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Vertical Diffusion of Ammonia Into Amorphous Ice Sturcture

  • Kim, Yeong-Sun;Mun, Ui-Seong;Gang, Heon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.280-280
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    • 2012
  • We examined ammonia diffusion on the surface of amorphous ice film through the measurement of decreasing residual quantity of $NH_3$ molecules compared to $H_2O$. The populations of $NH_3$ molecules on the surface of amorphous ice were monitored by using the techniques of temperature programmed reactive ion scattering (TPRIS) method. The ratio of intensity between ammonia and water was examined as a function of time at controlled temperature. When ammonia molecules were externally added onto an ice film at a temperature of 80 K, ammonia coverage with regard to ice was 0.12-0.16 ML. The intensity of ammonia molecules on the surface of ice decreased as time increased and the extent of decreased intensity of ammonia increased as controlled temperature increased. Moreover, energy barrier was estimated to be $51kJmol^{-1}$ on amorphous ice film. The results of the experiment indicate that ammonia molecules have a property of vertical diffusion into amorphous ice and the energy barrier of ammonia diffusion into bulk of ice is higher than that of hydrogen bonding.

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Dynamic Responses of a Slender Offshore Structure Subject to Level Ice Load (平坦氷荷重을 받는 細長形 해양구조물의 動的 거동)

  • Choi, Kyung-Sik
    • Journal of Ocean Engineering and Technology
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    • v.9 no.2
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    • pp.156-166
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    • 1995
  • Regrading the development of offshore natural gas field near Sakhalin Island which is an ice-infested area, this study aims to estimate the dynamic ice load for construction of offshore structures operating in this region. In this paper the design ice load and dynamic responses of a slender Arctic structure upon continuous ice movement are sutdied. Crushing agter a certain elastic deformation is assumed as a primary failure mechanism at the contact zone between semi-infinite level ice edge and the face of structure. Dynamic interaction forces are calculated using a modified Korzhavin's equation and a two-dimensional ice-structure interaction model is adopted. To verify the numerical model, dynamic analysis is performed for on of the Baltic Sea channel markers whose response patterns were presiously observed.

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A Study on the Speed Sea Trial on the Ice Field for Ice Breaking Research Vessel "Araon" (쇄빙연구선 "Araon"호를 활용한 빙해역 속력 시운전에 관한 연구)

  • Kim, Hyun-Soo;Lee, Chun-Ju;Jeong, Seong-Yeob;Choi, Kyung-Sik
    • Journal of the Society of Naval Architects of Korea
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    • v.48 no.5
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    • pp.421-425
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    • 2011
  • To know the speed performance of "ARAON" in Arctic ice field, the measurement of ice properties which is ice thickness & strength, snow depth and free board were performed on July 2010. The measuring method of nautical signals such as heading angle, power of engine, wind & current information etc. was described in this paper. The speed sea trials in ice were performed on the four different positions with different ice properties and engine powers because the uniform level ice is not detected in the Chukchi Sea. The test field was partially constrained ice floe with hummocks and it was superposed with small broken ice pieces each other. All of the measured ice properties were compared and evaluated according to the results of sea trial. The relations between speed, ice thickness, strength and power were summarized. Consequently according to the sea trial results, the speed of ARAON is 2.78knots at the 2.49m ice thickness with 6.55MW engine power.

Material Properties of Arctic Sea Ice during 2010 Arctic Voyage of Icebreaking Research Vessel ARAON: Part 2 - Compressive Strength, Flexural Strength, and Crystal Structures (쇄빙연구선 ARAON호를 이용한 북극해 해빙의 재료특성 (2) - 해빙의 압축강도, 굽힘강도 및 결정구조 -)

  • Kim, Dae-Hwan;Park, Young-Jin;Choi, Kyung-Sik
    • Journal of Ocean Engineering and Technology
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    • v.26 no.1
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    • pp.1-8
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    • 2012
  • To correctly estimate ice load and ice resistance for a ship's hull, it is essential to understand the material properties of sea ice during ice field trials and to use the proper experimental procedure for gathering ice strength data. The first Korean-made icebreaking research vessel (IBRV), ARAON, had her second sea ice trial in the Arctic Ocean during July and August of 2010. This paper describes the test procedures used to properly obtain sea ice strength data, which provides the basic information on the ship's performance in an ice-covered sea and can be used to estimate the correct ice load and ice resistance on the IBRV ARAON. The data gathered from three sea ice field trials during the Arctic voyage of the ARAON includes the ice compressive strength, flexural strength, and failure strain of sea ice. This paper analyzes the gathered sea ice data in comparison with data from the first voyage of the ARAON during her Antarctic Sea ice trial in January 2010.

A Study on the Strength Characteristics of Model Ice for Warm-up Time during Model Ice Preparation (모형빙 생성 시 승온 시간에 따른 모형빙의 강도 특성 연구)

  • Jeong, Seong-Yeob;Ha, Jung-Seok
    • Journal of the Society of Naval Architects of Korea
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    • v.57 no.1
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    • pp.15-22
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    • 2020
  • Understanding the strength characteristics of model ice is an important issue for model testing in an ice model basin to estimate the ship performance in ice. In particular, the mechanical properties of the model ice including elastic modulus, flexural strength and compressive strength are key consideration factors. In order to understand the characteristics of the model ice during warm-up phase at KRISO's ice model basin, the strength properties are tested in this study. The infinite plate-bending method, in-situ cantilever beam test and ex-situ uniaxial compressive test are conducted to determine the strength properties of model ice. The strength characteristics of the model ice are then analyzed in terms of the warm-up phase and seasonality. These results could be valuable to quality control of the model ice characteristics in KRISO's ice model basin and to better understand the variations in strength properties during the ice model tests.

Numerical simulation of propeller exciting force induced by milling-shape ice

  • Wang, C.;Li, X.;Chang, X.;Xiong, W.P.
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.11 no.1
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    • pp.294-306
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    • 2019
  • On the basis of the Computational Fluid Dynamics technique (CFD) combined with the overlap grid method, this paper establishes a numerical simulation method to study the problem of ice-propeller interaction in viscous flow and carries out a simulation forecast of the hydrodynamic performance of an ice-class propeller and flow characteristics when in the proximity of milling-shape ice (i.e., an ice block with a groove cut by a high-speed revolving propeller). We use a trimmed mesh in the entire calculation domain and use the overlap grid method to transfer information between the domains of propeller rotation calculation and ice-surface computing. The grid is refined in the narrow gap between the ice and propeller to ensure the accuracy of the flow field. Comparison with the results of the experiment reveals that the error of the hydrodynamic performance is within 5%. This confirms the feasibility of the calculation method. In this paper, we calculate the exciting force of the propeller, analyze the time domain of the exciting force, and obtain the curve of the frequency domain using a Fourier transform of the time-domain curve of the exciting force. The existence of milling-shape ice before the propeller can greatly disturb the wake flow field. Unlike in open water, the propeller bearing capacity shows a downward trend in three stages, and fluctuating pressure is more disordered near the ice.

Influence of Control Pressure and Concentration of Water Solution at Continuous Ice Making in a Tube (제어압력 및 수용액의 농도가 관내 연속제빙에 미치는 영향)

  • ;;Hideo Inaba;Akihiko Horibe;Naoto haruki;Hidetoshi Miura
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.12
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    • pp.1236-1244
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    • 2001
  • In the present study, the possibility of continuous slurry ice making using flowing water solution in a cooled tube has been investigated. The experiments were carried out at various concentration and velocity of water solution, temperature of cooled tube wall, and control pressure in a tube. As a result, four types of operating conditions, that is super-cooling, continuous ice making, intermittent ice making and ice blockage, were classified. And it was found that the critical condition for the continuous ice making was acquired as a function of these experimental parameters.

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Melting Heat Transfer of Liquid Ice in a Rectangular Vessel with Heated Top Wall (구형용기내 상부면가열에 의한 유동빙의 융해열전달)

  • 김명환;김경근
    • Journal of Advanced Marine Engineering and Technology
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    • v.19 no.1
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    • pp.36-44
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    • 1995
  • Melting characteristics of unrestrained liquid ice in a rectangular vessel with heated top wall were investigated experimentally. The liquid ice, a mixture of ice particles and ethylene-glycol aqueous solution, was adopted as a testing material. During the melting process the liquid ice was drawn by buoyancy to the heated top wall of the rectangular vessel where close-contact melting occured. The melting behavior and melting rate of the liquid ice as well as local/mean heat-transfer coefficient at the heated top wall were observed and measured under a variety of conditions of heat flux and various initial concentration of the aqueous binary solution. It was found that the heat transfer of the heated top wall is remarkably promoted by the close-contact melting, and that the dendritic frozen layer at the lower interface of the liquid ice is formed. Photographic evidence demonstrated that plumes containing solute-rich liquid issued from isolated chimneys within the liquid ice layer where segregation of interstitial channel took place.

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Dynamic ice force estimation on a conical structure by discrete element method

  • Jang, HaKun;Kim, MooHyun
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.13 no.1
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    • pp.136-146
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    • 2021
  • This paper aims to numerically estimate the dynamic ice load on a conical structure. The Discrete Element Method (DEM) is employed to model the level ice as the assembly of numerous spherical particles. To mimic the realistic fracture mechanism of ice, the parallel bonding method is introduced. Cases with four different ice drifting velocities are considered in time domain. For validation, the statistics of time-varying ice forces and their frequencies obtained by numerical simulations are extensively compared against the physical model-test results. Ice properties are directly adopted from the targeted experimental test set up. The additional parameters for DEM simulations are systematically determined by a numerical three-point bending test. The findings reveal that the numerical simulation estimates the dynamic ice force in a reasonably acceptable range and its results agree well with experimental data.

Fermentation Characteristics of Ice Wines Prepared with Freeze-dried Muscat Bailey A Grapes (동결건조 Muscat Bailey A 포도로 만든 아이스와인의 발효 특성)

  • Jeon, Eun-Jeong;Kim, Jae-Sik
    • Korean Journal of Food Science and Technology
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    • v.46 no.2
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    • pp.173-179
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    • 2014
  • The fermentation characteristics of ice wines made from freeze-dried Muscat Bailey A grapes were determined. Muscat Bailey A grapes were concentrated to 34.8 and $40.8^{\circ}Bx$ by freeze drying and were then fermented. The content of reducing sugar was 0.3% in conventional wine after fermentation, but was 21.5 and 23.9% in ice wines at 34 and $40^{\circ}Bx$, respectively. The content of alcohol was 9.6% in conventional wine but was 10.3 and 10.6% in ice wines at 34 and $40^{\circ}Bx$, respectively. It was observed that the red and violet colors of ice wines at 34 and $40^{\circ}Bx$ became dominant compared to the controls. In sensory evaluation studies, ice wines at 34 and $40^{\circ}Bx$ showed higher intensities in color, flavor, and overall preference.