• Title/Summary/Keyword: interaction parameters

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Solubilization of Para-Halogenated Benzoic Acid Isomers by the Solution of Tetradecyltrimethylammonium Bromide (Tetradecyltrimethylammonium Bromide 용액에서 Para-할로겐화 벤조산 이성질체들의 가용화에 대한 연구)

  • Lee, Nam-Min;Lee, Byung-Hwan
    • Applied Chemistry for Engineering
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    • v.22 no.5
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    • pp.473-478
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    • 2011
  • The interaction of para-halogenated benzoic acid isomers with the micellar system of tetradecyltrimethylammonium bromide was studied by the UV/Vis spectrophotometric method. The solubilization constants ($K_s$) of benzoic acid isomers into the micellar system of TTAB and the critical micelle concentration (CMC) of TTAB have been measured with the change of temperature. Various thermodynamic parameters have been calculated and analyzed from those measurement. The results show that the values of ${\Delta}G^{\circ}{_s}$ for the solubilization of all isomers are negative and the values of ${\Delta}H^{\circ}{_s}$ and ${\Delta}S^{\circ}{_s}$ are all positive within the measured temperature range. The effects of additives (n-butanol and NaCl) on the solubilization of benzoic acid isomers have been also measured. There was a great decrease on the values of $K_s$ and CMC simultaneously with these additives. From these changes we can postulate that the solubilization sites of each isomers in the TTAB micellar system are the surface or the palisade region of the micelle.

Axial behavior of the steel reinforced lightweight aggregate concrete (SRLAC) short columns

  • Mostafa, Mostafa M.A.;Wu, Tao;Liu, Xi;Fu, Bo
    • Steel and Composite Structures
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    • v.39 no.5
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    • pp.583-598
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    • 2021
  • The composite steel reinforced concrete (SRC) columns have been widely used in Structural Engineering due to their good performances. Many studies have been done on the SRC columns' performances, but they focused on the ordinary types with conventional configurations and materials. In this study, nine new types of steel reinforced lightweight aggregate concrete (SRLAC) short columns with cross-shaped (+shaped and X-shaped) steel section were tested under monotonically axial compressive load; the studied parameters included steel section ratio, steel section configuration, ties spacing, lightweight aggregate concrete (LWAC) strength, and longitudinal bars ratio. From the results, it could be found that the specimens with larger ties ratio, concrete strength, longitudinal bars ratio, and steel section ratio achieved great strength and stiffness due to the excellent interaction between the concrete and steel. The well-confined concrete core could strengthen the steel section. The ductility and toughness of the specimens were influenced by the LWAC strength, steel section ratio, and longitudinal bars ratio; in addition, larger ties ratio with smaller LWAC strength led to better ductility and toughness. The load transfer between concrete and steel section largely depends on the LWAC strength, and the ultimate strength of the new types of SRLAC short columns could be approximately predicted, referring to the codes' formulas of ordinary types of steel reinforced concrete (SRC) columns. Among the used codes, the BS-5400-05 led to the most conservative results.

Knowledge from recent investigations on sloshing motion in a liquid pool with solid particles for severe accident analyses of sodium-cooled fast reactor

  • Xu, Ruicong;Cheng, Songbai;Li, Shuo;Cheng, Hui
    • Nuclear Engineering and Technology
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    • v.54 no.2
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    • pp.589-600
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    • 2022
  • Investigations on the molten-pool sloshing behavior are of essential value for improving nuclear safety evaluation of Core Disruptive Accidents (CDA) that would be possibly encountered for Sodium-cooled Fast Reactors (SFR). This paper is aimed at synthesizing the knowledge from our recent studies on molten-pool sloshing behavior with solid particles conducted at the Sun Yat-sen University. To better visualize and clarify the mechanism and characteristics of sloshing induced by local Fuel-Coolant Interaction (FCI), experiments were performed with various parameters by injecting nitrogen gas into a 2-dimensional liquid pool with accumulated solid particles. It was confirmed that under different particle-bed conditions, three representative flow regimes (i.e. the bubble-impulsion dominant, transitional and bed-inertia dominant regimes) are identifiable. Aimed at predicting the regime transitions during sloshing process, a predictive empirical model along with a regime map was proposed on the basis of experiments using single-sized spherical solid particles, and then was extended for covering more complex particle conditions (e.g. non-spherical, mixed-sized and mixed-density spherical particle conditions). To obtain more comprehensive understandings and verify the applicability and reliability of the predictive model under more realistic conditions (e.g. large-scale 3-dimensional condition), further experimental and modeling studies are also being prepared under other more complicated actual conditions.

Emergence and Structure of Complex Mutualistic Networks

  • Lee, KyoungEun;Jung, Nam;Lee, Hyun Min;Maeng, Seung Eun;Lee, Jae Woo
    • Proceedings of the National Institute of Ecology of the Republic of Korea
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    • v.3 no.3
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    • pp.149-153
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    • 2022
  • The degree distribution of the plant-pollinator network was identified by analyzing the data in the ecosystem and reproduced by a model of the growing bipartite mutualistic networks. The degree distribution of pollinator shows power law or stretched exponential distribution, while plant usually shows stretched exponential distribution. In the growth model, the plant and the pollinator are selected with probability Pp and PA=1-Pp, respectively. The number of incoming links for the plant and the pollinator is lp and lA, respectively. The probability that the link of the plant selects the pollinator of the existing network given as $A_{k_i}=k^{{\lambda}_A}_i/{\sum}_i\;k^{{\lambda}_A}_i$, and the probability that the pollinator selects the plant is $P_{k_i}=k^{{\lambda}_p}_i/{\sum}_i\;k^{{\lambda}_p}_i$. When the nonlinear growth index is 𝛌X=1 (X=A or P), the degree distribution follows a power law, and if 0≤𝛌X<1, the degree distribution follows a stretched exponential distribution. The cumulative degree distributions of plants and pollinators of 14 empirical plant-pollinators included in Interaction Web Database were calculated. A set of parameters (PA,PP,lA,lP) that reproduces these cumulative degree distributions and a growth index 𝛌X (X=A or P) were obtained. We found that animal takes very heterogenous connections, whereas plant takes a more flexible connection network.

The study of sound source synthesis IC to realize the virtual engine sound of a car powered by electricity without an engine (엔진 없이 전기로 구동되는 자동차의 가상 엔진 음 구현을 위한 음원합성 IC에 관한 연구)

  • Koo, Jae-Eul;Hong, Jae-Gyu;Song, Young-Woog;Lee, Gi-Chang
    • The Journal of the Acoustical Society of Korea
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    • v.40 no.6
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    • pp.571-577
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    • 2021
  • This study is a study on System On Chip (SOC) that implements virtual engine sound in electric vehicles without engines, and realizes vivid engine sound by combining Adaptive Difference PCM (ADPCM) method and frequency modulation method for satisfaction of driver's needs and safety of pedestrians. In addition, by proposing an electronic sound synthesis algorithm applying Musical Instrument Didital Interface (MIDI), an engine sound synthesis method and a constitutive model of an engine sound generation system are presented. In order to satisfy both drivers and pedestrians, this study uses Controller Area Network (CAN) communication to receive information such as Revolution Per Minute (RPM), vehicle speed, accelerator pedal depressed amount, torque, etc., transmitted according to the driver's driving habits, and then modulates the frequency according to the appropriate preset parameters We implemented an interaction algorithm that accurately reflects the intention of the system and driver by using interpolation for the system, ADPCM algorithm for reducing the amount of information, and MIDI format information for making engine sound easier.

X-ray / gamma ray radiation shielding properties of α-Bi2O3 synthesized by low temperature solution combustion method

  • Reddy, B. Chinnappa;Manjunatha, H.C.;Vidya, Y.S.;Sridhar, K.N.;Pasha, U. Mahaboob;Seenappa, L.;Sadashivamurthy, B.;Dhananjaya, N.;Sathish, K.V.;Gupta, P.S. Damodara
    • Nuclear Engineering and Technology
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    • v.54 no.3
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    • pp.1062-1070
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    • 2022
  • In the present communication, pure and stable α-Bismuth Oxide (Bi2O3) nanoparticles (NPs) were synthesized by low temperature solution combustion method using urea as a fuel and calcined at 500℃. The synthesized sample was characterized by using powder X-ray Diffraction (PXRD), Scanning Electron Microscopy (SEM), Energy dispersive X-ray analysis (EDAX), Transmission Electron Microscopy (TEM), Fourier Transform Infrared Spectroscopy (FTIR) and UV-Visible absorption spectroscopy. The PXRD pattern confirms the formation of mono-clinic, stable and low temperature phase α-Bi2O3. The direct optical energy band gap was estimated by using Wood and Tauc's relation which was found to be 2.81 eV. The characterized sample was studied for X-ray/gamma ray shielding properties in the energy range 0.081-1.332 MeV using NaI (Tl) detector and multi channel analyzer (MCA). The measured shielding parameters agrees well with the theory, whereas, slight deviation up to 20% is observed below 356 keV. This deviation is mainly due to the influence of atomic size of the target medium. Furthermore an accurate theory is necessary to explain the interaction of X-ray/gamma ray with the NPs.The present work opens new window to use this facile, economical, efficient, low temperature method to synthesize nanomaterials for X-ray/gamma ray shielding purpose.

Coupled effect of variable Winkler-Pasternak foundations on bending behavior of FG plates exposed to several types of loading

  • Himeur, Nabil;Mamen, Belgacem;Benguediab, Soumia;Bouhadra, Abdelhakim;Menasria, Abderrahmane;Bouchouicha, Benattou;Bourada, Fouad;Benguediab, Mohamed;Tounsi, Abdelouahed
    • Steel and Composite Structures
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    • v.44 no.3
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    • pp.353-369
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    • 2022
  • This study attempts to shed light on the coupled impact of types of loading, thickness stretching, and types of variation of Winkler-Pasternak foundations on the flexural behavior of simply- supported FG plates according to the new quasi-3D high order shear deformation theory, including integral terms. A new function sheep is used in the present work. In particular, both Winkler and Pasternak layers are non-uniform and vary along the plate length direction. In addition, the interaction between the loading type and the variation of Winkler-Pasternak foundation parameters is considered and involved in the governing equilibrium equations. Using the virtual displacement principle and Navier's solution technique, the numerical results of non-dimensional stresses and displacements are computed. Finally, the non-dimensional formulas' results are validated with the existing literature, and excellent agreement is detected between the results. More importantly, several complementary parametric studies with the effect of various geometric and material factors are examined. The present analytical model is suitable for investigating the bending of simply-supported FGM plates for special technical engineering applications.

Drawbar Pull Estimation in Agricultural Tractor Tires on Asphalt Road Surface using Magic Formula (Magic Formula를 이용한 아스팔트 노면에서의 농업용 트랙터의 견인력 추정)

  • Kim, Kyeong-Dae;Kim, Ji-Tae;Ahn, Da-Vin;Park, Jung-Ho;Cho, Seung-Je;Park, Young-Jun
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.11
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    • pp.92-99
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    • 2021
  • Agricultural tractors drive and operate both off-road and on-road. Tire-road interaction significantly affects the tractive performance of a tractor, which is difficult to predict numerically. Many empirical models have been developed to predict the tractive performance of tractors using the cone index, which can be measured through simple tests. However, a magic formula model that can determine the tractive performance without a cone index can be used instead of traditional empirical models as the cone index cannot be measured on asphalt roads. The aim of this study was to predict the tractive performance of a tractor using the magic formula tire model. The traction force of the tires on an asphalt road was measured using an agricultural tractor. The dynamic wheel load was calculated to derive the coefficients of the traction-slip curve using the measured static wheel load and drawbar pull of the tractor. Curve fitting was performed to fit the experimental data using the magic formula. The parameters of the magic formula tire model were well identified, and the model successfully determined the coefficient of traction of the tractor.

The effects of cement thickness and cement shade on the final color of lithium disilicate crowns

  • Yigit Yamali;Merve Bankoglu Gungor;Secil Karakoca Nemli;Bilge Turhan Bal
    • The Journal of Advanced Prosthodontics
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    • v.15 no.2
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    • pp.93-100
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    • 2023
  • PURPOSE. The aim of this study is to evaluate the effect of resin cement color, cement thickness, and thermocycling on the final color of monolithic lithium disilicate crowns. MATERIALS AND METHODS. A total of ninety prepared central incisors of typodont teeth were restored with lithium disilicate crowns which have different cement thicknesses (40 ㎛, 80 ㎛, and 120 ㎛) and cement shades (clear, yellow, and white). Color parameters of restorations were measured with a spectrophotometer in three different steps 1) before cementing 2) after cementing and 3) after thermocycling with 10000 cycles. Color differences (ΔE00) were calculated with the CIEDE2000 formula and evaluated according to perceptibility (0.8) and acceptability (1.8) thresholds. The ΔE00 data were analyzed by using two-way ANOVA before and after thermocycling (α = .05). RESULTS. There was no interaction between the cement shade and the cement thickness factors. After cementation, the mean ΔE00 was under the perceptibility threshold in the group of 40 ㎛ cement thickness and clear cement while it was between the perceptibility and acceptability thresholds (0.8 < ΔE00 < 1.8) for all other groups. After thermocycling, the ΔE00 values were between the perceptibility and acceptability thresholds for all experimental groups. Although there were no significant differences among the groups, thermocycling increased the color difference values. CONCLUSION. The cementation of restorations with clear, yellow, and white resin cements resulted in color differences with uncemented restorations except for the group cemented with clear cement in 40 ㎛ cement thickness. All study groups revealed perceptible color change after thermocycling.

Comparative Study on the Clinical Trial of Acupotomy Treatment for Lumbar Disk Herniation

  • Beom Seok Kim;Ju Hyun Jeon;Tae Yong Park;Hong Kyoung Kim;Young Il Kim
    • Journal of Acupuncture Research
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    • v.40 no.3
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    • pp.252-264
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    • 2023
  • Background: The primary aim of this study is to statistically analyze and compare the difference in treatment outcomes based on the frequency and duration of acupotomy treatment for lumbar disk herniation. Methods: The evaluation of efficacy and safety involved using visual analog scale (VAS), numeric rating scale (NRS), Roland Morris disability questionnaire (RMDQ), EuroQol 5-dimention (EQ-5D), and similar parameters. This was achieved through the establishment of a comparable cohort using propensity score matching. Group A comprised 46 patients who underwent 4 sessions of acupotomy treatment for 2 weeks, while Group B consisted of 15 patients who received 6 acupotomy sessions for 3 weeks. Results: For Group A, the average amount of change in VAS values at weeks 4 and 6 was significantly decreased. However, the average amount of change in RMDQ values was not significant. Notably, the average amount of change of EQ-5D values at week 6 increased significantly. As for Group B, the average amount of change of NRS values in weeks 2 and 3 was significantly decreased. Conversely, the average amount of change in RMDQ and EQ-5D values was not significant. In comparing the 2 groups at the final follow-up, the average amount of change in all evaluation values was not significant. Further, no significant interaction effect was observed in the changes over time in all evaluation values between the 2 groups. Conclusion: This study establishes that there was no statistically significant difference in pain reduction, functional impairment, and quality of life improvement between 2 group.