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Influence of Gd0.1Ce0.9O2-δ Interlayer between La0.6Sr0.4Co0.2Fe0.8O3-δ Cathode and Sc-doped Zirconia Electrolyte on the Electrochemical Performance of Solid Oxide Fuel Cells (La0.6Sr0.4Co0.2Fe0.8O3-δ 공기극과 Sc이 도핑된 지르코니아 전해질 사이에 삽입한 Gd0.1Ce0.9O2-δ 중간층이 고체산화물 연료전지의 전기화학적 성능에 미치는 영향)

  • Lim, Jinhyuk;Jung, Hwa Young;Jung, Hun-Gi;Ji, Ho-Il;Lee, Jong-Ho
    • Ceramist
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    • v.21 no.4
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    • pp.378-387
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    • 2018
  • The optimal fabrication conditions for $Gd_{0.1}Ce_{0.9}O_{2-{\delta}}$(GDC) buffer layer and $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_{3-{\delta}}$ (LSCF) cathode on 1mol% $CeO_2-10mol%\;Sc_2O_3$ stabilized $ZrO_2$ (CeScSZ) electrolyte were investigated for application of IT-SOFCs. GDC buffer layer was used in order to prevent undesired chemical reactions between LSCF and CeScSZ. These experiments were carried out with $5{\times}5cm^2$ anode supported unit cells to investigate the tendencies of electrochemical performance, Microstructure development and interface reaction between LSCF/GDC/CeScSZ along with the variations of GDC buffer layer thickness, sintering temperatures of GDC and LSCF were checked, respectively. Electrochemical performance was analyzed by DC current-voltage measurement and AC impedance spectroscopy. Microstructure and interface reaction were investigated by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). Although the interfacial reaction between these materials could not be perfectly inhibited, We found that the cell, in which $6{\mu}m$ GDC interlayer sintered at $1200^{\circ}C$ and LSCF sintered at $1000^{\circ}C$ were applied, showed good interfacial adhesions and effective suppression of Sr, thereby resulting in fairly good performance with power density of $0.71W/cm^2$ at $800^{\circ}C$ and 0.7V.

Experiment and Simulation of Acoustic Detection for the Substitute for Sunken Hazardous and Noxious Substances Using the High Frequency Active Sonar (고주파 능동소나를 이용한 저층 침적 위험유해물질 대체물질 음향 탐지 실험 및 모의)

  • Han, Dong-Gyun;Seo, Him Chan;Choi, Jee Woong;Lee, Moonjin
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.24 no.4
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    • pp.459-466
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    • 2018
  • Hazardous and Noxious Substances (HNS) are defined as substances that are likely to create a significant impact on human health and marine ecosystem when they are released into the marine environment. Recently, as the volume of HNS transported by ships increases, the rate of leakage accidents also increases. Therefore, research should be conducted to control and monitor sunken materials from the viewpoint of technology development for hazardous material leakage accident response. In this paper, acoustic detection experiments were carried out using HNS substitute materials in order to confirm the possibility of acoustic detection of sunken HNS on the sediment. The castor oil, which has a similar acoustic impedance with chloroform, is used as a substitute. 200 kHz high frequency signals were used to discriminate the reflected signals and measure reflection loss from the interface between water and castor oil. The reflection loss measured is in good agreement with the modeling results, showing a possibility of acoustic detection for sunken HNS.

A Comparative Study on the Body Composition According to the Degree of Weight Gain in the Pregnancy (임신 중 체중증가 정도에 따른 체성분 비교연구)

  • Jang, Jun-Bock;Kim, Seung-Bo;Lee, Kyung-Sub;Cho, Jung-Hoon
    • Journal of Korean Medicine for Obesity Research
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    • v.2 no.1
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    • pp.37-42
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    • 2002
  • Objectives: To compare the body composition of the postpartal female weight-gained over the recommended during pregnancy with that of normal female with same age. female diagnosed as obesity and postpartal female weight-gained within the recommended during pregnancy. Methods: From Apr. 1. 2001 to Feb. 28. 2002, there were 745 delivery in Dept. of Obstetrics & Gynecology, Kyung-Hee Medical Center. 32 mothers of them wanted to be investigated about the weight gain during their pregnancy. We excluded 12 persons who had gained within the recommended weight$(15{\beta}{\prod})$ and had diagnosed as the diseases inducing pathologic edema, preeclamsia. gestational heart or renal diseases, for example. In 2 days after delivery(nomal) or 5 days after(Caesarean section) we analysed the body composition of 20 persons. Results: 1. Compared with normal female, body weight, body mass index and body fat of the women gained over the recommended were increased and there made alternation to the increase of the percentage of body fat or the decrease of the percentage of lean body mass. 2. Compared with obese women who had same body mass index, the women gained over the recommended showed a little increase of body fluid, protein and mineral, but had a little decrease of the percentage of body fat. 3. The percentages of body fat increased with the women gained over the recommended, the women gained within the recommended and the obese women in order. This could imply the relation between the pregnancy, weight gain during pregnancy and the obesity. 4. The weights before pregnancy were same in the women gained over the recommended and the women gained within the recommended. But the weights just after delivery kept the gap happened during pregnancy between them and its main cause was the increase of body fat. Conclusions : The women gained over the recommended during pregnancy experienced the chage of body composition and its main cause was the increase of body fat. So compared with the women gained within the recommende, postpartal obesity more frequently could happen.

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Effects of ${\beta}2-Adrenergic$ Receptor Polymorphism on Obesity (베타 2-아드레날린 수용체의 유전자 변이형이 비만도에 미치는 영향)

  • Kim, Kil-Soo;Oh, Hyun-Hee;Choi, Sun-Mi;Yang, Hyun-Sung;Bae, Jung-Hwan;Yoon, Yoo-Sik
    • Journal of Korean Medicine for Obesity Research
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    • v.3 no.1
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    • pp.7-16
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    • 2003
  • Objectives : The lipolytic effects of catecholamines in adipose tissue are mediated by members of adrenergic receptors. This study was conducted to examine the effects of ${\beta}2-AR$ Gln27Glu (Q27E) polymorphism on obesity indices and risk among obesity clinic patients. Methods : 532 subjects, 38 men and 494 women, who attended a weight loss program in a local obesity clinic were analyzed. Height, weight, BMI, WHR and obesity index were measured or calculated. Body composition was measured by bio-impedance analysis. Genotype of ${\beta}2-AR$ polymorphism in codon 27 was analyzed by PCR-RFLP method. Serum concentrations of fasting glucose, total and HDL cholesterol, and triglyceride were determined by autobiochemical analyzer. Results: The Genotype distributions of ${\beta}2-AR$ gene were QQ type 81.3%, QE type 17.9% and EE type 8%. Therefore, the frequency of E allele of ${\beta}2-AR$ gene was 0.170 in the total subjects. The frequency of the ${\beta}2-AR$ variant genotype(QE+EE) was significantly higher in obese group($BMI{\geqq}25$) compared with non-obese group(p=0.027). Weight was significantly higher in variant(QE+EE) type compared with normal(QQ) type in total subjects(p=0.001), male(p=0.022) and female(p=0.013). BMI, obesity index and WHR were also significantly higher in QE+EE type. Body fat man was significantly higher in QE+EE type in total subjects(p=0.005) and female(p=0.027). When forward stepwise regression analysis was used to create a model of risk predictors of obesity($BMI{\geqq}25$), QE+EE type of ${\beta}2-AR$ gene was found to be a significant risk factor for obesity (p=0.042, ORs 1.597). Conclusions: QE+EE genotype of ${\beta}2-AR$ was associated with increased obesity indices and might be a significant risk factor for obesity.

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Electrochemical Properties of Boron-doped Cathode Materials (LiNi0.90Co0.05Ti0.05O2) for Lithium-ion Batteries (붕소가 도핑된 리튬이온전지용 양극 활물질(LiNi0.90Co0.05Ti0.05O2)의 전기화학적 특성)

  • Kim, Geun Joong;Park, Hyun Woo;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.57 no.6
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    • pp.832-840
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    • 2019
  • To improve the electrochemical performances of the cathode materials, boron-doped $LiNi_{0.90}Co_{0.05}Ti_{0.05}O_2$ were synthesized by using concentration gradient precursor. The characteristics of the prepared cathode materials were analyzed by XRD, SEM, EDS, PSA, ICP-OES and electrical conductivity measurement. The electrochemical performances were investigated by initial charge/discharge capacity, cycle stability, C-rate, cyclic voltammetry and electrochemical impedance spectroscopy. The cathode material with 0.5 mol% boron exhibited a capacity of 187 mAh/g (0.5 C) in a voltage range of 2.7~4.3 V(vs. $Li/Li^+$), and an capacity retention of 94.7% after 50 cycles. In the relatively high voltage range of 2.7~4.5 V(vs. $Li/Li^+$), it showed a high capacity of 200 mAh/g and capacity retention of 80.5% after 50 cycles.

Effect of SUS316L Bipolar Plate Corrosion on Contact Resistance and PEMFC Performance (SUS316L 분리판 부식에 의한 접촉저항 및 고분자전해질 연료전지 성능에 미치는 영향)

  • Kim, Junseob;Kim, Junbom
    • Applied Chemistry for Engineering
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    • v.32 no.6
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    • pp.664-670
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    • 2021
  • Stainless steel was applied as bipolar plate (BP) of polymer electrolyte membrane fuel cell (PEMFC) due to high mechanical strength, electrical conductivity, and good machinability. However, stainless steel was corroded and increased contact resistance resulting PEMFC performance decrease. Although the corrosion resistance could be improved by surface treatment such as noble metal coating, there is a disadvantage of cost increase. The stainless steel corrosion behavior and passive layer influence on PEMFC performance should be studied to improve durability and economics of metal bipolar plate. In this study, SUS316L bipolar plate of 25 cm2 active area was manufactured, and experiments were conducted for corrosion behavior at an anode and cathode. The influence of SUS316L BP corrosion on fuel cell performance was measured using the polarization curve, impedance, and contact resistance. The metal ion concentration in drained water was analyzed during fuel cell operation with SUS316L BP. It was confirmed that the corrosion occurs more severely at the anode than at the cathode for SUS316L BP. The contact resistance was increased due to the passivation of SUS316L during fuel cell operation, and metal ions continuously dissolved even after the passive layer formation.

A Study on 8 × 4 Dual-Polarized Array Antenna for X-Band Using LTCC-Based ME Dipole Antenna Structure (LTCC 기반 ME Dipole 안테나 구조를 활용한 X-Band 용 8 × 4 이중편파 배열안테나에 관한 연구)

  • Jung, Jae-Woong;Seo, Deokjin;Ryu, Jong-In
    • Journal of the Microelectronics and Packaging Society
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    • v.28 no.3
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    • pp.25-32
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    • 2021
  • In this paper, the Magneto-Electric(ME) dipole array antenna with dual-polarization in the X-Band is proposed and it is implemented and measured. The proposed array antenna is composed of 32 single ME dipole antenna and a Teflon PCB. 1 × 1 ME dipole antenna is implemented dual-polarization by radiating vertical polarization and horizontal polarization from two pairs of radiators. 2-port feeding structures are realized by lamination process using LTCC. And, each port independently feeds the radiator through a Γ-shaped feeding strip with isolation between ports. The Teflon PCB used in the antenna array has a 4-layer structure, and 2-port is fed through the top and bottom layers. The λg/4 transformer is applied to the transmission line of the Teflon PCB for impedance matching of the arrayed antenna and the Teflon PCB, and the optimal parameters are obtained through simulation. The measured maximum antenna gains of port 1 was 18.2 dBi, Cross-pol was 1.0 dBi. And the measured maximum antenna gains of port 1 was 18.1 dBi, Cross-pol was 3.2 dBi.

Electrochemical Performance of Graphite/Silicon/Pitch Anode Composites Bonded with Graphite Surface PVP and Silica Amine Function Group (흑연 표면의 PVP와 실리카의 아민 작용기로 결합된 흑연/실리콘/피치 음극 복합소재의 전기화학적 성능)

  • Lee, Su Hyeon;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.57 no.1
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    • pp.118-123
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    • 2019
  • In this study, the electrochemical characteristics of Graphite/Silicon/Pitch anode composites were analyzed to improve the low theoretical capacity of graphite as a lithium ion battery. The Graphite/Silica composites were synthesized by bonding silica onto polyvinylpyrrolidone coated graphite. The surface of used silica was treated with (3-Aminopropyl)triethoxysilane(APTES). Graphite/Silicon/Pitch composites were prepared by carbonization of petroleum pitch, the fabrication processes including the magnesiothermic reduction of nano silica to obtain silicon and varying the mass ratio of silica. The Graphite/Silicon/Pitch composites were analysed by XRD, SEM and XRD. Also the electrochemical performances of Graphite/Silicon/Pitch composite as the anode of lithium ion battery were investigated by constant current charge/discharge, rate performance, cyclic voltammetry and electrochemical impedance tests in the electrolyte of $LiPF_6$ dissolved in organic solvents (EC:DMC:EMC=1:1:1 vol%). The Graphite/Silicon/Pitch anode composite (silica 28.5 in weight) has better capacity (537 mAh/g). The cycle performance has an excellent capacity retention to 30th cycle of 95% and the retention rate capability of 98% in 0.1 C/0.2 C.

Unequal Power Divider based on Adjustment Electrical Length of Uniform Transmission Line (단일 전송선로의 전기적 길이 조정을 이용한 비대칭 분배기)

  • Kwon, Sang-Keun;Kim, Young
    • Journal of Advanced Navigation Technology
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    • v.22 no.6
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    • pp.642-647
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    • 2018
  • In this paper, an unequal power divider based on adjusting electrical length of uniform transmission line is presented. This divider consists of three uniform transmission lines and one isolation resistor and have the different port impedances of input and output. The feature of proposed divider can changed the power dividing ratio to adjust only electrical length of uniform transmission lines. To verify the feasibility of proposed power divider, two divider circuits are designed, one is 1:2 power dividing ratio divider with $60{\Omega}$ uniform transmission line and $40{\Omega}$ input port impedances and $45{\Omega}$ output port impedances, the performance data were measured the insertion losses of 1.7 dB/ 5.0 dB, return losses of more than -30 dB and isolation of more than -35 dB. The other is 1:4 power dividing ratio divider with $40{\Omega}$ uniform transmission line and $50{\Omega}$ input port impedances and $75{\Omega}$ output port impedances, the performance data were measured the insertion losses of 1.3 dB/ 6.8 dB, return losses of more than -12 dB and isolation of more than -19 dB. The measured performance data agreed well with the simulated results.

A experimental Feasibility of Magnetic Resonance Based Monitoring Method for Underground Environment (지하 환경 감시를 위한 자기공명 기반 모니터링 방법의 타당성 연구)

  • Ryu, Dong-Woo;Lee, Ki-Song;Kim, Eun-Hee;Yum, Byung-Woo
    • Tunnel and Underground Space
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    • v.28 no.6
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    • pp.596-608
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    • 2018
  • As urban infrastructure is aging, the possibility of accidents due to the failures or breakdowns of infrastructure increases. Especially, aging underground infrastructures like sewer pipes, waterworks, and subway have a potential to cause an urban ground sink. Urban ground sink is defined just as a local and erratic collapse occurred by underground cavity due to soil erosion or soil loss, which is separated from a sinkhole in soluble bedrock such as limestone. The conventional measurements such as differential settlement gauge, inclinometer or earth pressure gauge have a shortcoming just to provide point measurements with short coverage. Therefore, these methods are not adequate for monitoring of an erratic subsidence caused by underground cavity due to soil erosion or soil loss which occurring at unspecified time and location. Therefore, an alternative technology is required to detect a change of underground physical condition in real time. In this study, the feasibility of a novel magnetic resonance based monitoring method is investigated through laboratory tests, where the changes of path loss (S21) were measured under various testing conditions: media including air, water, and soil, resonant frequency, impedance, and distances between transmitter (TX) and receiver (RX). Theoretically, the transfer characteristic of magnetic field is known to be independent of the density of the medium. However, the results of the test showed the meaningful differences in the path loss (S21) under the different conditions of medium. And it is found that the reflection coefficient showed the more distinct differences over the testing conditions than the path loss. In particular, input reflection coefficient (S11) is more distinguishable than output reflection coefficient (S22).