• Title/Summary/Keyword: hysteresis cycles

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Effect of K/Na ratio on Piezoelectric Properties of Modified-$(K_{1-x}Na_x)NbO_3$ "Hard" Lead-free Materials

  • Im, Jong-Bong;Jeon, Jae-Ho
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.50.1-50.1
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    • 2011
  • Lead-free ceramics with a composition of 0.55 mol%$K_4CuNb_8O_23-(K_{1-x}Na_x)NbO_3$ (KCN-KNNx) where $0.45{\leq}x{\leq}0.60$ were synthesized by conventional ceramic processing. Results revealed that the addition of Na was effective in changing the microstructure and relative density of KCN-KNNx. Further, the addition of Na resulted in a slight shift of the phase transition temperatures (To-t and Tc) toward low values. A high mechanical quality factor (Qm) of 1850 was found atx=0.54, which might be due to the build-up of an internal bias field (Ei) within KCN. Thermal hysteresis in KNNx was confirmed with an increase in the Na content during the heating and cooling cycles, resulting from structural changes. Thus, KCN-KNNx with x=0.54 exhibits excellent piezoelectric properties with d33 (97 pC/N), kp (36%), and Qm (1850), being promising candidates for application in high-power piezoelectric devices.

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Evaluation of Hydrogenation Properties on Ti-Cr-Nb Alloys Manufactured by Arc Melting (아크용해법에 의한 Ti-Cr-Nb합금의 제조와 수소와 특성 평가)

  • Lee, Young-Geun;Hong, Tae-Whan
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.6
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    • pp.482-489
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    • 2008
  • Ti-Cr alloys consist of BCC solid solution, C36, C14 and C15 Laves phase at high temperature. Among others, the BCC solid solution phase was reported to have a high hydrogen storage capacity. However, activation, wide range of hysteresis at hydrogenation/dehydrogenation, and degradation of hydrogen capacity due to hydriding/dehydriding cycles must be improved for its application. In this study, to improve such problems, we added a Nb. For attaining target materials, Ti-10Cr-xNb(x=1, 3, 5wt.%) specimens were prepared by arc melting. The arc melting process was carried out under argon atmosphere. As-received specimens were characterized using XRD(X-ray diffraction), SEM(Scanning Electron Microscopy) with EDX(Energy Dispersive X-ray) and TG/DSC(Thermo Gravimetric Analysis/Differential Scanning Calorimetry). In order to examine hydrogenation behavior, the PCI(pressure-Composition-Isotherm) was performed at 293, 323, 373 and 423K.

Properties of $Sr_{0.8}Bi_{2.3}{(Ta_{1-x}Nb_{x})}_{2}O_{9+{\alpha}}$ Thin Films

  • Park, Sang-Jun;Jang, Gun-Eik
    • Transactions on Electrical and Electronic Materials
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    • v.1 no.1
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    • pp.22-25
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    • 2000
  • Polycrystalline SBTN layered ferroelectric thin film with various Nb mole ratios were prepared by sol-gel method Pt/ $SiO_2$/Si (100) substrates. The films were annealed at different temperature and characterized in terms of phase and microstructure. The films were crystallized with a high (105) diffraction intensity and had rodike structure, SBTN films fired at 800$^{circ}C$ revealed standard hysteresis loops with no fatigue for up to 10$^{10}$ cycles. At an applied voltage of 5V the dielectric constant($varepsilon$) , dissipation factor (tan $delta$), remanent polarization(ZPr) and coercive field(Ec) of typical S $r_{0.8}$B $i_{2.3}$(T $a_{1-x}$ N $b_{x}$) $O_{9+}$$alpha$/ thin film(x=0.1) prepared on Pt/ $SiO_2$/Si (100) were about 277.7, 0.042, 3.74$mu$C/$textrm{cm}^2$, and 24.8kv/cm respectively.ly.y. respectively.ly.y.y..

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Torque Ripple Minimization of BLDC Motor Including Flux-Weakening Region (약계자영역을 포함한 BLDC 전동기의 새로운 토크 리플 최소화 방법)

  • 원태현;박한웅;이만형
    • Journal of Institute of Control, Robotics and Systems
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    • v.8 no.6
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    • pp.445-454
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    • 2002
  • Torque ripple control of brushless DC motors has been the persisting issue of the servo drive systems in which the speed fluctuation, vibration and acoustic noise should be minimized. In this paper, a novel approach to achieve the ripple-free torque control with maximum efficiency based on the d-q reference frame is presented and analyzed. The proposed approach can provide the optimized phase current waveforms over wide speed range incorporating cogging torque compensation without an access to the neutral point of the motor windings. Moreover, the undesirable errors caused by the assumptions such as 3 phase balance or symmetry of the phase back EMF between electrical cycles, which are related with the manufacturing imperfections, can be also eliminated. As a result, the proposed approach provides a simple and clear way to obtain the optimal motor excitation currents. A hysteresis current control system is employed to produce high-frequency electromagnetic torque ripples for compensation. The validity and applicability of the proposed control scheme to real situations are verified through the simulations and experimental results.

Nonvolatile Flexible Bistable Organic Memory (BOM) Device with Au nanoparticles (NPs) embedded in a Conducting poly N-vinylcarbazole (PVK) Colloids Hybrid

  • Son, Dong-Ick;Kwon, Byoung-Wook;Park, Dong-Hee;Yang, Jeong-Do;Choi, Won-Kook
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.440-440
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    • 2011
  • We report on the non-volatile memory characteristics of a bistable organic memory (BOM) device with Au nanoparticles (NPs) embedded in a conducting poly N-vinylcarbazole (PVK) colloids hybrid layer deposited on flexible polyethylene terephthalate (PET) substrates. Transmission electron microscopy (TEM) images show the Au nanoparticles distributed isotropically around the surface of a PVK colloid. The average induced charge on Au nanoparticles, estimated using the C-V hysteresis curve, was large, as much as 5 holes/NP at a sweeping voltage of ${\pm}3$ V. The maximum ON/OFF ratio of the current bistability in the BOM devices was as large as $1{\times}105$. The cycling endurance tests of the ON/OFF switching exhibited a high endurance of above $1.5{\times}105$ cycles and a high ON/OFF ratio of ~105 could be achieved consistently even after quite a long retention time of more than $1{\times}106$ s.

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A Study on the Cycling Effects and the Hydrogen Absorption-Desorption Characteristics Of Metal Hydrides (DiNi5-H2 system) (금속수소화물(DiNi5-H2 system)의 수소 흡수-방출 특성과 반복 효과에 관한 연구)

  • Kim, Youn-Sang;Zhoh, Choon-Koo
    • Applied Chemistry for Engineering
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    • v.1 no.1
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    • pp.30-34
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    • 1990
  • This paper summarizes fundamental research on a metal hydrides for the development of new energy. We made a study of the characteristics of the hydrogen absorption-desorption of $DiNi_5$ alloys. As a result, we found that the maximum amount of the hydrogen absorption of $DiNi_5$ alloys (the maximum in the absorption equilibrium pressure section) was H/M=1.04 at $30^{\circ}C$. The hysteresis was the smallest at $30^{\circ}C$. The capability of the hydrogen absorption-desorption was excellent. The number of cycles of the hydrogen absorption-desorption was about 9000 times at $30^{\circ}C$. We found also that the rate of the hydrogen desorption was the largest at $40^{\circ}C$.

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Retention and Fatigue Properties of MFS Devices using Ferroelectric $LiMbO_3$ Thin Films ($LiMbO_3$ 강유전체 박막을 이용한 MFS 디바이스의 Retention 및 Fatigue 특성)

  • 정순원;김채규;김용성;김진규;이남열;김광호;유병곤;이원재
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.17-20
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    • 1999
  • The retention and fatigue properties of ferroelectric LiNbO$_3$ thin films were studied. Metal-ferroelectric-semiconductor(MFS) devices by using rapid thermal annealed LiNbO$_3$/Si structures were successfully fabricated and demonstrated nonvolatile memory operations of the MFS devices. The I$_{D}$-V$_{G}$ characteristics of MFSFET\`s showed a hysteresis loop due to the ferroelectric nature of the LiNbO$_3$ thin film. The ferroelectric capacitors showed practically no polarization degradation up to about 10$^{10}$ switching cycles when subjected to symmetric bipolar voltage pulse (peak-to-peak 6V, 50% duty cycle) in the 500kHz. The retention properties of the LiNbO$_3$ thin films were quite good up to about 10$^{3}$ s . s .

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Ferroelectric Properties of PZT Thin Films by RF-Magnetron sputtering (RF 마그네트론 스퍼터링 법을 이용한 PZT 박막의 강유전 특성)

  • Park, Young;Joo, Pil-Yeoun;Yi, Ju-Sin;Song, Jun-Tae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.341-344
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    • 1999
  • The effects of post annealing treatments of ferroelectrlclty in PZT(P $b_{1.05}$(Z $r_{0.52}$, $Ti_{0.48}$) $O_3$ thin film deposited on Pt/ $SiO_2$/Si substrate by RF-Magnetron sputtering methode was Investigated. Analyses by RTA(Rapid Thermal Annealing) treatments reveled that the crystallization process strongly depend on the healing temperature. The Perovskite structure with strong PZT (101) plan was obtained by RTA treatments at 75$0^{\circ}C$ With increasing RTA temperature of PZI thin films, the coercive field and remanent Polarization decreased, while saturation polarization( $P_{r}$) was decreased. P-E curves of Pt/PZT/Pt capacitor structures demonstrate typical hysteresiss loops. The measure values of $P_{r}$,. $E_{c}$ and dielectric constants by post annealed at 75$0^{\circ}C$ were 38 $\mu$C/$\textrm{cm}^2$ 35KV/cm and 974, respectively. Switching polarization versus fatigue characteristic showed 12% degradation up to 10$^{7}$ cycles.s.s.s.s.s.s.

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Application of frictional sliding fuse in infilled frames, fuse adjustment and influencing parameters

  • Mohammadi-Gh, M.;Akrami, V.
    • Structural Engineering and Mechanics
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    • v.36 no.6
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    • pp.715-727
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    • 2010
  • An experimental investigation is conducted here to study the effects of applying frictional sliding fuses (FSF) in concrete infilled steel frames. Firstly, the influences of some parameters on the behavior of the sliding fuse are studied: Methods of adjusting the FSF for a certain sliding strength are explained and influences of time duration, welding and corrosion are investigated as well. Based on the results, time duration does not significantly affect the FSF, however influences of welding and corrosion of the constitutive plates are substantial. Then, the results of testing two 1/3 scale single-storey single-bay concrete infilled steel frames having FSF are presented. The specimens were similar, except for different regulations of their fuses, tested by displacement controlled cyclic loading. The results demonstrate that applying FSF improves infill behaviors in both perpendicular directions. The infilled frames with FSF have more appropriate hysteresis cycles, higher ductility, much lower deteriorations in strength and stiffness in comparison with regular ones. Consequently, the infills, provided with FSF, can be regarded as an engineered element, however, special consideration should be taken into the affecting parameters of their fuses.

Electric properties of Polymethyl methacrylate(PMMA) Films to thermal treatment Prepared by Spin Coating (회전 도포 공정을 이용한 Polymethyl methacrylate(PMMA) 박막의 열처리에 따른 전기적 특성 평가)

  • Na, Moon-Kyong;Kang, Dong-Pil;Ahn, Myeog-Sang;Myung, In-Hye;Kang, Young-Taec
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.1924-1926
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    • 2005
  • Poly(methyl methacrylate) (PMMA) is one of the promising representive of polymer gate dielectric for its high resistivity and sutible dielectric constant. PMMA (Mw=96700) films were prepared on p-Si by spin coating method. PMMA were coated compactively and flatly as observes by AFM. MIS(Al/PMMA/p-Si) structure was made and capacitance-voltage (C-V) and current-voltage (I-V) measurements were done with PMMA films for repeated annealing cycles at $100^{\circ}C$. 1-V measured at various delay times $(0{\sim}20sec)$ showed little change and the absence of hysteresis in the I-V characteristics with delay times, which eliminate the possibility of deep traps in the PMMA films. The observed thermal stability, smooth surfaces, dielectric constant, I-V behavior implies PMMA formed by spin coating can be used as an efficient gate dielectric layer in OTFTs.

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