• Title/Summary/Keyword: inorganic material

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Cadmium Sulphide Nanorods: Synthesis, Characterization and their Photocatalytic Activity

  • Giribabu, Krishnamoorthy;Suresh, Ranganathan;Manigandan, Ramadoss;Vijayaraj, Arunachalam;Prabu, Raju;Narayanan, Vengidusamy
    • Bulletin of the Korean Chemical Society
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    • v.33 no.9
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    • pp.2910-2916
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    • 2012
  • Cadmium sulphide (CdS) nanorods were prepared by a single precursor thermal decomposition (SPTD) method. The formation of CdS nanorods and their structure, morphology and elemental composition were studied by means of FT-IR, XRD, FE-SEM, HR-TEM and EDAX analysis. Photoluminescence (PL) and lifetime measurements were recorded to study the luminescence properties of the material. The PL spectrum of the CdS nanorods showed one broad peak and four shoulders and the cause for this emission was discussed. The PL emissions from the band edge and deep trap state of the CdS nanorods were studied by lifetime measurements. Further, the synthesized CdS nanorods showed an increase in efficiency of photocatalytic degradation of methylene blue (MB) and rhodamine B (RhB). The increase in the photocatalytic activity was attributed to the mixed phase of the CdS nanorods.

Fabrication and characterization of plastic fiber-optic radiation sensor tips using inorganic scintillator material (무기 섬광체를 이용한 플라스틱 광섬유 방사선 센서부 제작 및 특성평가)

  • Hwang, Young-Muk;Cho, Dong-Hyun;Lee, Bong-Soo;Cho, Hyo-Sung;Kim, Sin
    • Journal of Sensor Science and Technology
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    • v.14 no.4
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    • pp.244-249
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    • 2005
  • In this study, radiation sensor tips are fabricated for remote sensing of X or gamma ray with inorganic scintillators and plastic optical fiber. The visible range of light from the inorganic scintillator that is generated by radiation source is guided by the plastic optical fiber and is measured by optical detector and power-meter. Two kinds of sensor tips are designed and fabricated such as film type and powder type. Many kinds of inorganic scintillators are used to fabricate both sensor tips, and the different wavelength of emitting lights from them are measured to determine the optimal inorganic scintillator which has maximum light output. As a radiation source X-ray generator and Ir-192 are selected to test a performance of sensor tip. It is expected that the fiber-optic radiation sensor is widely used in nuclear industry and medical applications due to its special characteristics such as good flexibility, easy in processing, long lengths and no interference to electro magnetic field.

Electrical Properties of Organic/Inorganic Hybrid Composites for Insulation Materials

  • Kim, Sang-Cheol;Ok, Jeong-Bin;Aho, Myeong-Jin;Park, Do-Hyun;Lee, Gun-Joo
    • Transactions on Electrical and Electronic Materials
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    • v.3 no.1
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    • pp.9-13
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    • 2002
  • In this work, the surface of inorganic fillers were modified with some functional groups such as stearic acid, aliphatic long chain, vinylsilane and aminosilane to control the interaction between inorganic fillers and polymer matrix. Ethylene-vinyl acetate copolymers (EVA) with various amount of vinyl-acetate and copolyether-ester elastomer were used as polymer matrix. The addition of inorganic fillers increases flame retardancy, but results in steep drop of electrical and mechanical properties, which may be caused by the defects in the interface between organic/inorganic hybrid composites. The hybrid composites are found to show better mechanical properties and higher volume resistivities as inorganic fillers are well dispersed and have good adhesion with polymer matrix. Also, the most effective type of functional group coated on fillers depends on the chemical structure of polymer.

Solution-processible Inorganic-organic Hybrid Bipolar Field Effect Transistors

  • Chae, Gil Jo;Walker, Bright;Kim, Kang Dae;Cho, Shinuk;Seo, Jung Hwa
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.391.2-391.2
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    • 2014
  • Solution-processible hybrid bipolar field effect transistors (HBFETs) with balanced hole and electron mobilities were fabricated using a combination of the organic p-type poly (3-hexylthiophene) (P3HT) layer and inorganic n-type ZnO material. The hole and electron mobilities were first optimized in single layer devices by using acetonitrile as a solvent additive to process the P3HT and annealing to process the ZnO layer. The highest hole mobility of the P3HT-only-devices with 5% acetonitrile was 0.15 cm2V-1s-1, while the largest electron mobility was observed in the ZnO-only-devices annealed at $200^{\circ}C$ and found to be $7.2{\times}10-2cm2V-1s-1$. The inorganic-organic HBFETs consisting of P3HT with 5% acetonitrile and ZnO layer annealed at $200^{\circ}C$ exhibited balanced hole and electron mobilities of $4.0{\times}10-2$ and $3.9{\times}10-2cm2V-1s-1$, respectively. The effect on surface morphology and crystallinity by adding acetonitrile and thermal annealing were investigated through X-ray diffraction and atomic force microscopy (AFM). Our findings indicate that techniques demonstrated herein are of great utility in improving the performance of inorganic-organic hybrid devices

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Development of an Oraganic-Inorganic Hybrid Coating Solution for Improvement in Flame Retardant Properties of Wallpapers (벽지의 방염특성을 개선하기 위한 유-무기 하이브리드 코팅 용액 개발)

  • Jeong, Gyu Jin;Kang, Tae Wook;Kim, Jin Ho;Kim, Bong Man;Seo, Eun Kyung;Bae, Byungseo;Kim, Sun Woog
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.2
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    • pp.178-183
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    • 2022
  • For enhancing the flame-retardant properties of wallpapers, we developed an organic-inorganic hybrid solution with ZrSiO4 as a functional ceramic powder, coated on non-woven fabric using dip coating, spray coating, and slot-die coating methods. Their flame retardant properties were characterized by a 45° combustion tester, which is manufactured according to the flame-retardant performance standard (KOFEIS 1001 and KS F 2819). In organic-inorganic hybrid solution, with increasing the concentration of acid-catalyst (acetic acid), the precipitation of ZrSiO4 powders increased, and the flame retardant properties decreased. The highest flame retardant result was obtained for the solution adding 5 wt% acetic acid. The optimization of the coating method and coating number resulted in the most excellent flame-retardant properties being obtained for the non-woven fabric coated for 5 or 7 times by dip coating method, and their flame-retardant properties corresponded to class 2 flame-retardant performance of wallpapers.

Asperities on the Surface of Plate-like Alumina and their Effect on Nacre-inspired Alumina-PMMA Composites

  • Kim, Bo-Yeon;Lee, Yoonjoo;Kim, Soo-Ryong;Shin, Dong-Geun;Kwon, Woo-Teck;Choi, Duck-Kyun;Kim, Younghee
    • Journal of the Korean Ceramic Society
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    • v.52 no.4
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    • pp.248-252
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    • 2015
  • Natural materials often have unique mechanical properties, such as the hierarchical structure of nacre formed through mineral bridges or asperities created between an inorganic particle and a natural-layer surface. As these asperities produce an exceptional shear resistance, in this study, we aimed to emulate the natural structure of nacre by synthesizing inorganic asperities and mineral bridges with different temperatures in the range of $1100-1300^{\circ}C$ and clay contents from 10 - 50 wt%. Following the infiltration of methyl methacrylate, we measured the mechanical properties to assess whether they were improved by the asperities. It was confirmed that the asperities improved the bending strength by 10%, and the anchoring effect was observed on the fracture surface.

Bio-Inspired Synthesis of a Silicate/PMMA Composite

  • Nam, Kyung Mok;Lee, Yoon Joo;Kwon, Woo Teck;Kim, Soo Ryong;Shin, Dong-Geun;Lim, Hyung Mi;Kim, Hyungsun;Kim, Younghee
    • Journal of the Korean Ceramic Society
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    • v.51 no.1
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    • pp.7-10
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    • 2014
  • Abalone shell is composed of 95 wt% $CaCO_3$ platelets and 5 wt% of a protein-rich organic matrix which acts as an adhesive layer, connecting aragonite tablets, thus maintaining the structural integrity of the composite. By mimicking abalone shell, we prepared a silicate plate/polymer nanocomposite by infiltrating PMMA between silicate layers and warm-pressing them at $200^{\circ}C$ for 1 h under 15 tons to make organic-inorganic composite materials. To examine the organic-inorganic composite materials after the warm-pressing procedure, the composite sample was analyzed with FE-SEM and TG. The bending strengths and densities of the composites prepared by a silicate plate and PMMA after the warm-pressing process were ~140 MPa and 1.5, respectively.

Iron oxide nanopowder synthesized by electroerosion dispersion (EED) - Properties and potential for microwave applications

  • Halbedel, Bernd;Prikhna, Tatiana;Quiroz, Pamela;Schawohl, Jens;Kups, Thomas;Monastyrov, Mykola
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1410-1414
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    • 2018
  • Magnetic nanoparticles (MNP) have attracted considerable interest in many fields of research and applied science due to their impressive properties. In the past, especially biomedical problems have promoted the development of MNPs. For technical applications e.g. wastewater treatment and absorption of electromagnetic waves, the existing synthesis approaches are too expensive and/or the producible quantities are too low. In this work we present a method for simple preparation of size-controlled magnetic iron oxide nanoparticles by electroerosion dispersion (EED) of carbon steel in water. We describe the synthesis method, the laboratory installation and discuss the structural, chemical and electromagnetic properties of the synthetized EED powders as well as their applicability for microwave absorption compared to other available ferrite powders.

Thermal Insulation Properties of Sandwich Panel Core with EPS Bead and Glass Wool (EPS Bead와 유리섬유를 혼입한 샌드위치 패널 심재의 단열 특성)

  • Jeon, Eun-Yeong;Lee, Chang-Woo;Hwang, Woo-Jun;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.77-78
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    • 2022
  • To improve the fire vulnerability of the organic insulation sandwich panel core, which is the main culprit of the large-scale fire disaster, an experiment was conducted to examine the thermal conductivity properties of the core material mixed with the organic insulation material EPS Bead and the inorganic insulation material glass wool. As the Additional ratio of glass wool increased, the thermal conductivity decreased, and it was determined that the replacement of glass wool of 3% or more had little effect on the decrease in thermal conductivity. In addition, it can be seen that the most ideal thermal conductivity is exhibited when 1% Replacement ratio of EPS and 3% glass wool are added. The core material of such organic and inorganic insulation materials is judged to be a core material that can compensate for the fire vulnerability of existing insulation materials. Therefore, in order to determine whether it is used as a core material for sandwich panels, additional studies such as fire resistance experiments and sound absorption experiments are needed in the future.

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A Study on the Seismic Rehabilitation Method through Using Environmentally-friendly Ductile Mortar and Fiber Materials (친환경 연성모르타르와 섬유로드를 이용한 내진보강 방안에 관한 연구)

  • Baek, Jong-Myeong;Shin, Min-Ho;Kim, Han-Bae;Kim, Bag-Jin
    • Proceedings of the KSR Conference
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    • 2011.10a
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    • pp.3237-3250
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    • 2011
  • As the growing concern about environment and earthquake for the concrete structure, many seismic rehabilitation and retrofitting methods have recently been studied but they are not coping enough with the changes of structure, specificly various problems have been found in seismic rehabilitation method - both in exposure or non exposure - when they are implemented to the underground structure, utility conduit, water supply facilities, underground wall, parking lot, road pavement, and elevated structure etc. This study is about the seismic rehabilitation method using environmentally friendly functional inorganic mortar and resilient material, and it is effectively retrofitted seismic performance as it reinforces not only physical strength, but also flexural and bond strength from the resilient material, and it has been analyzed and evaluated when the environmentally friendly functional inorganic mortar and the resilient material are applied so as to countermeasure the effect of earthquake and viable problems and approved for possibility of various applications and wide use.

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