• Bulletin of the Korean Chemical Society
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• v.17 no.1
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• pp.46-50
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• 1996

Monoanionic nickel(Ⅲ) complexes, [Ni(dmbit)2]1- and [Ni(dmbbip)2]1- where dmbit2- and dmbbip2- denote 2-thiobenzo[d]-1,3-dithiole-5,6-dithiolate and 1,2-bis(isopropylthio)benzen-4,5-dithiolate, respectively, have been synthesized by the iodine oxidation of dianionic complexes. In the scanning electron microscopic(SEM) images, these complexes show the well-grown two-dimensional layered structures which are clearly comparable to the dianionic ones with three-dimensional structures. Magnetic susceptibilities of nickel(Ⅲ)complexes are fitted well with the two-dimensional Heisenberg antiferromagnet model of S=1/2 system resulting in the spin-exchange parameters (|J|/k) of 11.4 K and 0.45 K, respectively. The weaker magnetic interaction in [Ni(dmbbip)2]1- is resulted from the bulky isopropyl groups on the periphery of dmbbip ligand. EPR measurements for [Ni(dmbit)2]1- give the signal with axial symmetry and the anisotropic g-values for low-spin nickel(Ⅲ) (g//=2.158, g =2.030,gav=2.074 at 300 K; g//=2.162, g =2.038, gav=2.080 at 77 K). It is therefore concluded that nickel(Ⅱ) is oxidized to nickel(Ⅲ), rather than dmbit2- and dmbbip2- ligands are, by the iodine oxidation. The paramagnetic Ni(Ⅲ) would be located in the axial symmetry(D4h) with the electronic configuration of (dxz2dyz2dz22dxy1dx2-y20).

• Bulletin of the Korean Chemical Society
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• v.12 no.5
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• pp.474-477
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• 1991

The preferential transport phenomena of neutral cation-anion moieties in neutral macrocycle-facilitated emulsion liquid membrane were described in this study. Emulsion membrane systems consisting of (1) aqueous source phase containing 0.001 M M($NO_3$)$_2(M=Mn^{2+},\;Co^{2+},\;Ni^{2+},\;Cu^{2+},\;Zn^{2+},\;Sr^{2+},\;Cd^{2+},\;and\;Pb^{2+})$ (2) a toluene membrane containing 0.01 M ligand $(DBN_3O_2$, DA18C6, DT18C6, TT18C6, HT18C6) and the surfactant span 80 (sorbitan monooleate) (3% v/v) and (3) an aqueous receiving phase containing $Na_2S_2O_3$ or $NaNO_3$ were studied with respect to the disappearence of transition metal ions from the source phase as a function of time. Cation transports for various two component or three component equimolar mixture of transition metal and $Cu^{2+}$ in a emulsion membrane system incorporating macrocyclic ligand (HT18C6) as carrier were determinded. $Cu^{2+}$ was transported higher rates than the other $M^{2+}$ in the mixture solution. Equilibrium constants for cation-source phase co-anion, cation macrocycle and cation-receiving phase reagent interaction are examined as parameters for the prediction of cation transport selectivities.

• Steel and Composite Structures
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• v.33 no.3
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• pp.445-461
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• 2019

The ultrasonic guided wave-based technique has become one of the most promising methods in non-destructive evaluation and structural health monitoring, because of its advantages of large area inspection, evaluating inaccessible areas on the structure and high sensitivity to small damage. To further advance the development of damage detection technologies using ultrasonic guided waves for the inspection of welded components in structures, the transmission characteristics of the ultrasonic guided waves propagating through welded joints with various types of defects or damage in steel plates are studied and presented in this paper. A three-dimensional (3D) finite element (FE) model considering the different material properties of the mild steel, high strength steel and austenitic stainless steel plates and their corresponding welded joints as well as the interaction condition of the steel plate and welded joint, is developed. The FE model is validated against analytical solutions and experimental results reported in the literature and is demonstrated to be capable of providing a reliable prediction on the features of ultrasonic guided wave propagating through steel plates with welded joints and interacting with defects. Mode conversion and scattering analysis of guided waves transmitted through the different types of weld defects in steel plates are performed by using the validated FE model. Parametric studies are undertaken to elucidate the effects of several basic parameters for various types of weld defects on the transmission performance of guided waves. The findings of this research can provide a better understanding of the transmission behaviour of ultrasonic guided waves propagating through welded joints with defects. The method could be used for improving the performance of guided wave damage detection methods.

• Journal of the Microelectronics and Packaging Society
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• v.26 no.3
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• pp.51-57
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• 2019

To protect the Cu surface from oxidation in air, a two-step plasma process using Ar and $N_2$ gases was studied to form a copper nitride passivation as an anti-oxidant layer. The Ar plasma removes contaminants on the Cu surface and it activates the surface to facilitate the reaction of copper and nitrogen atoms in the next $N_2$ plasma process. This study investigated the effect of Ar plasma on the formation of copper nitride passivation on Cu surface during the two-step plasma process through the full factorial design of experiment (DOE) method. According to XPS analysis, when using low RF power and pressure in the Ar plasma process, the peak area of copper oxides decreased while the peak area of copper nitrides increased. The main effect of copper nitride formation in Ar plasma process was RF power, and there was little interaction between plasma process parameters.

• Structural Engineering and Mechanics
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• v.55 no.6
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• pp.1261-1278
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• 2015

Due to their low intrinsic damping, stay cables in cable-stayed bridges have often exhibited unanticipated and excessive vibrations which result in increasing maintenance frequency and disruption to normal operations of the entire bridges. Mitigation of undesired cable vibration can be achieved by attaching an external damping device near the anchorage. High Damping Rubber (HDR) dampers have many advantages such as compact size, better aesthetics, easy maintenance, temperature stability, and cost benefits; therefore, they have been widely used to increase cable damping. Although a single damper has been shown to reduce cable vibrations, it is not the most effective method due to geometric constraints. This paper proposes the use of two HDR dampers to improve effectiveness and robustness in suppressing cable vibration. Oscillation parameters of the cable-dampers system were investigated in detail by modeling the stay cable as a taut string and each HDR damper as complex-valued impedance and by using an analytical formulation of the complex eigenvalue problem. The problem of two HDR dampers arbitrarily located along a cable is solved and the solution is discussed. Asymptotic formulas to calculate the damping ratios of the cable with two HDR dampers installed near the anchorage(s) are proposed and compared with the exact solutions. Further, a design example is presented in order to justify the methodology. The results of this study show that when the two HDR dampers are installed close to each other on the same end of the cable, some interaction between the dampers leads to reduced damping ratio. When the dampers are on the opposite ends of the cable, they are effective in increasing damping ratio and can provide better vibration reduction to multiple modes.

• Journal of Soil and Groundwater Environment
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• v.21 no.1
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• pp.61-71
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• 2016

Visual MODFLOW was used for quantifying stream-aquifer interactions caused by seasonal groundwater pumping. A hypothetical conceptual model was assumed to represent a stream-aquifer system commonly found in Korea. The model considered a two-layered aquifer with the upper alluvium and the lower bedrock and a stream showing seasonal water level fluctuations. Our results show that seasonal variation of the stream depletion rate (SDR) as well as the groundwater depletion depends on the stream depletion factor (SDF), which is determined by aquifer parameters and the distance from the pumping well to the stream. For pumping wells with large SDF, groundwater was considerably depleted for a long time of years and the streamflow decreased throughout the whole year. The impacts of return flow were also examined by recalculating SDR with an assumed ratio of immediate irrigation return flow to the stream. Return flow over 50% of pumping rate could increase the streamflow during the period of seasonal pumping. The model also showed that SDR was affected by both the conductance between the aquifer and the stream bed and screen depths of the pumping well. Our results can be used for preliminary assessment of water budget analysis aimed to plan an integrated management of water resources in riparian areas threatened by heavy pumping.

• Nuclear Engineering and Technology
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• v.53 no.10
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• pp.3275-3285
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• 2021

A Nuclear Power Plant (NPP) is a complex dynamic system-of-systems with highly nonlinear behaviors. In order to control the plant operation under both normal and abnormal conditions, the different systems in NPPs (e.g., the reactor core components, primary and secondary coolant systems) are usually monitored continuously, resulting in very large amounts of data. This situation makes it possible to integrate relevant qualitative and quantitative knowledge with artificial intelligence techniques to provide faster and more accurate behavior predictions, leading to more rapid decisions, based on actual NPP operation data. Data-driven models (DDM) rely on artificial intelligence to learn autonomously based on patterns in data, and they represent alternatives to physics-based models that typically require significant computational resources and might not fully represent the actual operation conditions of an NPP. In this study, a feed-forward backpropagation artificial neural network (ANN) model was trained to simulate the interaction between the reactor core and the primary and secondary coolant systems in a pressurized water reactor. The transients used for model training included perturbations in reactivity, steam valve coefficient, reactor core inlet temperature, and steam generator inlet temperature. Uncertainties of the plant physical parameters and operating conditions were also incorporated in these transients. Eight training functions were adopted during the training stage to develop the most efficient network. The developed ANN model predictions were subsequently tested successfully considering different new transients. Overall, through prompt prediction of NPP behavior under different transients, the study aims at demonstrating the potential of artificial intelligence to empower rapid emergency response planning and risk mitigation strategies.

• Journal of Korean Association for Spatial Structures
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• v.21 no.4
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• pp.57-64
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• 2021

This paper conducted a comparative analysis of the shear buckling characteristics of trapezoidal and sinusoidal corrugated steel plates considering of their initial imperfection. Initial imperfection refers to the state where the shape of the corrugated plate is initially not perfect. As such, an initially imperfect shape was assumed using the eigen buckling mode. To calculate the buckling stress of corrugated steel plates, the linear buckling analysis used a boundary condition which was applied to the plate buckling analysis. For the comparison of trapezoidal and sinusoidal corrugation, the shape parameters were assumed using the case where the length and slope of each corrugation were the same, and the initial imperfection was considered to be from 0.1% to 5% based on the length of the steel plate. Here, for the buckling analysis, ANSYS, a commercial FEA program, was used. From the results of buckling analysis, the effect of overall initial imperfection showed that the larger the initial imperfection, the lower the buckling stress. However, in the very thin model, interaction or local buckling was dominant in the perfect shape, and in this case, the buckling stress did not decrease. Besides, the sinusoidal model showed higher buckling stress than the trapezoidal one, and the two corrugation shapes decreased in a similar way.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.49 no.8
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• pp.699-708
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• 2021

In this paper, the aerodynamic and aeroacoustic characteristics that vary depending on the rotation axial distance between the upper and lower rotor, which is one of the design parameters of the coaxial rotor, is analyzed in the hovering condition using the computational fluid dynamics. Aerodynamic analysis using the Reynolds Averaged Navier Stokes equation and the aeroacoustic analysis using the Ffowcs Williams ans Hawkings equation is performed and the results were compared. The upper and lower rotor of the coaxial rotor have different phase angle which changes periodically by rotation and have unsteady characteristics. As the distance between the upper and lower rotors increased, the aerodynamic efficiency of the thrust and the torque was increased as the flow interaction decreased. In the aeroacoustic viewpoint, the noise characteristics radiated in the direction of the rotational plane showed little effect by axis spacing. In the vertical downward direction of the axis increased, the SPL maintains its size as the frequency increases, which affects the increase in the OASPL. As the axial distance of the coaxial rotor increased, the noise characteristics of a coaxial rotor were similar with the single rotor and the SPL decreased significantly.

• Journal of Korean Tunnelling and Underground Space Association
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• v.20 no.6
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• pp.973-987
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• 2018

Most of the previous seismic analyses have been carried out by separating the ground and structures, and there is a lack of comparative study on the dynamic behavior of high-rise and low-rise buildings. Therefore, in this study, the sensitivity analysis was performed with selected parameters by using a finite element analysis program in order to grasp the dynamic behavior of high-rise and low-rise buildings. As a result, it was turned out that the horizontal displacement, the interstory drift ratio, and the bending stress of a high-rise building were more affected by a long seismic wave than a low-rise buildings. Also, the weak parts of a high-rise and low-rise building were more affected by type of seismic wave than the ground conditions. Therefore, it is inferred that it will be helpful for seismic designs to consider the influence of ground conditions and seismic wave type on buildings.