• Title/Summary/Keyword: index of dispersion

Search Result 293, Processing Time 0.028 seconds

Effect of Storage Temperature on the Dispersion Stability of O/W Nano-emulsions (O/W 나노에멀젼 분산안정성에 미치는 보관온도의 영향)

  • Lee, Ye-Eun;Yoo, In-Sang
    • KSBB Journal
    • /
    • v.29 no.5
    • /
    • pp.385-391
    • /
    • 2014
  • In this study, the emulsion dispersion stability of optimizing storage temperature was investigated. The system was based on oil/water (O/W) emulsions. In order to evaluate the stability, mean diameter of droplet was measured as a function of temperature with various mixed hydrophilic lipophilic balance (HLB). In addition, the correlations between phase inversion temperature (PIT) and the optimum storage temperature were probed. In this system, majority of the smallest droplet was shown at temperature of $20^{\circ}C$ below PIT. Whether the temperature was increased or decreased from the optimum, size of the droplet increased. According to the mixed HLB, the particle size and optimum storage temperature were also affected. As the concentrations of surfactant were increased, the size of particle decreased with lower optimum temperature for storage. If the surfactant (4 wt%) were mixed with HLB, the optimum storage temperature was $21^{\circ}C$ for maintaining the size of smallest droplet at 108.3 nm in diameter. At above optimum condition, increased size of particle was observed approximately 4 % increases from 108.2 nm to 112.3 nm after 600 hours. The size of particle in emulsion was maintained stably without any considerable effect of Ostwald ripening phenomena at the optimum storage temperature with low polydispersity index.

Optimum Coagulation of Water Treatment Plant using On-line Floc Monitoring System (정수장 응집제주입 최적화를 위한 플럭 모니터링)

  • Hwang, Hwando;Lim, Sangho;Sung, Kyujong;Han, Youngjin;Kim, Youngbeom;Kwak, Jongwoon
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.23 no.4
    • /
    • pp.397-406
    • /
    • 2009
  • This study was conducted to monitor the floc sizes forming in the mixing zone in the water treatment plant. The dosing amount of poly aluminium chloride(PAC) was determined by particle dispersion analyzer(iPDA) in the lab and field scale test. During a field test period, PAC coagulant was used and the raw water was taken from Nakdong river. PAC wad diluted to activate the coagulant, leading to bring the more homogeneous dispersion in the shorter time. To monitor the floc sizes, the unit of floc size index(FSI) was used. With increasing of raw water turbidity, FSI value was increased. Also, the increased dosing amount of PAC brought the increased FSI and with overdosing of coagulant was in turn decreased. When the PAC was fed into the raw water after dilution in a field scale test, the width of FSI was narrower compared with the feeding of the mother liquor of PAC, implying that the formed flocs are denser and more uniform sizes. The width of FSI in average was varied on depending on the basicity of coagulant. Also, dF value, fractal dimension was evalued with the different coagulants, showing from 2.01 to 2.03. On-line floc monitor was effective for the optimal dosing in the drinking water plant.

Contamination of Heavy Metals in Stream Sediments in the Vicinity of the Sambo Pb-Zn-Barite Mine (삼보 연-아연-중정석 광산 주변 하상퇴적물에서의 중금속 오염 연구)

  • Kim, Sang-Hyun;Chon, Hyo-Taek
    • Economic and Environmental Geology
    • /
    • v.26 no.2
    • /
    • pp.217-226
    • /
    • 1993
  • Stream sediment samples were collected in the vicinity of the Sambo Pb-Zn-barite mine in order to investigate dispersion patterns and pollution levels of heavy metals, and to find out their mode of occurrences. Those samples were analyzed for Cd, Cu, Pb, Zn, Fe, and Mn by using partial extraction and sequential extraction methods. Stream sediments of this studied area has been contaminated severely by Pb, Zn, and Cd. Dispersion patterns of heavy metals in those sediments are different according to their pollution source and sampling distance from the mine. The stream sediment pH is generally neutral in control area, and is slightly acidic in the lower part of tailing dam. The main pollution source of stream sediments was confirmed as tailing and mine drainage. Their pollution level depends mainly on inflowed water and distance from the mine. The tolerance index ranges from -0.9 to 0.7. The mode of occurrances of heavy metals in polluted stream sediment are identified as Fe-Mn oxides, organic bounded and carbonate-bounded compound which show high potential of bioavailablity.

  • PDF

A novel proficient and sufficient intensity measure for probabilistic analysis of skewed highway bridges

  • Bayat, M.;Daneshjoo, F.;Nistico, N.
    • Structural Engineering and Mechanics
    • /
    • v.55 no.6
    • /
    • pp.1177-1202
    • /
    • 2015
  • In this paper, a new intensity measure of earthquakes for probabilistic seismic analysis is presented for skewed highway bridges. Three different cases of skewed bridges with different skew angles ($0^{\circ}$, $30^{\circ}$ and $45^{\circ}$) are considered. Well-known intensity measures (e.g., PGA, $S_a$) are evaluated and critically discussed based on sensitivity analysis: efficiency, practically, proficiency and sufficiency of intensity measures are considered in detail. The analyses demonstrated that the intensity measures have to take into account structural acceleration on a wide range of periods so that a new seismic intensity measure is proposed showing that it has less dispersion compared to others. Since the proposed intensity represents the average value of the $S_a$ (between a lower and upper structural period) it has been called Averaged Spectral Acceleration (ASA). Based on performed incremental dynamic analysis (IDA), the seismic analytical fragility curves of typical skewed highway bridges have been evaluated for different states of damage controlling the low dispersion of the ASA index as well as its proficiency and sufficiency.

Geochemical Contamination Assessment and Distribution Property Investigation of Heavy Metals, Arsenic, and Antimony Vicinity of Abandoned Mine (폐광산 인근지역에서 중금속, 비소, 안티모니의 지구화학적 오염도 평가 및 분산 특성 조사)

  • Han-Gyum Kim;Bum-Jun Kim;Myoung-Soo Ko
    • Economic and Environmental Geology
    • /
    • v.55 no.6
    • /
    • pp.717-726
    • /
    • 2022
  • This study was conducted to assess the geochemical contamination degree of As, Cd, Cu, Pb, Sb, and Zn in the soil and water samples from an abandoned gold mine. Enrichment Factor (EF), Geoaccumulation Index (Igeo), and Pollution Load Index (PLI) were carried out to assess the geochemical contamination degree of the soil samples. Variations of sulfate and heavy metals concentration in water samples were determined to identify the geochemical distribution with respect to the distance from the mine tailing dam. Geochemical pollution indices indicated significant contaminated with As, Cd, Pb, and Zn in the soil samples that areas close to the mine tailing dam, while, Sb showed similar indices in all soil samples. These results indicated that the As, Cd, Pb, and Zn dispersion has occurred via anthropogenic sources, such as mining activities. In terms of water samples, anomalies in the concentrations of As, Cd, Zn, and SO42- was determined at specific area, in addition, the concentrations of the elements gradually decreased with distance. This result implies the heavy metals distribution in water has carried out by the weathering of sulfide minerals in the mine tailing and soil. The study area has been conducted the remediation of contaminated soil in the past, however, the geochemical dispersion of heavy metals was supposed to be occurred from the potential contamination source. Therefore, continuous monitoring of the soil and water is necessary after the completion of remediation.

Distribution Analysis of TRISO-Coated Particles in Fully Ceramic Microencapsulated Fuel Composites

  • Lee, Hyeon-Geun;Kim, Daejong;Lee, Seung Jae;Park, Ji Yeon;Kim, Weon-Ju
    • Journal of the Korean Ceramic Society
    • /
    • v.55 no.4
    • /
    • pp.400-405
    • /
    • 2018
  • FCM nuclear fuel, a concept proposed as an accident tolerant fuel in light water reactors, consists of TRISO fuel particles embedded in a SiC matrix. The uniform dispersion of internal TRISO fuel particles in the FCM fuel is very important for improving the fuel efficiency. In this study, FCM sintered pellets with various volume ratios of TRISO-coated particles were prepared by hot press sintering. The distribution of TRISO-coated particles was quantitatively analyzed using X-ray ${\mu}CT$ and expressed as a dispersion uniformity index. TRISO-coated particles were most uniformly dispersed in the FCM pellets prepared using only overcoated TRISO particles without mixing of additional SiC matrix powder. FCM pellets with uniformly dispersed TRISO particle volume fraction of up to 50% were prepared using overcoated TRISO particles with varying thickness.

Preparation and Dissolution of Polyvinylpyrrolidone(PVP)-Based Solid Dispersion Systems Containing Solubilizers (가용화 조성물을 함유한 PVP형 고체분산체의 제조 및 특성)

  • Cao, Qing-Ri;Kim, Tae-Wan;Choi, Choon-Young;Kwon, Kyoung-Ae;Lee, Beom-Jin
    • Journal of Pharmaceutical Investigation
    • /
    • v.33 no.1
    • /
    • pp.7-14
    • /
    • 2003
  • The PVP-based solid dispersion systems (SDs) containing lovastatin (LOS) and solubilizers (sodium lauryl sulfate, tween 80 and oleic acid) were prepared to enhance dissolution rate of practically water insoluble LOS using solvent evaporation method. Two different organic cosolvents either acetone/ethanol or acetonitrile/ethanol were used for the preparation of SDs. The LOS contents were highly decreased when acetone/ethanol cosolvents were used. The decrease of LOS contents was not caused by acetonitrile or acetone, based on HPLC data. The surface morphology as investigated by scanning electron microscope (SEM) and angle of repose as an index of flowability of SDs were highly dependent on the type and amount of solubilizers used. Based on differential scanning calorimetry (DSC) and X-ray powder diffraction data, the SDs made crystalline LOS into amorphous structure or partially eutectic mixtures. The simultaneous use of the solubilizers in SDs was also useful to increase dissolution rate of LOS in gastric or intestinal fluid. The SDs containing solubilizers reached 76% and 60% in gastric and intestinal fluid, respectively but the commercial tablet gave only less than 4%. These solubilizers in SDs could be also applicable for enhancing dissolution and bioavailability of poorly water-soluble drugs.

Development of Customer Satisfaction Quality Indicator Considering Producer's Specification Limits (생산자규격을 고려한 소비자만족품질지표의 개발)

  • Kim, Dong-Hyuk;Chung, Young-Bae
    • Journal of Korean Society of Industrial and Systems Engineering
    • /
    • v.41 no.4
    • /
    • pp.50-58
    • /
    • 2018
  • Process Capability ($C_{pk}$) is a representative measure of how well the producer manages dispersion and bias for the specifications needed by the consumer. This is expressed as a ratio of 6 times the natural tolerance to the specification. As the producer manages the dispersion small, the capacity index becomes higher. And it is classified into 5 grades according to the degree of management. It is a measure of the quality of processes used in most industrial fields. However, $C_{pk}$ is calculated by only reflecting the mean and dispersion of the process, there is a disadvantage that it can not give information about the economic loss caused by the inconsistency of the process with the target value. Overcoming these drawbacks, process capability indexes reflecting various types of loss functions such as $C_{pm}$, $C^+_{pm}$ and $C_{pl}$ have been developed. However, all of these previous studies have applied the limit to the consumer specification, which is based on the traditional and passive quality perception that the quality characteristic should exist within the limits of the consumer specification. In this study, we will develop 'Customer Satisfaction Quality Indicator (CSQI)' which is a quantitative indicator that can be fully evaluated when the manufacturer's specification limit, which is an aggressive quality strategy, is applied. This is expected to be useful decision information for both producers and consumers.

Determination of Optical Constants of TiNx was Sputtered with RF Magnetron Sputtering Method (RF 마그네트론 스퍼터링 방법으로 증착한 TiNx 박막의 광학상수 결정)

  • Park, Myung Hee;Kim, Sang Yong;Lee, Soonil;Koh, Ken Ha
    • Journal of Korean Ophthalmic Optics Society
    • /
    • v.12 no.3
    • /
    • pp.77-81
    • /
    • 2007
  • We sputtered $TiN_x$ (titanium nitride) thin films on silicon substrates using ultra high vacuum RF magnetron sputtering method, and measured spectra of ellipsometry angles ${\Delta}$ and ${\Psi}$ in the photon-energy range of 1.5-5.0 eV using a variable angle spectroscopic ellipsometer. The optical constants, refractive index and extinction coefficient of the $TiN_x$ films were determined via the dispersion parameters extracted from the curve-fitting process based on Drude+Lorentz oscillator dispersion function. The reliability of determined optical constants were verified through the comparison of between simulated reflectance and reflectance spectra measured using a spectrophotometer.

  • PDF

Evaluation of Coagulation Characteristics of Fe(III) and Al(III) Coagulant using On-line Monitoring Technique (On-line 모니터링 기법을 이용한 Al염계와 Fe염계 응집제의 응집특성 평가)

  • Son, Hee-Jong;Yoom, Hoon-Sik;Kim, Sang-Goo;Seo, Chang-Dong;Hwang, Young-Do
    • Journal of Environmental Science International
    • /
    • v.23 no.4
    • /
    • pp.715-722
    • /
    • 2014
  • Effects of coagulation types on flocculation were investigated by using a photometric dispersion analyzer (PDA) as an on-line monitoring technique in this study. Nakdong River water were used and alum and ferric chloride were used as coagulants. The aim of this study is to compare the coagulation characteristics of alum and ferric chloride by a photometric dispersion analyzer (PDA). Floc growing rates ($R_v$) in three different water temperatures ($4^{\circ}C$, $16^{\circ}C$ and $30^{\circ}C$) and coagulants doses (0.15 mM, 0.20 mM and 0.25 mM as Al, Fe) were measured. The floc growing rate ($R_v$) by alum was 1.8~2.8 times higher than that of ferric chloride during rapid mixing period, however, for 0.15 mM~0.25 mM coagulant doses the floc growing rate ($R_v$) by ferric chloride was 1.1~2.3 times higher than that of alum in the slow mixing period at $16^{\circ}C$ water temperature. Reasonable coagulant doses of alum and ferric chloride for turbidity removal were 0.1 mM (as Al) and 0.2 mM (as Fe), respectively, and the removal efficiency of those coagulant doses showed 94% for alum and 97% for ferric chloride. The appropriate coagulant dose of alum and ferric chloride for removing dissolved organic carbon (DOC) showed about 0.3 mM (as Al, Fe) and at this dosage, DOC removal efficiencies were 36% and 44%, and ferric chloride was superior to the alum for removal of the DOC in water.