• 제목/요약/키워드: hydrophilic barrier

검색결과 41건 처리시간 0.032초

Effects of Hydrophilic Surface Treatment on SUS Substrates by Using Dielectric Barrier Discharge

  • Joa, Sang-Beom;Kang, In-Je;Yang, Jong-Keun;Lee, Heon-Ju
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.458-458
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    • 2012
  • Fuel Cell is used stacking metal or polymer substrate. This hydro property of substrate surface is very important. Usually, surface property is hydrophilic. The surface oxidation of SUS is investigated through plasma treatments with an atmospheric-pressure dielectric barrier discharge (DBD) for increasing hydrophilic property. The plasma process makes an experiment under various operating conditions of the DBD, which operating conditions are treatment time, plasma gas mixture ratio, the plasma source supply frequency. Two kinds of SUS substrate, SUS-304 and SUS 316L, were used. Discharge frequency has a crucial impact on equipment performance and gas treatment. After the plasma treatment of a SUS plate, highly improved wettability was noted. But, when high oxygen supply, the substrate damaged seriously.

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오염물질 확산방지를 위한 토목섬유 연직차수벽 연결부의 투수성능 평가 (Permeability Characteristics of Geosynthetics Vertical Barrier Connections for the Prevention of Contaminants Diffusion)

  • 박정준
    • 한국재난정보학회 논문집
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    • 제18권1호
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    • pp.1-9
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    • 2022
  • 연구목적: 본 연구에서는 토목섬유 연직차수시스템에 사용되는 팽창 지수재를 사용하여 지수재의 팽창에 따른 차수성능을 평가하였다. 연구방법: 토목섬유 연직차수 공법 적용시 연결부에 대한 투수능을 판단하기 위하여 ASTM D5887과 ASTM D6766을 준용하였다. 팽창 지수재를 각 용액에 포화시킨 후 시간경과에 따른 무게, 두께, 부피 변화를 분석하였으며, 토목섬유 연직차수벽 연결부에 팽창지수재를 설치하여 투수 특성을 평가하였다. 연구결과: 염수조건에서 지수재의 팽창반응 시간이 상대적으로 늘어남에 따라 투수능의 저하도 담수에서 보다 작은 감소폭을 나타내었다. 또한 토목섬유 연직차수재료의 결속 방법에 따라 롤 이음방식이 인터록 방식 보다 수두차에 의한 압력저항이 커서 차수성능이 다소 우수하게 나타났다. 결론: 주유소, 유류저장시설 및 산업단지 등 오염물의 유출을 추정할 수 있는 도심지 오염원에서는 오염물질 확산을 방지할 수 있는 사전대응 기술이 피해규모를 현격하게 감소시킬 수 있다.

Semi-Permanent Hydrophilization of Polyester Textile by Polymerization and Oxidation Using Atmospheric Pressure Dielectric Barrier Discharge (APDBD)

  • Se Hoon Shin;Yoon Kee Kim
    • 한국재료학회지
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    • 제33권4호
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    • pp.115-123
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    • 2023
  • In this paper, we report and discuss the semi-permanently hydrophilic (SPH) treatment of polyester fabric using plasma polymerization and oxidation based on atmospheric pressure dielectric barrier discharge (APDBD) technology. SiOxCy(-H) was coated on polyester fabric using Hexamethylcyclotrisiloxane (HMCTSO) as a precursor, and then plasma oxidation was performed to change the upper layer of the thin film to SiO2-like. The degradation of hydrophilicity of the SPH polyester fabrics was evaluated by water contact angle (WCA) and wicking time after repeated washing. The surface morphology of the coated yarns was observed with scanning electron microscopy, and the presence of the coating layer was confirmed by measuring the Si peak using energy dispersive x-ray spectroscopy. The WCA of the SPH polyester fabric increased to 50 degrees after 30 washes, but it was still hydrophilic compared to the untreated fabric. The decrease in hydrophilicity of the SPH fabric was due to peeling of the SiOxCy(-H) thin film coated on polyester yarns.

대기압 RF DBD 방전으로 개질된 폴리이미드의 표면특성 (Surface Properties of Polyimide Modified with He/O2/NF3 Atmospheric Pressure RF Dielectric Barrier Discharge)

  • 이수빈;김윤기;김정순
    • 한국재료학회지
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    • 제16권9호
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    • pp.543-549
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    • 2006
  • Polyimides (PI) are treated with $He/O_2$ and $He/O_2/NF_3$ atmospheric pressure rf dielectric barrier discharge in order to investigate the roles of $NF_3$ that is one of the PI etching gases. Surface changes are analyzed by x-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), and contact angle measurement. The surface roughness of PI and the ratio of C=O, which is hydrophilic functional group, is more increased by $He/O_2/NF_3$ discharge than by $He/O_2$ discharge. The C=O species on the PI surface is increased up to 30 percent with rf power. The surface roughness of PI is increased from 0.4 to 11 nm with rf power. The water drop contact angles on PI, however, are reduced from $65^{\circ}\;to\;9^{\circ}$ by plasma treatment independently of $NF_3$.

대기압 저온 플라즈마 처리에 의한 폴리이미드의 친수화 효과 (Hydrophilic Effect of the Polyimide by Atmospheric Low-temperature Plasma Treatment)

  • 조중희;강방권;김경수;최병규;김세훈;최원열
    • 한국전기전자재료학회논문지
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    • 제18권2호
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    • pp.148-152
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    • 2005
  • Atmospheric low-temperature plasma was produced using dielectric barrier discharge (DBD) plate-type plasma reactor and high frequency of 13.56 Hz. The surfaces of polyimide films for insulating and packaging materials were treated by the atmospheric low-temperature plasma. The contact angle of 67$^{\circ}$ was observed before the plasma treatment. The contact angle was decreased with deceasing the velocity of plasma treatment. In case of oxygen content of 0.2 %, electrode gap of 2 mm, the velocity of plasma treatment of 20 mm/sec, and input power of 400 W, the minimum contact angle of 13$^{\circ}$ was observed. The chemical characteristics of polyimide film after the plama treatment were investigated using X-ray photoelectron spectroscopy (XPS), and new carboxyl group bond was observed. The surfaces of polyimide films were changed into hydrophilic by the atmospheric low-temperature plasma. The polyimide films having hydrophilic surface will be very useful as a packaging and insulating materials in electronic devices.

흰쥐에서 삼투개열법에 의한 $^{99m}Tc$-Diethylene Triamine Pentaacetic Acid 및 페니토인의 뇌로의 송달 (Brain Delivery of $^{99m}Tc$-Diethylene Triamine Pentaacetic Acid and Phenytoin by Transient Osmotic Opening Method in Rats)

  • 황만용;박경호;이민화
    • 약학회지
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    • 제42권2호
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    • pp.196-204
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    • 1998
  • The blood-brain barrier (BBB) of rats was modificated opening reversibly by infusing a hyperosmotic solution of arabinose (1.6 molal) into the right external carotid artery. Pre vious studies demonstrated that permeability was increased maxmmally in the first 15 min and remained slightly elevated at 1 hr. As control reference, saline was used. In the present study, to evaluate the effects of osmotic BBB opening on the BBB trasport according to hydrophilic or hydrophobic characteristics of drugs. And the differences of the uptakes of these compounds to right (treated osmotic opening) and left (untreated) hemispheres in same rats were compared each other following injection of 8 mCi per rat of $^{99m}Tc$-ethylene triamine pentaacetic acid (DTPA) as hydrophilic drug or 5mg/kg of phenytoin as hydrophobic drug mto the right external carotid artery of rats between two groups (1.6 molal arabinose vs saline). The uptakes of $^{99m}Tc$-DTPA and phenytoin in the right cerebral hemispheres were increased to about thirty three times and twice rather than those in the left cerebral heimspheres, respectively. And PAs (permeability X capillary surface area) were also increased from a control mean of 2.11${\times}10^{-4}$ (Untreated) to 6.98${\times}10^{-3}\;sec^{-1}$ (treated osmotic opening for $^{99m}Tc$-DTPA and 0.29 to 0.17 $sec^{-1}$ for phenytoin, respectively. From the results of present study, it is noted that osmotic opening of BBB is more effective in the brain delivery of hydrophilic drugs rather than that of hydrophobic drugs.

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대기압 플라즈마 처리에 의한 TAC 필름의 표면에너지 변화 (The Surface Energy Change of TAC Film Treated by an Atmospheric Pressure Plasma)

  • 이창호;정도영;박영직;송현직;이광식
    • 조명전기설비학회논문지
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    • 제23권12호
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    • pp.184-190
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    • 2009
  • 표면의 친수성 작용기 형성과 접촉각 향상을 위하여 대기압 플라즈마를 이용하여 Tri-acetyl-cellulose(TAC) 필름에 대한 표면개질을 연구하였다. TAC 필름의 표면개질 목적으로 대기압에서 플라즈마를 발생시키기 위한 Dielectric barrier discharge(DBD) 구조의 플라즈마 반응기 내에서 이온화된 질소 플라즈마를 사용하였다. 플라즈마 처리 공정변수인 처리속도, 방전전력, 방전 갭 및 질소 가스 유속을 변화시켜가며 접촉각을 측정하여 접촉각과 표면에너지 변화를 검토하였다. 대기압 플라즈마 처리속도 100[mm/sec], 방전 전력 1.5[kW], 방전 갭 2[mm] 및 $N_2$ 가스유량 140[LPM] 에서 가장 높은 접촉각과 표면에너지 값을 보였다. 표면친수화의 정도는 플라즈마 방전 전력과 처리 시간에 의존하였다.

Effect of Clay Type and Concentration on Optical, Tensile and Water Vapor Barrier Properties of Soy Protein Isolate/Clay Nanocomposite Films

  • Rhim, Jong-Whan
    • 한국포장학회지
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    • 제15권3호
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    • pp.99-104
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    • 2009
  • Soy protein isolate (SPI)-based nanocomposite films with three different types of nanoclays, such as Cloisite $Na^+$, Cloisite 20A, and Cloisite 30B, were prepared using a solution casting method, and their optical, tensile, and water vapor barrier properties were determined to investigate the effect of nano-clay type on film properties. Among the tested nanoclays, Cloisite $Na^+$, a hydrophilic montmorillonite (MMT), exhibited the highest transparency with least opaqueness, the highest tensile strength, and the highest water vapor barrier properties, indicating Cloisite $Na^+$ is the most compatible with SPI polymer matrix to form nanocomposite films. The film properties of SPI/Cloisite $Na^+$ nanocomposite films were strongly dependent on the concentration of the clay. Film properties such as optical, tensile, and water vapor barrier properties improved significantly (p<0.05) as the concentration of clay increased. However, the effectiveness of addition of the clay reduced above a certain level (i.e., 5wt%), indicating that there is an optimum amount of clay addition to exploit the full advantage of nanocmposite films.

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수의학강좌 I: 점안 안약의 전달 (Ocular Drug Delivery)

  • 최희연
    • 대한수의사회지
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    • 제47권1호
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    • pp.42-46
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    • 2011
  • 임상에 있어 눈에 적용하는 약물의 적용은 정상적인 조직을 손상시키지 않으면서 원하는 안구 조직에 목표로 하는 용량의 안약을 전달하는 것이 목적이라고 할 수 있다. 그러나 이러한 간단한 목적도 실제로 환자의 성격, 안구 조직의 민감성, 그리고 친지질성 각막 외피세포(lipophilic corneal epithelium), 친수성 각막 그리고 공막의 간질층(hydrophilic corneal and sclera stroma), 결막의 임파 조직, 맥락막의 혈관 등, Blood-ocular barrier등 안구의 조직 자체의 장벽들로 인해 어려움을 내포하고 있는 것 역시 사실이다. 평소에 처방하고 있는 안약들을 조금 더 효과적으로 전달하기 위해 필요한 눈에 대한 이해에 대해 다루어 보도록 한다.

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Transfersomes-mediated gene transfer into organs in mice by direct application on intact skin

  • Lee, Eun;Kim, Adele;Kim, Chong-Kook
    • 대한약학회:학술대회논문집
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    • 대한약학회 2002년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.2
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    • pp.416.2-416.2
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    • 2002
  • Transfersomes are highly detormable hydrophilic lipid vesicles that are able to penetrate the skin barrier so that they can be used to carry low- and high-molecular weight molecules into the body. Until recently. it has been reported that molecules such as insulin. interleukin-2 and several other large molecules have been transported into the body using Transfersomes as a delivery system. Here however, for the very first time, genes (GFP) have been transported into the mice non-invasively using the Transtersomes as a delivery vehicle. (omitted)

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