• Title/Summary/Keyword: inorganic composite

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Water Swelling and Methanol Transport Behaviour of $PVdF/SPEEK/TiO_2$ Hybrid Membrane (PVdF/SPEEK/TiO2 하이브리드 막의 수분함량과 메탄올 전이현상)

  • Yu Seon Gyeong;Kim Han Ju;Park Su Gil;Kim Yeong Jae
    • 한국전기화학회:학술대회논문집
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    • 2005.07a
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    • pp.233-240
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    • 2005
  • A series of inorganic-organic hybrid membranes were prepared with a systematic variation of titanium dioxidenanoparticles content. Their water uptake, methanol permeability and proton conductivity as a function of inoranic oxide content were investigated. The results obtained show that the inorganic oxide network decreases the proton conductivity and water swelling. It is also found that increase In inorganic oxide content leads to decrease of methanol permeability. In terms of the morphology, membranes are homogeneous and exhibit a good adhesion between inorganic domains and the polymer matrix. The properties of the composite membranes are compared with the standard nafion membrane.

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Liquid uptake and Methanol Transport Behaviour of $PVdF/SPEEK/TiO_2$ Hybrid Membrane for DMFC (DMFC용 $PVdF/SPEEK/TiO_2$ 하이브리드 막의 수분함량과 메탄올 전이현상)

  • You, Sun-Kyung;Kim, Han-Joo;Kim, Young-Jae;Park, Soo-Gil
    • Proceedings of the KIEE Conference
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    • 2005.11a
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    • pp.194-196
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    • 2005
  • A series of inorganic-organic hybrid membranes were prepared with a systematic variation of titanium dioxidenanoparticles content. Their liquid uptake, methanol permeability and proton conductivity as a function of inoranic oxide content were investigated. The results obtained show that the inorganic oxide network decreases the proton conductivity and liquid uptake. It is also found that increase in inorganic oxide content leads to decrease of methanol permeability. In terms of the morphology, membranes are homogeneous and exhibit a good adhesion between inorganic domains and the polymer matrix. The properties of the composite membranes are compared with the standard nafion membrane.

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Synthesis of Al2O3/SiC Whisker (Al2O3/SiC Whisker원료 합성)

  • Chung, K.C.;Joo, K.;Chun, Y.S.;Orr, K.K.;Kim, E.H.;Lee, S.K.
    • Journal of the Korean Ceramic Society
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    • v.26 no.2
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    • pp.167-170
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    • 1989
  • Al2O3/SiC composite-material was synthesized by the birth-spread mechanism through the carbothermal reduction reaction of SiO2 in Ha-Dong Kaolin with carbon powder under H2 gas atmosphere at 1300~140$0^{\circ}C$. Average diameter of synthesized SiC whiskers were 1${\mu}{\textrm}{m}$ and aspect ratio (c/a) was 10~100. Al2O3 particles and SiC whiskers were mixed homogeneously in the reacted pellet.

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Research Status on the Carbon Nanotube Reinforced Nanocomposite (탄소나노튜브 강화 나노복합재료의 연구현황)

  • 차승일;김경태;이경호;모찬빈;홍순형
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.25-28
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    • 2003
  • Carbon nanotubes(CNTs), since their first discovery, have been considered as new promising materials in various fields of applications including field emission displays, memory devices, electrodes, NEMS constituents, hydrogen storages and reinforcements in composites due to their extra-ordinary properties. The carbon nanotube reinforced nanocomposites have attracted attention owing to their outstanding mechanical and electrical properties and are expected to overcome the limit of conventional materials. Various application areas are possible for carbon nanotube reinforced nanocomposites through the functionalization of carbon nanotubes. Carbon nanotube reinforced polymer matrix nanocomposites have been fabricated by liquid phase process including surface functionalization and dispersion of CNTs within organic solvent. In case of carbon nanotube reinforced polymer matrix nanocomposites, the mechanical strength and electrical conducting can be improved by more than an order of magnitude. The carbon nanotube reinforced polymer matrix nanocomposites can be applied to high strength polymers, conductive polymers, optical limiters and EMI materials. In spite of successful development of carbon nanotube reinforced polymer matrix nanocomposites, the researches on carbon nanotube reinforced inorganic matrix nanocomposites show limitations due to a difficulty in homogeneous distribution of carbon nanotubes within inorganic matrix. Therefore, the enhancement of carbon nanotube reinforced inorganic nanocomposites is under investigation to maximize the excellent properties of carbon nanotubes. To overcome the current limitations, novel processes, including intensive milling process, sol-gel process, in-situ process and spark plasma sintering of nanocomposite powders are being investigated. In this presentation, current research status on carbon nanotube reinforced nanocomposites with various matrices are reviewed.

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Development of a Computer Program to Estimate Landfill Liner Thickness (매립지 차수재 두께 산정을 위한 컴퓨터 프로그램 개발)

  • Do, Nam-Young;Lee, Seung-Rae;Jeong, Kwang-Young
    • Journal of the Korean GEO-environmental Society
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    • v.6 no.4
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    • pp.13-26
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    • 2005
  • In this study, research results on organic and inorganic pollutant migration through single and composite liner were summarized. On the basis of these summarized research results, a design program for landfill liner, which can be used to optimize the liner thickness based on the allowable ground water criteria around the landfill subsurface, was developed. A reasonable liner thickness was obtained from the program output results, in the case of the migration of $Cl^-$ ion through a single clay liner. Therefore, the developed program could be used to carry out a preliminary design for landfill liners with respect to organic and inorganic pollutants.

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The Dynamic Properties of the Artificial Stone According to the Mixed Ratio Change of the Inorganic Composite and Waste Porcelain (폐자기와 3성분계 무기결합재의 혼합비율 변화에 따른 인조석재의 역학적 특성)

  • Yoo, Yong Jin;Bae, Sang Woo;Lee, Sang Soo;Song, Ha Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.11a
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    • pp.95-96
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    • 2012
  • This study makes with the environment-friendly artificial stone which doesn't use the cement and natural aggregate and increases the blast furnace slag that is the eco-friendly material that is the industrial byproduct, fly ash, and availability of the red mud and applies the coares aggregate substitute material as the cleistothecium. The experimental plan according to it indicated the compressive strength and flexural strength which is the most excellent in the mixied ratio 40% of the result degree of closeness magnetism of experimenting with the optimal mix obtained through the preceding stude.

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Synthesis of Inorganic/Organic Core-Shell Polymer Using Polyoxyethylene Alkylether Sulfate as a Surfactant (Polyoxyethylene Alkylether Sulfate 계면활성제를 사용한 무기/유기 코어-셀의 합성)

  • Kim, Duck-Sool;Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.1
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    • pp.93-97
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    • 2010
  • Silicone dioxide absorbed polyoxyethylene alkylether sulfate (EU-S75D) surfactant was prepared. The core-shell composite of inorganic/organic were polymerized by using styrene(St) as a shell monomer and potassium persulfate(KPS) as an initiator. We studied the effect of surfactants on the core-shell structure of silicone dioxide/styrene in the presence of an anionic surfactant lauryl sulfate(SLS). The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer(TGA) and morphology of latex by scanning electron microscope(SEM).

Titanium Dioxide Nanofibers Prepared by Using Electrospinning Method

  • Ding, Bin;Kim, Chul Ki;Kim, Hak Yong;Seo, Min Kang;Park, Soo Jin
    • Fibers and Polymers
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    • v.5 no.2
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    • pp.105-109
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    • 2004
  • The synthesis of titanium dioxide nanofibers with 200-300nm diameter was presented. The new inorganic-organic hybrid nanofibers were prepared by sol-gel processing and electrospinning technique using a viscous solution of titanium isopropoxide (TiP)/poly(vinyl acetate) (PVAc). Pure titanium dioxide nanofibers were obtained by high temperature calcination of the inorganic-organic composite fibers. SEM, FT-IR, and WAXD techniques were employed to characterize these nanofibers. The titanium dioxide nanostructured fibers have rougher surface and smaller diameter compare with PVAc/TiP composite nanofibers. The anatase to rutile phase transformation occurred when the calcination temperature was increased from $600^{\circ}C$ to $1000^{\circ}C$.

Flowing and Strength Properties of Low Carbon Inorganic Composite Depending to Fine Aggregate Types and Replacement Ratio (잔골재 종류 및 치환율에 따른 저탄소 무기결합재의 유동 및 강도특성)

  • Park, Jong-Pil;Bae, Sang-Woo;Lee, Yun-Seong;Lee, Kang-Pil;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.235-236
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    • 2011
  • This study analyzed flowing and strength properties of mortar depending to fine aggregate types and replacement ratio by using blast furnace slag, red mud, and silica fume that are industrial by products. The findings showed that higher replacement level of fine aggregate increased air content while decreased table flow. In addition, compressive strength showed that the higher replacement level was regardless of fine aggregate types, the lower strength became. Mortar substituted by the dredged sand showed high strength.

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Flowing and Strength Properties of Low Carbon Inorganic Composites Using Polysilicon Sludge by Si/Al Ratio (폴리실리콘 슬러지를 사용한 저탄소 무기복합재의 Si/Al별 유동 및 강도특성)

  • Moon, Ji-Hwan;Park, Jong-Pil;Lee, Yun-Seong;Lee, Kang-Pil;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.47-48
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    • 2011
  • According to Bali Roadmap, Korea is also included in nations with a duty to reduce greenhouse gas. This study aims to draw proper Si/Al ratio by analyzing flowing and strength properties as the 4-component low carbon inorganic composite to reduce the use of cement and discarded polysilicon sludge. As the result, when Si/Al ratio is 4, the highest strength was found.

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