Corrosion Science and Technology

The Corrosion Science Society of Korea (한국부식방식학회)
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Evaluation of Corrosion Resistance Properties of Hexagonal Boron Nitride Based Polymer Composite Coatings for Carbon Steel in a Saline Environment

  • Alabdullah, Fadhel T. (Department of Mechanical Engineering, College of Engineering, AlAsala Colleges) ;
  • Ali, C. (Department of Metallurgical and Materials Engineering, Colorado School of Mines) ;
  • Mishra, Brajendra (Mechanical Engineering, Worcester Polytechnic Institute)
  • Received : 2021.05.27
  • Accepted : 2021.11.24
  • Published : 2022.02.28
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Abstract

Herein, we report polyvinyl butyral composites coatings containing various loadings of 72-h bath sonicated hexagonal boron nitride particles (5 ㎛) to enhance barrier properties of coatings. Barrier properties of coatings were determined in 3.5 wt% NaCl after different time periods of immersion via electrochemical techniques such as open circuit potential, electrochemical impedance spectroscopy, and potentiodynamic polarization test. Coatings containing sonicated hexagonal boron particles exhibited improved corrosion resistance for longer periods of immersion compared to neat coating. We also discussed effects of hexagonal boron nitride on healing properties of polyvinyl butyral. Coatings containing 1.0 wt% loading of sonicated hexagonal boron nitride showed improved long-term barrier properties than coatings with other compositions. The presence of hexagonal boron nitride also affected the healing properties of polyvinyl butyral coatings besides their barrier properties. Such improved barrier properties of composites coatings were attributed to the high aspect ratio, plate-like shape, and electrically insulated nature of the filler.

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References

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