• Geophysics and Geophysical Exploration
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• v.20 no.3
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• pp.137-145
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• 2017

High-grade limestone applied to various chemical industries is abundant within upper Pungchon formation in Taebaeksan basin, South Korea. Geophysical exploration is one of the most efficient methods to investigate subsurface geological structure in an extensive area. Since the geophysical exploration for the high-grade limestone has rarely been conducted in Korea, its appropriate strategy has not been set up yet. In this study, we focused on to suggest the reasonable strategy and accumulate geophysical databases which are essential for interpreting geophysical images by characterizing laboratory physical properties of in-situ rocks. Hence, rocks were obtained from drilled cores consisting of lower Hwajeol formation, Pungchon formation, and dykes in Jeongseon area, Gangwon province. Geophysical laboratory experiments and petrography of the rocks were conducted. Since susceptibility values of the rocks in Pungchon Formation were obviously lower than those of upper Hwajeol and dykes, it is considered that the lithological boundaries could be distinguished by magnetic survey. In addition, electrical properties of the rocks in middle Pungchon formation were relatively different compared with those of upper/lower Pungchon formations. Thus, induced polarization is shown to be able to detect the high-grade limestone in upper Pungchon formation.

• The Bulletin of The Korean Astronomical Society
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• v.43 no.2
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• pp.44.4-45
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• 2018

(4179) Toutatis (Toutatis hereafter) is one of the Near-Earth Asteroids which has been studied most rigorously not only via ground-based photometric, spectroscopic, polarimetric, and radar observations, but also via the in-situ observation by the Chinese Chang'e-2 spacecraft. However, one of the most fundamental physical properties, the geometric albedo, is less determined. In order to derive the reliable geometric albedo and further study the physical condition on the surface, we made photometric observations of Toutatis near the opposition (i.e., the opposite direction from the Sun). We thus observed it for four days on 2018 April 7-13 using three 1.6-m telescopes, which consist of the Korean Microlensing Telescope Network (KMTNet). Since the asteroid has a long rotational period (5.38 and 7.40 days from Chang'e-2, Zhao et al., 2015), the continuous observations with KMTNet matches the purpose of our photometric study of the asteroid. The observed data cover the phase angle (Sun-asteroid-observer's angle) of 0.65-2.79 degree. As a result, we found that the observed data exhibited the magnitude changes with an amplitude of ~0.8 mag. We calculated the time-variable geometrical cross-section using the radar shape model (Hudson & Ostro 1995), and corrected the effect from the observed data to derive the geometric albedo. In this presentation, we will present our photometric results. In addition, we will discuss about the regolith particles size together with the polarimetric properties based on the laboratory measurements of albedo-polarization maximum.

• Polymer(Korea)
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• v.38 no.4
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• pp.510-517
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• 2014

A series of polyimide (PI) was prepared by reacting 4,4'-(hexafluoroisopropylidene)-diphthalic anhydride (6FDA) as the anhydride and bis(3-aminophenyl) sulfone (APS), bis[4-(3-aminophenoxy)-phenyl] sulfone (BAPS), 2,2-bis(4-aminophenyl)-hexafluoropropane (6FPD), 2,2-bis[4-(4-aminophenoxy)-phenyl]hexafluoropropane (6FBAPP), 2,2'-bis(trifluoromethyl)benzidine (TFDB), or 1,4-phenylenediamine (PDA) as the diamine. Residual stress behaviors were detected in-situ during thermal imidization of the polyimide precursors using a thin film stress analyzer (TFSA), and interpreted with respect to their morphology. According to the molecular orientation and packing order, the residual stress varied from 23.1 to 12.5 MPa, decreased with increasing chain rigidity. The thermal properties of the PI films were investigated using differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and thermomechanical analysis (TMA). Their optical properties were measured by ultraviolet-visible spectrophotometer (UV-vis), and spectrophotometry. The properties of PI films were found to be strongly dependent upon the morphological structure. However, trade-offs between residual stress and optical properties were identified.

• Journal of the Korean Geotechnical Society
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• v.19 no.4
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• pp.179-190
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• 2003

The grout based on solution type makes it difficult to get the improvement of ground strength and the effefct of water curtain because it has lower strength and durability than suspension type. Nowadays, the technology of particle acceleration, that enhance the material permeability, such as grout based on solution type, and inexpensive grout, is being required. For these reasons, in this study, using wet milling system, we evaluated physical properties of manufactured factors such as water-cement ratio of particles before being milled, optimum milling capacity by controlling milling time and rpm, viscosity of materials, permeation coefficient, and unconfined compressive strength. Also, using micro wet milling apparatus which could manufacture ordinary Portland cement and high speed shear mix which could forcefully separate conglomerate particles in situ, we performed electrical resistivity investigation and falling head permeability tests to analyze differences of grouting effects. From these results, we found that the permeability of the applied equipment was much superior, and in the case of using high speed shear mixer, particles of grout material were well separated.

• Journal of Pharmaceutical Investigation
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• v.17 no.4
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• pp.197-204
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• 1987

Novel pranoprofen algininate and lysinate salts were manufactured and their salt formation was confirmed by melting point, infrared spectroscopy, nuclear magnetic resornance spectroscopy, differential scanning calorimetry and powder X-ray diffractometry. The physical properties of pranoprofen lysinate and argininate salts were compared with those of pranoprofen through in vitro and in vivo tests. Solubility, $pK_a$ and lipid-water partition coefficient were measured through in vitro experiments, while antiinflammatory efficacy, analgesic effect, acute toxicity and in situ absorption were tested through in vivo experiments. The results obtained were as follows: 1) The solubilities of pranoprofen argininate and lysinate salts were increased markedly in pH 6.8 and pH 7.5 phosphate buffer solutions, comparing with that of pranoprofen itself. 2) $pK_a$ values of pranoprofen, pranoprofen argininate and lysinate salts were 6.34, 7.99 and 7.56 in carbon tetrachloride, and 5.86, 6.69 and 7.92 in chloroform, respectively by liquid-liquid partition method. 3) The lipid-water partition coefficients of pranoprofen argininate and lysinate salts were increased more than that of pranoprofen in carbon tetrachloride, chloroform, or benzene-pH 6.8 buffer system, but were nearly identical using pH 1.2 buffer as water phase. 4) Antiinflammatory effects of pranoprofen argininate and lysinate salts were remarkably increased and analgesic effects of the salts were as same as that of pranoprofen. 5) Pranoprofen argininate and lysinate salts were safer than pranoprofen itself in acute toxicity, and the in situ absorption rates of pranoprofen, pranoprofen argininate and lysinate salts were 0.392, 0.960 and $0.762\;hr^{-1}$, respectively according to the rat intestine recirculation experiment.

• Nano
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• v.13 no.12
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• pp.1850137.1-1850137.9
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• 2018

A series of silica surface-capped with hexamethyldisilazane (denoted as $H-SiO_2$) were prepared by liquid-phase in-situ surface-modification method. The as-obtained $H-SiO_2$ was incorporated into acrylic amino (AA) baking paint to obtain AA/$H-SiO_2$ composite extinction paints and/or coatings. $N_2$ adsorption-desorption tests were conducted to determine the specific surface area as well as pore size and pore volume of $H-SiO_2$. Moreover, the effects of $H-SiO_2$ matting agents on the physical properties of AA paint as well as the gloss and transmittance of AA-based composite extinction coatings were investigated. Results show that $H-SiO_2$ matting agents possess a large specific surface area and pore volume than previously reported silica obtained by liquid-phase method. Besides, they have better dispersibility in AA baking paint than the unmodified silica. Particularly, $H-SiO_2$ with a silica particle size of $6.7{\mu}m$ and the dosage of 4% (mass fraction) provides an extinction rate of 95.2% and a transmittance of 79.3% for the AA-based composite extinction coating, showing advantages over OK520, a conventional silica matting agent. Along with the increase in the silica particle size, $H-SiO_2$ matting agents cause a certain degree of increase in the viscosity of AA paint as well as a noticeable decrease in the gloss of the AA-based composite extinction coating, but they have insignificant effects on the hardness and adhesion to substrate of the AA-based composite coatings. This means that $H-SiO_2$ matting agents could be well applicable to preparing low-viscosity and low-gloss AA-based matte coatings.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.34 no.2
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• pp.529-536
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• 2014

Physical characteristics of cement-admixed clay such as water content, specific gravity, unit weight and void ratio are main factors for strength, compressibility and prediction of consolidation behavior. In the past, the physical characteristics of admixed soils could be understanded through complex laboratory tests and field survey after construction. In this study, the tests were performed with conditions such as clay water contents 0%-170%, cement contents 5%-25% and curing period 3-90days after that analyzed for changes which are water content, specific gravity unit weight and void ratio of admixed soils. A prediction of properties through mechanical relationships with clay in situ water content, cement content and curing period could be proposed using the test results. The prediction equation of void ratio of admixed soils was derived using void ratio equation in geotechnical engineering and compared with test results of bangkok clay and then this study could be verified.

• Journal of the Korean Geosynthetics Society
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• v.16 no.1
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• pp.73-83
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• 2017

Laboratory and in-situ tests were conducted to evaluate the cone factors for the layers with low plasticity containing a lot of silty and sand soils from the west coast (Incheon, Hwaseong and Gunsan areas) and its applicability was evaluated based on these results. The cone factors were evaluated from 19 to 23 based on unconfined compression strengths (qu), from 13 to 13.8 based on simple CU strengths and from 11.6 to 13.1 based on field vane strengths, respectively. The unconfined compression strengths of undisturbed silty soil samples with low plasticity were considerably underestimated due to the change of in-situ residual effective stress during sampling. Half of unconfined compression strength (qu/2) based cone factors of silty soils with low plasticity fluctuated and were approximately 1.8 times higher than simple CU based values of these soils. When evaluating cone factors of these soils, it should be judged overall on the physical properties such as the grain size distribution and soil plasticity and on the fluctuation of the corrected cone resistance and the sleeve friction due to the distribution of sandseam in the ground including pore pressure parameter.

• The Journal of Engineering Geology
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• v.26 no.4
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• pp.593-600
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• 2016

To understand the mechanical properties of rock masses and intact rock in Korea, data from 4,280 in situ and laboratory tests from 107 tunnels on general national roads were analyzed. The mechanical properties (unit weight, cohesion, friction angle, modulus of deformation, Young's modulus, Poisson's ratio, uniaxial compressive strength, tensile strength, coefficient of permeability, and specific gravity) were analyzed by rock types and strength of rock in each rock type. The results of analysis, the mean specific gravity was highest in gneiss. The coefficient of permeability and Poisson's ratio show the highest mean values in granite and metamorphic rock, respectively. In addition, the unit weight, cohesion and friction angle in sedimentary rock, modulus of deformation, Young's modulus, uniaxial compressive strength and tensile strength in volcanic rock have the highest mean values. The values for each mechanical property showed wide ranges by the heterogeneity and anisotropy of rock masses in spite of detailed analysis by rock type and classification of rocks according to the strength.

• Biomaterials Research
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• v.22 no.4
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• pp.235-248
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• 2018

Background: Injectable hydrogels have been extensively researched for the use as scaffolds or as carriers of therapeutic agents such as drugs, cells, proteins, and bioactive molecules in the treatment of diseases and cancers and the repair and regeneration of tissues. It is because they have the injectability with minimal invasiveness and usability for irregularly shaped sites, in addition to typical advantages of conventional hydrogels such as biocompatibility, permeability to oxygen and nutrient, properties similar to the characteristics of the native extracellular matrix, and porous structure allowing therapeutic agents to be loaded. Main body: In this article, recent studies of injectable hydrogel systems applicable for therapeutic agent delivery, disease/cancer therapy, and tissue engineering have reviewed in terms of the various factors physically and chemically contributing to sol-gel transition via which gels have been formed. The various factors are as follows: several different non-covalent interactions resulting in physical crosslinking (the electrostatic interactions (e.g., the ionic and hydrogen bonds), hydrophobic interactions, ${\pi}$-interactions, and van der Waals forces), in-situ chemical reactions inducing chemical crosslinking (the Diels Alder click reactions, Michael reactions, Schiff base reactions, or enzyme-or photo-mediated reactions), and external stimuli (temperatures, pHs, lights, electric/magnetic fields, ultrasounds, or biomolecular species (e.g., enzyme)). Finally, their applications with accompanying therapeutic agents and notable properties used were reviewed as well. Conclusion: Injectable hydrogels, of which network morphology and properties could be tuned, have shown to control the load and release of therapeutic agents, consequently producing significant therapeutic efficacy. Accordingly, they are believed to be successful and promising biomaterials as scaffolds and carriers of therapeutic agents for disease and cancer therapy and tissue engineering.