• Journal of the Korea Institute of Military Science and Technology
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• v.27 no.1
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• pp.8-14
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• 2024

In this study, the scale of renewable photovoltaic(PV) panels and hydrogen fuel storage facilities required to achieve "net zero carbon emissions" in military facilities were predicted based on actual electricity consumption. It was set up to expect the appropriate installation size of PV panel and hydrogen fuel storage facility for achieving carbon neutrality, limited to the electricity consumption in the public sector, including national defense and social security administration in Yeongcheon. The experimental results of this paper are largely composed of two parts. First, representative meteorological factors were considered to predict solar power generation in the Yeongcheon area, and solar power generation was estimated through a multiple regression model using deep learning techniques. Second, the size of solar power generation facilities and hydrogen storage facilities in military bases was estimated with the amount of solar power generation and electricity consumption. As a result of this analysis, it was calculated that a site of 155.76×104 m² for PV panels was needed and a facility capable of storing 27,657 kg of hydrogen gas was required. Through these results, it is meaningful to demonstrated the prospect that military units can lead the achievement of "carbon net zero 2050" by using PV panels and hydrogen fuel storage facilities on idle sites of military bases.

• Journal of the Korea Organic Resources Recycling Association
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• v.19 no.2
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• pp.22-27
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• 2011

This study was performed to find out the optimum condition for hydrogen production by changing mixture ratio from 3:7(food waste water : swine wastewater) without pre-treatment of food wastewater and swine wastewater using a continuous reaction process. It was confirmed that hydrogen generation according to pH is the highest in a condition of pH 5.5, and that the optimum pH for hydrogen production in case of mixing food wastewater with swine wastewater is 5.5 through this. Hydrogen generation according to HRT showed high hydrogen generation rate in case of 4 days rather than 3 days, and this involves largely in vitality of hydrogen producing bacteria according to variation of the HRT value, so it is judged that HRT also acts as an important factor to hydrogen producing bacteria. The organic removal efficiency recorded a removal efficiency of maximum TS 52%, VS 71%, TSS 83% and VSS 89% at the 6th day of operation, and it was confirmed that organic removal efficiency is possible even through an hydrogen production process.

• Journal of the Korean Electrochemical Society
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• v.14 no.4
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• pp.191-195
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• 2011

Wet chemical etching methods were utilized to conduct Si surface texturing, which could enhance photoelectrochemical hydrogen generation rate. Two different etching methods tested, which were anisotropic metal-catalyzed electroless etching and isotropic etching. The Si nano-texture that was fabricated by the anisotropic etching showed ~25% increase in photocurrent for H2 generation. The photocurrent enhancement was attributed to the reduced reflection loss at the nano-textured Si surface, which provided a layer of intermediate density between water and the Si substrate.

• Journal of Energy Engineering
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• v.5 no.2
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• pp.198-202
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• 1996

Reactive metals like aluminum generate hydrogen gas when it reacts with water. Aluminum, despite its high chemical affinity with water, cannot continue the reaction due to the passive oxide layers formed on its surface. When the reaction is assisted by electrical energy dissipation in the form of discharge, the reaction is more likely to be sustained. In this report, some preliminary experimental results are presented regarding the hydrogen generation based on this scheme.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2007.06a
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• pp.733-734
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• 2007

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.2850-2855
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• 2008

Very High Temperature Reactor (VHTR) has been selected as a high energy heat source for a nuclear hydrogen generation. The VHTR heat is transferred to a thermo-chemical hydrogen production process through an intermediate loop. Both Process Heat Exchanger and sulfuric acid evaporator provide the coupled components between the VHTR intermediate loop and hydrogen production module. A small scaled Compact Nuclear Hydrogen Coupled Components test loop is developed to simulate the VHTR intermediate loop and hydrogen production module. Main objective of the loop is to screening the candidates of NHDD (Nuclear Hydrogen Development and Demonstration) coupled components. The operating condition of the gas loop is a temperature up to $950^{\circ}C$ and a pressure up to 6.0MPa. The thermal and fluid dynamic design of the loop is dependent on the structures that enclose the gas flow, especially primary side that has fast gas velocity. We designed and constructed a small scale sulfuric acid experimental system which can simulate a part of the hydrogen production module also.

• Nuclear Engineering and Technology
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• v.55 no.1
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• pp.156-168
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• 2023

This study investigates the high temperature oxidation behaviour of a Ni-20Cr-1.2Si (wt.%) alloy in steam from 1200 ℃ to 1350 ℃ by Thermogravimetric Analysis (TGA), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDS) and X-ray Diffraction (XRD). The results demonstrate that exposed Ni-based alloy developed a thin oxide scale, consisted mainly of Cr₂O₃. The oxidation kinetics obtained from the experimental results was applied to evaluate the hydrogen generation considering a simplified reactor core model with different cladding alloys following an unmitigated Loss-Of-Coolant Accident (LOCA) scenario in a hypothetical Small Modular Reactor (SMR). Overall, experimental data and simulations results show that both Fe-based and Ni-based alloys may enhance cladding survivability, delaying its melting, as well as reducing hydrogen generation under accident conditions compared to Zr-based alloys. However, a substantial neutron absorption occurs when Ni-based alloys are used as cladding for current uranium-dioxide fuel systems, even when compared to Fe-based alloys.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.7
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• pp.3261-3266
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• 2012

Sodium borohydride($NaBH_4$) known as the material of hydrogen generation and storage can produce the hydrogen via catalytic hydrolysis. This protide chemical could be used in the hydrogen supply system for residential and mobile fuel cells, and thus many researches and developments regarding to these chemicals and decomposition reactions have been implemented. We experimented the hydrolysis of $NaBH_4$ alkaline solution by metal oxide-supported PGM(platinum group metal) catalysts and measured the generation rate of hydrogen which is product of decomposition reaction. We compared oxides as catalyst supports, and the precious metals, Pt and Ru for the catalysts and studied the effects of amounts of catalyst added and $NaBH_4$ concentrations on the hydrogen generation rates and patterns.

• Journal of Korean Society for Atmospheric Environment
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• v.31 no.2
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• pp.173-180
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• 2015

The purpose of this study was to fabricate a ferric nitrate impregnated activated carbon, and the performance for hydrogen sulfide by adsorption was evaluated. Sodium hydroxide was utilized to control pH in the process during generation of ferric hydroxide on the surface of the carbon. Critical mixing duration for generation of ferric hydroxide on the carbon was 48 hrs at pH 1 of the solution, in which the chemical adsorption of hydrogen sulfide was enhanced. The adsorption capacity of the impregnated carbon increased up to 0.10 g hydrogen sulfide/g carbon, which was 4.3 times higher than that of the raw carbon. Presence of FeOOH on the surface of the impregnated carbon was examined by X-ray diffraction.

• Journal of Energy Engineering
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• v.13 no.1
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• pp.1-11
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• 2004

Gasification is the essential technology that can meet the interim hydrogen demand of large quantity before entering the hydrogen economy. Although the hydrogen production that is based upon the pure renewable energy like wind and solar power will eventually prevail, the interim mass production of hydrogen for the next ten to twenty years will come from the technologies that can demonstrate the economic feasibility in production cost with a high potential in minimizing CO$_2$ generation and in improving plant efficiency. Particularly, feedstock such as natural gas, coal, petroleum residual oil, wastes, and biomass appears to be utilized in Korea as hydrogen source, at least during the short and medium period of time, owing to the advantage in production cost. Because one of the main reasons behind the recent hydrogen issue is the reduction requirement of CO$_2$ that would be controlled according to the climate change protocol, hydrogen production technologies must be developed to yield the minimal CO$_2$ generation.