• Journal of Welding and Joining
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• v.18 no.6
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• pp.48-54
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• 2000

The corrosion properties of Ni-Cr-W-Mo-B alloy sprayed by the high velocity oxy-fuel spraying (HVOF) was studied as a function of heat treatment by using both potentiodynamic polarization and immersion tests in the H₂SO₄ solution. The mechanical property was also evaluated by a microhardness tester. Microstructural characteristics of te as-sprayed and annealed coatings at 550, 750 and 950℃ have been analyzed by means of OM, XRD, SEM and TEM. The results showed that the corrosion resistance was improved by increasing the annealing temperature. As-sprayed coating had metastable and heterogeneous phases such as amorphous, nanocrystalline and very refined grain and precipitates, which induced a localized corrosion. The localized corrosion occurred preferentially at the unmelted particles which were composed of Ni matrix and Cr, W and Mo riched phase segregated in the boundaries. As annealing temperature was increased, the microstructure had shown some changes - reduction of porosity and s[plat boundary decomposition and crystallization of amorphous/nanocrystalline phases, grain coarsening,, formation and growth of precipitates such as {TEX}$M_{23}C_{6}${/TEX} and {TEX}$M_{7}C_{3}${/TEX}. In addition, the compositional difference between matrix and boundary phases gradually disappeared, which changed the corrosion type from localized corrosion to general corrosion and thus enhanced corrosion resistance.

• Journal of Applied Reliability
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• v.17 no.2
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• pp.122-128
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• 2017

Purpose: To investigate the corrosion inhibition effect of the natural spearmint oil extracted from Mentha Spicata plants on 304 stainless steel in different concentrations of hydrochloric acid. Method: The anti-corrosive effect has been investigated in 0.5m, 1m and 2m HCl using weight loss test and electrochemical polarization method as a function of inhibitor concentration and immersion time in strong chloride environment. The surface morphology was analysed by scanning electron microscopy (SEM). Results: The corrosion rate of steel decreased and inhibition efficiency increased with the increase in inhibitor concentration. Microscopic evaluation revealed significant corrosion in the specimens immersed in uninhibited conditions. Potentiodynamic polarization test results showed an increase in corrosion potential (Ecorr) and decrease in corrosion current (icorr) value with increasing concentration of inhibitor. Conclusions: Immersion of steel in higher concentration of inhibitor resulted in greater surface coverage value and hence lesser number of surface corrosion sites/pores were formed; thus lowering the corrosion rate.

• Journal of Surface Science and Engineering
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• v.57 no.3
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• pp.192-200
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• 2024

Cu as a heat exchanger tube is an important component in thermal fluid transfer. However, Cu tubes are exposed to stress in certain environments, leading to stress corrosion cracking (SCC). In this study, the effect of Sn addition on microstructure and corrosion characteristics was examined. The microstructural examination revealed the presence of columnar crystal and a grain refinement due to the addition of Sn. Electrochemical measurements showed that the 5 wt.% NH₃ environment was the most vulnerable environment to Cu corrosion, and the corrosion current density increased as stress increased. The immersion test exhibited the formation of Cu2O and Cu(OH)₂ corrosion product in 3.5 wt.% NaCl and 5 wt.% NH₃ environments, respectively. Results indicated that Sn addition to Cu was an important factor in improving the mechanical strength.

• Corrosion Science and Technology
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• v.9 no.2
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• pp.92-97
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• 2010

Many kinds of alternative fuels such as biodiesel, ethanol, methanol, and natural gas have been developed in order to overcome the limited deposits in fossil fuels. In some cases, the alternative fuels have been reported to cause degrade materials. The corrosion rates of metals were measured by immersion test, a kind of time consuming test because low conductivity of these fuels was not allowed to employ electrochemical tests. With twin two-electrode cell newly designed for the study, however, electrochemical impedance spectroscopy (EIS) test was successfully applied to evaluation of the corrosion resistance ($R_p$) of zinc, iron, aluminum, and its alloys in an oxidized biodiesel and gasoline/ethanol solutions and the corrosion resistance from EIS was compared with the corrosion rate from immersion test. In biodiesel, $R_p$ increased in the order of zinc, iron, and aluminum, which agreed with the corrosion resistance measured from immersion test. In addition, on aluminum showing the best corrosion resistance ($R_p$), the effect of magnesium as an alloying element was evaluated in gasoline/ethanol solutions as well as the oxidized biodiesel. $R_p$ increased with addition of magnesium in gasoline/ethanol solutions containing chloride and the oxidized biodiesel. In the mean while, in gasoline/ethanol solutions containing formic acid, Al-Mg alloy added 1% magnesium had the highest $R_p$ and the further addition of magnesium decreased $R_p$. It can be explained with the fact that the addition of more than 1% magnesium increases the passive current density of Al-Mg alloys.

• Journal of Surface Science and Engineering
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• v.51 no.6
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• pp.405-414
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• 2018

The present study investigated the adhesion and corrosion resistance of subsequent electrophoretic paint (E-paint) on "electroless" paint coated AZ31 Mg alloy, which was formed by immersion of AZ31 Mg alloy in E-painting solution. It was found that with increasing immersion time of AZ31 in E-painting solution, the amount of paint deposited by electroless process increased but it decreased the electrochemical equivalent of E-painting process and the adhesion of the subsequent E-paint layer. The E-paint on electroless paint coated AZ31 contained pores with the highest pore density and the largest pore size was obtained on the samples with electroless times of 2 and 5 minutes, respectively. Results of the salt-spray test showed an accelerated growth of blisters over the entire surface of the sample immersed for less than 5 minutes whereas blisters were observed only in the vicinity of the scratch in case of samples treated for 15 and 30 minutes. The E-paint on AZ31 with shorter electroless immersion time in E-painting solution was found to have good adhesion and better corrosion resistance.

• Proceedings of the KSME Conference
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• 2004.11a
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• pp.325-330
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• 2004

Recently, the request for the high strength of material is more and more increased in the area of industrial environment and machinery. To accomplish the high strength of materials, carbonizing treatment, nitrifying treatment, shot-peening method are representatively applied, however, shot-peening method is generally used among the surface processes. Shot peening is a cold working process used to impact Compressive residual stressed in the exposed surface layers. Benefits due to shot peening are increase in resistance to fatigue, stress corrosion cracking, fretting, galling, erosion and closing of pores. In this study, the influence of shot peening on the corrosion was investigated on spring steel immersed in 3.5% NaCl. The immersion test as performed on the two kinds of specimens. Corrsion potential, polarization curve, residual stress and etc, were investigated from experiment results. From test result the effect of shot peening on the corrosion was evaluated. The important results of the experimental study on the effects of shot peened on the environment corrosion of spring steels are as follows; In case of corrosion potential, shot peened specimen shows more activated negative direction as compared with parent mental. Surface of specimen, which is treated with the shot peened is placed as more activated state against inner base metal. It can cause t도 anti-corrosion effect on the base metal.

• Journal of the Korea Institute of Military Science and Technology
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• v.15 no.3
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• pp.315-321
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• 2012

In the study, corrosion characteristics of AZ31 magnesium alloy under various environments exposed during machining(immersion in cutting oil, 5 % cutting oil aqueous solution and distilled water & contact with dissimilar metals, SPC4 and A5052-H32) were investigated. A corrosion test was performed AZ31 magnesium alloy was immersed in each electrolyte solution after contacting with each dissimilar metals, and the results were observed by an electron microscope. In immersion tests, corrosion of AZ31 magnesium alloy showed to be in the sequence of distilled water> 5 % cutting oil aqueous solution> cutting oil> air, and in the test of contact with dissimilar metals, corrosion showed to be in the sequence of SPC4> A5052-H32> AZ31. It can be concluded that to prevent corrosion during machining, AZ31 magnesium alloy must prevent contacting water and use magnesium alloy for raw material of Jig & Fixture.

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.2
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• pp.35-42
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• 2008

The compressive residual stress due to shot peening process can increase the intrinsic fatigue strength of surface and therefore would be beneficial in reducing the probability of fatigue damage. However, it was not known that the effect of shot peening on corrosion environment. In this study, the influence of shot peening and corrosion condition on corrosion property was investigated on immersed in 3.5% NaCl, 10% $HNO_3$+3% HF, 6% $FeCl_3$. The immersion test was performed with two kind of specimens. The immersion test periods were carried out on performed 360days. Corrosion potential and weight loss were investigated from experimental results. From these results, the effect of shot peening on the corrosion characteristics was evaluated.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.38 no.1
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• pp.79-88
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• 2002

13%Cr martensitic stainless steel has been used mainly with a material for fish pre-processing machinery. However, it has not very nice cutting section because of little of the carbon content. Therefore, SUS420J2 steel that contents 0.3%C with high-strength in spite of the rust is used with a material for fish pre-processing machinery. However, studies on the corrosion characteristics of SUS420J2 steel are relatively rare. Especially, the corrosion phenomenon may cause serious degradation because the fish pre-processing machinery is exposed always to seawater environment. In this paper, the immersion corrosion test was carried out at seawater environment (pH=7.52) on SUS420J2 steel specimens that have various post-treatment conditions and its corrosion characteristics were evaluated. From test results, the specimens such as base metal, vacuum heat treatment, electrolytic polishing and tempering after quenching tend somewhat sensitive from the corrosion. In the case of vacuum heat treatment specimen of continuous immersion during 360 days, the weight loss ratio was high about seven times when compared with the different specimens. On the contrary, SUS420J2 steel specimen that has the heat treatment of tempering after quenching and the electrolytic polishing was less sensitive from the corrosion, and the weight loss ratio was very low.

• Corrosion Science and Technology
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• v.21 no.1
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• pp.41-52
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• 2022

Herein, we report polyvinyl butyral composites coatings containing various loadings of 72-h bath sonicated hexagonal boron nitride particles (5 ㎛) to enhance barrier properties of coatings. Barrier properties of coatings were determined in 3.5 wt% NaCl after different time periods of immersion via electrochemical techniques such as open circuit potential, electrochemical impedance spectroscopy, and potentiodynamic polarization test. Coatings containing sonicated hexagonal boron particles exhibited improved corrosion resistance for longer periods of immersion compared to neat coating. We also discussed effects of hexagonal boron nitride on healing properties of polyvinyl butyral. Coatings containing 1.0 wt% loading of sonicated hexagonal boron nitride showed improved long-term barrier properties than coatings with other compositions. The presence of hexagonal boron nitride also affected the healing properties of polyvinyl butyral coatings besides their barrier properties. Such improved barrier properties of composites coatings were attributed to the high aspect ratio, plate-like shape, and electrically insulated nature of the filler.