• Journal of Korea Foresty Energy
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• v.22 no.1
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• pp.17-23
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• 2003

Three different aged Chinese bamboo (Phyllostachys pubescense; 3, 5, and 7 years) was carbonized using three different types of kilns (special, improved and simple kiln) and their physicochemical charcoal properties were investigated. The fixed carbon of the bamboo charcoal prepared from the special kiln (800 - $1,000^{\circ}C$) tended to be decreased, while the specific surface area tended to be increased, according to the increase of bamboo ages. The bamboo charcoal prepared from the 5-year-aged showed the highest value in iodine value. In the improved kiln (600 - $700^{\circ}C$), the specific surface area and the iodine value increased with the growth period. In the simple kiln (400 - $500^{\circ}C$), the amount of volatile matter of the bamboo charcoal was approximately two times higher than that obtained from the special and improved kilns. Despite of the high amount of volatile matter in the simple kiln, the fixed carbon was more than 80%. The 5-year-aged bamboo charcoal showed the highest levels in specific surface area and iodine value. The physical properties of the bamboo charcoals prepared from the 3- and 5-year-aged Chinese bamboo were relatively worse those of Korean bamboo of the same ages. It was probably thought caused by less dense structure of the Chinese bamboo of 3- and 5-year-aged than the domestic in morphological aspects.

• Journal of the Korean Wood Science and Technology
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• v.39 no.3
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• pp.230-237
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• 2011

The study was performed to investigate the characteristics of charcoal and temperature change of a kiln's inner and outer walls in carbonization process using improved kiln. In this kiln system, carbonization process was completed in eight days. In the kiln, the ignition temperature was kept about $720^{\circ}C$. And then the temperature were increased gradually prior to be refined. Finally, the temperature in refining process was reached to maximum point, $1,000^{\circ}C$. In the chimney, the temperature was increased gradually from $90^{\circ}C$ at ignition to $750^{\circ}C$ at refining. The temperature change of the kiln wall resembles a temperature change progress curve during a carbonization process. The highest temperature of the kiln wall that appeared by a carbonization process was around $500^{\circ}C$. As a result of having measured an inner wall and the outer wall of the kiln using an infrared thermography camera, it was judged with there being considerable latent heat on kiln wall and ceiling. Fixed carbon contented of charcoal was 85.9~89.9%. Refining degree of charcoal, hardness, calorific value and pH were l, 12, 7,047~7,456 kcal/kg, 9.0~9.9, respectively. The yield of wood charcoal was 13.8%, and compared to conventional kiln's yield increased 1.5%.

• Journal of the Korean Wood Science and Technology
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• v.30 no.4
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• pp.87-95
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• 2002

Three different species of green and air-dried Korean bamboos were carbonized by using three different types of kilns designated as special (800~1000℃), improved (600~700℃) and simple kiln (400~500℃), and the bamboo vinegars obtained from the carbonization processes were characterized. In the case of the special kiln, most of the bamboo vinegars obtained at the first recovery stage showed high values of specific gravity and also in content of organic acid and water-soluble tar. The bamboo vinegars obtained from the improved kiln showed various physical properties depending on their species. In the case of simple kiln, the bamboo vinegars obtained from air-dried bamboos and at temperatures below 80℃, showed a higher specific gravity and more water-soluble tar as well as total organic components than those obtained at 80~150℃. A good linear relationship (correlation coefficient of ca. 0.90) was obtained between the specific gravities and the sum of organic acids and water-soluble tars. Therefore, this correlation coefficient might be a good index to determine the quality of bamboo vinegars. The major chemical constituents of the bamboo vinegars were acetic acid and considerable amounts of phenols: guaiacol, ethyl guaiacol, syringol, and methyl syringol.

• Journal of The Korean Society of Agricultural Engineers
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• v.52 no.2
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• pp.19-25
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• 2010

This study was conducted to determine the resilient modulus (Mr) and the unconfined compressive strength (UCS) of two recycled roadway materials such as recycled pavement material (RPM) and road surface gravel (RSG) with or without cement kiln dust (CKD). The recycled materials were blended with two CKD contents (5, 10 %) and 28 day curing time. Mr and UCS tests were also conducted after 10cycles of freezing and thawing to asses the impact of freeze-thaw cycling. Mr was determined conducting by the laboratory test method described by NCHRP 1-28A. Stabilized RPM and RSG had a modulus and a strength higher than unstabilized RPM and RSG. Mr and UCS of RPM and RSG mixed with CKD increased with increasing CKD content. The results indicated that the addition of CKD could be improved the strength and the stiffness of RPM and RSG. Therefore, RPM, RSG and CKD could be used as an effective materials in the reconstruction of roads.

• Journal of Korea Foresty Energy
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• v.21 no.2
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• pp.17-24
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• 2002

Activated carbons were prepared from pine bark by steam activation, and pore structures and specific surface areas were then investigated. Three different types of kilns were used for the activation. When the stationary-vertical-or stationary-horizontal-type kiln was used for the steam activation to prepare an activated carbon from the bark, it was not possible to produce activated carbon having high specific surface areas exceeding 1,000 $m^2／g$. Using bark powder improved the specific surface area, but it was still not high enough. When the rotary-horizontal-type kiln was used for the activation, the activated carbons prepared had high specific surface areas of more than 1,000$m^2／g$, which was similar to a commercial first-grade activated carbon. The activated carbon prepared by the rotary kiln had a wide distribution of pore size ranging from microporous to mesoporous.

• Journal of the Korean Ceramic Society
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• v.53 no.1
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• pp.13-17
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• 2016

It is highlighted that increasing the adsorbent surface area on volumetric basis is very important in providing an easy access for gas molecules. Fine particles around $3{\mu}m$ of soft-burned dolomite kiln dust (SB-DKD) were hydrated to wet slurry samples by ball mill process and then placed in a chamber to use spray dryer method. Spherical granules with particle size distribution of $50{\sim}60{\mu}m$ were prepared under the experimental condition with or without addition of a pore-forming agent. The relationship between bead size of the pore-forming agent and size of SB-DKD particles is the most significant factor in preparation of spherical granules with a high porosity. Whereas addition of smaller beads than SB-DKD resulted in almost no change in the surface porosity of spherical granules, addition of larger beads than SB-DKD contributed to obtaining of the particles with both 15 times larger average pore volume and 1 order of magnitude larger porosity. It is considered that spherical granules with improved $N_2$ gas adsorption ability may also be utilized for other atmospheric gas adsorption.

• Journal of the Korean Society of Combustion
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• v.22 no.4
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• pp.9-18
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• 2017

This paper is to suggest a simple flame model for the analysis of an internal flame of rotary kilns and to present the application cases. Reaction rates in the multi combustion stages of the selected solid fuel were calculated considering the reaction rates with the Arrhenius type equations. In addition, primary and secondary air flow arrangement were considered. As a simple application case, the combustion trends according to the different solid fuels were described. Improved operating conditions as related with the fuel characteristics were shown to be important for the stable combustion characteristics and the performance of the reactors as defined by the exit temperature of the solid materials.

• Journal of Korea Foresty Energy
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• v.21 no.2
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• pp.1-9
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• 2002

Pine bark was carbonized by using a small-scale experimental kiln and three different types of large-scale kilns (simple (400-$500^{\circ}C$), improved (600-$700^{\circ}C$) and special kiln (800-$1,000^{\circ}C$). The physical properties and pore structures of the bark charcoals prepared were analyzed. When the bark was carbonized at various temperatures ranging from 500 to $900^{\circ}C$in the presence of nitrogen, carbonization yield decreased rapidly with increasing carbonization temperature and it remained constant from 700 to $900^{\circ}C$. The carbonization yield of the bark was 16 - 18% higher than that of pine wood. The BET specific surface areas and iodine values increased with a decrease in carbonization yield. The BET specific surface areas of the bark charcoals reached about 400 -$500m^2／g$ for carbonization yield of 32-40%. The pine wood charcoal prepared at $600^{\circ}C$ for 30 min resulted in a more microporous structure, whereas the bark charcoal prepared at the same condition was more mesoporous. The carbonization yields and physical properties such as iodine values and BET specific surface areas of bark charcoals prepared by using the large-scale kilns were very similar to those of the small-scale kiln. The results indicated that the pine bark could be used as starting material to produce good quality charcoal having a large specific surface area and a high carbonization yield.

• Journal of Industrial Convergence
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• v.21 no.7
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• pp.19-27
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• 2023

As the secondary battery market expands, the process of producing laterite ore using the rotary kiln and electric furnace method is expanding worldwide. As ESG management expands, the management of air pollutants such as nitrogen oxides in exhaust gases is strengthened. The rotary kiln, one of the main facilities of the pyrometallurgy process, is a facility for drying and preliminary reduction of ore, and it generate nitrogen oxides, thus prediction of nitrogen oxide is important. In this study, LSTM for regression prediction and LightGBM for classification prediction were used to predict and then model optimization was performed using AutoML. When applying LSTM, the predicted value after 5 minutes was 0.86, MAE 5.13ppm, and after 40 minutes, the predicted value was 0.38 and MAE 10.84ppm. As a result of applying LightGBM for classification prediction, the test accuracy rose from 0.75 after 5 minutes to 0.61 after 40 minutes, to a level that can be used for actual operation, and as a result of model optimization through AutoML, the accuracy of the prediction after 5 minutes improved from 0.75 to 0.80 and from 0.61 to 0.70. Through this study, nitrogen oxide prediction values can be applied to actual operations to contribute to compliance with air pollutant emission regulations and ESG management.

• Analytical Science and Technology
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• v.18 no.4
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• pp.329-337
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• 2005

TL dating using pre-dose effect is concerned with the sensitivity increase of $110^{\circ}C$ TL peak in quartz following the pre-exposure of irradiation (pre-dose) in antiquity and heating to thermal activation temperature. Using the multiple activation (MA) method for determining an equivalent dose, the activation temperature was selected to $500^{\circ}C$ and the region of interest was selected from $85^{\circ}C$ to $105^{\circ}C$ on quartz sample from archaeological remains, roof-tile kiln. which was excavated at Chudong-Ri cultural site. It was concluded that the resultant date was determined to the age of $1725{\pm}25years$ AD (l ${\sigma}$ SD), which had more improved precision considering with e radiocarbon dates and was in good agreement with the age derived by archaeological assessment. Also it was concluded that the pre-dose dating should contribute significantly to future archaeological dating work in the range of the last 2000 years.