• Title/Summary/Keyword: inert gas

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High Permeability, High Selectivity Carbon-Silica Membranes for Gas Separation (기체분리용 고투과선택성 탄소-실리카막)

  • 이영무;박호범
    • Membrane Journal
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    • v.12 no.2
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    • pp.107-119
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    • 2002
  • Carbon-silica ($C-SiO_2$) membranes can be easily prepared by the pyrolysis of two-phase copolymers containing an aromatic imide block and a siloxane block and remarkably high permselectivities of $He/N_2, O_2/N_2,$ and $CO_2/N_2$. The pyrolysis of the imide-siloxane block copolymers was carried out at different final temperatures, $600^{\circ}C, 800^{\circ}C,$ and $1000^{\circ}C$ under an inert atmosphere, and is the first reported case of the precursors being used for the preparation of carbon membrane. The polymeric precursors were synthesized in a wide range of siloxane content and different final morphology, and the pyrolozed membranes were tested with a high vacuum time-lag method at $25^{\circ}C$ and 76cmHg of feed pressure. In experiments with He, $CO_2, O_2 \;and \;N_2$, the membranes were found to have good $O_2/N_2$ selectivity up to 32.2 and $O_2$ permeability on the order of $10-8/cm^2(STP)cm/cm^2seccmHg.$.

A Study on Percent Agent in Pipe as a Criterion to Evaluate Limitations and Performance of Gaseous Fire Extinguishing Systems (가스계 소화설비의 제한사항 및 성능평가를 위한 배관 내 약제비율에 관한 연구)

  • Son, Bong-Sei;Kim, Hee-Woo
    • Fire Science and Engineering
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    • v.21 no.4
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    • pp.1-11
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    • 2007
  • This study aims to investigate, review, and summarize the definition, development, and applications of "percent agent in pipe", "percent of agent in pipe" which is used as a key factor in testing and evaluating the performance of gaseous fire extinguishing agents, including Halon 1301 and $CO_2$. This study also analyzes and compares the local and international standards on testing and evaluating the performance of gaseous fire extinguishing systems, as well as the results of system performance tests conducted as a part of performance evaluation and approval programs for gaseous fire extinguishing systems, especially, Korean Gaseous Fire Extinguishing System Performance Approval Program called KFI Approval. Percent agent in pipe was defined first in NFPA 12A, Standard on Halon 1301 Fire Extinguishing Systems, dating back to the 1970's. After the phaseout of Halon 1301 systems in 1994 in the developed countries, the percent agent in pipe has been widely used in Halon 1301 alternative clean agent fire extinguishing systems, both halocarbon clean agent systems and inert gas clean agent systems, as an essential criterion to assure the system design accuracy, determine the limitations and performance of a system, and to predict the system performance results accurately, especially, in association with their system flow calculations. Underwriters Laboratories has their own standards such as UL 2127 and 2166 applying percent agent in pipe in testing and evaluating the performance of clean agent fire extinguishing systems. As a part of a system performance test and approval program called KFI Approval System, Korea also has started to apply the percent agent in pipe as a key factor to test, evaluate, and approve the performance of gaseous fire extinguishing systems, including both high and low pressure $CO_2$ systems, from the early 2000's. This study outlines and summarizes the relevant UL and KFI standards and also describes the actual test resultant data, including the maximum percents of agent in pipe for gaseous fire extinguishing systems. As evidenced in lots of tests conducted as a part of the system performance test and approval programs like KFI Approval System, it has been proven that the percent agent in pipe may work as a key factor in testing, evaluating, and determining the limitations and performance of gaseous fire extinguishing systems, especially compared with the hydraulic flow calculations of computer design programs of gaseous fire extinguishing systems, and will remain as such in the future. As one thing to note, however, there are some difficulties in using the unified percent agent in pipe to determine the maximum lengths of pipe networks for gaseous fire extinguishing systems, because the varying definitions used by some of the flow calculations (not in accordance with NFPA 12A definition) make it impossible to do any direct comparison of pipe lengths based on percent agent in pipe.

A Study on the Measurement of Explosion Range by CO2 Addition for the Process Safety Operation of Propylene (프로필렌의 공정안전 운전을 위한 CO2 첨가량에 따른 폭발범위 측정에 관한 연구)

  • Choi, Yu-Jung;Heo, Jong-Man;Kim, Jung-Hun;Choi, Jae-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.7
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    • pp.599-606
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    • 2019
  • Most facilities that manufacture products made from the hazardous materials operate at high temperatures and pressures. Therefore, there is a risk of fire explosion. In particular, an explosion accident is a major risk factor for facilities with hazardous materials, such as oil, chemical, and gas. Propylene is often used in sites producing basic raw materials and synthetic materials by addition polymerization at petrochemical plants. To prevent an explosion in the business using propylene, the explosion range with the oxygen concentration was calculated according to the changes in temperature and pressure using an inert gas, carbon dioxide. In these measurements, the temperature was $25^{\circ}C$, $100^{\circ}C$, and $200^{\circ}C$ and the amount of carbon dioxide in the container was $1.0kgf/cm^2.G$, $1.5kgf/cm^2.G$, $2.0kgf/cm^2.G$, and $2.5kgf/cm^2.G$. The explosion limit was related to temperature, pressure, and oxygen concentration. The minimum oxygen concentration for an explosion decreased with increasing temperature and pressure. The range of explosion narrowed with decreasing oxygen concentration. In addition, no explosion occurred at concentrations below the minimum oxygen concentration, even with steam and an ignition source of propylene.

Crystal Growth of $Cr:Al_2O_3$ and $Ti:Al_2O_3$ by Czochralski Technique (용액인상법에 의한 $Cr:Al_2O_3$$Ti:Al_2O_3$ 단결정 육성)

  • Yu, Yeong-Mun;Lee, Yeong-Guk;Park, Ro-Hak
    • Korean Journal of Crystallography
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    • v.6 no.1
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    • pp.1-13
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    • 1995
  • Cr:A12O3 and Ti:A12O3 single crystals were grown by Czochralski method, and the effects of crystal growth parameters such as pulling rate, rotation rate, dopant and growth atmosphere on crystal quality were investigated. And spectroscopic properties including lasing efficiency were also measured. Single crystals, sized of 20mm in diameter and 100-135mm in length, were successfully grown from the seed of <001> direction. With the doping level of 0.5w/o Cr2O3, pulling rate 2.0mm/hr, rotation rate of 30rpm and inert atmosphere by nitrogen gas, high quality crystals of Cr:A12O3 were grown. While in case of Ti:A12O3 crystals, high quality crystals were grown under the conditions of the doping level of 0.25w/o TiO2, pulling rate of 1.5mm/hr, rotation rate of 30rpm and reducing atmosphere by hydrogen - nitrogen mixed gas. It was confirmed that Cr3+ ion which maintains its ionoc valence during growth easily de-bubbled than Ti4+ ion which changes its valence, Fe3+ ion also has do-bubbling effect to Ti:A12O3 crystal and the reducing atmosphere by 90% N2 - 10% H2 mixed gas gave effective result on the changing of Ti4+ to Ti3+ and de-bubbling. As a result of spectroscopic measurements of Cr:A12O3 crystal, 4A2 →4F2 and 4F1 absorption transitions and E →4A2(R1) and 2A →4A2(R2) fluorenscence transitions were confirmed. And it was measured that wavelengths of laser R1 and R2 transitions were 696±5nm and 692±5nm respectively, line width of these transitions were 12A, and life-time of fluorenscence was 152μsec. In case of Ti:A12O3 crystals, it was confirmed that absortion transition of 4T2→4E and fluorescence transition of 4E→4T2 with wide range of 650-1050nm was occured. And 147μsec of life-time of fluorescence, 125.4 of figure of merit and 9% of laser efficience were also measured.

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Elementary School in Gwangju Gwangsan Radon gas Density Measurement (광주광역시 광산구 소재 초등학교 라돈가스 농도 계측)

  • Ahn, Byungju;Oh, Jihoon
    • Journal of the Korean Society of Radiology
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    • v.8 no.4
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    • pp.211-216
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    • 2014
  • Radium is rock or soil of crust or uranium of building materials after radioactivity collapse process are created colorless and odorless inert gas that accrue well in sealed space like basement. It inflow to lung circulate respiratory organ and caused lung cancer because of deposition of lung or bronchial tubes. In this study, the air in the elementary school classroom nongdoeul tonkatsu place of measured values were compared using the calculated annual internal radiation exposure. La tonkatsu exposure measured in primary school classroom at least five schools when you close the windows in the average floor 0.56mSv 2 floors ground floor windows when opened 0.384mSv 048mSv 3 floors, 2 floor levels of the same three layers 0.31mSv 0.296mSv the human exposure to radon and radiation on the first floor of 3 floors above ground in a lot of exposure was moderate. When you close the window from the first floor up 0.384mSv 056mSv 3 floors with a minimum annual radiation exposure due to natural radiation in the 16 to 23.3 percent minimum 2.4mSv accounted for. When I opened the window to the maximum annual radiation exposure 2.4mSv 0.296mSv 0.31mSv least a minimum of 12.3 to 12.91% accounted for Results suggest that more than five chodeunghakgyoeun La tonkatsu domestic radon measurements conducted below regulatory requirements and internal exposure has also fall within the normal range. People The less the radiation exposure to the human body because it reduces the impact in the classroom in elementary school vent windows often reduced to the maximum radon concentration in the air, if called tonkatsu be able to reduce radiation exposure for the immune system is weak and elementary will be helpful to experiment more in the future for the school authorities called tonkatsu investigation is done to him if the action to establish a more secure school building facilities is thought would be helpful.

Evaluation of Indoor Radon Levels in a Hospital Underground Space and Internal Exposure (의료기관 지하시설의 라돈가스 측정과 내부피폭 조사)

  • Song, Jea-Ho;Jin, Gye-Hwan
    • Journal of the Korean Society of Radiology
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    • v.5 no.5
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    • pp.231-235
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    • 2011
  • Radium is rock or soil of crust or uranium of building materials and thorium after radioactivity collapse process are created colorless and odorless inert gas that accrue well in sealed space like mine or basement. It inflow to lung circulate respiratory organ and caused lung cancer because of deposition of lung or bronchial tubes. Radium sheath of medical institution treat person's life is possible big danger to professional regarding radioactivity who has much amount exposed radioactivity and weaker immune patient. so we do this test. Using measuring instrument at test is real time radium measuring instrument, Professional Continuous Radon monitor, and measuring places are basement first floor and second floor of two hospitals and measure from 10 a.m to 3 p.m. Measurement result of Professional Continuous Radon monitor is minimum 14.8 Bq/$m^3$ to maximum 70.3 Bq/$m^3$ and show domestic baseline below 148 Bq/$m^3$, effective dose-rate is minimum 0.296 mSv to maximum 1.406 mSv that show 2.4 mSv, 10~58.3% level, exposed radiation amount from nature radiation one year.

Performance enhancement of Organic Thin Film Transistor by Ar Ion Beam treatment (Ar Ion Beam 처리를 통한 Organic Thin Film Transistor의 성능향상)

  • Jung, Suk-Mo;Park, Jae-Young;Yi, Moon-Suk
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.44 no.11
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    • pp.15-19
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    • 2007
  • This paper reports the effects of Ar ion beam surface treatment on a $SiO_2$ dielectric layer in organic thin film transistors. We compared the electrical properties of pentacene-based OTFTs, treated by $O_2$ plasma or Ar ion beam treatments and characterized the states of the surface of the dielectric by using atomic force microscopy and X-ray photoelectron spectroscopy. For the sample which received $O_2$ plasma treatment, the mobility increased significantly but the on/off current ratio was found very low. The Ar ion beam-treated sample showed a very high on/off current ratio as well as a moderately improved mobility. XPS data taken from the dielectric surfaces after each of treatments exhibit that the ratio of between Si-O bonds and O-Si-O bonds was much higher in the $O_2$ plasma treated surface than in the Ar ion beam treated surface. We believe that our surface treatment using an inert gas, Ar, carried out an effective surface cleaning while keeping surface damage very low, and also the improved device performances was achieved as a consequence of improved surface condition.

Numerical Study of the Optimization of Combustion and Emission Characteristics of Air-Staged Combustion in a Pulverized Coal-Fired Boiler (석탄 화력 보일러의 공기 다단공급방식을 통한 연소 및 배기 배출물 특성 최적화에 관한 수치해석 연구)

  • Yoon, Min-Ji;Lee, Byoung-Hwa;Song, Ju-Hun;Kim, Gyu-Bo;Chang, Young-June;Jeon, Chung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.6
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    • pp.587-597
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    • 2010
  • Air-staged combustion is known to be one of the techniques of NOx reduction. The objective of this study is to determine the optimal ratio of air flow distributed for CCOFA and SOFA; at this optimal ratio, the combustion and exhaust emission characteristics of a pulverized coal-fired boiler are maintained at a satisfactory level. A numerical investigation was performed at various airflow ratios of 16.7/83.3%, 25/75%, 50/50%, 75/25%, and 83.3/16.7%. An inert gas was considered as a substitute for air to isolate the effects of the cooling process and chemical reaction on NOx reduction; during NOx reduction in air-staged combustion, both the effects typically occur simultaneously. The results of our study show that the optimum condition, under which the maximum NOx reduction and highest boiler efficiency can be obtained, corresponds to the equal splitting of the over-fire air between CCOFA and SOFA.

Evaluation of Weld Defects in Stainless Steel 316L Pipe Using Guided Wave (스테인레스 316L강의 배관용접결함에 대한 유도초음파 특성 평가)

  • Lee, Jin-Kyung;Lee, Joon-Hyun
    • Journal of the Korean Society for Nondestructive Testing
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    • v.35 no.1
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    • pp.46-51
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    • 2015
  • Stainless steel is a popular structural materials for liquid-hydrogen storage containers and piping components for transporting high-temperature fluids because of its superior material properties such as high strength and high corrosion resistance at elevated temperatures. In general, tungsten inert gas (TIG) arc welding is used for bonding stainless steel. However, it is often reported that the thermal fatigue cracks or initial defects in stainless steel after welding decreases the reliability of the material. The objective of this paper is to clarify the characteristics of ultrasonic guided wave propagation in relation to a change in the initial crack length in the welding zone of stainless steel. For this purpose, three specimens with different artificial defects of 5 mm, 10 mm, and 20 mm in stainless steel welds were prepared. By considering the thickness of s stainless steel pipe, special attention was given to both the L(0,1) mode and L(0,2) mode in this study. It was clearly found that the L(0,2) mode was more sensitive to defects than the L(0,1) mode. Based on the results of the L(0,1) and L(0,2) mode analyses, the magnitude ratio of the two modes was more effective than studying each mode when evaluating defects near the welded zone of stainless steel because of its linear relationship with the length of the artificial defect.

BACTERIOLOGIC FEATURES INVESTIGAED BY ASPIRATION TECHNIQUE IN ORAL AND MAXILLOFACIAL INFECTIONS (구강악안면 감염 환자에서 흡인법을 이용하여 조사한 세균감염 양상)

  • Cho, Hyun-Young;Kim, Il-Kyu;Baek, Min-Kyu;Chang, Keum-Soo;Park, Seung-Hoon;Park, Jong-Won;Cho, Jung-Hyun
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.34 no.5
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    • pp.562-570
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    • 2008
  • Most purulent maxillofacial infections are of odontogenic origin. Treatment of infection includes the surgical intervention, such as incision and drainage, and adjunctive treatment. The use of high-dose antibiotics is also indicated. The choice of an antibiotics should be based on the knowledge of the usual causative microbes and the results of antibacterial sensitivity test. We have undertaken clinical studies on 119 patients in Dept. of Oral and Maxillofacial Surgery, Inha University Hospital from January 2000 to December 2007. Many anaerobic microbes are killed quickly when exposed to oxygen. Thus the needle aspiration techniques and the transfer under inert gas were used when culturing. The aim of this study was to obtain informations for the bacteriologic features and the effective antimicrobial therapy against maxillofaical odontogenic infections. The obtained results were as follows: 1. The most frequent causes of infections were odontogenic (88.3%), and in odontogenic cause, pulpal infections were the most common causes(53.8%). 2. The buccal and submandibular spaces (respectively 23.5%) were the most frequent involved fascial spaces, followed by masticator spaces (14.3%). 3. The most common underlying medical problems were diabetes (17.6%), however the relation with prognosis was not discovered. 4. The complications were the expiry, mediastinitis, necrotizing fasciitis, orbital abscess, and osteomyelitis. 5. The most common admission periods were 1-2 weeks, and the most patients were discharged within 3 weeks. However, patients who admitted over 5 weeks were about 10%. 6. A total of 99 bacterial strains (1.1 strains per abscess) was isolated from 93 patients (78.2%). The most common bacterium isolated was Streptococcus viridans (46.2%), followed by $\beta$-hemolytic group streptococcus (10.1%). 7. Penicillins (penicillin G 58.3%, oxacillin 80.0%, ampicillin 80.0%) have slightly lower sensitivity. Thus we recommend the antibiotics, such as glycopeptides (teicoplanin 100%, vancomycin 100%) and quinolones (ciprofloxacin 90.0%) which have high susceptibility in cases in which peni cillin therapy failed or severe infections.