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http://dx.doi.org/10.5762/KAIS.2012.13.7.3261

Catalytic Hydrolysis of Sodium Borohydride on LiCoO3 - Supported Pt, Ru Catalysts  

Ahn, Jong-Gwan (Dept. of Resource Recyling Eng., Joongwon University)
Choi, Seung-Hoon (Dept. of Envrion. & Chem. Eng., Seonam University)
Lee, Su-Chol (SeAH M&S Corp.)
Publication Information
Journal of the Korea Academia-Industrial cooperation Society / v.13, no.7, 2012 , pp. 3261-3266 More about this Journal
Abstract
Sodium borohydride($NaBH_4$) known as the material of hydrogen generation and storage can produce the hydrogen via catalytic hydrolysis. This protide chemical could be used in the hydrogen supply system for residential and mobile fuel cells, and thus many researches and developments regarding to these chemicals and decomposition reactions have been implemented. We experimented the hydrolysis of $NaBH_4$ alkaline solution by metal oxide-supported PGM(platinum group metal) catalysts and measured the generation rate of hydrogen which is product of decomposition reaction. We compared oxides as catalyst supports, and the precious metals, Pt and Ru for the catalysts and studied the effects of amounts of catalyst added and $NaBH_4$ concentrations on the hydrogen generation rates and patterns.
Keywords
Sodium borohydride; Hydrogen generation; Catalysts; Hydrolysis; $LiCoO_3$-supported Pt,Ru;
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