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Microstructural Characterization of Clad Interface in Welds of Ni-Cr-Mo High Strength Low Alloy Steel (Ni-Cr-Mo계 고강도 저합금강 용접클래드 계면의 미세조직 특성 평가)

  • Kim, Hong-Eun;Lee, Ki-Hyoung;Kim, Min-Chul;Lee, Ho-Jin;Kim, Keong-Ho;Lee, Chang-Hee
    • Korean Journal of Metals and Materials
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    • v.49 no.8
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    • pp.628-634
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    • 2011
  • SA508 Gr.4N Ni-Cr-Mo low alloy steel, in which Ni and Cr contents are higher than in commercial SA508 Gr.3 Mn-Mo-Ni low alloy steels, may be a candidate reactor pressure vessel (RPV) material with higher strength and toughness from its tempered martensitic microstructure. The inner surface of the RPV is weld-cladded with stainless steels to prevent corrosion. The goal of this study is to evaluate the microstructural properties of the clad interface between Ni-Cr-Mo low alloy steel and stainless weldment, and the effects of post weld heat treatment (PWHT) on the properties. The properties of the clad interface were compared with those of commercial Mn-Mo-Ni low alloy steel. Multi-layer welding of model alloys with ER308L and ER309L stainless steel by the SAW method was performed, and then PWHT was conducted at $610^{\circ}C$ for 30 h. The microstructural changes of the clad interface were analyzed using OM, SEM and TEM, and micro-Vickers hardness tests were performed. Before PWHT, the heat affected zone (HAZ) showed higher hardness than base and weld metals due to formation of martensite after welding in both steels. In addition, the hardness of the HAZ in Ni-Cr-Mo low alloy steel was higher than that in Mn-Mo-Ni low alloy steel due to a comparatively high martensite fraction. The hardness of the HAZ decreased after PWHT in both steels, but the dark region was formed near the fusion line in which the hardness was locally high. In the case of Mn-Mo-Ni low alloy steel, formation of fine Cr-carbides in the weld region near the fusion line by diffusion of C from the base metal resulted in locally high hardness in the dark region. However, the precipitates of the region in the Ni-Cr-Mo low alloy steel were similar to that in the base metal, and the hardness in the region was not greatly different from that in the base metal.

A Case Study of the Heavy Asian Dust Observed in May 2011 (2011년 5월 관측된 고농도 황사 사례 연구)

  • Ahn, Bo-Yeong;Lim, Byunghwan
    • Journal of the Korean earth science society
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    • v.43 no.3
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    • pp.386-404
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    • 2022
  • From April 29 to 30, 2011, under the influence of Asian dust originated from Mongolia, a high concentration of Asian dust was observed nationwide for 4 days in Korea. This study investigated the causes and characteristics of and weather conditions associated with Asian dust at high concentrations at its source in Mongolia. For analysis, Asian dust weather data, Asian dust monitoring tower data, satellite data, backward trajectory data, observation data (PM10 and OPC data), and ECMWF reanalysis data were used. In the synoptic analysis, it was observed that the intervals of isobars were densely distributed in the central region of Mongolia and the pressure gradient force was strong. It could be inferenced that Asian dust occurred due to strong winds. The temperature was relatively high, above 10℃, just before the occurrence of Asian dust, and it decreased sharply at the onset of the dust. The relative humidity had a low value of less than approximately 40%. After the occurrence of Asian dust, it increased sharply to over 50% and then showed a tendency to decrease. In the aerosol index shown by the COMS satellite, a high concentration value of over 25 was detected in Inner Mongolia, and it was consistent with the observations made with naked eyes. In the 72-hour backward trajectory, the northwest airflow streamed into Korea, and on May 2, Heuksando showed the highest PM10 concentration of 1,025 ㎍ m-3(times the average). Especially, in kinematic vertical analysis, it was observed that low pressure on the ground was strengthened by cyclonic relative vorticity developed in the upper layer. Also, the vertical velocity development is considered to have played a major role in the occurrence of high concentration Asian dust.

Effect of AlF3 addition to the plasma resistance behavior of YOF coating deposited by plasma-spraying method (플라즈마-스프레이법에 의해 코팅한 옥시불화이트륨(YOF) 증착층의 플라즈마 내식성에 미치는 불화알루미늄(AlF3) 첨가 효과)

  • Young-Ju Kim;Je Hong Park;Si Beom Yu;Seungwon Jeong;Kang Min Kim;Jeong Ho Ryu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.33 no.4
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    • pp.153-157
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    • 2023
  • In order to manufacture a semiconductor circuit, etching, cleaning, and deposition processes are repeated. During these processes, the inside of the processing chamber is exposed to corrosive plasma. Therefore, the coating of the inner wall of the semiconductor equipment with a plasma-resistant material has been attempted to minimize the etching of the coating and particle contaminant generation. In this study, we mixed AlF3 powder with the solid-state reacted yttrium oxyfluoride (YOF) in order to increase plasma-etching resistance of the plasma spray coated YOF layer. Effects of the mixing ratio of AlF3 with YOF powder on crystal structure, microstructure and chemical composition were investigated using XRD and FE-SEM. The plasma-etching ratios of the plasma-spray coated layers were calculated and correlation with AlF3 mixing ratio was analyzed.

Assessment of structural fire resistance of a fire-proofed immersed tunnel under tunnel fire scenarios (화재시나리오별 침매터널 구조물의 화재저항성 평가)

  • Choi, Soon-Wook;Chang, Soo-Ho;Kim, Heung-Yon;Jo, Bong-Hyun
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.12 no.6
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    • pp.429-441
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    • 2010
  • In this study, fire resistance of a fireproof material sprayed upon an immersed tunnel was experimentally evaluated under $HC_{inc}$ and IS0834(duration of 4 hours) fire scenarios. Under $HC_{inc}$ fire scenario, the maximum inner temperatures of a concrete specimen at the depth of 0, 25 and 50 mm from the interface between the structure and the fire-proofing layer were $311^{\circ}C$, $194^{\circ}C$ and $142^{\circ}C$ respectively. Similarly, the corresponding maximum temperatures under IS0834 fire scenario were $332^{\circ}C$, $222^{\circ}C$ and $179^{\circ}C$ respectively. From the results, it was revealed that the two different fire scenarios assumed in this study have almost the same fire capacity as each other in the maximum temperature concept. In addition, a structural analysis of the immersed tunnel under $HC_{inc}$ fire scenario was carried out to verify the effects of the fireproof material on its structural stability. Material loss and deterioration of a concrete specimen without any fire-proofing measure was also experimentally evaluated to obtain input parameters for the structural analysis under such a severe fire scenario. From the results, it was confirmed that the application of fireproof measures to the immersed tunnel is essential for its structural stability even under a severe fire scenario.

A Study on the Histopathological Changes and Growth Inhibition of the Chick Embryos after Incubation with Radioactive Sulfur($^{35}S$) (방사성황산(放射性黃酸)($^{35}S$)이 부화계란(孵化鷄卵)의 발육(發育) 및 주요장기(主要臟器)의 병리조직상(病理組織像)에 미치는 영향(影響)에 관(關)한 연구(硏究))

  • Shin, Soo-Young
    • The Korean Journal of Nuclear Medicine
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    • v.1 no.1
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    • pp.37-54
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    • 1967
  • The changes in histopathology of various organs and growth inhibition of the chick embryos incubated with radioactive sulfur ($^{35}S$) were experimentally studied. The various doses of $^{35}S$ were injected into the yolk sac at different intervals and the weight changes of the embryos were evaluated to determine the growth inhibition rates. The embryos sacrified on various incubation days were used for the study of histopathological changes in organs such as the bone, liver, kidney, gonad, and eye. Following were the results: 1) The weight changes of the $^{35}S$ treated groups were as follows: i. Embryos treated on the 5 th incubation day: No weight changes were noted on the 8th incubation day, however, the growth inhibition rate of 32.1% was noted in the group treated with $50{\mu}C$ and of 38.2% in the group treated with $150{\mu}C$ on the 12th incubation day. The rates were 9.1 and 12.1% on the 15th incubation day, and 6.5 and 10.6% on the 18th incubation day respectively. ii. Embryos treated on the 8th incubation day: The growth inhibition rates on the 12th, 15th and 18th incubation days in the groups treated with $50{\mu}C$ were 20.9, 25.9 and 18.8% and in those treated with $150{\mu}C$ were 20.0, 14.9 and 16.9% respectively. iii. Embryos treated on the 12th incubation day: The growth inhibition rates on the 15th and 18th in the groups treated with $50{\mu}C$ were 13.6 and 21.1% and in those treated with $150{\mu}C$ were 26.7 and 6.5% and in those treated with $250{\mu}C$ were 10.6 and 12.6% respectively. iv. Embryos treated on the 15th incubation day: The growth inhibition rates on the 18th in the groups treated with $50{\mu}C$ were 6.5% and in those treated with $150{\mu}C$ were 10.1% and in those treated with $250{\mu}C$ were 8.5% respectively. In summary, the longer the incubation days, the less the growth inhibition rates. II) The histopathological changes in the various organs were as follows: i. Bone: Hyperplasia and edematous changes of the bone cavity, irregular distribution of immature granular cells and increased number of the myeloblast, megakaryocyte and reticuloendothelial cells were noted. ii. Liver: The embryos treated with $150{\mu}C\;of\;^{35}S$ on the 8th incubation day showed necrosis and nucleolysis of the liver cell and abnormal enlargement of sinusoid on the 12th incubation day. The longer the incubation days, the more severe the changes such as the pyknotic artophy of the liver cells and heterochromatism. The embryos treated on the 5th incubation day with 50 and $150{\mu}C\;of\;^{35}S$ showed little changes, but sight enlargement and accumulation of serous fluid in the sinusoid on the 8th incubation day. iii. Kidney: No particular changes except atrophic changes of epithelium were noted in early stage, however, the infiltration of the granular cell and monocyte into the cortex and pyknotic changes of vascular glomeruli were noted in later stage. These changes were not closely related to the doses of $^{35}S$ given. iv. Gonad: The degenerative changes such as destruction of the immature germ cells, hyperplasia and vacuolization of the stroma were noted in testis and ovary. v. Eye: A slight distortion of the cornea and sclera was noted. The hypertrophy of inner layer and blood cell infiltration into the vascular layer of the choroid membrane were noted in embryo groups on the 12, 15 and 18th incubation days.

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Community Structure of the Macrobenthos in the Soft Bottom of Yongsan River Estuary, Korea 2. The Occurrence of Summer Hypoxia and Benthic Community (영산강 하구역의 연성저질에 서식하는 저서동물 군집 2. 여름철 빈산소 수괴의 출현과 저서동물 분포)

  • LIM Hyun-Sig;PARK Kyung-Yang
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.31 no.3
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    • pp.343-352
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    • 1998
  • The relationship between summer hypoxia in bottom water layer and benthic community structure was discussed at forty sampling stations in semi-enclosed Youngsan River estuarine bay, Korea. The oxygen deficient layer less than $2.0 mg/\ell$ was widely developed in the inner estuarine stations in summer due to the summer stratification. A total of 141 species was occurred, with a mean density of $1,923 ind./m^2$ and biomass of $79.44\;g/m^2$ in summer season. The species number was significantly increased with the increment of the bottom dissolved oxygen, whereas density and biomass were partially correlated within the low oxygen level of $2.0\;mg/\ell$. These results imply that benthic community structures are affected by bottom oxygen depletion in summer. Cluster analysis showed that the benthic community could be classified into three station groups. These station groups from the species composition coincided with the groups based on the environmental factors. This fact suggests that the overall spatial distribution of macrozoobenthos in Youngsan River estuarine bay in summer should be controlled by the summer hypoxia and clay content of the area. Group-I was located the innermost estunrine bay from Mokpo Harbour to near the dike, where summer hypoxia was developed and one bivalve Theora fragilis, two polychaetes, Tharyx sp. and Lumbrineris longifolia were dominated. Group-II, the central transitory area of the estuarine bay between two another stational groups, where two bivalves Theora fragilis, Raetellops pulchella and a polychaete Tharyx sp. predominated with relatively low density compared to that of Group-I. Group-III, the mouth part of the estunrine bay exposed to the open sea, where a polychaetes Poecilochaetus johnsoni and a bivalve Yoldia Johanni predominated.

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Numerical Simulation of the Formation of Oxygen Deficient Water-masses in Jinhae Bay (진해만의 빈산소 수괴 형성에 관한 수치실험)

  • CHOI Woo-Jeung;PARK Chung-Kill;LEE Suk-Mo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.27 no.4
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    • pp.413-433
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    • 1994
  • Jinhae Bay once was a productive area of fisheries. It is, however, now notorious for its red tides; and oxygen deficient water-masses extensively develop at present in summer. Therefore the shellfish production of the bay has been decreasing and mass mortality often occurs. Under these circumstances, the three-dimensional numerical hydrodynamic and the material cycle models, which were developed by the Institute for Resources and Environment of Japan, were applied to analyze the processes affecting the oxygen depletion and also to evaluate the environment capacity for the reception of pollutant loads without dissolved oxygen depletion. In field surveys, oxygen deficient water-masses were formed with concentrations of below 2.0mg/l at the bottom layer in Masan Bay and the western part of Jinhae Bay during the summer. Current directions, computed by the $M_2$ constituent, were mainly toward the western part of Jinhae Bay during flood flows and in opposite directions during ebb flows. Tidal currents velocities during the ebb tide were stronger than that of the flood tide. The comparision between the simulated and observed tidal ellipses showed fairly good agreement. The residual currents, which were obtained by averaging the simulated tidal currents over 1 tidal cycle, showed the presence of counterclockwise eddies in the central part of Jinhae Bay. Density driven currents were generated southward at surface and northward at the bottom in Masan Bay and Jindong Bay, where the fresh water of rivers entered. The material cycle model was calibrated with the data surveyed in the field of the study area from June to July, 1992. The calibrated results are in fairly good agreement with measured values within relative error of $28\%$. The simulated dissolved oxygen distributions of bottom layer were relatively high with the concentration of $6.0{\sim}8.0mg/l$ at the boundaries, but an oxygen deficient water-masses were formed within the concentration of 2.0mg/l at the inner part of Masan Bay and the western part of Jinhae Bay. The results of sensitivity analyses showed that sediment oxygen demand(SOD) was one of the most important influence on the formation of oxygen depletion. Therefore, to control the oxygen deficient water-masses and to conserve the coastal environment, it is an effective method to reduce the SOD by improving the polluted sediment. As the results of simulations, in Masan Bay, oxygen deficient water-masses recovered to 5.0mg/l when the $50\%$ reduction in input COD loads from Masan basin and $70\%$ reduction in SOD was conducted. In the western part of Jinhae Bay, oxygen deficient water-masses recovered to 5.0mg/l when the $95\%$ reduction in SOD and $90\%$ reduction in culturing ground fecal loads was conducted.

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Distribution of Salinity and Temperature due to the Freshwater Discharge in the Yeongsan Estuary in the Summer of 201 (2010년 여름 담수방류에 의한 영산강 하구의 염분 및 수온 분포 변화)

  • Park, Hyo-Bong;Kang, Kiryong;Lee, Guan-Hong;Shin, Hyun-Jung
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.17 no.3
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    • pp.139-148
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    • 2012
  • The short-term variation of salinity and temperature in a dyked estuarine environment is mainly controlled by the freshwater discharge from the dyke. We examined the distribution of salinity and temperature by the freshwater discharge in the Yeongsan River estuary using the CTD data obtained from 8 stations through three surveys in June (weak discharge) and August (intensive discharge), 2010. During the weak discharge in June, the surface salinity showed 30-32.5 psu and its horizontal gradient was relatively high around Goha-do (0.25~0.32 psu/km). On the other hand, the salinity of the bottom layer was almost constant in the range of 33 psu. Water temperature ranged $19{\sim}21^{\circ}C$ and displayed higher gradient in north-south direction than the gradient of east-west direction. During the intensive freshwater discharge on August 12, the salinity dropped to 9~26 psu. The maximum horizontal gradient of surface salinity reached 3.8 psu/km in the north of Goha-do where the strong salinity front was formed, and the horizontal salinity gradient of bottom layer was 0.28 psu/km. The horizontal gradient of water temperature was $-0.45^{\circ}C/km$ in the surface and $-0.12^{\circ}C/km$ in the bottom with high surface temperature near the dyke and decreasing gradually to the river mouth. After 3 days of the intensive discharge ($3^{rd}$ survey), the surface salinity increased to 22~26 psu. However, there still existed relatively high horizontal gradient around Goha-do. In the mean time, the bottom salinity decreased to 26.5~27.5 psu, but its gradient was not big as much as the surface gradient. According to time series of CTD profile near the dyke, the discharged fresh water jetted down temporarily and then recovered gradually with the recovering speed of 0.4 m/hour for the discharge case of $13{\times}10^6$ ton. Due to the combined effects of freshwater discharge and surface heating during the summer of 2010, the Yeongsan estuary, in general, underwent intensified vertical stratification, which in turn caused the inhibition of vertical mixing, especially inside area of estuary. Based on the spatial distribution of salinity and temperature, the Yeongsan estuary can be divided into three regions: the Goha-do area with strong horizontal gradient of salinity and temperature, inner estuary from Goha-do to the dyke with low salinity, and outer estuary from Goha-do to the coasts with relatively high salinity.

Effect of Carbon Dioxide Pressure on Mineral Carbonation in Acidic Solutions (산성용액에서 이산화탄소의 압력이 광물탄산화에 미치는 영향)

  • Ryu, Kyoung Won;Hong, Seok Jin;Choi, Sang Hoon
    • Economic and Environmental Geology
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    • v.53 no.1
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    • pp.1-9
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    • 2020
  • Magnesium silicate minerals such as serpentine [Mg3Si2O5(OH)4] have a high potential for the sequestration of CO2; thus, their reactivity toward dissolution under CO2-free and CO2-containing conditions in acidic solvents is a critical process with respect to their carbonation reactions. To examine the carbonation efficiency and dissolution mechanism of serpentine, hydrothermal treatment was performed to the starting material via a modified direct aqueous carbonation process at 100 and 150℃. The serpentine dissolution experiments were conducted in H2SO4 solution with concentration range of 0.3-1 M and at a CO2 partial pressure of 3 MPa. The initial pH of the solution was adjusted to 13 for the carbonation process. Under CO2-free and CO2-containing conditions, the carbonation efficiency increased in proportion to the concentration of H2SO4 and the reaction temperature. The leaching rate under CO2-containing conditions was higher than that under CO2-free conditions. This suggests that shows the presence of CO2 affects the carbonation reaction. The leaching and carbonation efficiencies at 150℃ in 1 M H2SO4 solution under CO2-containing conditions were 85 and 84%, respectively. The dissolution rate of Mg was higher than that of Si, such that the Mg : Si ratio of the reacted serpentine decreased from the inner part (approximately 1.5) to the outer part (less than 0.1). The resultant silica-rich layer of the reaction product ultimately changed through the Mg-depleted skeletal phase and the pseudo-serpentine phase to the amorphous silica phase. A passivating silica layer was not observed on the outer surface of the reacted serpentine.

Yield Increase and Energy Saving Effect on Plastic Greenhouse Covered with Polyolefin Film (PO필름 피복 온실의 수량 증대 및 에너지 절감 효과)

  • Moon, Jong Pil;Park, Seok Ho;Kim, Jin Gu;Lee, Jae Han;Kang, Youn Koo;Lim, Mi Young;Kim, Hye Min
    • Journal of Bio-Environment Control
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    • v.29 no.4
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    • pp.428-439
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    • 2020
  • This study was carried out to investigate the effect of PO film on the increase of crop yield and energy saving through PO and PE film greenhouse application and comparison test. As a experimental greenhouse, two single span greenhouses (1-1 W) and two double span greenhouses (1-2 W) were used. During winter season, PO film (0.15 mm outer layer, 0.10mm inner layer) was used as a covering material of greenhouse in double layers for double-span (B15) and single-span(B21), and PE film used for double-span (B15), and single-span (B23) as a control. The experimental vegetable was tomato(Solanum lycopersicum L.) cultivated in soil and the cultivar of that was 'Happiness'. That was cultivated from December 3, 2019 to April 30, 2020. The temperature at night inside the greenhouse was maintained at 15℃, and the side and roof windows were opened to maintain 23 ~ 24℃ during the day. As a result, this study showed that the yield in single-span greenhouse(B21) covered with a PO film increased 20% and that in double-span greenhouse (B16) increased by 9% compared to the greenhouse covered with a PE film (B23, B15). Fuel consumption of the single-span greenhouse (B21) with the cover of PO film was reduced by 12.4% and that of double-span greenhouse was done by 11.5% compared to that of the PE film greenhouse (B23, B15) without any difference between them in growing state.