• Title/Summary/Keyword: initial ratios

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Influence of Initial Molar Ratios on the Performance of Low Molar Ratio Urea-Formaldehyde Resin Adhesives

  • LUBIS, Muhammad Adly Rahandi;PARK, Byung-Dae
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.2
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    • pp.136-153
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    • 2020
  • In this paper, the influence of initial formaldehyde/urea (F/U) molar ratios on the performance of low molar ratio (1.0) urea-formaldehyde (UF) resin adhesives has been investigated. Two initial F/U molar ratios, i.e., the first and second initial molar ratios were used for the alkaline addition reaction. Three levels of the first initial F/U molar ratios (2.0, 3.0, and 4.0) and two levels of the second initial molar ratios (2.0 and 1.7) were employed to prepare a total of six UF resins with an identical final molar ratio (1.0). The basis properties, functional groups, molecular weight, crystallinity, and thermal curing properties of the UF resins were characterized in detail. Higher levels (3.0 and 4.0) of the first initial F/U molar ratio provided the UF resins with better properties (non-volatile solids content, viscosity, gelation time, pH, and specific gravity) than those of the resins prepared with the conventional level F/U molar ratio of 2.0. Statistical analysis suggested that combining the first and second initial molar ratio of 4.0 with 1.7 would result in UF resins with greater adhesion strength and lower formaldehyde emission than those of the resins prepared with other molar ratios. The results showed that higher levels of the first initial molar ratio resulted in a more branched structure, as indicated by GPC, FTIR, DSC, XRD, and greater adhesion strength than those of the other UF resins with an identical final molar ratio of 1.0.

The Prosodic Characteristics of Korean Read Sentences in Dicourse Context (한국어 낭독체 담화문의 운율적 특징 - 단독발화문과 연속발화문의 비교를 통하여 -)

  • Seong Cheol-Jae
    • MALSORI
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    • no.35_36
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    • pp.1-12
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    • 1998
  • This study aims to investigate the prosodic characteristics of Korean discourse sentences, especially focusing the initial and final part of a sentence. 50 disourse sentences were read in two different styles; one, sentence by sentence, the other, continuous of all 50's. First, we tried to get two kinds of ratios from the acoustic results: first, ratio of the final syllable to the initial syllable in first word in a sentence; second, ratio of the final syllable to the initial syllable in last word in a sentence. We, then, calculated statistical values of the ratios including mean, standard deviation, minimum, maximum, and p-values in t-test. With respect to duration, there were little difference between two different styles. If any, we could see tiny unharmonious durational aspect in the initial of continuous reading. More concisely, there could be observed some deviation from standard. In case of F0, there was prominent statistical difference between ratios of last words in two styles. This difference might play a role as a prosodic feature. Energy seems to show similar pattern with that of F0. The results showed that final syllable in last word was pronounced with about 85 % of initial syllable in the same context and the last words in continuous speech were strongly articulated compared with those of sentence by sentence reading.

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patterns and crust - mantle interactio

  • Du, Y.
    • Proceedings of the KSEEG Conference
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    • 2000.04a
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    • pp.110-110
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    • 2000
  • Temporal and spatial distribution patterns of the magmatic rocks and associated ore deposits in the Mesozoic magmatic - metallogenic belt along the Yangtz River, Anhui Province are used to determine and discuss the crust - mantle interaction processes. The magmatic rocks are Cu - Au mineralized high - K calc - alkalic intermediate ¬acidic (CAK) and Fe - Cu mineralized high - Na alkalic - calc intermediate - basic intrusive rocks (FCN) in the central part of the belt and grade to Cu - Mo - Pb - Zn - Ag mineralized calc - alkalic granitoids (CMG) and A - type granites (AG) in the southern and northern parts of the belt. Samples from the CAK and CMG yield Rb - Sr isochron ages of 137 - 140Ma with $(^{87}Sr/^{86}Sr)_{o}$ = 0.7060 - 0.7101, while those from the FCN and AG yield the ages of 120 - 129Ma with $(^{87}Sr/^{86}Sr)_{o}$ = 0.7047 - 0.7077. The Sr isotope ratios, CriTh ratios 0.4 - 3.1), Eu/Eu* ratios < 0.79 - 1.05) and initial epsilon (Nd) values (-16.6 - -6.3) for the CAK and CMG are consistent with magma derivation from old metamorphic basement rocks rich in metallogenic elements through a two - stage process of mantle - derived magma underplating caused by primary lithosphere extension and subsequent partial melting. On the basis of Sr isotope data, CriTh ratios (3.4 - 13.8), Eu/Eu* ratios (0.86 - 1.13) and initial epsilon (Nd) values (-7.7 - +1.4), the FCN and AG are considered to be formed through syntexis with material input from the mantle that resulted from further lithosphere extension followed by mantle - derived magma underplating on a large scale.

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Determining minimum analysis conditions of scale ratio change to evaluate modal damping ratio in long-span bridge

  • Oh, Seungtaek;Lee, Hoyeop;Yhim, Sung-Soon;Lee, Hak-Eun;Chun, Nakhyun
    • Smart Structures and Systems
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    • v.22 no.1
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    • pp.41-55
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    • 2018
  • Damping ratio and frequency have influence on dynamic serviceability or instability such as vortex-induced vibration and displacement amplification due to earthquake and critical flutter velocity, and it is thus important to make determination of damping ratio and frequency accurate. As bridges are getting longer, small scale model test considering similitude law must be conducted to evaluate damping ratio and frequency. Analysis conditions modified by similitude law are applied to experimental test considering different scale ratios. Generally, Nyquist frequency condition based on natural frequency modified by similitude law has been used to determine sampling rate for different scale ratios, and total time length has been determined by users arbitrarily or by considering similitude law with respect to time for different scale ratios. However, Nyquist frequency condition is not suitable for multimode system with noisy signals. In addition, there is no specified criteria for determination of total time length. Those analysis conditions severely affect accuracy of damping ratio. The focus of this study is made on the determination of minimum analysis conditions for different scale ratios. Influence of signal to noise ratio is studied according to the level of noise level. Free initial value problem is proposed to resolve the condition that is difficult to know original initial value for free vibration. Ambient and free vibration tests were used to analyze the dynamic properties of a system using data collected from tests with a two degree-of-freedom section model and performed on full bridge 3D models of cable stayed bridges. The free decay is estimated with the stochastic subspace identification method that uses displacement data to measure damping ratios under noisy conditions, and the iterative least squares method that adopts low pass filtering and fourth order central differencing. Reasonable results were yielded in numerical and experimental tests.

Initial shear strength of RC hollow sectional columns (RC 중공단면 기둥의 초기전단강도 특성)

  • Sun, Chang-Ho;Kim, Ick-Hyun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.449-450
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    • 2009
  • In this study, the characteristics of initial shear strength of hollow sectional columns were investigated by experiments with parameters of the aspect ratios, void ratios, web area ratios and load patterns. The test results were analyzed with comparison of the values expected by the empirical equations. The empirical equation was newly proposed on the basis of mechanical characteristics and test results, and its validity was evaluated.

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Analyses on Viscosity Properties of $TiO_2$ Sol and $SiO_2$ Sol using Sol-Gel Method (솔젤법에 의해 제작된 $TiO_2$ 솔과 $SiO_2$ 솔의 점도 특성에 대한 분석)

  • You Do-Hyun
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.12
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    • pp.573-577
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    • 2005
  • [$TiO_2$] sol and $SiO_2$ sol were prepared using sol-gel method. As $H_{2}O$/Alkoxide ratios increased, sol had cluster structure and as $H_{2}O$/Alkoxide ratios decreased, sol had linear structure. Gelation time of $TiO_2$ sol was faster than that of $SiO_2$ sol according to the time. In comparison with initial viscosity between $TiO_2$ sol and $SiO_2$ sol, $TiO_2$ sol was highest at $H_{2}O/Ti(OC_{3}H_{7})_{4}=5$, $SiO_2$ sol was almost constant according to $H_{2}O/Si(OC_{2}H_{5})_{4}$ ratios.

질소원의 종류 및 초기 당농도가 곰팡이 Thraustochytrium aureum ATCC 34304의 성장 및 발효 특성에 미치는 영향

  • Kim, Won-Ho;Heo, Byeong-Gi
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.313-316
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    • 2000
  • The effects of initial sugar concentration and the various nitrogen sources on the fermentation characteristics of Thraustochytrium aureum were investigated. The sugar conversion ratios decrease with increase in the initial sugar concentration regardless of the kinds of nitrogen sources. The specific growth rate, the biomass yield, and the DHA yield also decreased but approached constant values higher than the concentration of 30g/L. The sugar conversion ratios and the specific growth rate showed the highest values in case of using the yeast extract as nitrogen source. It was difficult to conclude that the variation of nitrogen source had some effects on the biomass yield. However, the initial sugar concentration had a rather effects on the biomass yield for the sugar concentration of 40 g/L showed 0.27. The nitrogen source that showed the greatest yield of DHA was sodium glutamate.

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Experimental Evaluation of the Seismic Performance and Engineering Damage State of Reinforced Concrete Columns (철근콘크리트 기둥의 내진성능 및 공학적 손상상태에 대한 실험적 평가)

  • Lee, Do Hyung
    • Journal of the Earthquake Engineering Society of Korea
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    • v.27 no.2
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    • pp.119-127
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    • 2023
  • In this paper, seismic performance evaluation was carried out for eight circular reinforced concrete columns designed seismically by KRTA[1]and KCI[8]. Primary design parameters for such columns included many longitudinal reinforcements, yield strength of reinforcements, the vertical spacing of spirals, aspect ratio, and axial force ratio. The test results showed that all the columns exhibited stable hysteretic and inelastic responses. Based on the test results, drift ratios corresponding to each damage state, such as initial yielding, initial cover spalling, initial core concrete crushing, buckling, and fracture of longitudinal reinforcement and final spalled region, were evaluated. Then, those ratios were compared with widely accepted damage limit states. The comparison revealed that the existing damage states were considerably conservative. This implies that additional research is required for the damage limit states of such columns designed seismically by current Korean design codes.

Determination of Initial Billet Size using The Artificial Neural Networks and The Finite Element Method for a Forged Product (신경망과 유한요소법을 이용한 단조품의 초기 소재 형상 결정)

  • 김동진;고대철;김병민;최재찬
    • Transactions of Materials Processing
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    • v.4 no.3
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    • pp.214-221
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    • 1995
  • In the paper, we have proposed a new method to determine the initial billet for the forged products using a function approximation in the neural network. The architecture of neural network is a three-layer neural network and the back propagation algorithm is employed to train the network. By utilizing the ability of function approximation of a neural network, an optimal billet is determined by applying the nonlinear mathematical relationship between the aspect ratios in the initial billet and the final products. The amount of incomplete filling in the die is measured by the rigid-plastic finite element method. The neural network is trained with the initial billet aspect ratios and those of the unfilled volumes. After learning, the system is able to predict the filling regions which are exactly the same or slightly different to the results of finite element simulation. This new method is applied to find the optimal billet size for the plane strain rib-web product in cold forging. This would reduce the number of finite element simulation for determining the optimal billet size of forging product, further it is usefully adapted to physical modeling for the forging design.

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Propagation of plane waves in an orthotropic magneto-thermodiffusive rotating half-space

  • Sheokand, Suresh Kumar;Kumar, Rajeshm;Kalkal, Kapil Kumar;Deswal, Sunita
    • Structural Engineering and Mechanics
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    • v.72 no.4
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    • pp.455-468
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    • 2019
  • The present article is aimed at studying the reflection phenomena of plane waves in a homogeneous, orthotropic, initially stressed magneto-thermoelastic rotating medium with diffusion. The enuciation is applied to generalized thermoelasticity based on Lord-Shulman theory. There exist four coupled waves, namely, quasi-longitudinal P-wave (qP), quasi-longitudinal thermal wave (qT), quasi-longitudinal mass diffusive wave (qMD) and quasi-transverse wave (qSV) in the medium. The amplitude and energy ratios for these reflected waves are derived and the numerical computations have been carried out with the help of MATLAB programming. The effects of rotation, initial stress, magnetic and diffusion parameters on the amplitude ratios are depicted graphically. The expressions of energy ratios have also been obtained in explicit form and are shown graphically as functions of angle of incidence. It has been verified that during reflection phenomena, the sum of energy ratios is equal to unity at each angle of incidence. Effect of anisotropy is also depicted on velocities of various reflected waves.