• 대한기계학회논문집A
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• 제26권10호
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• pp.2165-2171
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• 2002

Poly-butylene-terephalate(PBT) can be impact-modified by blending with ABS material. The effects of compatibilizers and ABS content on the mechanical properties of PBT/ABS blend were examined in this study. EPDM-g-GMA and polycarbonate(PC) were used as a compatibilizer. As the GMA content in EPDM-g-GMA increased, the tensile strength of PBT/ABS blend increased and the impact strength decreased. With increasing the EPDM-g-GMA content in PBT/ABS blend, the tensile strength and impact strength decreased. With PC compatibilizer, the particle size of ABS in PBT/ABS blend became smaller than that of the blend without compatibilizer and the particles were more evenly dispersed in matrix. The maximum impact strength of the PBT/ABS blend was observed in the range of 20~30% ABS content.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2001년도 추계학술발표대회 논문집
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• pp.149-152
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• 2001

Poly-butylene-terephalate(PBT) can be impact modified by blending with ABS material. The effects of the type of compatibilizer and ABS content on the mechanical properties of PBT/ABS blend were examined in this study. EVA-g-GMA and three type of polycarbonates were used as the compatibilizer. As the GMA content in EVA-g-GMA was increased, the tensile strength of PBT/ABS blend increased and the impact strength of it decreased. With increasing the EVA-g-GMA content in PBT/ABS blend, the tensile strength and impact strength decreased. With PC compatibilizer, the tensile strength of PBT/ABS blend decreased as the ABS content increased. However, the maximum impact strength was observed in 20~30% ABS content range.

• 공업화학
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• 제26권2호
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• pp.173-177
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• 2015

본 연구에서는 Polycarbonate (PC)/Poly(acrylonitrile-butadiene-styrene) (ABS)의 충격강도에 대한 말레인산 무수물(maleic anhydride, MAH)이 그라프트(graft)된 ABS (ABS-g-MAH)의 영향과 graphene oxide (GO)의 첨가에 의한 영향을 고찰하였다. 상용화제로 ABS-g-MAH가 적용된 PC/ABS 블렌드(blend)와 PC/ABS/GO 복합체의 제조에는 이축압출기(twin screw extruder)를 사용하였으며 상용화제인 ABS-g-MAH는 DCP (dicumyl peroxide)를 개시제로 이축압출기에서 제조하였다. FT-IR 스펙트럼의 $1780cm^{-1}$ 근처에서 나타나는 카보닐기(C=O)의 존재 여부를 통해 ABS-g-MAH 제조를 확인하였다. ABS-g-MAH 함량별로 제조된 PC/ABS 블렌드의 열적, 유변학적, 충격특성 측정결과 5 phr을 ABS-g-MAH의 최적 함량으로 선정하였다. 상용화제를 5 phr (parts per hundred resin)로 고정하고 GO의 함량을 0.5, 1, 3, 5 phr로 변화하면서 물성변화를 고찰하였다. PC/ABS/GO 복합체의 분해온도는 증가하였고, 아이조드(Izod) 충격강도는 유사하거나 감소하였으며, ABS/GO를 이용한 복합체의 아이조드 충격강도는 소폭 증가하는 것을 TGA 분석결과와 아이조드 충격시험을 통해 확인하였다. 가공특성을 살펴보기 위해 동적유변분석기를 이용하여 복소점도(complex viscosity)를 측정한 결과, 상용화제를 포함하는 PC/ABS 블렌드의 복소점도는 증가하였으나, GO의 첨가에 의한 복소점도 변화는 크게 나타나지 않았다.

• 한국염색가공학회지
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• 제22권1호
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• pp.37-42
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• 2010

ABS/MWNT nanocomposites were prepared by using MWNT wrapped with SAN through melt compounding. Effect of wrapping of MWNT by SAN on the morphology, mechanical and electrical properties of ABS/MWNT were analyzed. It was found that SAN could wrap MWNT effectively indicated by the increased thickness after wrapping, which is presumably due to helical structure of polyacrylonitrile component in a block copolymer of SAN. MWNT was observed to be dispersed more evenly in ABS matrix by SAN wrapping, which resulted in improved tensile properties of the composites. On the other hand, there was little effect on the impact strength and electrical properties of ABS having inherently high impact strength.

• 한국산업융합학회 논문집
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• 제23권3호
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• pp.375-380
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• 2020

In this study, we tried to evaluate the mechanical properties of Polycarbonate(PC) and acrylonitrile-butadiene-styrene(ABS) plastic materials, which are frequently used as parts of home appliances and machinery, when repeated impacts were applied. A repeating impact tester for this research was designed and manufactured to apply repetitive impacts. Two types of plastic were repeatedly impacted under a constant load, and a tensile test was performed on the plastic material that was impacted. The tensile strength of PC plastic materials that received impact more than 2000 times was reduced by about 45 % and elongation was reduced by about 10 % when compared to impact free specimens. On the other hand, in ABS plastic, a reduction of tensile strength of about 20 % was observed at about 2,000 impacted specimen, but at about 20,000 repetitive impacted specimen, a tensile strength decrease of about 65 % was observed. And the elongation was reduced by 10 % due to the cyclic harding behavior of the material.

• 실천공학교육논문지
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• 제7권2호
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• pp.119-123
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• 2015

ABS 소재는 가공이 쉽고 충격과 열에 대한 내성이 강해 가전제품뿐만 아니라 자동차용 내외장재 금속 대체용으로도 많이 사용되고 있다. 이러한 특성으로 ABS의 수요가 늘어감에 따라 ABS를 이용한 가공교육도 그 중요성이 커지고 있다. 그 교육의 일환으로 전국 기능대회 및 지방 기능대회 금형 가공 부분에서 ABS 소재가 쓰이고 있다. 이때 ABS 소재를 이용한 가공에 있어서 ABS 소재를 고정하는 바이스의 힘은 가공 후 최종 형상에 영향을 미치게 된다. 하지만 가공 교육 작업 주의사항이나 지시사항 등에 이에 관한 정확한 명시가 되어있지 않은 상황이다. 따라서 이번 연구에서는 ABS 소재를 이용한 가공 교육에 있어서 교육에 사용하는 기초 형상에 대한 바이스의 고정시키는 힘이 가공 후 최종 형상에 미치는 영향을 알아보고, ABS 소재의 가공 교육 시 적합한 바이스 주의사항을 제시하고자 한다.

• Korea-Australia Rheology Journal
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• 제17권1호
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• pp.1-7
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• 2005

Acrylonitrile-Butadiene-Styrene (ABS), polycarbonate (PC) and their alloys are an important class of engineering thermoplastics that are widely used for automotive industry, computer and equipment housings. For the process of recycling mixtures of ABS and PC, it is desirable to know how sensitive the blend properties are to changes in compositions. It was for this reason that blends of virgin ABS and virgin PC at five different compositions, namely, $15\%,\;30\%,\;50\%,\;70%$ and $85\%$ by weight of ABS were prepared and characterised by rheological and mechanical measurements. Rheological properties of these blends in steady, oscillatory and transient step shear and mechanical properties, namely, tensile strength, elongation-at-break and Izod impact strength are reported. The results show that PC behaves in a relatively Newtonian manner, but ABS exhibits significant shear thinning. The ABS-rich blends show a trend that is similar to that of ABS, while PC-rich blends, namely $0\%$ and $15\%$, exhibit a nearly Newtonian behaviour. However, at a fixed shear rate or frequency, the steady shear or the dynamic viscosity varied respectively in a non-mono-tonic manner with composition. Except for $15\%$ blend, the viscosities of other blends fall into a narrow band indicating a wide-operation window of varying blend ratio. The blends exhibited a lower viscosity than either of the two pure components. The other noticeable feature was that the blends at $70\%$ and $85\%$ ABS content had a higher G' than pure ABS, indicating an enhancement of elastic effect. The tensile yield strength of the blends followed the 'rule of mixtures' showing a decreasing value with the increase of ABS content in PC. However, the elongation-at-break and the impact strength did not appear to obey this 'rule of mixtures,' which suggests that morphology of the blends also plays a significant role in determining the properties. Indeed, scanning electron micrographs of the fracture surfaces of the different blends validate this hypothesis, and the $15\%$ blend is seen to have the most distinct morphology and correspondingly different behaviour and properties.

• Elastomers and Composites
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• 제39권4호
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• pp.324-329
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• 2004

인계난연제가 함유된 Polycarbonate (PC)/Acrylonitrile-Butadiene-Styrene (ABS) 블렌드에서 사출온도가 상승될 경우 모폴로지 변화와 크레이즈 (Craze) 발생 정도 및 기계적 강도와의 상관관계에 대하여 연구하였다. 사출온도가 상승될 경우 분산상의 합체현상(Coalescence)이 나타났으며 파괴시편에서 크레이즈가 많이 발생하였음을 관찰하였다. 또한 급격한 충격강도의 저하가 발생하였다. 소량의 상용화제를 첨가한 경우 합체현상이 억제됨을 관찰하였으며 크레이즈도 많이 줄여 들었음을 관찰하였다.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2002년도 추계학술대회 논문집
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• pp.896-899
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• 2002

Microcellular foaming Process has several merits, impact strength elevation, thermal insulation, noise insulation, and raw material saving etc. This method make the glass transition temperature of polymers low, and diminish the residual stress of polymers. This characteristics of Microcellular foaming process influences the physical properties of recycled polymers. This paper describes about the impact strength change of Microcellular foamed recycled ABS.

• 폴리머
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• 제31권1호
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• pp.8-13
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• 2007

나일론 6/poly(acrylonitrile-co-butadiene-co--styrene) (ABS) 블렌드의 단점을 해결하기 위해 ABS의 고무상인 폴리부타디엔 대신 폴리(부틸 아크릴레이트)를 고무상으로 포함하고 있는 poly(acrylonitrile-co-styrene-co-acrylic rubber) (ASA)를 사용하여 새로운 나일론/ASA 블렌드를 실험하였다. 고충격성을 갖는 블렌드 제조를 위하여 상용화제로 무수 말레산을 25 wt% 포함한 poly(styrene-co-maleic anhydride) (SMA)와 이를 3 wt% 이하 포함한 poly(styrene-co-acrylonitrile-co-maleic anhydride) (SANMA)를 사용하여 블렌드를 제조하였다. 나일론/ASA 블렌드에서 상용화제의 함량에 따른 물성 변화는 나일론/ABS 블렌드와 유사한 경향을 나타내었다. 블렌드 내의 고무 함량이 20 wt% 이상일 때 안정된 물성의 고충격 블렌드가 제조되었다. 블렌드를 사출 성형 온도에서 사출 성형기 내에 체류시킨 후 제조한 시편의 충격 강도를 시험한 결과 SMA를 상용화제로 사용한 경우 충격 강도의 감소가 관찰된 반면 SANMA를 상용화제로 사용한 블렌드에서는 충격 강도의 변화가 거의 없었다.