• Title/Summary/Keyword: inorganic component

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Ionic Compositions of PM2.5 during Summer and Winter in the Downtown Area of Jeju City in Jeju Island (제주시 도심지역에서 여름과 겨울의 PM2.5 이온조성 특성)

  • Lee, Ki-Ho;Hu, Chul-Goo
    • Journal of Environmental Science International
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    • v.26 no.4
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    • pp.447-456
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    • 2017
  • Chemical properties of aerosols were investigated by analyzing the inorganic water-soluble content in $PM_{2.5}$ collected in the downtown area of Jeju City in Jeju Island. Due to an increase in both the number of visiting tourists and the size of local population, the number of cars in this area is increasing, causing an increase in $PM_{2.5}$. Eight $PM_{2.5}$-bound major inorganic ions were analyzed during the summer and winter periods. The water-soluble inorganic component represents a significant fraction of $PM_{2.5}$. In particular, secondary inorganic aerosols contribute 36.2% and 47.5% of $PM_{2.5}$ mass in summer and winter, respectively. Nitrate concentrations increase for $[NH_4{^+}]/[SO_4{^{2-}}]$>1.5, and excess ammonium, which is necessary for ammonium nitrate formation, is linearly correlated with nitrate. These results are clearly observed during the winter because conditions are more conducive to the formation of ammonium nitrate. A significant negative correlation between Nitrogen Oxidation Ratio (NOR) and temperature was observed. The obtained results can be useful for a better understanding of the aerosol dynamics in the downtown area in Jeju City.

Multi-component kinetics for the growth of the cyanobacterium Synechocystis sp. PCC6803

  • Kim, Hyun-Woo;Park, Seongjun;Rittmann, Bruce E.
    • Environmental Engineering Research
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    • v.20 no.4
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    • pp.347-355
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    • 2015
  • The growth kinetics of phototrophic microorganisms can be controlled by the light irradiance, the concentration of an inorganic nutrient, or both. A multi-component kinetic model is proposed and tested in novel batch experiments that allow the kinetic parameters for each factor to be estimated independently. For the cyanobacterium Synechocystis sp. PCC6803, the estimated parameters are maximum specific growth rate $({\mu}_{max})=2.8/d$, half-maximum-rate light irradiance $(K_L)=11W/m^2$, half-inhibition-rate light irradiance $(K_{L,I})=39W/m^2$, and half-maximum-rate concentration for inorganic carbon $(K_{S,Ci})=0.5mgC/L$, half-maximum-rate concentration for inorganic nitrogen $(K_{S,Ni})=1.4mgN/L$, and half-maximum-rate concentration for inorganic phosphorus $(K_{S,Pi})=0.06mgP/L$. Compared to other phototrophs having ${\mu}max$ estimates, PCC6803 is a fast-growing r-strategist relying on reaction rate. Its half-maximum-rate and half-inhibition rate values identify the ranges of light irradiance and nutrient concentrations that PCC6803 needs to achieve a high specific growth rate to be a sustainable bioenergy source. To gain the advantages of its high maximum specific growth rate, PCC6803 needs to have moderate light illumination ($7-62W/m^2$ for ${\mu}_{syn}{\geq}1/d$) and relatively high nutrient concentrations: $N_i{\geq}2.3 mgN/L$, $P_i{\geq}0.1mgP/L$, and $C_i{\geq}1.0mgC/L$.

Theoretical Proposal for the Mix Design of Recycled Cement Utilizing Inorganic Construction Wastes (무기계 건설폐기물을 이용한 재생시멘트 배합설계에 관한 이론적 제안)

  • Kim, Ji-Hoon;Tae, Sung-Ho;Song, Hun;Shin, Hyeon-Uk
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.3
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    • pp.250-258
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    • 2016
  • Until now, the construction material industry has been recognized as a typical environmental destruction industry. However, recently, in order to reduce $CO_2$ emission, the main cause of environmental problems, lots of studies have been done about recycling industrial by-products and construction wastes. Therefore, the purpose of this study is to confirm whether it is possible to use as an alternative material in cement production process as a part of the development of recycled cement using an inorganic construction waste. For this study, the inorganic construction wastes was collected and analyzed each chemical component by XRF(X-ray Fluorescene). Also, the inorganic construction wastes were combined based on the chemical component of the cement, to perform this analysis. As a result, when the inorganic construction wastes was properly combined, it is possible to consider the development of the recycled cement used the inorganic construction wastes.

Characteristics and Analysis of Natural Pine-Needles Extract (천연 솔잎추출물의 특성 및 분석)

  • Sung, Ki-Chun
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.4
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    • pp.320-326
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    • 2004
  • We have extracted the natural pine-needles to use ethanol in solvent, and could obtain the refined oil component from pine-needles extract. We have tested the antimicrobial effect from microbe experiment and analyzed with ICP/OES, GC/MS. we could obtain the next conclusion from the result of this experiment. In the first result of this experiment we could know that in case of increasing concentration of pine-needles, the number of microbe decreased more and more. Also we could know that the refined oil component of pine-needles appeared the sterilization effect of S-aureus and E-coli after 96hrs and 120hrs. So we could know that the refined oil component of appeared effect to microbe. In the second result of this experiment we could know that inorganic materials of Ca, Mg, V, Mn etcs from pine-needles detected to ICP/OES analysis and the aromatic compounds from refined oil component of pine-needles was certificated to GC/MS analysis.

An effect of component layers on the phases and dielectric properties in $PbTiO_3$ thin films prepared from multilayer structure (다층구조박막으로부터 $PbTiO_3$ 박막 제조시 요소층이 상형성 및 유전특성에 미치는 영향)

  • Do-Won Seo;Song-Min Nam;Duck-Kyun Choi
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.4 no.4
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    • pp.378-387
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    • 1994
  • To improve the properties of $PbTiO_3$ thin films successfully grown by thermal diffusion of 3 component layers of $Ti0_2/Pb/TiO_2(900{\AA}/900{\AA}/900{\AA})$ in preceding research, 3, 5, 7, 9, and 11 multilayer structures $(TiO_2/Pb/.../Tio_2)$ with thinner component layer of $200~300 {\AA}$ thick were deposited on Si substrate by RF sputtering, which were followed by RTA to form $PbTiO_3$ thin films. As a result, $PbTiO_3$ single phase was formed above $500^{\circ}C$. When the thickness of component layer reduced and the number of component layers increased, suppression of Pb-silicate and voids formation resulted in relatively sharp interfaces and the film composition became more homogeneous. Relative dielectric constants in MIM structure were independent of the annealing condition, but they increased with increasing thickness of the $PbTiO_3$ thin films. The maximum breakdown field in MIS structure reached 150kV/cm.

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Desalting of tobacco extract using electrodialysis

  • Ge, Shaolin;Li, Wei;Zhang, Zhao;Li, Chuanrun;Wang, Yaoming
    • Membrane and Water Treatment
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    • v.7 no.4
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    • pp.341-353
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    • 2016
  • Papermaking reconstituted tobacco is an important strategy for recycling the waste tobacco residues. To indentify the influences of the inorganic components on harmful components delivery in cigarette smoke, a self-made electrodialysis stack was assembled to desalt the tobacco extract. The influences of the applied current and extract content on the removal rate of the inorganic ions were investigated. Results indicated that the applied current was a dominant impact on the desalination performance. High currents lower than the limiting current density could accelerate the desalting efficiency but cause higher energy consumption. A current of 2 A, or current density of ${\sim}11mA{\cdot}cm^{-2}$, was an optimal choice by considering both the energy consumption and desalting efficiency. A 20% tobacco extract was an appropriate content for the electrodialysis process. More than 90% of inorganic ions could be removed under the optimum condition. The preliminary result indicated that removal of inorganic components was beneficial to decrease the harmful component delivery in cigarette smoke. Naturally, ED is an environmentally friendly and high-effective technology for desalting the tobacco extract.

Synthesis of Inorganic/Organic Core-Shell Polymer (무기/유기 Core-Shell 에멀젼 고분자의 합성)

  • Kim, Nam-Seok;Kim, Duck-Sool;Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.19 no.4
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    • pp.265-272
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    • 2002
  • $CaCO_{3}$ absorbed sodium lauryl sulfate (SLS) surfactant was prepared, Core-shell polymers of inorganic/organic pair, which have both core and shell component, were synthesized by sequential emulsion polymerization using styrene(St) as a shell monomer and potasium persulfate (KPS) as an initiator, We found that when $CaCO_{3}$; core prepared by adding 2,0 wt% SLS, $CaCO_{3}$ core/PSt shell polymerization was carried out on the surface of $CaCO_{3}$ particle without forming the new PSt particle during St shell polymerization in the inorganic/organic core-shell polymer preparation, The structure of core-shell polymer were investigated by measuring the degree of decomposition of $CaCO_{3}$ using HCl solution, thermal decomposition of polymer composite using thermogravimetric analyzer and morphology by scanning electron microscope.

Development of environmentally friendly inorganic fluorescent pigments, A3V5O14 (A = K and Rb) and Cs2V4O11: Crystal structure, optical and color properties (친환경 무기 형광 안료 A3V5O14 (A = K and Rb) and Cs2V4O11 개발: 결정구조, 광학적 특성 및 착색 특성)

  • Jeong, Gyu Jin;Kim, Jin Ho;Lee, Younki;Hwang, Jonghee;Toda, Kenji;Bae, Byoungseo;Kim, Sun Woog
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.2
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    • pp.47-54
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    • 2020
  • To develop the bright-vivid red- and yellow-inorganic fluorescent pigments with high luminescence properties, A3V5O14 (A = K and Rb) and Cs2V4O11 inorganic pigments were synthesized by a water assisted solid state reaction (WASSR) method and a conventional solid state reaction method. Although impurity peaks corresponding to the AVO3 and AV3O8 (A = K, Rb, and Cs) were observed in all samples prepared, the trigonal structure A3V5O14 (A = K and Rb) and orthorhombic structure Cs2V4O11 were successfully obtained as a main phase. These inorganic pigments showed the broad absorption band (under 550 nm) originated from CT transitions of VO4 polyhedron, and the strong broad red- and green-emission bands due to 3T21A1 and 3T11A1 transitions of the [VO4]3- group. The A3V5O14 (A = K and Rb) and Cs2V4O11 pigments showed a bright-vivid red- and yellow-body color, where the a* values of the A3V5O14 (A = K and Rb) were +35.5 and +45.9, respectively, and b* value of Cs2V4O11 pigments was +50.3. The L* values of the A3V5O14 (A = K and Rb) and Cs2V4O11 inorganic pigments were over +45. These results indicate that the A3V5O14 (A = K and Rb) and Cs2V4O11 inorganic pigments could be an attractive candidate as a bright-vivid red- and yellow inorganic pigments.

Standing Biomass and Inorganic Nutrients Distribution for a Camellia japonica Stand at Mt. Cheon-gwan(Janghueng-gun, Jeonnam) (천관산(전남 장흥군) 동백나무(Camellia japonica) 천연림의 현존량과 무기영양소 분포)

  • Hwang, Jae-Hong;Lee, Sang-Tae;Kim, Byeong-Bu;Kwon, Bong-Sam;Shin, Hyun-Cheol;Lee, Kyung-Jae;Park, Nam-Chang
    • The Korean Journal of Ecology
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    • v.28 no.3
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    • pp.163-168
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    • 2005
  • This study was carried out to estimate above-ground biomass and inorganic nutrient distribution for a Camellia japonica stand located Mt. Cheon-gwan, Jeonnam province. Regression analysis of biomass for stem, current twig, branch and foliage versus diameter at breast height(DBH) was used to calculate regression equations of the form of logY = a + blogD(Y: component biomass, D: DBH). Total above-ground biomass for a Camellia japonica stand was 115.2 ton/ha(47.9 for main stem, 1.4 for current twig, 53.4 for live and dead branch, 5.6 for current foliage and 6.9 for ${\geq}1$-yr-old foliage). Component biomass was non-linearly correlated with DBH, and the difference in biomass between ${\geq}1$-yr-old and current foliage increased in proportion to DBH. Current foliage and live branch showed higher N, P and K concentrations compared to ${\geq}1$-yr-old foliage and dead branch, respectively. However, Ca concentration of current foliage and live branch was lower than that of ${\geq}1$-yr-old foliage and dead branch, respectively. Total above-ground inorganic nutrient contents(kg/ha) were distributed as follows; K: 366.4. N: 442.7, Ca: 433.3, Mg: 118.4, P: 50.5 and Na: 25.3. The proportions of inorganic nutrient content for live branch were generally the highest in all the inorganic nutrients.

Adsorption of Flexography Ink on Inorganic Particles Patched with Cationic Polymer (양이온성 고분자로 처리한 무기입자에 대한 플렉소그라피 잉크의 흡착)

  • Jeong, Young Bin;Kim, Jin Woo;Oh, Kyu Duk;Youn, Hye Jung;Lee, Hak Lae
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.5
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    • pp.8-13
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    • 2012
  • The flexography ink has disadvantage in a deinking process because it tends to form too fine particles in alkali condition to be removed in flotation deinking. The influence of pH conditions on the particle size of phthalocyanine cyan ink used for flexo-printing was investigated to see the effect of pH conditions on flexography ink dispersion. Flexography ink particles prepared by grinding dried ink films were used in this experiment. Greater reduction of the ink particle size was noticed under alkaline pH condition, which was attributed to dissolution of resin component of the ink. Adsorption behavior of flexography ink onto pigment particles was examined using clay and talc as substrate pigments. Pretreatment of inorganic pigments with a cationic poly-DADMAC increased the surface adsorption of flexography ink particles, which improved the removal of the inks by centrifugal sedimentation of inorganic pigments. Most efficient removal of the ink particles was achieved when an optimal addition level of the cationic polymer was used for pretreatment of inorganic pigments, and this optimal addition level corresponds to the surface saturation point of the polyelectrolyte. Adsorption of flexography ink particles onto inorganic pigments improved the ink removal in flotation deinking since the pigment particles has the optimal particle size for flotation deinking.