Browse > Article
http://dx.doi.org/10.14773/cst.2022.21.1.41

Evaluation of Corrosion Resistance Properties of Hexagonal Boron Nitride Based Polymer Composite Coatings for Carbon Steel in a Saline Environment  

Alabdullah, Fadhel T. (Department of Mechanical Engineering, College of Engineering, AlAsala Colleges)
Ali, C. (Department of Metallurgical and Materials Engineering, Colorado School of Mines)
Mishra, Brajendra (Mechanical Engineering, Worcester Polytechnic Institute)
Publication Information
Corrosion Science and Technology / v.21, no.1, 2022 , pp. 41-52 More about this Journal
Abstract
Herein, we report polyvinyl butyral composites coatings containing various loadings of 72-h bath sonicated hexagonal boron nitride particles (5 ㎛) to enhance barrier properties of coatings. Barrier properties of coatings were determined in 3.5 wt% NaCl after different time periods of immersion via electrochemical techniques such as open circuit potential, electrochemical impedance spectroscopy, and potentiodynamic polarization test. Coatings containing sonicated hexagonal boron particles exhibited improved corrosion resistance for longer periods of immersion compared to neat coating. We also discussed effects of hexagonal boron nitride on healing properties of polyvinyl butyral. Coatings containing 1.0 wt% loading of sonicated hexagonal boron nitride showed improved long-term barrier properties than coatings with other compositions. The presence of hexagonal boron nitride also affected the healing properties of polyvinyl butyral coatings besides their barrier properties. Such improved barrier properties of composites coatings were attributed to the high aspect ratio, plate-like shape, and electrically insulated nature of the filler.
Keywords
Coating; h-BN; EIS; OCP; Carbon steel; Polymer;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 V. Mittal, and A. U. Chaudhry, Effect of amphiphilic compatibilizers on the filler dispersion and properties of polyethylene-thermally reduced graphene nanocomposites, Journal of Applied Polymer Science, 132(35) (2015). Doi: https://doi.org/10.1002/app.42484   DOI
2 A. U. Chaudhry, V. Mittal, and B. Mishra, Nano nickel ferrite (NiFe2O4) as anti-corrosion pigment for API 5L X-80 steel: An electrochemical study in acidic and saline media, Dyes and Pigments, 118, 18 (2015). Doi: https://doi.org/10.1016/j.dyepig.2015.02.023   DOI
3 D. Asefi, M. Arami, and N. M. Mahmoodi, Effect of Chain Length Compatibility between Surfactants and Co-Surfactants on Corrosion Inhibition of Steel, ECS Transactions, 35, 1 (2011). Doi: https://doi.org/10.1149/1.3647848   DOI
4 L. Song, L. Ci, H. Lu, P. B. Sorokin, C. Jin, J. Ni, A. G. Kvashnin, D. G. Kvashnin, J. Lou, and B. I. Yakobson, Large scale growth and characterization of atomic hexagonal boron nitride layers, Nano letters, 10, 3209 (2010). Doi: https://doi.org/10.1021/nl1022139   DOI
5 Z. Lin, A. Mcnamara, Y. Liu, K.-S. Moon, and C.-P. Wong, Exfoliated hexagonal boron nitride-based polymer nanocomposite with enhanced thermal conductivity for electronic encapsulation, Composites Science and Technology, 90, 123 (2014). https://doi.org/10.1016/j.compscitech.2013.10.018   DOI
6 Y. Lin, T. V. Williams, and J. W. Connell, Soluble, exfoliated hexagonal boron nitride nanosheets, The Journal of Physical Chemistry Letters, 1, 277 (2009). Doi: https://doi.org/10.1021/jz9002108   DOI
7 A. U. Chaudhry, R. Bhola, V. Mittal, and B. Mishra, Ni0.5Zn0.5Fe2O4 as a Potential Corrosion Inhibitor for API 5L X80 Steel in Acidic Environment, International Journal of Electrochemical Science, 9, 4478 (2014). Doi: http://www.electrochemsci.org/papers/vol9/90804478.pdf
8 H. Rahman, and S. J. Zaidi, Desalination in Qatar: Present Status and Future Prospects, Civil Engineering Research Journal, 6, 555700 (2018). Doi: http://doi.org/10.19080/CERJ.2018.06.555700   DOI
9 G. E. Luckachan, and V. Mittal, Anti-corrosion behavior of layer by layer coatings of cross-linked chitosan and poly(vinyl butyral) on carbon steel, Cellulose, 22, 3275 (2015). Doi: https://doi.org/10.1007/s10570-015-0711-2   DOI
10 A. U. Chaudhry, B. Mansoor, T. Mungole, G. Ayoub, and D. P. Field, Corrosion mechanism in PVD deposited nano-scale titanium nitride thin film with intercalated titanium for protecting the surface of silicon, Electrochimica Acta, 264, 69 (2018). Doi: https://doi.org/10.1016/j.electacta.2018.01.042   DOI
11 A. Chaudhry, V. Mittal, and B. Mishra, Impedance response of nanocomposite coatings comprising of polyvinyl butyral and Haydale's plasma processed graphene, Progress in Organic Coatings, 110, 97 (2017). Doi: https://doi.org/10.1016/j.porgcoat.2017.04.032   DOI
12 A. Chaudhry, V. Mittal, and B. Mishra, Inhibition and promotion of electrochemical reactions by graphene in organic coatings, RSC Advances, 98, 80365 (2015). Doi: https://doi.org/10.1039/C5RA12988E   DOI
13 A. Chaudhry, V. Mittal, M. Hashmi, and B. Mishra, Evaluation of Ni0. 5Zn0. 5Fe2O4 nanoparticles as anti-corrosion pigment in organic coatings for carbon steel, Anti-Corrosion Methods and Materials, 64, 644 (2017). Doi: https://doi.org/10.1108/ACMM-10-2016-1725   DOI
14 A. Chaudhry, V. Mittal, and M. Hashmi, A quick review for rheological properties of polyolefin composites, Sindh University Research Journal-SURJ (Science Series), 44, 75 (2012). https://sujo-old.usindh.edu.pk/index.php/SURJ/article/view/1399
15 S. Chongdar, G. Gunasekaran, and P. Kumar, Corrosion inhibition of mild steel by aerobic biofilm, Electrochimica Acta, 50, 4655 (2005). Doi: https://doi.org/10.1016/j.electacta.2005.02.017   DOI
16 W. Wu, J. Liu, X. Li, T. Hua, X. Cong, Z. Chen, F. Ying, W. Shen, B. Lu, K. Dou, and X. Zhou, Incorporation graphene into sprayed epoxy-polyamide coating on carbon steel: corrosion resistance properties, Corrosion Engineering, Science and Technology, 53, 625 (2018). Doi: https://doi.org/10.1080/1478422X.2018.1521590   DOI
17 K. E. Spirydowicz, E. Simpson, R. A. Blanchette, A. P. Schniewind, M. K. Toutloff, and A. Murray, Alvar and Butvar: The Use of Polyvinyl Acetal Resins for the Treatment of the Wooden Artifacts from Gordion, Turkey, Journal of the American Institute for Conservation, 40, 43 (2001). Doi: https://doi.org/10.1179/019713601806113139   DOI
18 B. Mishra, A. Chaudhry, and V. Mittal, Development of Polymer-Based Composite Coatings for the Gas Exploration Industry: Polyoxometalate Doped Conducting Polymer Based Self-Healing Pigment for Polymer Coatings, Materials Science Forum, 879, 60 (2016). https://doi.org/10.4028/www.scientific.net/MSF.879.60   DOI
19 L. Jinlong, L. Tongxiang, W. Chen, and D. Limin, Surface corrosion enhancement of passive films on NiTi shape memory alloy in different solutions, Materials Science and Engineering: C, 63, 192 (2016). Doi: https://doi.org/10.1016/j.msec.2016.02.066   DOI
20 A. U. Chaudhry, B. Mishra, and V. Mittal, Graphene for Corrosion Protection, in Functional Nanomaterials and Nanotechnologies Applications for Energy and Environment, pp. 207 - 236, V. Mittal, Editor, Central West Publishing: Australia (2018).
21 Gamry, Basics of Electrochemical Impedance Spectroscopy. https://www.gamry.com/application-notes/EIS/basics-of-electrochemical-impedance-spectroscopy/
22 F. T. Alabdullah, Exfoliated hexagonal boron nitride based anti-corrosion polymer nano-composite coatings for carbon steel in a saline environment, Colorado School of Mines, Arthur Lakes Library (2018). https://hdl.handle.net/11124/172804
23 D. G. Enos, and L. L. Scribner, The potentiodynamic polarization scan, Technical Report 33, Solartron Instruments, Hampshire, UK (1997). https://www.ameteksi.com/documentations/technical-report-33
24 S. Arayachukiat, V. A. Doan, T. Murakami, S. Nobukawa, and M. Yamaguchi, Autonomic self-healing of poly(vinyl butyral), Journal of Applied Polymer Science, 132, 42008 (2015). Doi: https://doi.org/10.1002/app.42008   DOI
25 U. Khan, P. May, A. O'Neill, A. P. Bell, E. Boussac, A. Martin, J. Semple, and J. N. Coleman, Polymer reinforcement using liquid-exfoliated boron nitride nanosheets, Nanoscale, 5, 581 (2013). Doi: https://doi.org/10.1039/C2NR33049K   DOI
26 V. Mittal, A. U. Chaudhry, and M. I. Khan, Comparison of Anti-Corrosion Performance of Polyaniline Modified Ferrites, Journal of Dispersion Science and Technology, 33, 1452 (2012). Doi: https://doi.org/10.1080/01932691.2011.620827   DOI
27 X. Wang, C. Xu, Y. Chen, C. Tu, Z. Wang, and X. Song, Effects of stray AC on corrosion of 3-layer polyethylene coated X70 pipeline steel and cathodic delamination of coating with defects in 3.5 wt% NaCl solution, Corrosion Engineering, Science and Technology, 53, 214 (2018). Doi: https://doi.org/10.1080/1478422X.2018.1436736   DOI
28 AU Chaudhry, Abdel Nasser Mabrouk and Ahmed Abdala, Thermally enhanced polyolefin composites: fundamentals, progress, challenges, and prospects, 21, 737 (2020). https://doi.org/10.1080/14686996.2020.1820306   DOI
29 M. Rajabi, G. R. Rashed, and D. Zaarei, Assessment of graphene oxide/epoxy nanocomposite as corrosion resistance coating on carbon steel, Corrosion Engineering, Science and Technology, 50, 509 (2015). Doi: https://doi.org/10.1179/1743278214Y.0000000232   DOI
30 A. U. Chaudhry, V. Mittal, and B. Mishra, Impedance response of nanocomposite coatings comprising of polyvinyl butyral and Haydale's plasma processed graphene, Progress in Organic Coatings, 110, 97 (2017). Doi: https://doi.org/10.1016/j.porgcoat.2017.04.032   DOI
31 S. Radhakrishnan, C. R. Siju, D. Mahanta, S. Patil, and G. Madras, Conducting polyaniline-nano-TiO2 composites for smart corrosion resistant coatings, Electrochimica Acta, 54, 1249 (2009). Doi: https://doi.org/10.1016/j.electacta.2008.08.069   DOI
32 T. Monetta, A. Acquesta, and F. Bellucci, Graphene/epoxy coating as multifunctional material for aircraft structures, Aerospace, 2, 423 (2015). Doi: https://doi.org/10.3390/aerospace2030423   DOI
33 F. Zhou, Z. Li, G. J. Shenoy, L. Li, and H. Liu, Enhanced Room-Temperature Corrosion of Copper in the Presence of Graphene, ACS Nano, 7, 6939 (2013). Doi: https://doi.org/10.1021/nn402150t   DOI
34 L. H. Li, T. Xing, Y. Chen, and R. Jones, Boron nitride nanosheets for metal protection, Advanced materials interfaces, 1, 1300132 (2014). Doi: https://doi.org/10.1002/admi.201470047   DOI
35 ASTM-G3-89, Standard Practice for Conventions Applicable to Electrochemical Measurements in Corrosion Testing, ASTM International (2010).
36 C. A. Usman, Anti-corrosion behaviour of barrier, electrochemical and self-healing fillers in polymer coatings for carbon steel in a saline environment, Colorado School of Mines (2016). http://hdl.handle.net/11124/170102
37 ASTM-G61-86, Standard Test Method for Conducting Cyclic Potentiodynamic Polarization Measurements for Localized Corrosion Susceptibility of Iron-, Nickel-, or Cobalt-Based Alloys, ASTM International: West Conshohocken, PA (2009).