• 제목/요약/키워드: interface properties

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Mass Transport Properties and Influence of Natural Convection for Voltammetry at the Agarose Hydrogel Interface

  • Kim, Byung-Kwon;Park, Kyungsoon
    • Journal of Electrochemical Science and Technology
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    • 제13권3호
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    • pp.347-353
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    • 2022
  • Agarose hydrogel, a solid electrolyte, was investigated voltammetrically in terms of transport properties and natural convection effects using a ferrocenyl compound as a redox probe. To confirm the diffusion properties of solute on the agarose interface, the diffusion coefficients (D) of ferrocenemethanol in agarose hydrogel were determined by cyclic voltammetry (CV) according to the concentration of agarose hydrogel. While the value of D on the agarose interface is smaller than that in the bulk solution, the square root of the scan rate-dependent peak current reveals that the mass transport behavior of the solute on the agarose surface shows negligible convection or migration effects. In order to confirm the reduced natural convection on the gel interface, scan rate-dependent CV was performed in the solution phase and on the agarose surface, respectively. Slow scan voltammetry at the gel interface can determine a conventional and reproducible diffusion-controlled current down to a scan rate of 0.3 mV/s without any complicated equipment.

강화섬유 배치구조에 따른 MMC계면에서의 탄소성거동 평가 (Evaluation of elastic-plastic behavior in MMC interface according to the reinforced fiber placement structure)

  • 강지웅;김상태;권오헌
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 춘계학술대회
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    • pp.410-414
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    • 2004
  • Under longitudinal loading continuous fiber reinforced metal matrix composite(MMC) have interpreted an outstanding performance. However, the applicability of continuous fiber reinforced MMCs is somewhat limited due to their relatively poor transverse properties. Therefore, the transverse properties of MMCs are significantly influenced by the properties of the fiber/matrix interface. In this study, elastic-plastic behavior of transversely loaded unidirectional fiber reinforced metal matrix composites investigated by using elastic-plastic finite element analysis. Different fiber placement(square and hexagon) and fiber volume fractions were studied numerically. The interface was treated as three thin layer (with different properties) with a finite thickness between the fiber and the matrix. The analyses were based on a two-dimensional generalized plane strain model of a cross-section of an unidirectional composite by the ANSYS finite element analysis code.

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Toughened Epoxy/Rubber계면의 교류 절연파괴 현상에 관한 연구 (Study on the AC Interfacial Breakdown Prosperities in the Interface between Toughened Epoxy and Rubber)

  • 김태형;배덕권;이동규;정일형;김충혁;이홍표;이준웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.771-774
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    • 2000
  • Recently, complex insulation method is used in insulation system for underground power delivery devices. Considering the interfaces which affect stability of insulation system, By modeling interface between Epoxy and Rubber, AC interfacial breakdown properties with variation of many conditions to influence on electrical properties were investigated. In this paper, toughened Epoxy and Silicone rubber were used for materials to make interface .

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횡하중을 받는 SiC/Ti-15-3 MMC 복합재 계면영역에서의 탄소성 응력장분포거동(II) (Elastic-Plastic Stress Distributions Behavior in the Interface of SiC/Ti-15-3 MMC under Transverse Loading(II))

  • 강지웅;권오헌
    • 한국안전학회지
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    • 제20권2호
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    • pp.26-31
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    • 2005
  • The strong continuous fiber reinforced metal matrix composites (MMCs) are recently used in aerospace and transportation applications as an advanced material due to its high strength and light weight. Unidirectional fiber-metal matrix composites have superior mechanical properties along the longitudinal direction. However, the applicability of continuous fiber reinforced MMCs is somewhat limited due to their relatively poor transverse properties. Therefore, the transverse properties of MMCs are significantly influenced by the properties of the fiber/matrix interface. In order to be able to utilize these MMCs effectively and with safety, it must be determined their elastic plastic behaviors at the interface. In this study, the interfacial stress states of transversely loaded unidirectional fiber reinforced metal matrix composites investigated by using elastic-plastic finite element analysis. Different fiber volume fractions $(5-60\%)$ were studied numerically. The interlace was treated as three thin layer (with different properties) with a finite thickness between the fiber and the matrix. The fiber is modeled as transversely isotropic linear-elastic, and the matrix as isotropic elastic-plastic material. Using proposed model, the effects of the interface region and fiber arrangement in MMCs on the distributions of stress and strain are evaluated. The stress distributions of a thin multi layer interface have much less changes compared with conventional perfect interface. The analyses were based on a two-dimensional generalized plane strain model of a cross-section of an unidirectional composite by the ANSYS finite element analysis code.

XLPE와 EPDM의 계면에 따른 유전특성과 온도, 전계, 압력의존성 (Temperature, Electric Field, Pressure Dependency and Dielectric properties on the interface between XLPE and EPDM)

  • 김동식;박대희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 추계학술대회 논문집
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    • pp.109-111
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    • 1997
  • In this paper, we have evaluated temperature, electric field, Pressure dependency and dielectric properties of EPDM XLPE and EPDM/XLPE\`s interface. Temperature dependency of EPDM had great influence with dielectric properties, but pressure and applied voltage of EPDM had no effect on dielectric properties. Dielectric properties of XLPE were influenced by not only temperature but also pressure and applied voltage. We knowed that dielectric properties of EPDM/XLPE were trended toward tendency of those of EPDM

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마아카-에폭시 복합재료 계면에서의 왜도 특성 (The Skewness Properties at Interface in Mica-Epoxy Composite)

  • 임장섭;이은학;구할본;김태성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1992년도 추계학술대회 논문집
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    • pp.128-131
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    • 1992
  • In this paper, the skewness properties of partial discharge at interface layer in mica-epoxy composite material were investigated and studied on interface specimens which has internal electrodes. As a result, it has been confirmed that the interface exists as abnormal resin layer and the contact condition at the interface is depended upon the density of si lane aqueous solution. The Pulse frequency of discharge at abnormal interface has been shown a linear increasing with enlargement of discharge quantity according to rising of the applied voltage. Whereas, in case of normal interface, pulse frequency represented exponential increasing at the saturating point of discharge quantity. The aging model can be represented from the variable characteristics of skewness.

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전자제품 휴먼인터페이스의 객체지향적 모델링 (Human Interface Modeling of Consumer Electronic Products by Using the Object-Oriented Technique)

  • 홍상우;한성호;곽지영
    • 대한인간공학회지
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    • 제17권2호
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    • pp.83-96
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    • 1998
  • This paper suggests a data modeling scheme of human interface elements and their properties for consumer electronic products. The human interface elements were classified into three categories: individual, interaction and integration interface. The representative properties of each interface element were identified, and modeled by using the object-oriented technique. The results of this study are expected to be used for expressing the user interface of consumer electronic products. They are also expected to help understand the relationship between the usability and the user interface elements of a product.

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PECVD와 NO 어닐링 공정을 이용하여 제작한 N-based 4H-SiC MOS Capacitor의 SiC/SiO2 계면 특성 (SiC/SiO2 Interface Characteristics in N-based 4H-SiC MOS Capacitor Fabricated with PECVD and NO Annealing Processes)

  • 송관훈;김광수
    • 전기전자학회논문지
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    • 제18권4호
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    • pp.447-455
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    • 2014
  • 본 연구에서는 4H-SiC MOSFET의 주요 문제점인 $SiC/SiO_2$ 계면의 특성을 향상시키기 위해 PECVD (plasma enhanced chemical vapor deposition) 공정을 이용하여 n-based 4H-SiC MOS Capacitor를 제작하였다. 건식 산화 공정의 낮은 성장속도, 높은 계면포획 밀도와 $SiO_2$의 낮은 항복전계 등의 문제를 극복하기 위하여 PECVD와 NO어닐링 공정을 사용하여 MOS Capacitor를 제작하였다. 제작이 끝난 후, MOS Capacitor의 계면특성을 hi-lo C-V 측정, I-V 측정 및 SIMS를 이용해 측정하고 평가하였다. 계면의 특성을 건식 산화의 경우와 비교한 결과 20% 감소한 평탄대 전압 변화, 25% 감소한 $SiO_2$ 유효 전하 밀도, 8MV/cm의 증가한 $SiO_2$ 항복전계 및 1.57eV의 유효 에너지 장벽 높이, 전도대 아래로 0.375~0.495eV만큼 떨어져 있는 에너지 영역에서 69.05% 감소한 계면 포획 농도를 확인함으로써 향상된 계면 및 산화막 특성을 얻을 수 있었다.

강-콘크리트 계면의 계면상수 결정 : 계면상수의 역학적 성질 (Determination of Steel-concrete Interface Parameters: Me chanical Properties of Interface Parameters)

  • 이타;주영태;이용학
    • 콘크리트학회논문집
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    • 제21권6호
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    • pp.781-788
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    • 2009
  • 강-콘크리트 계면의 성질을 대표하는 부착강도, 부착 및 비부착 마찰계수, 부착 및 비부착 마찰계수의 연화영역에서 잔류량의 크기, 모드 I 파괴에너지, 부착 및 비부착 모드 II 파괴에너지, 파괴포락선의 형상계수를 포함한 총 9개 계면상수의 값을 계면거동실험결과와 파괴포락선의 기하학적 형상 및 구성모델을 이용하는 민감도 해석을 통해 결정하였다. 계면의 거동이 계면의 부착상태뿐만 아니라 계면법선방향 응력의 방향과 크기에 따라 매우 민감하게 작용하므로 계면상수 값의 결정에서는 이러한 구속압의 크기와 부착 및 비부착 계면조건을 고려하였다. 강재판 사이에 콘크리트가 타설된 강-콘크리트 계면실험체의 거동해석을 위한 계면유한요소해석을 결정된 계면상수를 적용하여 수행하였으며 실험결과와의 비교를 통해 상수값의 적정성을 검토하였다.

계면파괴인성과 콘크리트 역학적 성질의 상관관계 (Corelationship between Interfacial Fracture Toughness and Mechanical Properties of Concrete)

  • 이광명;안기석;이회근;김태근
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1998년도 봄 학술발표회 논문집(I)
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    • pp.359-364
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    • 1998
  • The interfacial zone in concrete materials is extensive, geometrically complex, and constitutes inherently weak zones that limit the concrete performance. Motar-aggregate interfaces play a major role in the fracture processing in concrete composites. Also, the interfacial bond considerably influence mechanical properties of concrete such as modulus of elasticity, strength, and fracture energy, Characterization of the interfacial properties is, therefore, essential to overcome the limitations associated with the interfaces. an objective of this paper is to investigate the corelationship between the fracture toughness of mortar-aggregate interface and the concrete properties such as strengths and elastic moduli. It is observed from the test results that interface fracture toughness is closely related with the compressive strength rather than other properties. At early ages, the development of both tensile strength and elastic modulus are much greater thatn that of both interface fracture toughness and compressive strength.

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