• Title/Summary/Keyword: hydrogen evolution

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A Study on Corrosion Failure of a Weathering Steel Weldment with Various Applied Potentials in Acid-chloride Solution (산-염소이온 분위기의 인자전위에 따른 내후성강 용접부의 부식파괴에 관한 연구)

  • 최윤석;김정구;김종집;이병훈
    • Journal of Welding and Joining
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    • v.18 no.3
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    • pp.97-105
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    • 2000
  • The stress corrosion cracking(SCC) and hydrogen embrittlement cracking(HEC) characteristics of a weathering steel weldment were investigated in aerated acid-chloride solution. The electrochemical properties of weldment were investigated by polarization test and galvanic corrosion test. Weathering steel did not show passive behavior in the acid-chloride solution. Galvanic corrosion between the weld metal and the base metal was not observed because the base metal was anodic to the weld metal. The slow-strain-rate tests(SSRT0 were conducted at a constant strain rate o 7.87×{TEX}$10^{-7}${/TEX}/s at corrosion potential, and at potentiostatically controlled anodic and cathodic potentials. The weldment of weathering steel was susceptible to both anodic dissolution SCC and hydrogen evolution HEC.

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Fabrication of Metal-Semiconductor Interface in Porous Silicon and Its Photoelectrochemical Hydrogen Production

  • Oh, Il-Whan;Kye, Joo-Hong;Hwang, Seong-Pil
    • Bulletin of the Korean Chemical Society
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    • v.32 no.12
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    • pp.4392-4396
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    • 2011
  • Porous silicon with a complex network of nanopores is utilized for photoelectrochemical energy conversion. A novel electroless Pt deposition onto porous silicon is investigated in the context of photoelectrochemical hydrogen generation. The electroless Pt deposition is shown to improve the characteristics of the PS photoelectrode toward photoelectrochemical $H^+$ reduction, though excessive Pt deposition leads to decrease of photocurrent. Furthermore, it is found that a thin layer (< 10 ${\mu}m$) of porous silicon can serve as anti-reflection layer for the underlying Si substrate, improving photocurrent by reducing photon reflection at the Si/liquid interface. However, as the thickness of the porous silicon increases, the surface recombination on the dramatically increased interface area of the porous silicon begins to dominate, diminishing the photocurrent.

Characterization of a Hydrogen evolving strain of Rhodopseudomonas sphaeroides (수소생성 Rhodopseudomonas sphaeroides의 특성)

  • 이혜주
    • Korean Journal of Microbiology
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    • v.24 no.1
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    • pp.62-66
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    • 1986
  • Many photosynthetic bacteria capable of hydrogen production were isolated from samples of mud flats of paddy field collected in Kim Hae and Dae Jeo. A strain 230 was selected for the high capability of hydrogen evolution. As the results of examination in physiological, morghological and cultural characteristics, the strain 230 was identified as Rhodopseudomonas sphaeroides.

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A Study on the RuO2 Electrode Catalyst Prepared by Colloidal Method (콜로이드법으로 합성한 RuO2 전극촉매의 연구)

  • PARK, JIN-NAM
    • Journal of Hydrogen and New Energy
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    • v.30 no.3
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    • pp.193-200
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    • 2019
  • $RuO_2$, $PtO_2$, and various $(Ru,Pt)O_2$ colloidal solution were prepared using modified Watanabe method. Electrodes were manufactured by dipping of Ni mesh into the colloidal solution. Manufactured electrodes were characterized by XRD, SEM, and EDS. $(Ru,Pt)O_2$ electrodes showed $RuO_2$ crystal structure and high roughness. The hydrogen evolution reaction (HER) activities were evaluated by Linear Sweep Voltammetry. 1Ru2Pt electrode showed similar activity with commercial electrode, HER potentials are -0.9 V for both.

THE CLASSIFICATION AND PHYSICS OF SUPERNOVAE

  • Wheeler, J. Craig
    • Publications of The Korean Astronomical Society
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    • v.8 no.1
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    • pp.169-177
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    • 1993
  • Observed spectra of supernovae allow the empirical classification of supernovae into two basic categories, Type I with little or no evidence of hydrogen, and Type II with obvious evidence for hydrogen. The broad class of Type I can be subdivided depending on whether helium or silicon and other intermediate mass elements is observed. Understanding the physical processes that underlie these classifications---the progenitor evolution. the explosion mechanism, and end products---requires calculation of radiative transfer and model spectra. While most Type II occur in evolved massive stars that undergo core collapse. some may span the dividing line between degenerate and non-degenerate carbon burning and involve both core collapse and thermonuclear explosion. Type Ia are still most plausibly explained as thermonuclear explosions in carbon/oxygen white dwarfs in binary systems. Type Ib reveal helium atmospheres and are probably the result of core collapse in the helium core of a massive star that has lost its hydrogen envelope to a binary companion or to a wind. Type Ic supernovae are probably related to Type Ib but have also lost their helium envelope to reveal a mantle rich in oxygen.

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Study on the global distribution of far-ultraviolet emission in our Galaxy

  • Jo, Young-Soo;Seon, Kwang-Il;Min, Kyoung-Wook;Edelstein, Jerry
    • The Bulletin of The Korean Astronomical Society
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    • v.40 no.2
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    • pp.52.1-52.1
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    • 2015
  • FIMS/SPEAR is a dual-channel far-ultraviolet imaging spectrograph on board the Korean microsatellite STSAT-1, which was launched on 2003 September 27. The primary mission goal of FIMS was to conduct a survey of diffuse far UV emissions in our Galaxy. For this purpose, FIMS completed a survey of about 84% of the sky during its operation of a year and a half. The present study aims to analyze this survey data made in the far UV wavelengths to understand the global evolution of our Galaxy. The far UV wavelength band is known to contain important cooling lines of hot gas: hence, the study will show how the hot gas in our Galaxy, produced by stellar winds and supernova explosion, evolves globally to cool down and become mixed with ambient cooler medium. One of the main findings from previous analyses of the FIMS data is that molecular hydrogen exists ubiquitously in our Galaxy. This discovery leads to another important scientific question: how is molecular hydrogen distributed in our Galaxy and how does it affect globally the evolution of our Galaxy as a cold component? Hence, the present study will cover both the hot and cold components of the ISM, which will also provide the opportunity to investigate the interactions between the two.

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Electrochemical Reduction of Perchlorate Ion on Porous Carbon Electrodes Deposited with Iron Nanoparticles (영가철 나노 입자가 전착된 다공성 탄소전극을 이용한 과염소산 이온의 전기화학적 환원)

  • Rhee, Insook;Kim, Eun Yong;Lee, Bokyoung;Paeng, Ki-Jung
    • Journal of the Korean Electrochemical Society
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    • v.18 no.2
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    • pp.81-85
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    • 2015
  • A method for degradation of the perchlorate anion ($ClO{_4}^-$) has been studied using electrochemically generated zero-valent iron (ZVI) deposited on a porous carbon electrode. The first strategy of this study is to produce the ZVI via the electrochemical reduction of iron (II) on a porous carbon electrode coated with a conducting polymer, instead of employing expensive $NaBH_4$. The present method produced well distributed ZVI on conducting polymer (polypyrrole thin film) and increased surface area. ZVI surface can be regenerated easily for successive reduction. The second strategy is to apply a mild reducing condition (-0.3 V) to enhance the efficiency of the degradation of perchlorate with ZVI without the evolution of hydrogen. The electrochemically generated ZVI nanoparticles may offer an alternative means for the complete destruction perchlorate without evolution of hydrogen in water with high efficiency and at low cost.

Evolution of Crystal Structure by Post-extension in Nylon 56 Fibers (연신에 따른 나일론 56 섬유의 결정 구조 및 수소결합 변화)

  • Jo, Kuk Hyun;Cho, Jung Hyeong;Kim, Hyo Jung;Lee, Hyun Hwi
    • Textile Coloration and Finishing
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    • v.28 no.1
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    • pp.33-39
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    • 2016
  • The crystal structure of nylon 56 fibers post extended by drawing process was investigated by synchrotron x-ray scattering measurement. In as-cast fiber, distinct (004) and (020) diffraction peaks were observed and they were related to initial metastable alignment of nylon molecules. With increase in the drawing ratio, (110) peak intensity was increased in vertical direction with decreasing (020) peak. At the same time, (004)' peak evolved position tilted to 29 degrees from the (004) peak. This evolution is directly related to stable crystalline phase of nylon 56 originated from additional formation of hydrogen bondings between N-H and C=O by post drawing process. We also compared density variation, stress-strain curves of the fiber as a function of drawing ratio and strain. The variations of density and tanacity also supported the increase of stable structure of nylon 56.

Electrochemical Characterization of Electrospun LaCoO3 Perovskite Nanofibers Prepared at Different Temperature for Oxygen Reduction and Evolution in Alkaline Solution (다양한 온도에서 합성한 전기방사 LaCoO3 페롭스카이트 나노섬유의 알칼리용액에서 산소환원 및 발생반응에 대한 전기화학 특성)

  • Lopez, Kareen J.;Sun, Ho-Jung;Park, Gyungse;Eom, Seungwook;Shim, Joongpyo
    • Journal of Hydrogen and New Energy
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    • v.26 no.2
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    • pp.148-155
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    • 2015
  • Electrospun $LaCoO_3$ perovskite nanofibers were produced for the air electrode in Zn-air rechargeable batteries using electrospinning technique with sequential calcination. The final calcination temperature was varied from 500 to $800^{\circ}C$ in order to determine its effect on the physical and electrochemical properties of the prepared $LaCoO_3$ perovskite nanofibers. The surface area of the electrospun $LaCoO_3$ perovskite nanofibers were observed to decrease with increasing final calcination temperature. Electrospun $LaCoO_3$ perovskite nanofibers calcined with final calcination temperature of $700^{\circ}C$ had the best electrocatalytic activity among the prepared perovskite nanofibers.

Near-infrared Spectroscopy of Iron Knots in Cassiopeia A Supernova Remnant

  • Lee, Yong-Hyun;Koo, Bon-Chul;Moon, Dae-Sik
    • The Bulletin of The Korean Astronomical Society
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    • v.35 no.2
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    • pp.68.1-68.1
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    • 2010
  • Cassiopeia A supernova remnant is a young (~330 yr) remnant of Type IIb SN explosion with a massive progenitor. It shows two distinct optical knots; fast moving ejecta knots (FMKs) and quasi stationary circumstellar knots (QSFs). These knots offer an unique opportunity to explore the details of the explosion and also the end state evolution of the Type IIb SN progenitor. We have obtained NIR long-slit (30") spectra of 7 positions around the bright rim of Cas A in [Fe II] 1.644 micron using Triplespec which is a cross-dispersed near-infrared spectrograph that provides continuous wavelength coverage from 0.95-2.46um at intermediate resolution of 2700. Most of the FMKs show strong sulfur, silicon, and iron forbidden lines but no hydrogen or helium lines. The QSFs, on the other hand, show a much richer spectrum with strong hydrogen, helium, and iron lines, but no sulfur and silicon lines. We measure their fluxes and radial velocities, and derive their physical parameters such as electron density and temperature. We also measure the proper motion of these knots from two [Fe II] 1.644 micron images obtained at 3-year interval. We analyze the physical properties of these knots and discuss the evolution and explosion of the progenitor of Cas A.

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