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Fabrication and Electrical Characteristics of Ferredoxin Self-Assembled Layer for Biomolecular Electronic Device Application

  • NAM YUN SUK;CHOI JEONG-WOO
    • Journal of Microbiology and Biotechnology
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    • v.16 no.1
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    • pp.15-19
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    • 2006
  • A ferredoxin adsorbed hetero self-assembled layer was fabricated on chemically modified Au substrate, 4-Aminothiophenol (4-ATP) was deposited onto Au substrate and then N-succinimidyl-3-[2-pyridyldithio] propionate (SPDP) was adsorbed on the 4-ATP layer, since SPDP was used as a bridging molecule for ferredoxin adsorption, Ferredoxin/SPDP/4-ATP structured hetero layer was constructed because of strong chemical binding of ferredoxin, SPDP, and 4-ATP, The surface of the ferredoxin-adsorbed SPDP/4-ATP layer was observed by scanning tunneling microscopy, The hetero film formation was verified by surface plasmon resonance measurement. The current flow and rectifying property based on the scanning tunneling spectroscopy I-V characteristics was achieved in the proposed hetero layer. Thus, the hetero layer structure of ferredoxin functioned as a molecular diode with rectifying property, The proposed molecular diode can be usefully applied for the development of molecular scale electronic devices.

Seepage Characteristics of Embankment as with/without Gravel Layer under the Earth Fill (성토층 하부의 자갈층 유·무에 따른 침투특성 변화)

  • Lee Haeng Woo;Chang Pyoung Wuck;Chang Woong Hee;Kim See-Woon
    • Journal of The Korean Society of Agricultural Engineers
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    • v.47 no.4
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    • pp.53-61
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    • 2005
  • A series of laboratory tests was carried out fur analyzing of seepage characteristics of two-layers embankment model which consists of gravel and earth fill layers. Gravel layers were built under the earth fill for a half and one-third width of earth fill of the model. Permeability of earth fill was ranged between $5.00\times10^{-5}\~3.00\times10^{-4}\;m/s$.. The tests were performed with hydraulic gradients(i), $0.10\~0.55$. From the test results, hydraulic head of earth fill with gravel layer was 1.6 times higher than that of earth fill without gravel layer. Seepage rate was increased up to $4\~22$ times and safety factor for piping was decreased to $13\~43\;\%$ comparing the earth fill with gravel layer to that without gravel layer. The gravel layer under the earth fill could, in general, give some serious seepage problems to seadike embankment.

Comparison of Filtration Resistances according to Membrane Cleaning Methods (막표면의 케이크층 세정 방법에 따른 여과 저항값 비교)

  • Han, Song-Hee;Chang, In-Soung
    • Journal of Environmental Science International
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    • v.25 no.6
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    • pp.817-827
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    • 2016
  • The resistance in series model has been frequently used for determination of various filtration resistance to correctly understand the membrane fouling behaviour in MBR (membrane bio-reactor) for wastewater treatment. The cake layer resistance ($R_c$) which is commonly determined by calculation of flux dataset that are obtained empirically before and after removing the cake layer on membrane surface. However, the calculated Rc values are very dependent on the cleaning methods adapted for removal of cake layer. This study investigated how the various cleaning options affect $R_c$. Seven different cleaning methods were employed: i) ultrasonication (100 W, 10 min), ii) ultrasonication (200 W, 60 min), iii) ultrasonication (400 W, 120 min), iv) water rinsing in a shaker (100 rpm, 10 min), v) water rinsing in a shaker (300 rpm, 60 min), vi) water rinsing, vii) sponge scrubbing. For the hydrophilic PES membrane, the cake layer removal efficiencies ranged from 64% to 10%, indicating that the removal of cake layer was highly dependent on the cleaning options. For the hydrophobic PVDF membrane, the cake layer removal efficiencies ranged from 79% to 97%. Consequently, a standardized method for cake layer removal to determine cake resistance ($R_c$) is needed for correct interpretation of the fouling phenomena.

Separation of Low Molecular Weight of Dye from Aqueous Solution Using the Prepared Nano-composite Hollow Fiber Membranes (중공사형 나노복합막 제조를 이용한 수용액으로부터 저분자량의 염료 분리 연구)

  • Park, Cheol Oh;Lee, Sung Jae;Rhim, Ji Won
    • Membrane Journal
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    • v.28 no.3
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    • pp.180-186
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    • 2018
  • The nano-composite membranes were prepared onto the polyvinylidene fluoride (PVDF) hollow fiber membranes through twice dip-coating known layer-by-layer method. For the first coating, poly(vinylsulfonic acid, sodium salt)(PVSA) and Poly(styrene sulfonic acid)(PSSA) were used with varying the concentration and ionic strength (IS) and the poly(ethyleneimine)(PEI) as the second coating material was fixed at 10,000 ppm and IS = 0.3. To characterize the prepared nano-composite membranes, the permeabilities and rejection ratio were measured for each 100 ppm NaCl, $CaSO_4$, $MgCl_2$, and 25 ppm MO aqueous solution. The rejections were increased as the concentrations of coating materials increased. And it was confirmed that the salt rejections for PSSA as the coating material were higher than for PVSA. Typically, the permeability, 1.848 LMH and the rejection for MO 76.3% were obtained at the coating conditions of PSSA 30,000 ppm and I.S = 1.0.

The Planting Models of Carpinus turczaninowii Community by the Plant Community Structure Analysis in Badahyanggi Arboretum - Case Study of Daebu-Yeongheung Islands - (군집구조분석을 통한 바다향기수목원 소사나무림 식재모델 연구 - 대부도 및 영흥도를 대상으로 -)

  • Kim, Yong-Hoon;Kwon, Oh-Jung;Ban, Su-Hong;Oh, Choong-Hyeon
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.23 no.4
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    • pp.31-45
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    • 2020
  • This study suggested the planting models of Carpinus turczaninowii community to make in Badahyanggi Arboretum and was carried out to the structure of C. turczaninowii commnity in Daebu-Yeongheung Islands. In order to identify the current ecological environment, this study set to 13 plots(i.e. 100㎡) for analysing detailed structure of plant communities. The research methodology was qualitative analysis. It used TWINSPAN, PCA and Indicator Species Analysis tools which are performed well in several comparisons of classification techniques and one of the ordination techniques showed that the plant communities. The results were classified into 3 communities that C. turczaninowii-Pinus densiflora community(I), C. turczaninowii-Quercus serrata community(II) and C. turczaninowii-Platycarya strobilacea community(III). In all of communities, C. turczaninowii was dominant species in canopy layer and understory layer, the degree of closure was high. Proposed the planting models that are I~II communities based on planting status in Badahyanggi Arboretum(Island Plant Botanical Garden), the structure of plant communities, indicator species and individual distribution by DBH classes. Also, The multi-layer planting plans are necessary, such as P. strobilacea, Lindera erythrocarpa, Viburnum carlesii, V. dilatatum, Ligustrum obtusifolium, Zanthoxylum schinifolium and so on.

Bonding effects of cleaning protocols and time-point of acid etching on dentin impregnated with endodontic sealer

  • Tatiane Miranda Manzoli;Joissi Ferrari Zaniboni;Joao Felipe Besegato;Flavia Angelica Guiotti;Andrea Abi Rached Dantas;Milton Carlos Kuga
    • Restorative Dentistry and Endodontics
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    • v.47 no.2
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    • pp.21.1-21.11
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    • 2022
  • Objectives: This study aimed to investigate the bonding effects of cleaning protocols on dentin impregnated with endodontic sealer residues using ethanol (E) or xylol (X). The effects of dentin acid etching immediately (I) or 7 days (P) after cleaning were also evaluated. For bonding to dentin, universal adhesive (Scotchbond Universal; 3M ESPE) was used. The persistence of sealer residues, hybrid layer formation and microshear bond strength were the performed analysis. Materials and Methods: One hundred and twenty bovine dentin specimens were allocated into 4 groups (n = 10): G1 (E+I); G2 (X+I); G3 (E+P); and G4 (X+P). The persistence of sealer residues was evaluated by SEM. Confocal laser scanning microscopy images were taken to measure the formed hybrid layer using the Image J program. For microshear bond strength, 4 resin composite cylinders were placed over the dentin after the cleaning protocols. ANOVA followed by Tukey test and Kruskal-Wallis followed by Dunn test were used for parametric and non-parametric data, respectively (α = 5%). Results: G2 and G4 groups showed a lower persistence of residues (p < 0.05) and thicker hybrid layer than the other groups (p < 0.05). No bond strength differences among all groups were observed (p > 0.05). Conclusions: Dentin cleaning using xylol, regardless of the time-point of acid etching, provided lower persistence of residues over the surface and thicker hybrid layer. However, the bond strength of the universal adhesive system in etch-and-rinse strategy was not influenced by the cleaning protocols or time-point of acid etching.

New Diffuser Film Using Coating Technology for LCD Backlight

  • Hwang, Hee-Nam;Choi, Woong-Hyun;Lee, Ki-Ho;Kim, In-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1066-1067
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    • 2004
  • New diffuser film for LCD backlight is developed. A diffuser film was manufactured through coating UV curable monomer on a plastic film. The diffuser layer coated on plastic film showed excellent optical transmittance.

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Interface Control to get Higher Efficiency in a-Si:H Solar Cell

  • Han, Seung-Hee;Kim, En-Kyeom;Park, Won-Woong;Moon, Sun-Woo;Kim, Kyung-Hun;Kim, Sung-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.193-193
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    • 2012
  • In thin film silicon solar cells, p-i-n structure is adopted instead of p/n junction structure as in wafer-based Si solar cells. PECVD is the most widely used thin film deposition process for a-Si:H or ${\mu}c$-Si:H solar cells. Single-chamber PECVD system for a-Si:H solar cell manufacturing has the advantage of lower initial investment and maintenance cost for the equipment. However, in single-chamber PECVD system, doped and intrinsic layers are deposited in one plasma chamber, which inevitably impedes sharp dopant profiles at the interfaces due to the contamination from previous deposition process. The cross-contamination between layers is a serious drawback of single-chamber PECVD system. In this study, a new plasma process to solve the cross-contamination problem in a single-chamber PECVD system was suggested. In order to remove the deposited B inside of the plasma chamber during p-layer deposition, a high RF power was applied right after p-layer deposition with SiH4 gas off, which is then followed by i-layer, n-layer, and Ag top-electrode deposition without vacuum break. In addition to the p-i interface control, various interface control techniques such as FTO-glass pre-annealing in O2 environment to further reduce sheet resistance of FTO-glass, thin layer of TiO2 deposition to prevent H2 plasma reduction of FTO layer, and hydrogen plasma treatment prior to n-layer deposition, etc. were developed. The best initial solar cell efficiency using single-chamber PECVD system of 10.5% for test cell area of 0.2 $cm^2$ could be achieved by adopting various interface control methods.

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Fabrication of [320×256]-FPA Infrared Thermographic Module Based on [InAs/GaSb] Strained-Layer Superlattice ([InAs/GaSb] 응력 초격자에 기초한 [320×256]-FPA 적외선 열영상 모듈 제작)

  • Lee, S.J.;Noh, S.K.;Bae, S.H.;Jung, H.
    • Journal of the Korean Vacuum Society
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    • v.20 no.1
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    • pp.22-29
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    • 2011
  • An infrared thermographic imaging module of [$320{\times}256$] focal-plane array (FPA) based on [InAs/GaSb] strained-layer superlattice (SLS) was fabricated, and its images were demonstrated. The p-i-n device consisted of an active layer (i) of 300-period [13/7]-ML [InAs/GaSb]-SLS and a pair of p/n-electrodes of (60/115)-period [InAs:(Be/Si)/GaSb]-SLS. FTIR photoresponse spectra taken from a test device revealed that the peak wavelength (${\lambda}_p$) and the cutoff wavelength (${\lambda}_{co}$) were approximately $3.1/2.7{\mu}m$ and $3.8{\mu}m$, respectively, and it was confirmed that the device was operated up to a temperature of 180 K. The $30/24-{\mu}m$ design rule was applied to single pixel pitch/mesa, and a standard photolithography was introduced for [$320{\times}256$]-FPA fabrication. An FPA-ROIC thermographic module was accomplished by using a $18/10-{\mu}m$ In-bump/UBM process and a flip-chip bonding technique, and the thermographic image was demonstrated by utilizing a mid-infrared camera and an image processor.