• Title/Summary/Keyword: inorganic materials

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The Synthesis of High-purity Zirconia Powders and Its Properties (Compaction and Sintering Behaviro as a Function of Granulation Methods) (고순도 지르코니아 분말의 합성 및 그 특성 (조립방법에 따른 성형 및 소결 특성))

  • Kim, Hwan;Lee, Jong-Kook;Kim, Ju-Young;Hwang, Kyu-Hong
    • Journal of the Korean Ceramic Society
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    • v.25 no.4
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    • pp.357-363
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    • 1988
  • Ccompaction and sintering behavior of highly pure PSZ powders were investigated by laying the stress on the granulation processes. The particle size of coprecipitated PSZ powder was so fine that the agglomeration was severely formed during drying and calcing step and by this agglomeration differential sinering was occurred. The methanol dispersion of precipitates was the good method of avoiding severe agglomeration formed during drying process because of small surface tension than water. But perfect deagglomeraton was not possible due to high surface area of powders. So homogenization by granulation was needed, and among the method spray granulation was the most desirable to obtain homogeneous compacts and subsequent flaw-free ceramics.

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Inorganic-organic Hybrid Proton Conductive Membranes Doped with Phosphoric Acid

  • Huang Sheng-Jian;Lee Yong Su;Lee Hoi Kwn;Kang Won Ho
    • Proceedings of the KAIS Fall Conference
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    • 2004.06a
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    • pp.96-99
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    • 2004
  • A new proton conductive inorganic-organic hybrid membrane doped with $H_3PO_4$ was fabricated via sol-gel process wit 3- glycidoxypropyltrimethoxysilane(GPTMS), 3-aminopropyltriethoxysilane(APTES) and tetraethoxysilane(TEOS) asprecursors. Theproto conductivity of about 3.0$\times10^{-3}S/cm$ was obtained at $120^{\circ}C$ under $50\%$ relative humidity (R.H). DTA curves showed that the thermal stability of the membrane is significantly enhanced by the presence of $SiO_2$ framework up to $250^{\circ}C$. SEM and XRD revealed that the gel is microporou and amorphous. The addition of APTES improved the conductivity of the membranes and the effect of the APTES on the conductivity was also discussed in this paper.

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The Influence of KCl on the Hydration Property of OPC (시멘트의 수화 특성에 미치는 KCl의 영향)

  • Lee, Eui-Hak;Jeong, Chan-Il;Park, Soo-Kyung;Lee, Kyung-Hee
    • Journal of the Korean Ceramic Society
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    • v.39 no.10
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    • pp.943-947
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    • 2002
  • In order to examine the possibility of incineration of inderstrial by-product and wastes which contains a large percentage of chlorine by the cement kiln, measured heat of hydration, setting time, flow, change of length, compressive strength of OPC by the amount of KCl. The result was that a shorter setting time, a lower flow, a increasing the degree of initial shrinkage, a increasing of compressive strength before 3 days and decrease after 7 days by the induction period is shorter as promote the hydration with KCl.

Characteristics of Alumina Particles Synthesized by Microwave Heating (마이크로파 가열에 의하여 합성된 알루미나 입자의 특성)

  • Kim, Sung-Wan;Lee, Sung-Hwan;Park, Jae-Hyun;Kim, Jun-Ho;Park, Seong-Soo;Park, Hee-Chan
    • Journal of the Korean Ceramic Society
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    • v.39 no.10
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    • pp.1007-1010
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    • 2002
  • Alpha alumina platelet particles were synthesized from the powder mixture of ${\gamma}-Al_2O_3and\;Na_2SO_4$ with the use of microwave heating. The characteristics of the particles such as particle size and particle size distribution were compared with those of particles obtained from the same mixture without the use of microwave. Sample with the use of microwave showed small particle size and narrow particle size distribution compared to that without the use of microwave.

Desalting of tobacco extract using electrodialysis

  • Ge, Shaolin;Li, Wei;Zhang, Zhao;Li, Chuanrun;Wang, Yaoming
    • Membrane and Water Treatment
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    • v.7 no.4
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    • pp.341-353
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    • 2016
  • Papermaking reconstituted tobacco is an important strategy for recycling the waste tobacco residues. To indentify the influences of the inorganic components on harmful components delivery in cigarette smoke, a self-made electrodialysis stack was assembled to desalt the tobacco extract. The influences of the applied current and extract content on the removal rate of the inorganic ions were investigated. Results indicated that the applied current was a dominant impact on the desalination performance. High currents lower than the limiting current density could accelerate the desalting efficiency but cause higher energy consumption. A current of 2 A, or current density of ${\sim}11mA{\cdot}cm^{-2}$, was an optimal choice by considering both the energy consumption and desalting efficiency. A 20% tobacco extract was an appropriate content for the electrodialysis process. More than 90% of inorganic ions could be removed under the optimum condition. The preliminary result indicated that removal of inorganic components was beneficial to decrease the harmful component delivery in cigarette smoke. Naturally, ED is an environmentally friendly and high-effective technology for desalting the tobacco extract.

Particle Size Effects on Microstructure Evolution and Microwave Dielectric Characteristics in $0.93MgTiO_3-0.07CaTiO_3$Ceramics

  • Lee, Jung-A;Kim, Jeong-Joo;Kim, Nam-Kyong;Cho, Sang-Hee;Hahn, Jin-Woo
    • The Korean Journal of Ceramics
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    • v.5 no.3
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    • pp.260-264
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    • 1999
  • Effect of the particle size of $MgTiO_3$ and $CaTiO_3$ on the microstructural evolution during sintering of $0.93MgTiO_3-0.07CaTiO_3$ system was investigated. Microwave dielectric characteristics of the sintered ceramics were also measured. The microstructural evolutions were explained with an emphasis on the entrapping behavior of $CaTiO_3$ grain into the $MgTiO_3$ grain and were correlated with microwave dielectric characteristics. With an increasing particle size ratio between $CaTiO_3$and $MgTiO_3$, the fraction of entraped $CaTiO_3$ grains increased, which grain growth of $MgTiO_3$were concurrently accelerated due to decreasing drag force of its boundary migration. Besides, $CaTiO_3$-grain entrapment into the $MgTiO_3$grain interior led to decreaseing quality factor values.

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Development of PTCR Ceramics Device Fabricated by Liquid Phase Addition Method (액상첨가법에 의한 PTCR세라믹스 소자 개발)

  • Lee, Dong-Soo;Yun, Young-Ho;Park, Sung;Lee, Byung-Ha
    • Journal of the Korean Ceramic Society
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    • v.34 no.7
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    • pp.703-712
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    • 1997
  • The PTCR devices of BaTiO3 doped with Sb2O3, SiO2 were prepared by Liquid Addition Method(LPAM) where doping sources were used in the forms of Liquid. The amounts of doping in LPMA is smaller than that in solid state mixing method. Also the doping process in LPMA is very suitable for BaTiO3-based PTCR devices because it is easy to obtain homogeneous mixing and reproductivity. By optimizing the doping condition in BaTiO3 system, (0.09 mol% Sb2O3, 0.25 wt% SiO2 and 0.02 wt% MnO2) it was possible to fabricate BaTiO3-based PTCR devices whee the room-temperature resistivity and specific resistivity were 15{{{{ OMEGA }}cm and 2$\times$106 respectively.

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A Comparison Study of Output Performance of Organic-Inorganic Piezoelectric Nanocomposite Made of Piezoelectric/Non-piezoelectric Polymers and BaTiO3 Nanoparticles (압전 및 비압전 폴리머와 BaTiO3 나노입자로 제조된 유-무기 압전 나노복합체의 발전성능 비교연구)

  • Hyeon, Dong Yeol;Park, Kwi-Il
    • Journal of Powder Materials
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    • v.26 no.2
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    • pp.119-125
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    • 2019
  • Piezoelectric energy harvesting technology is attracting attention, as it can be used to convert more accessible mechanical energy resources to periodic electricity. Recent developments in the field of piezoelectric energy harvesters (PEHs) are associated with nanocomposites made from inorganic piezoelectric nanomaterials and organic elastomers. Here, we used the $BaTiO_3$ nanoparticles and piezoelectric poly(vinylidene fluoride) (PVDF) polymeric matrix to fabricate the nanocomposites-based PEH to improve the output performance of PEHs. The piezoelectric nanocomposite is produced by dispersing the inorganic piezo-ceramic nanoparticles inside an organic piezo-polymer and subsequently spin-coat it onto a metal plate. The fabricated organic-inorganic piezoelectric nanocomposite-based PEH harvested the output voltage of ~1.5 V and current signals of ~90 nA under repeated mechanical pushings: these values are compared to those of energy devices made from non-piezoelectric polydimethylsiloxane (PDMS) elastomers and supported by a multiphysics simulation software.

Highly-closed/-Open Porous Ceramics with Micro-Beads by Direct Foaming

  • Jang, Woo Young;Seo, Dong Nam;Park, Jung Gyu;Kim, Hyung Tae;Lee, Sung Min;Kim, Suk Young;Kim, Ik Jin
    • Journal of the Korean Ceramic Society
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    • v.53 no.6
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    • pp.604-609
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    • 2016
  • This study reports on wet-foam stability with respect to porous ceramics from a particle-stabilized colloidal suspension that is achieved through the addition of polymethyl methacrylate (PMMA) using a wet process. To stabilize the wet foam, an initial colloidal suspension of $Al_2O_3$ was partially hydrophobized by the surfactant propyl gallate (2 wt.%) and $SiO_2$ was added as a stabilizer. The influence of the PMMA content on the bubble size, pore size, and pore distribution in terms of the contact angle, surface tension, adsorption free energy, and Laplace pressure are described in this paper. The results show a wet-foam stability of more than 83%, which corresponds to a particle free energy of $2.7{\times}10^{-12}J$ and a pressure difference of 61.1 mPa for colloidal particles with 20 wt.% of PMMA beads. It was possible to control the uniform distribution of the open/closed pores by increasing the PMMA content and by adding thick struts, leading to the achievement of a higher-stability wet foam for use in porous ceramics.

Encapsulation Method of OLED with Inorganic Multi-layered Thin Films Sealed with Flat Glass (평판 유리로 봉인된 다층 무기 박막을 갖는 OLED 봉지 방법)

  • Park, Min-Kyung;Ju, Sung-Hoo;Yang, Jae-Woong;Paek, Kyeong-Kap
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.11
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    • pp.905-910
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    • 2011
  • To study encapsulation method for large-area organic light emitting diodes (OLEDs), red emitting OLEDs were fabricated, on which LiF and Al were deposited as inorganic protective films. And then the OLED was attached to flat glass by printing method using epoxy. In case of direct coating of epoxy onto OLED by printing method, luminance and current efficiency were remarkably decreased because of the damage to the OLED by epoxy. In case of depositing LiF and Al as inorganic protective films and then coating of epoxy onto OLED, luminance and current efficiency were not changed. OLED lifetime was more increased through inorganic protective films between OLED and flat glass than that without any encapsulation (8.8 h), i.e., 47 (LiF/Al/epoxy/glass), 62 (LiF/Al/LiF/epoxy/glass), and 84 h (LiF/Al/Al/epoxy/glass). The characteristics of OLED encapsulated with inorganic protective films (attached to flat glass) showed the possibility of application of protective films.