh-Heon
    • Journal of the Korean Society of Safety
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    • v.20 no.2 s.70
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    • pp.26-31
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    • 2005
  • The strong continuous fiber reinforced metal matrix composites (MMCs) are recently used in aerospace and transportation applications as an advanced material due to its high strength and light weight. Unidirectional fiber-metal matrix composites have superior mechanical properties along the longitudinal direction. However, the applicability of continuous fiber reinforced MMCs is somewhat limited due to their relatively poor transverse properties. Therefore, the transverse properties of MMCs are significantly influenced by the properties of the fiber/matrix interface. In order to be able to utilize these MMCs effectively and with safety, it must be determined their elastic plastic behaviors at the interface. In this study, the interfacial stress states of transversely loaded unidirectional fiber reinforced metal matrix composites investigated by using elastic-plastic finite element analysis. Different fiber volume fractions $(5-60\%)$ were studied numerically. The interlace was treated as three thin layer (with different properties) with a finite thickness between the fiber and the matrix. The fiber is modeled as transversely isotropic linear-elastic, and the matrix as isotropic elastic-plastic material. Using proposed model, the effects of the interface region and fiber arrangement in MMCs on the distributions of stress and strain are evaluated. The stress distributions of a thin multi layer interface have much less changes compared with conventional perfect interface. The analyses were based on a two-dimensional generalized plane strain model of a cross-section of an unidirectional composite by the ANSYS finite element analysis code.

Temperature, Electric Field, Pressure Dependency and Dielectric properties on the interface between XLPE and EPDM (XLPE와 EPDM의 계면에 따른 유전특성과 온도, 전계, 압력의존성)

  • 김동식;박대희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.109-111
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    • 1997
  • In this paper, we have evaluated temperature, electric field, Pressure dependency and dielectric properties of EPDM XLPE and EPDM/XLPE\`s interface. Temperature dependency of EPDM had great influence with dielectric properties, but pressure and applied voltage of EPDM had no effect on dielectric properties. Dielectric properties of XLPE were influenced by not only temperature but also pressure and applied voltage. We knowed that dielectric properties of EPDM/XLPE were trended toward tendency of those of EPDM

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The Skewness Properties at Interface in Mica-Epoxy Composite (마아카-에폭시 복합재료 계면에서의 왜도 특성)

  • Lim, Jang-Seob;Lee, Eun-Hak;Gu, Hal-Bon;Kim, Tae-Seoung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1992.11a
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    • pp.128-131
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    • 1992
  • In this paper, the skewness properties of partial discharge at interface layer in mica-epoxy composite material were investigated and studied on interface specimens which has internal electrodes. As a result, it has been confirmed that the interface exists as abnormal resin layer and the contact condition at the interface is depended upon the density of si lane aqueous solution. The Pulse frequency of discharge at abnormal interface has been shown a linear increasing with enlargement of discharge quantity according to rising of the applied voltage. Whereas, in case of normal interface, pulse frequency represented exponential increasing at the saturating point of discharge quantity. The aging model can be represented from the variable characteristics of skewness.

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Human Interface Modeling of Consumer Electronic Products by Using the Object-Oriented Technique (전자제품 휴먼인터페이스의 객체지향적 모델링)

  • Hong, Sang-U;Han, Seong-Ho;Gwak, Ji-Yeong
    • Journal of the Ergonomics Society of Korea
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    • v.17 no.2
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    • pp.83-96
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    • 1998
  • This paper suggests a data modeling scheme of human interface elements and their properties for consumer electronic products. The human interface elements were classified into three categories: individual, interaction and integration interface. The representative properties of each interface element were identified, and modeled by using the object-oriented technique. The results of this study are expected to be used for expressing the user interface of consumer electronic products. They are also expected to help understand the relationship between the usability and the user interface elements of a product.

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SiC/SiO2 Interface Characteristics in N-based 4H-SiC MOS Capacitor Fabricated with PECVD and NO Annealing Processes (PECVD와 NO 어닐링 공정을 이용하여 제작한 N-based 4H-SiC MOS Capacitor의 SiC/SiO2 계면 특성)

  • Song, Gwan-Hoon;Kim, Kwang-Soo
    • Journal of IKEEE
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    • v.18 no.4
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    • pp.447-455
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    • 2014
  • In this research, n-based 4H-MOS Capacitor was fabricated with PECVD (plasma enhanced chemical vapor deposition) process for improving SiC/$SiO_2$ interface properties known as main problem of 4H-SiC MOSFET. To overcome the problems of dry oxidation process such as lower growth rate, high interface trap density and low critical electric field of $SiO_2$, PECVD and NO annealing processes are used to MOS Capacitor fabrication. After fabrication, MOS Capacitor's interface properties were measured and evaluated by hi-lo C-V measure, I-V measure and SIMS. As a result of comparing the interface properties with the dry oxidation case, improved interface and oxide properties such as 20% reduced flatband voltage shift, 25% reduced effective oxide charge density, increased oxide breakdown field of 8MV/cm and best effective barrier height of 1.57eV, 69.05% reduced interface trap density in the range of 0.375~0.495eV under the conduction band are observed.

Determination of Steel-concrete Interface Parameters: Me chanical Properties of Interface Parameters (강-콘크리트 계면의 계면상수 결정 : 계면상수의 역학적 성질)

  • Lee, Ta;Joo, Young-Tae;Lee, Yong-Hak
    • Journal of the Korea Concrete Institute
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    • v.21 no.6
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    • pp.781-788
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    • 2009
  • Mechanical properties of steel-concrete interface were evaluated on the basis of experimental observations. The properties included bond strength, unbounded and bonded friction angles, residual level of friction angle, mode I fracture energy, mode II bonded fracture energy and unbonded slip-friction energy under different levels of normal stress, and shape parameters to define geometrical shape of failure envelope. For this purpose, a typical type of constitutive model of describing steel-concrete interface behavior was presented based on a hyperbolic three-parameter Mohr-Coulomb type failure criterion. The constitutive model depicts the strong dependency of interface behavior on bonding condition of interface, bonded or unbounded. Values of the interface parameters were determined through interpretation of experimental results, geometry of failure envelope and sensitivity analysis. Nonlinear finite element analysis that incorporates steel-concrete interface as well as material nonlinearities of concrete and steel were performed to predict the experimental results.

Corelationship between Interfacial Fracture Toughness and Mechanical Properties of Concrete (계면파괴인성과 콘크리트 역학적 성질의 상관관계)

  • 이광명;안기석;이회근;김태근
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.04a
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    • pp.359-364
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    • 1998
  • The interfacial zone in concrete materials is extensive, geometrically complex, and constitutes inherently weak zones that limit the concrete performance. Motar-aggregate interfaces play a major role in the fracture processing in concrete composites. Also, the interfacial bond considerably influence mechanical properties of concrete such as modulus of elasticity, strength, and fracture energy, Characterization of the interfacial properties is, therefore, essential to overcome the limitations associated with the interfaces. an objective of this paper is to investigate the corelationship between the fracture toughness of mortar-aggregate interface and the concrete properties such as strengths and elastic moduli. It is observed from the test results that interface fracture toughness is closely related with the compressive strength rather than other properties. At early ages, the development of both tensile strength and elastic modulus are much greater thatn that of both interface fracture toughness and compressive strength.

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