• 제목/요약/키워드: initial modulus

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Clay/Acrylamide Hydrogels Having Fucoidan (푸코이단을 함유한 Clay/아크릴아미드 하이드로젤)

  • Hwang, Sun-Ae;Lee, Jong-Hwi
    • Polymer(Korea)
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    • v.35 no.4
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    • pp.332-336
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    • 2011
  • Hydrogels have been investigated due to their potential in a myriad of applications. The introduction of functional moiety such as sulfide has expanded their applicability. In this study, an investigation was carried out on the introduction of fucoidan into the hydrogels of clay/acrylamide. In the resulting semi-IPN nanocomposite hydrogels, the linear polysaccharide, fucoidan, has strong ionic interactions with clay. It was also confirmed from simple mixing tests that fucoidan can physically crosslink with clay without chemical crosslinks. In the semi-IPN hydrogels, equilibrium swelling ratio increased with the content of fucoidan. Elastic modulus increased with an initial increase in the content of fucoidan, and decreased with a further increase. The work of fracture results of these hydrogels showed their tough properties. These hydrogels could provide functional properties such as mucoadhesiveness with tunable hydrogel characteristics.

Synthesis and Characterization of Transparent Copolyimide Films (I) (투명한 폴리이미드 공중합체 필름의 합성과 특성 연구 (I))

  • Park, Jong-Su;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.32 no.6
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    • pp.580-586
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    • 2008
  • Copolyimides were synthesized from 4,4'-(hexafluoroisopropylidene)diphthalic anhydride (6FDA) and 1,3-bis(3-aminophenoxy)benzene (BAPB) with different mole ratios of 2,2-bis[4-(4-aminophenoxy)pheny1]hexafluoropropane (BAPP). The solution cast film of poly(amic acid) (PAA) was heat treated at different temperatures to create copolyimide films. The PI copolymer films were found to exhibit good optical transparencies. The thermomechanical properties, morphology, and optical transparency of PI films were examined using fourier transform infrared spectroscopy (FT-IR), wide-angle X-ray diffraction (XRD), scanning electron microscopes (SEM), differential scanning calorimeter(DSC), thermo-gravimetric analyzer (TGA), universal tensile machine (UTM), and IN - Vis. spectrometer. The glass transition temperature ($T_g$), ultimate strength, and initial modulus linearly increased with increasing BAPP mole fraction. However, thermal stability($T_D{^i}$) of the copolyimide remains constant regardless of BAPP loadings. It was found, however, that the optical transparency decreases slightly upon increasing the BAPP content because of the formation of the charge transfer complexes.

Determination of Rock Abrasiveness using Cerchar Abrasiveness Test (세르샤 마모시험을 통한 암석의 마모도 측정에 관한 연구)

  • Lee, Su-Deuk;Jung, Ho-Young;Jeon, Seok-Won
    • Tunnel and Underground Space
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    • v.22 no.4
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    • pp.284-295
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    • 2012
  • Abrasiveness of rock plays an important role on the wear of rock cutting tools. In this study, Cerchar abrasiveness tests were carried out to assess the abrasiveness of 19 different Korean rocks. Cerchar abrasiveness test is widely used to assess the abrasiveness of rock because of its simplicity and inexpensive cost. This study examines the relationship between Cerchar Abrasiveness Index (CAI) and mechanical properties (uniaxial compressive strength, Brazilian tensile strength, Young's modulus, Poisson's ratio, porosity, shore hardness of rock), and the effect of quartz content, equivalent quartz content, which was obtained from XRD analysis. As a result of test, CAI was more influenced by petrographical properties than by the bonding strength of the matrix material of rock. CAI prediction model which consisted of UCS and EQC was proposed. CAI decreased linearly with the hardness of the steel pin. Numerical analysis was performed using Autodyn-3D for simulating the Cerchar abrasiveness test. In the simulations, most of pin wear occurred during the initial scratching distance, and CAI increased with the increase of normal loading.

The Effects of Hexamethoxymethylmelamine on the Adhesion of Rubber to Brase-Plated Steel Cord (Hexamethoxymethylmelamine이 고무-황동피복코드간의 접착에 미치는 영향)

  • Kim, Wan-Young;Kim, Youn-Sop;Yug, Gyeong-Chang;Kim, Hyung-Soon;Lee, Jeong-Yong;Choi, Sang-Won
    • Applied Chemistry for Engineering
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    • v.3 no.3
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    • pp.422-429
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    • 1992
  • The morphology and adhesion properties of rubber compounds containing resorcinol formaldehyde(RF) resin and hexamethoxymethylmelamine(HMMM) used in adhesion of rubber to brass-plated steel cord was investigated. The resins were spherical particles about $2000{\AA}$ diameter and distributed in rubber compounds homogeneously, and the cured compound with steel cord showed migration of resin to steel cord. Also, modulus was increased with increasing HMMM contents. The loss of adhesion between rubber and steel cord was likely to be at initial stages by thermal aging. Considering the physical properties, suability of adhesion layer and thermal aging property, optimum ratio of RF resin and HMMM was 1 : 0.9.

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Evaluation of Reproducibility for Mechanical Properties of Lightweight Concrete using Bottom Ash Aggregates and Foam (바텀애시 골재와 기포를 이용한 경량 콘크리트의 역학적 특성에 대한 재현성 평가)

  • Ji, Gu-Bae;Mun, Ju-Hyun;Yang, Keun-Hyeok
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.3
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    • pp.202-209
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    • 2019
  • The objective of this study is to examine the reproducibility for compressive strength development and mechanical properties of lightweight concrete made using bottom ash aggregates and foam(LWC-BF). Based on the mix proportions conducted by Ji et al., six identical mixes were prepared with different actual foam volume ratios from 0% to 25% and water-to-binder ratios from 25% to 30%. The presently measured properties, including initial slump, slurry density, compressive strength gains at different ages, splitting tensile strength, and modulus of rupture, were very close to those determined in the previous tests by Ji et al. Thus, the developed LWC-BF has a good potential in obtaining a reproducibility for compressive strength development and mechanical properties even though the troubles of mixing control owing to the addition of preformed foam.

Stress-Strain Model in Compression for Lightweight Concrete using Bottom Ash Aggregates and Air Foam (바텀애시 골재와 기포를 융합한 경량 콘크리트의 압축 응력-변형률 모델)

  • Lee, Kwang-Il;Mun, Ju-Hyun;Yang, Keun-Hyeok;Ji, Gu-Bae
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.3
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    • pp.216-223
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    • 2019
  • The objective of this study is to propose a reliable stress-strain model in compression for lightweight concrete using bottom ash aggregates and air foam(LWC-BF). The slopes of the ascending and descending branches in the fundamental equation form generalized by Yang et al. were determined from the regression analyses of different data sets(including the modulus of elasticity and strains at the peak stress and 50% peak stress at the post-peak performance) obtained from 9 LWC-BF mixtures. The proposed model exhibits a good agreement with test results, revealing that the initial slope decreases whereas the decreasing rate in the stress at the descending branch increases with the increase in foam content. The mean and standard deviation of the normalized root-square mean errors calculated from the comparisons of experimental and predicted stress-strain curves are 0.19 and 0.08, respectively, for the proposed model, which indicates significant lower values when compared with those(1.23 and 0.47, respectively) calculated using fib 2010 model.

A Performance Evaluation of the CCA Adaptive Equalization Algorithm by Step Size (스텝 크기에 의한 CCA 적응 등화 알고리즘의 성능 평가)

  • Lim, Seung-Gag
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.19 no.3
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    • pp.67-72
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    • 2019
  • This paper evaluates the performance of CCA (Compact Constellation Algorithm) adaptive equalization algorithm by varying the step size for minimization of the distortion effect in the communication channel. The CCA combines the conventional DDA and RCA algorithm, it uses the constant modulus of the transmission signal and the considering the output of decision device by the power of compact slice weighting value in order to improving the initial convergence characteristics and the equalization noise by misadjustment in the steady state. In this process, the compact slice weight values were fixed, and the performance of CCA adaptive equalization algorithm was evaluated by the varing the three values of step size for adaptation. As a result of computer simulation, it shows that the smaller step size gives slow convergence speed, but gives excellent performance after at steady state. Especially in SER performance, the small step size gives more robustness that large values.

An extension of a high order approach for free vibration analysis of the nano-scale sandwich beam with steel skins for two types of soft and stiff cores

  • Marandi, S. Masoud;Dehkordi, Mohsen Botshekanan;Nourbakhsh, S. Hassan
    • Steel and Composite Structures
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    • v.31 no.3
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    • pp.261-276
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    • 2019
  • The study investigates the free vibration of a nano-scale sandwich beam by an extended high order approach, which has not been reported in the existing literature. First-order shear deformation theory for steel skins and so-called high-order sandwich panel theory for the core are applied. Next, the modified couple stress theory is used for both skins and cores. The Hamilton principle is utilized for deriving equations and corresponding boundary conditions. First, in the study the three-mode shapes natural frequencies for various material parameters are investigated. Also, obtained results are evaluated for two types of stiff and soft cores and isotropic, homogenous steel skins. In the research since the governing equations and also the boundary conditions are nonhomogeneous, therefore some closed-form solutions are not applicable. So, to obtain natural frequencies, the boundary conditions are converted to initial conditions called the shooting method as the numerical one. This method is one of the most robust approaches to solve complex equations and boundary conditions. Moreover, three types of simply supported on both sides of the beam (S-S), simply on one side and clamp supported on the other one (S-C) and clamped supported on both sides (C-C) are scrutinized. The parametric study is followed to evaluate the effect of nano-size scale, geometrical configurations for skins, core and material property change for cores as well. Results show that natural frequencies increase by an increase in skins thickness and core Young modulus and a decrease in beam length, core thickness as well. Furthermore, differences between obtained frequencies for soft and stiff cores increase in higher mode shapes; while, the more differences are evaluated for the stiff one.

Buckling resistance behavior of WGJ420 fire-resistant weathering steel columns under fire

  • Yiran Wu;Xianglin Yu;Yongjiu Shi;Yonglei Xu;Huiyong Ban
    • Steel and Composite Structures
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    • v.47 no.2
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    • pp.269-287
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    • 2023
  • The WGJ420 fire-resistant weathering (FRW) steel is developed and manufactured with standard yield strength of 420 MPa at room temperature, which is expected to significantly enhance the performance of steel structures with excellent fire and corrosion resistances, strong seismic capacity, high strength and ductility, good resilience and robustness. In this paper, the mechanical properties of FRW steel plates and buckling behavior of columns are investigated through tests at elevated temperatures. The stress-strain curves, mechanical properties of FRW steel such as modulus of elasticity, proof strength, tensile strength, as well as corresponding reduction factors are obtained and discussed. The recommended constitutive model based on the Ramberg-Osgood relationship, as well as the relevant formulas for mechanical properties are proposed, which provide fundamental mechanical parameters and references. A total of 12 FRW steel welded I-section columns with different slenderness ratios and buckling load ratios are tested under standard fire to understand the global buckling behavior in-depth. The influences of boundary conditions on the buckling failure modes as well as the critical temperatures are also investigated. In addition, the temperature distributions at different sections/locations of the columns are obtained. It is found that the buckling deformation curve can be divided into four stages: initial expansion stage, stable stage, compression stage and failure stage. The fire test results concluded that the residual buckling capacities of FRW steel columns are substantially higher than the conventional steel columns at elevated temperatures. Furthermore, the numerical results show good agreement with the fire test results in terms of the critical temperature and maximum axial elongation. Finally, the critical temperatures between the numerical results and various code/standard curves (GB 51249, Eurocode 3, AS 4100, BS 5950 and AISC) are compared and verified both in the buckling resistance domain and in the temperature domain. It is demonstrated that the FRW steel columns have sufficient safety redundancy for fire resistance when they are designed according to current codes or standards.

Evaluation of Physical Properties of Material Combination for Fabricating Protection Pads for Women's Army Combat Uniforms (여군 전투복 내 관절 부위 보호 패드 개발을 위한 설계 변인 조합에 따른 물성 평가)

  • Okkyung Lee;Heeran Lee;Soyoung Kim;Yejin Lee
    • Journal of the Korean Society of Clothing and Textiles
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    • v.47 no.2
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    • pp.311-322
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    • 2023
  • In this study, the properties of various material combinations were evaluated and an ideal material for fabricating protection pads for women's army combat uniforms was determined. Eight specimens were used for the evaluation: two types of materials, namely thermoplastic polyurethane for 3D printing, T and ethylene-vinyl acetate, E; two infill densities, namely 10%, 10 and 30%, 30; two types of pad designs, i.e., without holes, A and with holes, B; 2×2×2=8 and control E. The tensile strength, flexural strength, impact absorption, and weight of these specimens were evaluated. Results revealed that E was the most flexible material; however, its tensile strength and impact absorption were very low. Protection pads made from T (T-10A, T-10B, T-30A, and T-30B) had excellent tensile strength and impact absorption; however, they had low performance in ease of movement. Alternatively, protection pad with holes and an infill density of 30% produced using a combination of T and E had a high initial tensile modulus and exhibited excellent impact absorption. Moreover, it was flexible and light, which satisfies the standards and conditions required by protection pads. However, if T-E-10A and T-E-30B exhibited low impact absorption, as required, they can be regarded as appropriate materials for protection pads.